journal article·2007-09

Preparation and characterization of blends of recycled polystyrene with cassava starch

Tais A. P. F. Pimentel, Jussara A. Durães, Adriana L. Drummond, Daniela Schlemmer, Rosana Falcão, Maria José Araújo Sales

Journal of Materials Science· Volume 42· Issue 17
Publisher page

Abstract

Secondary recycling is an alternative to solve at least part of the worldwide pollution problem caused by persistence of petrochemical plastic materials in the environment. In this work we report the secondary recycling of disposable polystyrene (PS) using cassava starch (Manihot esculenta Crantz) and a natural plasticizer extracted from a palm tree of the Amazon: Buriti (Mauritia flexuosa L.) oil. 13C-NMR spectroscopy reveals incorporation of the oil in the polymer matrix. Although phase separation had occurred, SEM depicts a very good dispersion of the thermoplastic starch (TPS) in the PS matrix with distinct domains. Thermal analyses indicate smaller thermal stability of the PS/TPS blends compared to PS and that possess intermediate characteristics between the pure PS and TPS, confirmed by DRX. Kinetic study shows a lowering of the activation energy for the thermal degradation of the blends.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: biodegradable polymer synthesis and properties · Nanocomposite Films for Food Packaging · Natural Fiber Reinforced Composites

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (34)

Show source-provided references
1. Aggarwal P (1999) Thermochim Acta 340–341:19510.1016/S0040-6031(99)00264-6 ↗
2. Ali MF, Siddiqui MN (2005) J Anal Appl Pyrolysis 74:28210.1016/j.jaap.2004.12.010 ↗
3. Kim J, Lee W, Lee S, Kim S, Choi M (2003) Catal Today 87:5910.1016/j.cattod.2003.10.004 ↗
4. Zhibo Z, Nishio S, Morioka Y, Ueno A, Ohkita H, Tochihara Y, Mizushima T, Kakuta N (1996) Catal Today 29:30310.1016/0920-5861(95)00296-0 ↗
5. Williams PT, Bagri R (2004) Int J Energy Res 28:3110.1002/er.949 ↗
6. ke H, Li-hua T, Zi-Bin Z, Cheng-Fang Z (2005) Polym Degrad Stab 89:31210.1016/j.polymdegradstab.2005.01.014 ↗
7. Karaduman A, Simsek EH, Cicek B, Bilgesu AY (2002) J Anal Appl Pyrolysis 62:27310.1016/S0165-2370(01)00125-5 ↗
8. Pedroso AG, Rosa DS (2005) Carbohydr Polym 59:110.1016/j.carbpol.2004.08.018 ↗
9. Rodriguez-Gonzalez FJ, Ramsay BA, Favis BD (2003) Polymer 44:151710.1016/S0032-3861(02)00907-2 ↗
10. Thomson DA (1995) Plast Rubber Paper Recycling ACS Symp Ser 609:8910.1021/bk-1995-0609.ch008 ↗
11. Kiatkamjornwong S, Sonsuk M, Wittayapichet S, Prasassarakich P, Vejjanukroh P (1999) Polym Degrad Stab 66:32310.1016/S0141-3910(99)00082-8 ↗
12. Parra DF, Tadini CC, Ponce P, Lugao AB (2004) Carbohydr Polym 58:47510.1016/j.carbpol.2004.08.021 ↗
13. Fran ça LF, Reber G, Meireles MAA, Machado NT, Brunner G (1999) J Supercrit Fluids 14:24710.1016/S0896-8446(98)00122-3 ↗
14. Bernal-Alvarado J, Mansanares AM, da Silva EC, Moreira SGC (2003) Ver Sci Instrum 74:69710.1063/1.1517726 ↗
15. Garcia-Quiroz A, Moreira SGC, de Morais AV, Silva AS, Rocha GN, Alcântara P (2003) Instrum Sci Technol 31:9310.1081/CI-120018411 ↗
16. Albuquerque MLS, Guedes I, Alcântara P, Moreira SGC (2003) Vib Spectrosc 33:12710.1016/S0924-2031(03)00098-5 ↗
17. Albuquerque MLS, Guedes I, Alcântara P, Moreira SGC, Neto NMB, Correa DS, Zílio SC (2005) J Braz Chem Soc 16:111310.1590/S0103-50532005000700004 ↗
18. Lognay G, Trebejo E, Jordan E, Marlier M, Severin M, Ortiz de Záate I (1987) Grasas y Aceites 38:303
19. Durães JA, Drummond AL, Pimentel TAPF, Murta MM, Moreira SGC, Bicalho FS, Sales MJS (2006) Eur Polym J (unpublished)
20. Durães JA, Drummond AL, Pimentel TAPF, Murta MM, Moreira SGC, Sales MJS (2004) Br PI 0403407-4
21. Chrastil J (1987) Carbohydr Res 159:15410.1016/S0008-6215(00)90013-2 ↗
22. Godbole S, Gote S, Latkar M, Chakrabarti T (2003) Bioresour Technol 86:3310.1016/S0960-8524(02)00110-4 ↗
23. Ozawa T (1965) Bull Chem Soc Jpn 38:188110.1246/bcsj.38.1881 ↗
24. Lorcks J (1998) Polym Degrad Stab 59:24510.1016/S0141-3910(97)00168-7 ↗
25. Wu RR, Kao HM, Chaing JC, Woo EM (2002) Polymer 43:17110.1016/S0032-3861(01)00570-5 ↗
26. Jayasekara R, Harding I, Bowater I, Christie GBY, Lonergan GT (2004) Polym Test 23:1710.1016/S0142-9418(03)00049-7 ↗
27. Tester RF, Karkalas J, Qi X (2004) J Cereal Sci 39:15110.1016/j.jcs.2003.12.001 ↗
28. Carvalho AJF, Curvelo AAS, Agnelli JAM (2001) Carbohydr Polym 45:18910.1016/S0144-8617(00)00315-5 ↗
29. Shalaby SW (1981) In: Turi EA (ed) Thermal characterization of polymeric materials. Academic Press Inc., Florida, p 287
30. Rudnik E, Matushek G, Milanov N, Kettrup A (2006) J Thermal Anal Calorimetr 85:26710.1007/s10973-005-7274-7 ↗
31. Ozawa T (1971) Polymer 12:15010.1016/0032-3861(71)90041-3 ↗
32. Chan JH, Balke ST (1997) Polym Degrad Stab 57:13510.1016/S0141-3910(96)00160-7 ↗
33. Leloup LM, Colonna P, Buleon A (1991) J Cereal Sci 13:110.1016/S0733-5210(09)80023-4 ↗
34. Bastioli C (1995) In: Scott G, Gilead D (eds) Degradable polymers. Chapman & Hall, London, p 11210.1007/978-94-011-0571-2_6 ↗