DataVXJournal of Materials SciencePaper
journal article·2026-01

Sustainable pervaporation membranes based on carboxymethyl cellulose modified with metal organic frameworks for water/isopropanol separation

Anna Kuzminova, Mariia Dmitrenko, Anastasia Stepanova, Anna Mikulan, Margarita Puzikova, Artem Selyutin, Elizaveta Mukhanova, Anastasia Penkova

Journal of Materials Science· Volume 61· Issue 1
Publisher page
Bibliographic record

Abstract

No abstract is available for this record. The assistant can identify its topic from the title, but cannot infer the study’s results.

Source: Not provided · Quality: missing

Research context

OpenAlex topics: Membrane Separation and Gas Transport · Membrane Separation Technologies · Metal-Organic Frameworks: Synthesis and Applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (65)

Show source-provided references
1. Yang G, Xie Z, Cran M et al (2019) Enhanced desalination performance of poly (vinyl alcohol)/carbon nanotube composite pervaporation membranes via interfacial engineering. J Membr Sci 579:40–51. https://doi.org/10.1016/j.memsci.2019.02.03410.1016/j.memsci.2019.02.034 ↗
2. Yin J, Zhang C, Ding S et al (2025) The strategies to improve the interfacial compatibility in mixed-matrix membranes: a review. Mater Today Energy 49:101811. https://doi.org/10.1016/j.mtener.2025.10181110.1016/j.mtener.2025.101811 ↗
3. Jia Z, Wu G (2016) Metal-organic frameworks based mixed matrix membranes for pervaporation. Microporous Mesoporous Mater 235:151–159. https://doi.org/10.1016/j.micromeso.2016.08.00810.1016/j.micromeso.2016.08.008 ↗
4. Zhang H, Xiao F, Wu Y (2024) Fluorinated Metal–Organic Framework–Polymer Mixed Matrix Membrane with Tunable Hydrophobic Channel for Efficient Pervaporation of Butanol/Water. Small Struct 5:. https://doi.org/10.1002/sstr.20230033310.1002/sstr.202300333 ↗
5. Liu R, Sui Y, Wang X (2019) Metal–organic framework-based ultrafiltration membrane separation with capacitive-type for enhanced phosphate removal. Chem Eng J 371:903–913. https://doi.org/10.1016/j.cej.2019.04.13610.1016/j.cej.2019.04.136 ↗
6. Al-Shaeli M, Smith SJD, Jiang S et al (2021) Long-term stable metal organic framework (MOF) based mixed matrix membranes for ultrafiltration. J Membr Sci 635:119339. https://doi.org/10.1016/j.memsci.2021.11933910.1016/j.memsci.2021.119339 ↗
7. Vatanpour V, Ardic R, Esenli B et al (2024) Defected Ag/Cu-MOF as a modifier of polyethersulfone membranes for enhancing permeability, antifouling properties and heavy metal and dye pollutant removal. Sep Purif Technol 345:127336. https://doi.org/10.1016/j.seppur.2024.12733610.1016/j.seppur.2024.127336 ↗
8. Li S, Liu Y, Wong DA, Yang J (2021) Recent advances in polymer-inorganic mixed matrix membranes for CO2 separation. Polymers (Basel) 13:2539. https://doi.org/10.3390/polym1315253910.3390/polym13152539 ↗
9. Tanh Jeazet HB, Staudt C, Janiak C (2012) Metal-organic frameworks in mixed-matrix membranes for gas separation. Dalt Trans 41:14003–14027. https://doi.org/10.1039/c2dt31550e10.1039/c2dt31550e ↗
10. Daglar H, Aydin S, Keskin S (2022) MOF-based MMMs breaking the upper bounds of polymers for a large variety of gas separations. Sep Purif Technol 281:119811. https://doi.org/10.1016/j.seppur.2021.11981110.1016/j.seppur.2021.119811 ↗
11. Vatanpour V, Yuksekdag A, Ağtaş M et al (2023) Zeolitic imidazolate framework (ZIF-8) modified cellulose acetate NF membranes for potential water treatment application. Carbohydr Polym 299:120230. https://doi.org/10.1016/j.carbpol.2022.12023010.1016/j.carbpol.2022.120230 ↗
12. Yao A, Hua D, Zhao F et al (2022) Integration of P84 and porphyrin–based 2D MOFs (M−TCPP, M = Zn, Cu, Co, Ni) for mixed matrix membranes towards enhanced performance in organic solvent nanofiltration. Sep Purif Technol 282:120022. https://doi.org/10.1016/j.seppur.2021.12002210.1016/j.seppur.2021.120022 ↗
13. Rowsell JLC, Yaghi OM (2004) Metal–organic frameworks: a new class of porous materials. Microporous Mesoporous Mater 73:3–14. https://doi.org/10.1016/j.micromeso.2004.03.03410.1016/j.micromeso.2004.03.034 ↗
14. Chui SS-Y, Lo SM-F, Charmant JPH, et al (1999) A Chemically Functionalizable Nanoporous Material [Cu 3 (TMA) 2 (H 2 O) 3 ] n. Science (80- ) 283:1148–1150. https://doi.org/10.1126/science.283.5405.114810.1126/science.283.5405.1148 ↗
15. Echarri I, Casado-Coterillo C, Rumayor M et al (2023) Environmental impact improvement of chitosan‐based mixed‐matrix membranes manufacture for CO 2 gas separation by life cycle assessment. Chem Eng Technol 46:2184–2191. https://doi.org/10.1002/ceat.20220039710.1002/ceat.202200397 ↗
16. Huang Y-H, Huang S-H, Gallardo MR et al (2024) Metal-organic framework integrated surface-engineered polyelectrolyte membranes enhancing tetrahydrofuran dehydration. J Taiwan Inst Chem Eng 162:105581. https://doi.org/10.1016/j.jtice.2024.10558110.1016/j.jtice.2024.105581 ↗
17. Sorribas S, Kudasheva A, Almendro E et al (2015) Pervaporation and membrane reactor performance of polyimide based mixed matrix membranes containing MOF HKUST-1. Chem Eng Sci 124:37–44. https://doi.org/10.1016/j.ces.2014.07.04610.1016/j.ces.2014.07.046 ↗
18. Dubovenko R, Dmitrenko M, Mikulan A et al (2025) Thin-film composite polyamide membranes modified with HKUST-1 for water treatment: characterization and nanofiltration performance. Polymers 17:1137. https://doi.org/10.3390/polym1709113710.3390/polym17091137 ↗
19. Zhang F, Dou J, Zhang H (2018) Mixed membranes comprising carboxymethyl cellulose (as capping agent and gas barrier matrix) and nanoporous ZIF-L nanosheets for gas separation applications. Polymers (Basel) 10:1340. https://doi.org/10.3390/polym1012134010.3390/polym10121340 ↗
20. Rahman MS, Hasan MS, Nitai AS et al (2021) Recent developments of carboxymethyl cellulose. Polymers 13:1345. https://doi.org/10.3390/polym1308134510.3390/polym13081345 ↗
21. Kalahal PB, Sajjan AM, Yunus Khan TM et al (2022) Novel polyelectrolyte complex membranes containing carboxymethyl cellulose–gelatin for pervaporation dehydration of azeotropic bioethanol for biofuel. Polymers 14:5114. https://doi.org/10.3390/polym1423511410.3390/polym14235114 ↗
22. Jo S, Chaudhari S, Shin H et al (2023) Strategies to overcome the limitations of cross-linked hydrophilic PVA membranes; carboxy methyl cellulose blending for epichlorohydrin-isopropanol-water pervaporation dehydration. J Water Process Eng 55:104101. https://doi.org/10.1016/j.jwpe.2023.10410110.1016/j.jwpe.2023.104101 ↗
23. Araújo T, Parnell AJ, Bernardo G, Mendes A (2023) Cellulose-based carbon membranes for gas separations - unraveling structural parameters and surface chemistry for superior separation performance. Carbon N Y 204:398–410. https://doi.org/10.1016/j.carbon.2022.12.06210.1016/j.carbon.2022.12.062 ↗
24. Gasemloo S, Khosravi M, Sohrabi MR et al (2019) Response surface methodology (RSM) modeling to improve removal of Cr (VI) ions from tannery wastewater using sulfated carboxymethyl cellulose nanofilter. J Clean Prod 208:736–742. https://doi.org/10.1016/j.jclepro.2018.10.17710.1016/j.jclepro.2018.10.177 ↗
25. Burts K, Plisko T, Dmitrenko M et al (2022) Novel thin film nanocomposite membranes based on chitosan succinate modified with Fe-BTC for enhanced pervaporation dehydration of isopropanol. Membranes 12:653. https://doi.org/10.3390/membranes1207065310.3390/membranes12070653 ↗
26. Wang C, Park MJ, Yu H et al (2022) Recent advances of nanocomposite membranes using layer-by-layer assembly. J Membr Sci 661:120926. https://doi.org/10.1016/j.memsci.2022.12092610.1016/j.memsci.2022.120926 ↗
27. Dmitrenko M, Kuzminova A, Zolotarev A et al (2023) Nanofiltration mixed matrix membranes from cellulose modified with Zn-based metal–organic frameworks for the enhanced water treatment from heavy metal ions. Polymers 15:1341. https://doi.org/10.3390/polym1506134110.3390/polym15061341 ↗
28. Kochan J, Wintgens T, Wong JE, Melin T (2010) Properties of polyethersulfone ultrafiltration membranes modified by polyelectrolytes. Desalination 250:1008–1010. https://doi.org/10.1016/j.desal.2009.09.09210.1016/j.desal.2009.09.092 ↗
29. Wang Q, Lu T-D, Yan X-Y et al (2020) Designing nanofiltration hollow fiber membranes based on dynamic deposition technology. J Membr Sci 610:118336. https://doi.org/10.1016/j.memsci.2020.11833610.1016/j.memsci.2020.118336 ↗
30. Anantharaman A, Chun Y, Hua T et al (2020) Pre-deposited dynamic membrane filtration – a review. Water Res 173:115558. https://doi.org/10.1016/j.watres.2020.11555810.1016/j.watres.2020.115558 ↗
31. Gallardo MR, Huang C-H, Huang H et al (2025) High-flux thin-film nanocomposite membrane enabled by ZIF-8–sulfobetaine–dopamine nanoparticles for pervaporation. J Membr Sci 734:124443. https://doi.org/10.1016/j.memsci.2025.12444310.1016/j.memsci.2025.124443 ↗
32. Dmitrenko M, Mikhailovskaya O, Kuzminova A et al (2025) Membranes from carboxymethyl cellulose/carboxylated graphene oxide for sustainable water treatment by pervaporation and nanofiltration. Molecules 30:3751. https://doi.org/10.3390/molecules3018375110.3390/molecules30183751 ↗
33. Chavan SG, Premakshi HG, Kariduraganavar MY (2025) Effect of incorporation of nanofillers to the tetraethylorthosilicate (TEOS) crosslinked poly(vinyl alcohol) (PVA) membranes for pervaporation dehydration of isopropanol. J Polym Res 32:272. https://doi.org/10.1007/s10965-025-04463-410.1007/s10965-025-04463-4 ↗
34. Polyakov V, Dmitrenko M, Kalmakhelidze M et al (2024) Development and characterization of PVA membranes modified with In(BTC) metal-organic framework for sustainable pervaporation separation of isopropanol/water. Sustainability 16:10257. https://doi.org/10.3390/su16231025710.3390/su162310257 ↗
35. Chavan SG, Achari DD, Munavalli BB et al (2024) Development of sulfonated graphite oxide incorporated poly(styrene sulfonic acid-co-malic acid) crosslinked sodium alginate membranes for pervaporation dehydration of isopropanol. Polym Eng Sci 64:4653–4666. https://doi.org/10.1002/pen.2687110.1002/pen.26871 ↗
36. Huang Z, Ru X, Zhu Y-T et al (2019) Poly(vinyl alcohol)/ZSM-5 zeolite mixed matrix membranes for pervaporation dehydration of isopropanol/water solution through response surface methodology. Chem Eng Res Des 144:19–34. https://doi.org/10.1016/j.cherd.2019.01.02610.1016/j.cherd.2019.01.026 ↗
37. Jose T, George SC, Thomas S (2018) Tunable physicochemical properties of PVA nanocomposite membranes for enhanced pervaporation performance. Polym Eng Sci 58:849–858. https://doi.org/10.1002/pen.2463710.1002/pen.24637 ↗
38. Swapna VP, Jose T, George SC, et al (2019) Pervaporation separation of an azeotropic mixture of a tetrahydrofuran–water system with nanostructured polyhedral oligomeric silsesquioxane embedded poly(vinyl alcohol). J Appl Polym Sci 136:. https://doi.org/10.1002/app.4706010.1002/app.47060 ↗
39. Abraham J, Jose T, Moni G et al (2019) Ionic liquid modified multiwalled carbon nanotube embedded styrene butadiene rubber membranes for the selective removal of toluene from toluene/methanol mixture via pervaporation. J Taiwan Inst Chem Eng 95:594–601. https://doi.org/10.1016/j.jtice.2018.09.01910.1016/j.jtice.2018.09.019 ↗
40. Zhang Y, Yu C, Lü Z, Yu S (2016) Modification of polysulfone ultrafiltration membrane by sequential deposition of cross-linked poly(vinyl alcohol) (PVA) and sodium carboxymethyl cellulose (CMCNa) for nanofiltration. Desalin Water Treat 57:17658–17669. https://doi.org/10.1080/19443994.2015.108734310.1080/19443994.2015.1087343 ↗
41. Baker RW (2000) Membrane technology and applications. McGraw-Hill, N.Y.
42. Baker RW, Wijmans JG, Huang Y (2010) Permeability, permeance and selectivity: a preferred way of reporting pervaporation performance data. J Memb Sci 348:346–352. https://doi.org/10.1016/j.memsci.2009.11.02210.1016/j.memsci.2009.11.022 ↗
43. Yang J, Tong L, Alsubaie AS et al (2022) Hybrid proton exchange membrane used in fuel cell with amino-functionalized metal–organic framework in sulfonated polyimide to construct efficient ion transport channel. Adv Compos Hybrid Mater 5:834–842. https://doi.org/10.1007/s42114-022-00469-410.1007/s42114-022-00469-4 ↗
44. Zhang Y, Jia H, Wang Q et al (2021) Optimization of a MOF blended with modified polyimide membrane for high-performance gas separation. Membranes (Basel) 12:34. https://doi.org/10.3390/membranes1201003410.3390/membranes12010034 ↗
45. Kuzminova A, Dmitrenko M, Zolotarev A et al (2022) Pervaporation polyvinyl alcohol membranes modified with Zr-based metal organic frameworks for isopropanol dehydration. Membranes 12:908. https://doi.org/10.3390/membranes1210090810.3390/membranes12100908 ↗
46. Kuzminova A, Dmitrenko M, Mazur A et al (2021) Novel pervaporation membranes based on biopolymer sodium alginate modified by FeBTC for isopropanol dehydration. Sustainability 13:6092. https://doi.org/10.3390/su1311609210.3390/su13116092 ↗
47. Deng Y, Dai M, Wu Y et al (2022) High-efficient novel super-wetting HKUST-1 membrane for oil-water separation: development, characterization and performance. J Clean Prod 333:130109. https://doi.org/10.1016/j.jclepro.2021.13010910.1016/j.jclepro.2021.130109 ↗
48. Hidayat S, Ardiaksa P, Riveli N, Rahayu I (2018) Synthesis and characterization of carboxymethyl cellulose (CMC) from salak-fruit seeds as anode binder for lithium-ion battery. J Phys Conf Ser 1080:012017. https://doi.org/10.1088/1742-6596/1080/1/01201710.1088/1742-6596/1080/1/012017 ↗
49. Penkova AV, Kuzminova AI, Dmitrenko ME et al (2021) Novel pervaporation mixed matrix membranes based on polyphenylene isophtalamide modified by metal–organic framework UiO-66(NH2)-EDTA for highly efficient methanol isolation. Sep Purif Technol 263:118370. https://doi.org/10.1016/j.seppur.2021.11837010.1016/j.seppur.2021.118370 ↗
50. Jose T, George SC, G MM et al (2014) Effect of bentonite clay on the mechanical, thermal, and pervaporation performance of the poly(vinyl alcohol) nanocomposite membranes. Ind Eng Chem Res 53:16820–16831. https://doi.org/10.1021/ie502632p10.1021/ie502632p ↗
51. DeCoste JB, Denny MS Jr, Peterson GW et al (2016) Enhanced aging properties of HKUST-1 in hydrophobic mixed-matrix membranes for ammonia adsorption. Chem Sci 7:2711–2716. https://doi.org/10.1039/C5SC04368A10.1039/C5SC04368A ↗
52. Yáñez-S M, Matsuhiro B, Maldonado S et al (2018) Carboxymethylcellulose from bleached organosolv fibers of Eucalyptus nitens: synthesis and physicochemical characterization. Cellulose 25:2901–2914. https://doi.org/10.1007/s10570-018-1766-710.1007/s10570-018-1766-7 ↗
53. Kuzminova A, Dmitrenko M, Dubovenko R et al (2025) Sustainable novel membranes based on carboxymethyl cellulose modified with ZIF-8 for isopropanol/water pervaporation separation. Sustainability 17:3801. https://doi.org/10.3390/su1709380110.3390/su17093801 ↗
54. Hu D, Ren X, Fu H et al (2022) Constructing highly rough skin layer of thin film (nano)composite polyamide membranes to enhance separation performance: a review. J Appl Polym Sci. https://doi.org/10.1002/app.5269210.1002/app.52692 ↗
55. Xu L-H, Lv J, Liu W-M et al (2024) Pearl-necklace-structured hollow MOF filled in membrane for molecular separation. J Memb Sci 712:123244. https://doi.org/10.1016/j.memsci.2024.12324410.1016/j.memsci.2024.123244 ↗
56. Dubovenko R, Kuzminova A, Dmitrenko M et al (2024) Enhanced sodium alginate membranes modified with metal-organic frameworks based on zirconium for energy-efficient isopropanol dehydration by pervaporation. ACS Appl Polym Mater 6:12675–12690. https://doi.org/10.1021/acsapm.4c0222910.1021/acsapm.4c02229 ↗
57. Benzaqui M, Semino R, Carn F et al (2019) Covalent and selective grafting of polyethylene glycol brushes at the surface of ZIF-8 for the processing of membranes for pervaporation. ACS Sustain Chem Eng 7:6629–6639. https://doi.org/10.1021/acssuschemeng.8b0558710.1021/acssuschemeng.8b05587 ↗
58. Fazlifard S, Allahgholi N, Mohammadi T, Bakhtiari O (2017) P84/ZIF-8 mixed matrix membranes for pervaporation dehydration of isopropanol. Desalin Water Treat 77:282–290. https://doi.org/10.5004/dwt.2017.2088610.5004/dwt.2017.20886 ↗
59. Amirilargani M, Sadatnia B (2014) Poly ( vinyl alcohol )/ zeolitic imidazolate frameworks ( ZIF-8) mixed matrix membranes for pervaporation dehydration of isopropanol. J Memb Sci 469:1–10. https://doi.org/10.1016/j.memsci.2014.06.03410.1016/j.memsci.2014.06.034 ↗
60. Shi GM, Yang T, Chung TS (2012) Polybenzimidazole (PBI)/zeolitic imidazolate frameworks (ZIF-8) mixed matrix membranes for pervaporation dehydration of alcohols. J Memb Sci 415:577–586. https://doi.org/10.1016/J.MEMSCI.2012.05.05210.1016/J.MEMSCI.2012.05.052 ↗
61. Dmitrenko ME, Penkova AV, Kuzminova AI et al (2018) Investigation of new modification strategies for PVA membranes to improve their dehydration properties by pervaporation. Appl Surf Sci 450:527–537. https://doi.org/10.1016/j.apsusc.2018.04.16910.1016/j.apsusc.2018.04.169 ↗
62. Kharissova AB, Kharissova OV, Kharisov BI, Méndez YP (2024) Carbon negative footprint materials: a review. Nano-Struct Nano-Objects 37:101100. https://doi.org/10.1016/j.nanoso.2024.10110010.1016/j.nanoso.2024.101100 ↗
63. Do THT, Haaz E, Toth AJ (2025) Model development of isopropanol dehydration from binary and ternary mixtures with pervaporation: Comparison and environmental evaluation of hybrid separation methods. Results Eng 25:104058. https://doi.org/10.1016/j.rineng.2025.10405810.1016/j.rineng.2025.104058 ↗
64. Marino T, Galiano F, Molino A, Figoli A (2019) New frontiers in sustainable membrane preparation: Cyrene™ as green bioderived solvent. J Memb Sci 580:224–234. https://doi.org/10.1016/j.memsci.2019.03.03410.1016/j.memsci.2019.03.034 ↗
65. Gontarek-Castro E, Castro-Muñoz R (2024) How to make membrane distillation greener: a review of environmentally friendly and sustainable aspects. Green Chem 26:164–185. https://doi.org/10.1039/D3GC03377E10.1039/D3GC03377E ↗