Achieving a high oxidation-resistant Mg-Al-Ca alloys by coordinating oxidation of α-Mg matrix and intermetallic phases
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OpenAlex topics: Magnesium Alloys: Properties and Applications · Aluminum Alloy Microstructure Properties · High-Temperature Coating Behaviors
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References (49)
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1. Wang GG, Weiler JP (2023) Recent developments in high-pressure die-cast magnesium alloys for automotive and future applications. J Magnes Alloys 11(1):78–87. https://doi.org/10.1016/j.jma.2022.10.00110.1016/j.jma.2022.10.001 ↗
2. Huang PZ, Sang MQ, Wang D, Huang HL, Wu RZ, Yang XY, Han Y, Yu R, Zhang L (2025) The effects of solid solution and aging on the mechanical and damping capacity of magnesium-lithium alloys under high temperature and high-pressure conditions. J Alloys Compd 1022:179877. https://doi.org/10.1016/j.jallcom.2025.17987710.1016/j.jallcom.2025.179877 ↗
3. Bao RR, Zhang JH, He YY, Li ZH, Liu SJ, Dong H, Yang Q, Zhang XB, Qiu X (2023) Exploring low-alloyed as-extruded Mg alloy with high strength and high corrosion resistance. J Magnes Alloys. https://doi.org/10.1016/j.jma.2025.06.00210.1016/j.jma.2025.06.002 ↗
4. Feng LB, Zhang LY, Shen HX, Qiu Z, Cao GY, Cao FY, Ning ZL, Huang YJ, Sun JF (2024) Investigating the influence of pressure on the ignition and oxidation behavior of EV33 alloy. J Mater Res Technol 32:3640–3651. https://doi.org/10.1016/j.jmrt.2024.08.17610.1016/j.jmrt.2024.08.176 ↗
5. Yeganeh H, Bahmani A, Lotfpour M, Malekan M, Emamy M, Nayebi B, Shin KS (2023) Enhanced oxidation and overheating resistance of the extruded Mg-Zn-Al-Mn magnesium alloy by Calcium addition. J Magnes Alloys 11(4):1276–1291. https://doi.org/10.1016/j.jma.2023.03.00410.1016/j.jma.2023.03.004 ↗
6. Wu LP, Yang ZD, Qin GW (2017) Kinetic study of a novel electroless Ni-P deposition on AZ91D magnesium alloy using nickel hypophosphite as the metal salt. J Alloys Compd 694:1133–1139. https://doi.org/10.1016/j.jallcom.2016.10.14110.1016/j.jallcom.2016.10.141 ↗
7. Yua XW, Shen SJ, Jian B, Jiang ZT, Yang H, Pan FS (2016) The effect of the existing state of Y on high temperature oxidation properties of magnesium alloys. J Alloys Compd 370:357–363. https://doi.org/10.1016/j.apsusc.2016.02.15610.1016/j.apsusc.2016.02.156 ↗
8. Liu LC, Le QC, Zhong X, Ji A, Jiang YC, Lin YB, Li DJ (2024) Effect of Ca and Y microalloying on oxidation behavior of AZ31 at high temperature. J Alloys Compd 1002:175472. https://doi.org/10.1016/j.jallcom.2024.17547210.1016/j.jallcom.2024.175472 ↗
9. Wu JJ, Yuan Y, Yu XW, Chen T, Li DJ, Wu L, Jiang B, Atrens A, Pan FS (2021) The high temperature oxidation resistance properties of magnesium alloys alloyed with Gd and Ca. J Mater Sci 56(14):8745–8761. https://doi.org/10.1007/s10853-020-05758-110.1007/s10853-020-05758-1 ↗
10. Chen JC, Li MX, Yu ZY, Meng ZY, Wang C, Yang ZZ, Wang HY (2023) Simultaneous refinement of α-Mg grains and β-Mg17Al12 in Mg-Al based alloys via heterogeneous nucleation on Al8Mn4Sm. J Magnes Alloys 11(1):348–360. https://doi.org/10.1016/j.jma.2022.11.01610.1016/j.jma.2022.11.016 ↗
11. Zhong X, Le QC, Liu LC, Ren L, Chen RM, Wang T (2024) Effect of Er addition on the oxidation behavior of Mg-4Al-0.2 Mn alloy at high temperatures. J Alloys Compd 1002:175233. https://doi.org/10.1016/j.jallcom.2024.17523310.1016/j.jallcom.2024.175233 ↗
12. Cheng CL, Li XQ, Le QC, Guo RZ, Lan Q, Cui JZ (2020) Effect of REs (Y, Nd) addition on high temperature oxidation kinetics, oxide layer characteristic and activation energy of AZ80 alloy. J Magnes Alloys 8(4):1281–1295. https://doi.org/10.1016/j.jma.2019.09.01310.1016/j.jma.2019.09.013 ↗
13. Fan MY, Cui Y, Zhang ZW, Liu LY, Li Q, Luo Q (2023) Enhanced oxidation resistance in Mg-Y-Zn-Ho alloys via introducing dense low-oxygen-diffusion Ho2O3 oxide film. Corros Sci 213:110976. https://doi.org/10.1016/j.corsci.2023.11097610.1016/j.corsci.2023.110976 ↗
14. Zeng XQ, Wang QD, Lü YZ, Ding WJ, Lu C, Zhu YP, Zhai CQ, Xu XP (2000) Study on ignition proof magnesium alloy with beryllium and rare earth additions. Scr Mater 43:403–409. https://doi.org/10.1016/S1359-6462(00)00440-110.1016/S1359-6462(00)00440-1 ↗
15. Lee DB (2013) High temperature oxidation of AZ31+ 0.3 wt.% Ca and AZ31+ 0.3 wt.% CaO magnesium alloys. Corros Sci 70:243–251. https://doi.org/10.1016/j.corsci.2013.01.03610.1016/j.corsci.2013.01.036 ↗
16. Wu J, Yuan Y, Chen T, Tang A, Wu L, Li D, Steinbrück M, Pan FS (2023) The oxidation behavior and reaction thermodynamics and kinetics of the Mg-X (X=Ca/Gd/Y) binary alloys. Corros Sci 225:111609. https://doi.org/10.1016/j.corsci.2023.11160910.1016/j.corsci.2023.111609 ↗
17. Villegas-Armenta LA, Drew L RA, Pekguleryuz MO (2020) The ignition behavior of Mg-Ca binary alloys: the role of heating rate. Oxid Met 93(5):545–558. https://doi.org/10.1007/s11085-020-09970-x10.1007/s11085-020-09970-x ↗
18. Ha SH, Lee JK, Kim SK (2008) Effect of CaO on oxidation resistance and microstructure of pure Mg. Mater Trans 49(5):1081–1083. https://doi.org/10.2320/matertrans.MC20078610.2320/matertrans.MC200786 ↗
19. Yue M, You GQ, Qi L, Yao FJ, Zhang J, Jiang B (2023) Flame resistance and oxidation behaviour of Mg-xCa (x=0.3, 1.0, 2.0 and 3.6 wt%) alloys. Corros Sci 215:2111059. https://doi.org/10.1016/j.corsci.2023.11105910.1016/j.corsci.2023.111059 ↗
20. Yue M, You GQ, Yao FJ, Zeng S, Zhang J, Zhao JH, Zeng W (2022) High temperature oxidation of Mg-Ca alloy: experimentation and density functional theory. Corros Sci 196:110046. https://doi.org/10.1016/j.corsci.2021.11004610.1016/j.corsci.2021.110046 ↗
21. You BS, Park WW, Chung IS (2000) The effect of calcium additions on the oxidation behavior in magnesium alloys. Scr Mater 42(11):1089–1094. https://doi.org/10.1016/S1359-6462(00)00344-410.1016/S1359-6462(00)00344-4 ↗
22. Ha SH, Lee K, Jo HH, Jung SB, Kim SK (2006) Behavior of CaO and calcium in pure magnesium. Rare Met 25:150–15410.1016/S1001-0521(08)60071-6 ↗
23. Jin SS, You ZY, Jiang AX, Sun CL, Wang LB, Liu SL (2025) First-principles study of Mg2Ca as a reinforcing phase. Spec Cast Nonferrous Alloys 45(01):46–52. https://doi.org/10.15980/j.tzzz.T20230489. (in Chinese)10.15980/j.tzzz.T20230489 ↗
24. Jiang XJ, Chen XY, Li QA, Wang DZ, Wu Z (2024) Application and research progress of first principles calculation in magnesium alloys. Mater Today Commun. https://doi.org/10.1016/j.mtcomm.2024.11031710.1016/j.mtcomm.2024.110317 ↗
25. Li ZT, Zhang XD, Zheng MY, Qiao XG, Wu K, Xu C, Kamado S (2017) Effect of Ca/Al ratio on microstructure and mechanical properties of Mg-Al-Ca-Mn alloys. Mater Sci Eng, A 682:423–432. https://doi.org/10.1016/j.msea.2016.11.02610.1016/j.msea.2016.11.026 ↗
26. Li YR, Zhang SH, Gong CW, Liu BS, Wei YH (2024) A comprehensive investigation of alloying elements on site preferences, elastic properties and electronic structure of Mg17Al12 by first-principles calculations. Vacuum 227:113450. https://doi.org/10.1016/j.vacuum.2024.11345010.1016/j.vacuum.2024.113450 ↗
27. Amerioun S, Simak SI, Häussermann U (2003) Laves-phase structural changes in the system CaAl2-x Mgx. Inorg Chem 42(5):1467–1474. https://doi.org/10.1021/ic020596m10.1021/ic020596m ↗
28. Liang JX, Qi BM, Lu MM, Zhou YY, Ren F, Shen Y, Li GH, Pang SF, Wang YB, Su Q (2024) Investigation on Be, Mg, Ca, B, Ga, C, Si, and Ge atoms doped on Al (111) surface and their effect on oxygen adsorption: a first-principle calculation. Surf Interfaces 53:105075. https://doi.org/10.1016/j.surfin.2024.10507510.1016/j.surfin.2024.105075 ↗
29. Zhang XX, Cui ZL, Yi L, Li YL, Xiao HY, Chen DC (2018) Theoretical study of the interaction of SF6 molecule on Ag (111) surfaces: a DFT study. Appl Surf Sci 457:745–751. https://doi.org/10.1016/j.apsusc.2018.06.30510.1016/j.apsusc.2018.06.305 ↗
30. Wang Y, Liu C, Ma T, Liu Y, Zhang Y, Zhou L (2022) Improvement in oxidation resistance of TiAl alloys by in-situ precipitation of Ti2AlC at the interface of α2 and γ lamellae. Corros Sci 208:110639. https://doi.org/10.1016/j.corsci.2022.11063910.1016/j.corsci.2022.110639 ↗
31. Fan JF, Yang CL, Xu BS (2012) Effect of Ca and Y additions on oxidation behavior of magnesium alloys at high temperatures. J Rare Earths 30(5):497–502. https://doi.org/10.1016/S1002-0721(12)60079-910.1016/S1002-0721(12)60079-9 ↗
32. Zhong X, Le QC, Liu LC, Ren L, Chen RM, Wang T (2024) Effect of Er addition on the oxidation behavior of Mg-4Al-0.2 Mn alloy at high temperatures. J Alloys Compd 1002:175233. https://doi.org/10.1016/j.jallcom.2024.17523310.1016/j.jallcom.2024.175233 ↗
33. Inoue S, Yamasaki M, Kawamura Y (2020) Classification of high temperature oxidation behavior of Mg-1 at% X binary alloys and application of proposed taxonomy to nonflammable multicomponent Mg alloys. Corros Sci 174:108858. https://doi.org/10.1016/j.corsci.2020.10885810.1016/j.corsci.2020.108858 ↗
34. Aydin DS, Bayindir Z, Pekguleryuz MO (2015) High temperature oxidation behavior of hypoeutectic Mg-Sr binary alloys: the role of the two-phase microstructure and the surface activity of Sr. Adv, Eng Mater 17(5):697–708. https://doi.org/10.1002/adem.20140019110.1002/adem.201400191 ↗
35. Zhou DW, Peng P, Liu JS (2007) Energetics, electronic structure, and structure stability of the calcium alloying Mg17Al12 phase from first principles calculations. Mater Sci Pol 25:145–153
36. Wei L, Chen L, Liu H, Han L, Gong N, Misra RDK (2020) Precipitation behavior of Laves phase in the vicinity of oxide film of ferritic stainless steel: selective oxidation-induced precipitation. Oxid Met 93(1):195–213. https://doi.org/10.1007/s11085-019-09955-510.1007/s11085-019-09955-5 ↗
37. Zhong W, Zhao JC (2017) First experimental measurement of calcium diffusion in magnesium using novel liquid-solid diffusion couples and forward-simulation analysis. Scr Mater 127:92–96. https://doi.org/10.1016/j.scriptamat.2016.09.00810.1016/j.scriptamat.2016.09.008 ↗
38. Zhong W, Zhao JC (2020) A comprehensive diffusion mobility database comprising 23 elements for magnesium alloys. Acta Mater 201:191–208. https://doi.org/10.1016/j.actamat.2020.09.07910.1016/j.actamat.2020.09.079 ↗
39. Ma S, Xing FZ, Ta N, Zhang LJ (2020) Kinetic modeling of high temperature oxidation of pure Mg. J Magnes Alloys 8(3):819–831. https://doi.org/10.1016/j.jma.2019.12.00510.1016/j.jma.2019.12.005 ↗
40. Wang XM, Zeng XQ, Zhou Y, Wu GS, Yao SS, Lai YJ (2008) Early oxidation behaviors of Mg-Y alloys at high temperatures. J Alloys Compd. https://doi.org/10.1016/j.jallcom.2007.06.06510.1016/j.jallcom.2007.06.065 ↗
41. Saleh H, Weling T, Seidel J, Schmidtchen M, Kawalla R, Mertens F, Vogt HP (2013) An XPS study of native oxide and isothermal oxidation kinetics at 300 ℃ of AZ31 twin roll cast magnesium alloy. Oxid Met 81:529–548. https://doi.org/10.1007/s11085-013-9466-z10.1007/s11085-013-9466-z ↗
42. Luis Angel VA, Pekguleryuz MO (2020) The ignition behavior of a ternary Mg-Sr-Ca alloy. Adv Eng Mater 22:1901318. https://doi.org/10.1002/adem.20190131810.1002/adem.201901318 ↗
43. Pan YK, He SY, Wang DG, Huang DL, Zheng TT, Wang SQ, Dong P, Chen CZ (2015) In vitro degradation and electrochemical corrosion evaluations of microarc oxidized pure Mg, Mg-Ca and Mg-Ca-Zn alloys for biomedical applications. Mater Sci Eng, C 47:85–96. https://doi.org/10.1016/j.msec.2014.11.04810.1016/j.msec.2014.11.048 ↗
44. Cheng CL, Le QC, Li DJ, Hu WX, Wang T, Guo RZ, Hu CL (2021) Effect of Y on high temperature oxidation behavior and products of AZ80 alloy. Mater Chem Phys 269:124732. https://doi.org/10.1016/j.matchemphys.2021.12473210.1016/j.matchemphys.2021.124732 ↗
45. Wang ZP, Shen Z, Zhao YH, Hu B, Li DJ, Zeng XQ (2023) A study on the high temperature oxidation of ZM6 alloy through advanced characterization. Corros Sci 218:111150. https://doi.org/10.1016/j.corsci.2023.11115010.1016/j.corsci.2023.111150 ↗
46. Liu SY, Apell J, Li B, Liu ZH, Liu GJ, Lang XY, Zhu YF, Jiang Q (2025) Effect of preheating treatment in Ar atmosphere on oxidation resistance of Mg-Y alloys and formation of oxide film. Vacuum 232:113836. https://doi.org/10.1016/j.vacuum.2024.11383610.1016/j.vacuum.2024.113836 ↗
47. Somasundaram M, NarendraKumar U, Annamalai AR (2023) The oxidation behavior of stir-cast and heat-treated EV31A at high temperatures in an air atmosphere. Corros Sci 211:110894. https://doi.org/10.1016/j.corsci.2022.11089410.1016/j.corsci.2022.110894 ↗
48. Lee DB, Hong LS, Kim YJ (2008) Effect of Ca and CaO on the high temperature oxidation of AZ91D Mg alloys. Mater Trans 49(5):1084–1088. https://doi.org/10.2320/matertrans.MC20079910.2320/matertrans.MC200799 ↗
49. Lee TW, Park HW, Lim H, Kim SK, Lim SH (2017) Microstructural characterization of oxide layers in CaO added AZ31 Mg alloy. J Alloys Compd 714:397–408. https://doi.org/10.1016/j.jallcom.2017.04.26210.1016/j.jallcom.2017.04.262 ↗