Research progress on halogen-free flame retardant epoxy resins
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OpenAlex topics: Flame retardant materials and properties · Fire dynamics and safety research · Polymer composites and self-healing
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References (100+)
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1. Chen R, Luo ZJ, Yu XJ, Tang H, Zhou Y, Zhou H (2020) Synthesis of chitosan-based flame retardant and its fire resistance in epoxy resin. Carbohydr Polym. https://doi.org/10.1016/j.carbpol.2020.11653010.1016/j.carbpol.2020.116530 ↗
2. Wan JT, Zhao JQ, Zhang XW, Fan H, Zhang JH, Hu DD, Jin PJ, Wang DY (2020) Epoxy thermosets and materials derived from bio-based monomeric phenols: transformations and performances. Prog Polym Sci. https://doi.org/10.1016/j.progpolymsci.2020.10128710.1016/j.progpolymsci.2020.101287 ↗
3. Yang XT, Zhu JH, Yang D, Zhang JL, Guo YQ, Zhong X, Kong J, Gu JW (2020) High-efficiency improvement of thermal conductivities for epoxy composites from synthesized liquid crystal epoxy followed by doping BN fillers. Compos Part B Eng. https://doi.org/10.1016/j.compositesb.2020.10778410.1016/j.compositesb.2020.107784 ↗
4. Peng XL, Li ZK, Wang DH, Li ZF, Liu CB, Wang R, Jiang L, Liu QY, Zheng PL (2021) A facile crosslinking strategy endows the traditional additive flame retardant with enormous flame retardancy improvement. Chem Eng J. https://doi.org/10.1016/j.cej.2021.13040410.1016/j.cej.2021.130404 ↗
5. Chen Q, Liu L, Zhang AL, Wang WD, Wang ZZ, Zhang JZ, Feng JB, Huo SQ, Zeng XS, Song PA (2023) An iron phenylphosphinate@graphene oxide nanohybrid enabled flame-retardant, mechanically reinforced, and thermally conductive epoxy nanocomposites. Chem Eng J. https://doi.org/10.1016/j.cej.2022.14042410.1016/j.cej.2022.140424 ↗
6. Naresh K, Shankar K, Rao BS, Velmurugan R (2016) Effect of high strain rate on glass/carbon/hybrid fiber reinforced epoxy laminated composites. Compos Part B-Eng 100:125–135. https://doi.org/10.1016/j.compositesb.2016.06.00710.1016/j.compositesb.2016.06.007 ↗
7. Marx JC, Robbins SJ, Grady ZA, Palmieri FL, Wohl CJ, Rabiei A (2020) Polymer infused composite metal foam as a potential aircraft leading edge material. Appl Surf Sci. https://doi.org/10.1016/j.apsusc.2019.14411410.1016/j.apsusc.2019.144114 ↗
8. Banerjee P, Kumar S, Bose S (2021) Thermoreversible bonds and graphene oxide additives enhance the flexural and interlaminar shear strength of self-healing epoxy/carbon fiber laminates. ACS Appl Nano Mater 4(7):6821–6831. https://doi.org/10.1021/acsanm.1c0088810.1021/acsanm.1c00888 ↗
9. Zhang XY, Gu AJ, Liang GZ, Zhuo DX, Yuan L (2011) Liquid crystalline epoxy resin modified cyanate ester for high performance electronic packaging. J Polym Res 18(6):1441–1450. https://doi.org/10.1007/s10965-010-9549-310.1007/s10965-010-9549-3 ↗
10. Liu JM, Liu XH, Chen BF, Feng ZQ, Qin JJ, Wu MQ, Chen L, Chen X, Liang LY (2022) High-performance naphthalene epoxy resins cured by catalyst for packaging materials. Mater Today Commun. https://doi.org/10.1016/j.mtcomm.2022.10448310.1016/j.mtcomm.2022.104483 ↗
11. Chen C, Li JX, Wang X, Wu K, Cheng CH, Wang C, Fu YW (2022) Transport characteristics of interfacial charge in SiC semiconductor-epoxy resin packaging materials. Front Chem. https://doi.org/10.3389/fchem.2022.87943810.3389/fchem.2022.879438 ↗
12. Jeong H, Jang KS (2022) Catalysis of reduced tin oxide in various epoxy resins. Mater Today Commun 30:10317810.1016/j.mtcomm.2022.103178 ↗
13. Murray RE, Jenne S, Snowberg D, Berry D, Cousins D (2019) Techno-economic analysis of a megawatt-scale thermoplastic resin wind turbine blade. Renew Energy 131:111–119. https://doi.org/10.1016/j.renene.2018.07.03210.1016/j.renene.2018.07.032 ↗
14. Wu ZC, Li CY, Shan R, Zhang J (2024) Synergistic effects for co-pyrolysis of epoxy resin and polyurethane from retired wind turbine blades. Waste Biomass Valoriz 15(3):1603–1614. https://doi.org/10.1007/s12649-023-02263-910.1007/s12649-023-02263-9 ↗
15. Yang SL, Shao LM, Ma JY, Ren SZ, Chen YS (2023) Research on the application of domestic high-modulus carbon fiber/epoxy composites to solar panels for solar arrays. Coatings. https://doi.org/10.3390/coatings1307125910.3390/coatings13071259 ↗
16. Pashabeygi A, Fathalizadeh N, Ahmadi-Kandjani S (2025) Flexible luminescent solar concentrator based on epoxy resin: a simple, cost-effective approach for enhanced energy harvesting. Sol Energy Mater Sol Cells. https://doi.org/10.1016/j.solmat.2025.11342010.1016/j.solmat.2025.113420 ↗
17. Shi XH, Li XL, Li YM, Li Z, Wang DY (2022) Flame-retardant strategy and mechanism of fiber reinforced polymeric composite: a review. Compos Part B Eng. https://doi.org/10.1016/j.compositesb.2022.10966310.1016/j.compositesb.2022.109663 ↗
18. Wang P, Xia L, Jian RK, Ai YF, Zheng XL, Chen GL, Wang JS (2018) Flame-retarding epoxy resin with an efficient P/N/S-containing flame retardant: preparation, thermal stability, and flame retardance. Polym Degrad Stabil 149:69–77. https://doi.org/10.1016/j.polymdegradstab.2018.01.02610.1016/j.polymdegradstab.2018.01.026 ↗
19. Özmen FK, Üreyen ME, Koparal AS (2020) Cleaner production of flame-retardant-glass reinforced epoxy resin composite for aviation and reducing smoke toxicity. J Clean Prod. https://doi.org/10.1016/j.jclepro.2020.12406510.1016/j.jclepro.2020.124065 ↗
20. Sykam K, Hussain SS, Sivanandan S, Narayan R, Basak P (2023) Non-halogenated UV-curable flame retardants for wood coating applications: review. Prog Org Coat. https://doi.org/10.1016/j.porgcoat.2023.10754910.1016/j.porgcoat.2023.107549 ↗
21. Costes L, Laoutid F, Brohez S, Dubois P (2017) Bio-based flame retardants: when nature meets fire protection. Materials Science & Engineering R-Reports 117:1–25. https://doi.org/10.1016/j.mser.2017.04.00110.1016/j.mser.2017.04.001 ↗
22. Salmeia KA, Gaan S (2015) An overview of some recent advances in DOPO-derivatives: chemistry and flame retardant applications. Polym Degrad Stabil 113:119–134. https://doi.org/10.1016/j.polymdegradstab.2014.12.01410.1016/j.polymdegradstab.2014.12.014 ↗
23. Sun S, Yu QL, Yu B, Zhou F (2023) New progress in the application of flame-retardant modified epoxy resins and fire-retardant coatings. Coatings. https://doi.org/10.3390/coatings1310166310.3390/coatings13101663 ↗
24. Howell BA (2022) Thermal degradation of organophosphorus flame retardants. Polymers. https://doi.org/10.3390/polym1422492910.3390/polym14224929 ↗
25. Dasari A, Yu ZZ, Cai GP, Mai YW (2013) Recent developments in the fire retardancy of polymeric materials. Prog Polym Sci 38(9):1357–1387. https://doi.org/10.1016/j.progpolymsci.2013.06.00610.1016/j.progpolymsci.2013.06.006 ↗
26. Huo SQ, Song PA, Yu B, Ran SY, Chevali VS, Liu L, Fang ZP, Wang H (2021) Phosphorus-containing flame retardant epoxy thermosets: recent advances and future perspectives. Prog Polym Sci. https://doi.org/10.1016/j.progpolymsci.2021.10136610.1016/j.progpolymsci.2021.101366 ↗
27. Jin SL, Qian LJ, Qiu Y, Chen YJ, Xin F (2019) High-efficiency flame retardant behavior of bi-DOPO compound with hydroxyl group on epoxy resin. Polym Degrad Stabil 166:344–352. https://doi.org/10.1016/j.polymdegradstab.2019.06.02410.1016/j.polymdegradstab.2019.06.024 ↗
28. Peng W, Nie SB, Xu YX, Yang W (2021) A tetra-DOPO derivative as highly efficient flame retardant for epoxy resins. Polym Degrad Stab. https://doi.org/10.1016/j.polymdegradstab.2021.10971510.1016/j.polymdegradstab.2021.109715 ↗
29. Hua YF, Sun J, Jiang SL, Gu XY, Zhang S (2023) Synthesis of a DOPO derivative to improve the fire safety and mechanical performance of epoxy resin. Macromol Mater Eng. https://doi.org/10.1002/mame.20220056510.1002/mame.202200565 ↗
30. Yang YX, Wang DY, Jian RK, Liu ZQ, Huang GY (2023) Chemical structure construction of DOPO-containing compounds for flame retardancy of epoxy resin: a review. Prog Org Coat. https://doi.org/10.1016/j.porgcoat.2022.10731610.1016/j.porgcoat.2022.107316 ↗
31. Fu F, Zhou X, Shen MG, Wang D, Xu X, Shang SB, Song ZQ, Song J (2023) Preparation of hydrophobic low-k epoxy resins with high adhesion using a benzocyclobutene-rosin modifier. ACS Sustain Chem Eng 11(15):5973–5985. https://doi.org/10.1021/acssuschemeng.2c0769810.1021/acssuschemeng.2c07698 ↗
32. Xiao D, Wang ZB, Gohs U, Harre K, Wang DY (2022) A novel highly-efficient bio-based fire retardant for poly (lactic acid): synthesis, preparation, property and mechanism. Chem Eng J. https://doi.org/10.1016/j.cej.2022.13709210.1016/j.cej.2022.137092 ↗
33. Ma K, Chen Q, Li YQ, You Y, Zou GL, Xie HB (2024) Atom-economic synthesis of phosphorus-containing biobased aromatic diol for flame-retardant robust polyurethane. ACS Appl Polym Mater 6(8):4830–4839. https://doi.org/10.1021/acsapm.4c0054110.1021/acsapm.4c00541 ↗
34. Luo YR, Ming L, Wang X, Zhan ZH, Xu CY (2025) Research on the flame retardancy properties and mechanism of modified epoxy resin with graphene-based hybrid. J Vinyl Addit Technol. https://doi.org/10.1002/vnl.2220410.1002/vnl.22204 ↗
35. Xu ZS, Deng N, Yan L, Chu ZY (2018) Functionalized multiwalled carbon nanotubes with monocomponent intumescent flame retardant for reducing the flammability and smoke emission characteristics of epoxy resins. Polym Adv Technol 29(12):3002–3013. https://doi.org/10.1002/pat.442010.1002/pat.4420 ↗
36. Yang Q, Jia YX, Zhou XM, Zhang HJ (2022) Mechanically reinforced flame-retardant epoxy resins by layered double hydroxide in situ decorated carbon nanotubes. ACS Appl Polym Mater 4(9):6731–6741. https://doi.org/10.1021/acsapm.2c0111010.1021/acsapm.2c01110 ↗
37. Jiang SD, Tang G, Chen JM, Huang ZQ, Hu Y (2018) Biobased polyelectrolyte multilayer-coated hollow mesoporous silica as a green flame retardant for epoxy resin. J Hazard Mater 342:689–697. https://doi.org/10.1016/j.jhazmat.2017.09.00110.1016/j.jhazmat.2017.09.001 ↗
38. Rao WH, Liu CJ, Zhao Y, He S, Yu CB, Wang YT, Zhao HB (2024) Hierarchical nanospheres toward flame-retardant, mechanically strong, and low-toxicity epoxy resins. ACS Appl Polym Mater 6(15):9238–9248. https://doi.org/10.1021/acsapm.4c0166010.1021/acsapm.4c01660 ↗
39. Li Z, Liu ZQ, Zhang J, Fu C, Wagenknecht U, Wang DY (2019) Bio-based layered double hydroxide nanocarrier toward fire-retardant epoxy resin with efficiently improved smoke suppression. Chem Eng J. https://doi.org/10.1016/j.cej.2019.12204610.1016/j.cej.2019.122046 ↗
40. Zotti A, Borriello A, Ricciardi M, Antonucci V, Giordano M, Zarrelli M (2015) Effects of sepiolite clay on degradation and fire behaviour of a bisphenol A-based epoxy. Compos Part B Eng 73:139–148. https://doi.org/10.1016/j.compositesb.2014.12.01910.1016/j.compositesb.2014.12.019 ↗
41. Guo Y, Yang Q, Huo S, Li J, Jafari P, Fang Z, Song P, Wang H (2025) Recyclable fire-retardant bio-based thermosets: from molecular engineering to performances and applications. Prog Polym Sci. https://doi.org/10.1016/j.progpolymsci.2025.10193510.1016/j.progpolymsci.2025.101935 ↗
42. Hou B, Wang Y, Li B, Li N, Yang D, Liu H, Li J (2023) Bio-based flame-retardant plasticizers derived from l-lactic acid: effects of valence states of phosphorus structure on fire safety, flexibility and transparency of poly(lactic acid). Chem Eng J. https://doi.org/10.1016/j.cej.2023.14556310.1016/j.cej.2023.145563 ↗
43. You GY, Cheng ZQ, Peng H, He HW (2015) Synthesis and performance of a novel nitrogen-containing cyclic phosphate for intumescent flame retardant and its application in epoxy resin. J Appl Polym Sci. https://doi.org/10.1002/app.4185910.1002/app.41859 ↗
44. Morgan AB, Benin V, Klosterman DA, Bin Sulayman A, Mukhtar M, Galaska ML (2020) Organophosphorus-hydrazides as potential reactive flame retardants for epoxy. J Fire Sci 38(1):28–52. https://doi.org/10.1177/073490411989028010.1177/0734904119890280 ↗
45. Wang C, Huo S, Ye G, Zhang Q, Cao C-F, Lynch M, Wang H, Song P, Liu Z (2024) Strong self-healing close-loop recyclable vitrimers via complementary dynamic covalent/non-covalent bonding. Chem Eng J. https://doi.org/10.1016/j.cej.2024.15741810.1016/j.cej.2024.157418 ↗
46. Ye G, Huo S, Wang C, Zhang Q, Wang H, Song P, Liu Z (2024) Strong yet tough catalyst‐free transesterification vitrimer with excellent fire‐retardancy, durability, and closed‐loop recyclability. Small. https://doi.org/10.1002/smll.20240463410.1002/smll.202404634 ↗
47. Yu M, Gao Z, Xie W, Shi X, Zhang O, Shen Z, Fang L, Ren M, Sun J (2024) A novel strategy utilizing oxidation states of phosphorus for designing efficient phosphorus-containing flame retardants and its performance in epoxy resins. Polym Degrad Stabil. https://doi.org/10.1016/j.polymdegradstab.2024.11101610.1016/j.polymdegradstab.2024.111016 ↗
48. Chen XL, Jiao CM, Li SX, Sun J (2011) Flame retardant epoxy resins from bisphenol-A epoxy cured with hyperbranched polyphosphate ester. J Polym Res 18(6):2229–2237. https://doi.org/10.1007/s10965-011-9636-010.1007/s10965-011-9636-0 ↗
49. Jirasutsakul I, Paosawatyanyong B, Bhanthumnavin W (2012) Flame-retarding epoxy resin films by curing with organophosphorus containing diamine. Rare Met Mater Eng 41:47–51
50. Xu XQ, Wu YM, Wang CS (2015) Synthesis of DOPO-based spiroorthocarbonate and its application in epoxy resin. Des Monomers Polym 18(7):690–697. https://doi.org/10.1080/15685551.2015.107050110.1080/15685551.2015.1070501 ↗
51. Bao QE, Wang BW, Liu Y, Wang Q, Yang ZQ (2020) Epoxy resin flame retarded and toughed via flexible siloxane chain containing phosphaphenanthrene. Polym Degrad Stabil. https://doi.org/10.1016/j.polymdegradstab.2019.10905510.1016/j.polymdegradstab.2019.109055 ↗
52. Lu LG, Zeng ZJ, Qian XD, Shao GS, Wang HY (2019) Thermal degradation and combustion behavior of flame-retardant epoxy resins with novel phosphorus-based flame retardants and silicon particles. Polym Bull 76(7):3607–3619. https://doi.org/10.1007/s00289-018-2567-810.1007/s00289-018-2567-8 ↗
53. Ren JJ, Jin FB, Bao YW, Yu J, Li XZ, Li S, Cheng YF, Zhang F (2023) Microcapsule preparation of melamine and orange peel charcoal encapsulated by sodium alginate and its effect on combustion performance of epoxy resins. J Therm Anal Calorim 148(18):9489–9500. https://doi.org/10.1007/s10973-023-12338-310.1007/s10973-023-12338-3 ↗
54. Yang S, Wang J, Huo SQ, Cheng LF, Wang M (2015) Preparation and flame retardancy of an intumescent flame-retardant epoxy resin system constructed by multiple flame-retardant compositions containing phosphorus and nitrogen heterocycle. Polym Degrad Stabil 119:251–259. https://doi.org/10.1016/j.polymdegradstab.2015.05.01910.1016/j.polymdegradstab.2015.05.019 ↗
55. Mestry S, Mhaske ST (2019) Synthesis of epoxy resins using phosphorus-based precursors for flame-retardant coating. J Coat Technol Res 16(3):807–818. https://doi.org/10.1007/s11998-018-00157-310.1007/s11998-018-00157-3 ↗
56. Abniki M, Hadavand BS, Najafi F, Ghasedi I (2022) Synthesis of the effective flame retardant via modification of epoxy resin with phenylboronic acid. J of Macromol Sci Part a-Pure Appl Chem 59(6):411–420. https://doi.org/10.1080/10601325.2022.205434910.1080/10601325.2022.2054349 ↗
57. Huo SQ, Wang J, Yang S, Chen X, Zhang B, Wu QL, Zhang B (2018) Flame-retardant performance and mechanism of epoxy thermosets modified with a novel reactive flame retardant containing phosphorus, nitrogen, and sulfur. Polym Adv Technol 29(1):497–506. https://doi.org/10.1002/pat.414510.1002/pat.4145 ↗
58. Battig A, Markwart JC, Wurm FR, Schartel B (2019) Matrix matters: hyperbranched flame retardants in aliphatic and aromatic epoxy resins. Polym Degrad Stabil. https://doi.org/10.1016/j.polymdegradstab.2019.10898610.1016/j.polymdegradstab.2019.108986 ↗
59. Pourchet S, Sonnier R, Ben-Abdelkader M, Gaillard Y, Ruiz Q, Placet V, Plasseraud L, Boni G (2019) New reactive isoeugenol based phosphate flame retardant: toward green epoxy resins. ACS Sustain Chem Eng 7(16):14074–14088. https://doi.org/10.1021/acssuschemeng.9b0262910.1021/acssuschemeng.9b02629 ↗
60. Soni V, Dahiya JB (2024) Synthesis and flame-retardant analysis of a novel P/N containing flame retardant on epoxy resin composites. Fire Mater 48(5):525–535. https://doi.org/10.1002/fam.320010.1002/fam.3200 ↗
61. Liu J, Wu M, Fu Z, Liu J, Yu G, Yu Q, Han Y, Wang Z (2024) Enhancing flame retardancy and dielectric performance of epoxy resins through benzoxazine-phosphorus modification. Polymer. https://doi.org/10.1016/j.polymer.2024.12717310.1016/j.polymer.2024.127173 ↗
62. Wang D, Liu Q, Peng X, Liu C, Li Z, Li Z, Wang R, Zheng P, Zhang H (2021) High-efficiency phosphorus/nitrogen-containing flame retardant on epoxy resin. Polym Degrad Stab. https://doi.org/10.1016/j.polymdegradstab.2021.10954410.1016/j.polymdegradstab.2021.109544 ↗
63. Li Q, Li Y, Chen Y, Wu Q, Wang S (2021) An effective method for preparation of liquid phosphoric anhydride and its application in flame retardant epoxy resin. Materials. https://doi.org/10.3390/ma1409220510.3390/ma14092205 ↗
64. Sun Y, Zhong S, Luo Q, Yu B, Song J, Tan D (2022) A vanillin-derived flame retardant based on 2-aminopyrimidine for enhanced flame retardancy and mechanical properties of epoxy resin. Polym Adv Technol 34(1):166–180. https://doi.org/10.1002/pat.587510.1002/pat.5875 ↗
65. Ren J, Yang G, Deng X, Huang S, Lu C (2023) A tryptamine-based DOPO derivative as a flame retardant for epoxy resins. Polym Degrad Stab. https://doi.org/10.1016/j.polymdegradstab.2023.11059510.1016/j.polymdegradstab.2023.110595 ↗
66. Liu P, Wang X, Huang J, Jiang X (2024) Halogen-free epoxy flame retardant & promoter with diimidazole skeleton improves overall properties of epoxy resins. Chem Eng J. https://doi.org/10.1016/j.cej.2024.15540810.1016/j.cej.2024.155408 ↗
67. Bao Q, Wang B, Liu Y, Wang Q, Yang Z (2020) Epoxy resin flame retarded and toughed via flexible siloxane chain containing phosphaphenanthrene. Polym Degrad Stab. https://doi.org/10.1016/j.polymdegradstab.2019.10905510.1016/j.polymdegradstab.2019.109055 ↗
68. Wang P, Chen L, Xiao H, Zhan T (2020) Nitrogen/sulfur-containing DOPO based oligomer for highly efficient flame-retardant epoxy resin. Polym Degrad Stab. https://doi.org/10.1016/j.polymdegradstab.2019.10902310.1016/j.polymdegradstab.2019.109023 ↗
69. Yuan J, Wang Y, Wang H, Huang S, Deng H, Rao W, Lin X, Zhu Z (2022) A phosphaphenanthrene-based derivative as multifunctional flame retardant for epoxy resins. React Funct Polym. https://doi.org/10.1016/j.reactfunctpolym.2022.10537510.1016/j.reactfunctpolym.2022.105375 ↗
70. Ma X, Kang N, Zhang Y, Min Y, Yang J, Ban D, Zhao W (2023) Enhancing flame retardancy and smoke suppression in epoxy resin composites with sulfur–phosphorous reactive flame retardant. Molecules. https://doi.org/10.3390/molecules2901022710.3390/molecules29010227 ↗
71. Li Z, Liu C, Cao W, Yao Q (2018) Reactive cyclic phosphonamide flame retardant for epoxy resins. J Appl Polym Sci. https://doi.org/10.1002/app.4741110.1002/app.47411 ↗
72. Zhou J, Guo Y, Chen Z, Chen T, Yu Y, Zhang Q, Jiang J (2024) A synthesized P/N/S oligomer flame retardant to construct superior flame-retardant, transparent, and mechanical properties epoxy resin. Mater Today Chem. https://doi.org/10.1016/j.mtchem.2024.10220110.1016/j.mtchem.2024.102201 ↗
73. Peng X, Li Z, Wang D, Li Z, Liu C, Wang R, Jiang L, Liu Q, Zheng P (2021) A facile crosslinking strategy endows the traditional additive flame retardant with enormous flame retardancy improvement. Chem Eng J. https://doi.org/10.1016/j.cej.2021.13040410.1016/j.cej.2021.130404 ↗
74. Ren B, Wang C, Ma R, Huang Y, Li X (2024) Bio-based flame retardants containing a biphenyl unit for enhancing mechanical properties and fire safety of epoxy resins. High Perform Polym 36(3):188–207. https://doi.org/10.1177/0954008324122758910.1177/09540083241227589 ↗
75. Zhang T, Liu Y (2023) Preparation of high-transparency phosphenanthrene-based flame retardants and studies of their flame-retardant properties. Polymers. https://doi.org/10.3390/polym1524466510.3390/polym15244665 ↗
76. Wang S, Meng L, Chen Q, Li S, Zhang A (2023) Flame retardancy and mechanical properties of epoxy resin with the phytic acid‐derived flame retardant. J Appl Polym Sci. https://doi.org/10.1002/app.5460810.1002/app.54608 ↗
77. Meng C, Jiao Y, Wu W, Li Q, Yang Y, Qu H (2025) Synthesis of phosphonitrile derivative-modified halloysite flame retardants and their simultaneous enhancement of epoxy resins flame retardancy and mechanical properties. Appl Clay Sci. https://doi.org/10.1016/j.clay.2024.10762910.1016/j.clay.2024.107629 ↗
78. Luo Q, Sun Y (2024) Facile synthesis of a novel organic salt containing DOPO and pyrimidine as a reactive additive for high‐efficiency flame retarding epoxy resin. Polym Adv Technol. https://doi.org/10.1002/pat.635810.1002/pat.6358 ↗
79. Wang J (2020) Mechanistic study of the flame retardancy of epoxy resin with a novel phosphorus and silicon-containing flame retardant. J Macromol Sci B 59(7):479–489. https://doi.org/10.1080/00222348.2020.174602310.1080/00222348.2020.1746023 ↗
80. Liu J, Dai J, Wang S, Peng Y, Cao L, Liu X (2020) Facile synthesis of bio-based reactive flame retardant from vanillin and guaiacol for epoxy resin. Compos Part B Eng. https://doi.org/10.1016/j.compositesb.2020.10792610.1016/j.compositesb.2020.107926 ↗
81. Jiao D, Zhao H, Sima H, Cheng C, Liu B, Zhang C (2024) Engineering flame retardant epoxy resins with strengthened mechanical property by using reactive catechol functionalized DOPO compounds. Chem Eng J. https://doi.org/10.1016/j.cej.2024.14991010.1016/j.cej.2024.149910 ↗
82. Bai X, Guan H, Li Z, Meng J, Guo K (2024) Reactive organophosphorus retardant-enhanced sorbitol epoxy resins with highly thermal and flame-retardant performance. React Funct Polym. https://doi.org/10.1016/j.reactfunctpolym.2024.10597410.1016/j.reactfunctpolym.2024.105974 ↗
83. Peng W, Nie S-b, Xu Y-x, Yang W (2021) A tetra-DOPO derivative as highly efficient flame retardant for epoxy resins. Polym Degrad Stab. https://doi.org/10.1016/j.polymdegradstab.2021.10971510.1016/j.polymdegradstab.2021.109715 ↗
84. Cai H, Huang W, Li B, Gao L, Huang X, Mao Y (2023) A multi‐element flame retardant for rail transit to improve the flame retardant performance of epoxy resin while reducing smoke density. J Appl Polym Sci. https://doi.org/10.1002/app.5484110.1002/app.54841 ↗
85. Liu S, Wei H, Xiong Y, Ding Y, Xu L (2022) Synthesis of a highly efficient flame retardant containing triazine and pentaerythritol phosphate groups and its intumescent flame retardancy on epoxy resin. High Perform Polym 34(8):889–903. https://doi.org/10.1177/0954008322109816010.1177/09540083221098160 ↗
86. You G-Y, He H-W, Feng B, Tang Y-Y, Cheng Z-Q, Fan F-F (2020) Synthesis and application of a novel phosphoryl thiourea-containing flame retardant for epoxy resin. Chem Pap 74(8):2403–2414. https://doi.org/10.1007/s11696-020-01086-510.1007/s11696-020-01086-5 ↗
87. Dun L, Ouyang Z, Sun Q, Yue X, Wu G, Li B, Kang W, Wang Y (2024) A simple and efficient magnesium hydroxide modification strategy for flame-retardancy epoxy resin. Polymers. https://doi.org/10.3390/polym1611147110.3390/polym16111471 ↗
88. Wang H, Li S, Zhu Z, Yin X, Wang L, Weng Y, Wang X (2021) A novel DOPO-based flame retardant containing benzimidazolone structure with high charring ability towards low flammability and smoke epoxy resins. Polym Degrad Stab. https://doi.org/10.1016/j.polymdegradstab.2020.10942610.1016/j.polymdegradstab.2020.109426 ↗
89. Miao Z, Yan D, Wang X, Zhang X, Zhou W, Qiu M, Yang F, Wu Z (2022) New flame retardant epoxy resins based on cyclophosphazene-derived curing agents. Chin Chem Lett 33(8):4026–4032. https://doi.org/10.1016/j.cclet.2021.12.00310.1016/j.cclet.2021.12.003 ↗
90. Greiner L, Kukla P, Eibl S, D鰎ing M (2022) Phosphorylated salicylic acid as flame retardant in epoxy resins and composites. J Renew Mater 10(7):1931–1950. https://doi.org/10.32604/jrm.2022.01954810.32604/jrm.2022.019548 ↗
91. Tang G, Hu Y, Fang Y, Guan M, Gong Z, Wang G, Deng D, Liu X (2024) Synthesis of a tris(DOPO-grafted piperazine)-triazine phosphoramide and its application as a highly efficient flame retardant for epoxy resins. J Therm Anal Calorim 149(17):9233–9247. https://doi.org/10.1007/s10973-024-13508-710.1007/s10973-024-13508-7 ↗
92. Liu D, Jiang F, Zhang T, Yu C, Hu Z, Zhang L, Shi S (2023) A DOPO‐based reactive flame retardant containing benzimidazole groups: synthesis and its flame‐retardation on epoxy resin. J Appl Polym Sci. https://doi.org/10.1002/app.5489010.1002/app.54890 ↗
93. Wang H, Yuan J, Zhu Z, Yin X, Weng Y, Wang Z, Yang F, Zhan J, Wang H, Wang L (2021) High performance epoxy resin composites modified with multifunctional thiophene/phosphaphenanthrene-based flame retardant: excellent flame retardance, strong mechanical property and high transparency. Compos Part B Eng. https://doi.org/10.1016/j.compositesb.2021.10939210.1016/j.compositesb.2021.109392 ↗
94. Wan C, Duan H, Zhang C, Liu C, Zhao H, Ma H (2023) Synthesis of a multielement flame retardant and its application in epoxy resin. ACS Appl Polym Mater 5(3):1775–1785. https://doi.org/10.1021/acsapm.2c0187510.1021/acsapm.2c01875 ↗
95. Wang C, Ren B, Ma R, Li X (2024) A bio-based reactive P/N synergistic flame retardant for improving the fire safety and mechanical properties of epoxy resin. Polym Eng Sci 64(10):4730–4745. https://doi.org/10.1002/pen.2687710.1002/pen.26877 ↗
96. Cen X, Cao Z, Wang Z (2024) Flame retardancy, thermal behavior and mechanical properties of an epoxy resin and cyanate ester resin copolymer containing a bio phytate-based flame retardant. Polymer. https://doi.org/10.1016/j.polymer.2023.12661010.1016/j.polymer.2023.126610 ↗
97. Zhou R, Lin L, Zeng B, Yi X, Huang C, Du K, Liu X, Xu Y, Yuan C, Dai L (2022) Diblock copolymers containing titanium-hybridized polyhedral oligomeric silsesquioxane used as a macromolecular flame retardant for epoxy resin. Polymers. https://doi.org/10.3390/polym1409170810.3390/polym14091708 ↗
98. Huang X, Cai H, Gao L, Mao Y, Huang W (2024) The synthesis of biphenyl ether/vanillin‐based flame retardants for enhancing both the flame retardant properties and mechanical performance of epoxy resin. J Appl Polym Sci. https://doi.org/10.1002/app.5528110.1002/app.55281 ↗
99. Luo H, Rao W, Zhao P, Wang L, Liu Y, Yu C (2020) An efficient organic/inorganic phosphorus–nitrogen–silicon flame retardant towards low-flammability epoxy resin. Polym Degrad Stab. https://doi.org/10.1016/j.polymdegradstab.2020.10919510.1016/j.polymdegradstab.2020.109195 ↗
100. Howell BA, Lienhart GW, Livingstone VJ, Aulakh D (2020) 1-dopyl-1,2-(4-hydroxyphenyl)ethene: a flame retardant hardner for epoxy resin. Polym Degrad Stabil. https://doi.org/10.1016/j.polymdegradstab.2020.10911010.1016/j.polymdegradstab.2020.109110 ↗