journal article·2025-12

The piezoelectric nanogenerators based on PVDF/BaTiO3/MWCNT ternary composite prepared by the electrospinning method

Muhterem Koç, Sevinj Guluzade, Farida Tatardar, Nahida Nazim Musayeva, Ali Sarı, Levent Paralı

Journal of Materials Science· Volume 60· Issue 48
Publisher page

Abstract

No abstract is available for this record. The assistant can identify its topic from the title, but cannot infer the study’s results.

Source: Not provided · Quality: missing

Research context

OpenAlex topics: Advanced Sensor and Energy Harvesting Materials · Dielectric materials and actuators · Advanced Materials and Mechanics

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (64)

Show source-provided references
1. Luo J, Gao S, Luo H, Wang L, Huang X, Guo Z, Lai X, Lin L, Li RKY, Gao J (2021) Superhydrophobic and breathable smart MXene-based textile for multifunctional wearable sensing electronics. Chem Eng J 406:126898. https://doi.org/10.1016/j.cej.2020.12689810.1016/j.cej.2020.126898 ↗
2. Pu X, Hu W, Wang ZL (2018) Toward wearable self-charging power systems: the integration of energy-harvesting and storage devices. Small 14:1–19. https://doi.org/10.1002/smll.20170281710.1002/smll.201702817 ↗
3. Bai Y, Jantunen H, Juuti J (2018) Energy harvesting research: the road from single source to multisource. Adv Mater 30:1707271. https://doi.org/10.1002/adma.20170727110.1002/adma.201707271 ↗
4. Safaei M, Sodano HA, Anton SR (2019) A review of energy harvesting using piezoelectric materials: state-of-the-art a decade later (2008–2018). Smart Mater Struct 28:113001. https://doi.org/10.1088/1361-665X/ab36e410.1088/1361-665X/ab36e4 ↗
5. Wang D, Yuan G, Hao G, Wang Y (2018) All-inorganic flexible piezoelectric energy harvester enabled by two-dimensional mica. Nano Energy 43:351–358. https://doi.org/10.1016/j.nanoen.2017.11.03710.1016/j.nanoen.2017.11.037 ↗
6. Mishra S, Unnikrishnan L, Nayak SK, Mohanty S (2019) Advances in piezoelectric polymer composites for energy harvesting applications: a systematic review. Macromol Mater Eng 304(1):1800463. https://doi.org/10.1002/mame.20180046310.1002/mame.201800463 ↗
7. Varghese H, Chandran A (2021) A facile mechanical energy harvester based on spring assisted triboelectric nanogenerators. Sustain Energy Fuels 5:5287–5294. https://doi.org/10.1039/d1se00788b10.1039/d1se00788b ↗
8. Satish B, Sridevi K, Vijaya MS (2002) Study of piezoelectric and dielectric properties of ferroelectric PZT-polymer composites prepared by hot-press technique. J Phys D Appl Phys 35:2048–205010.1088/0022-3727/35/16/321 ↗
9. Lam KH, Chan HLW (2005) Piezoelectric and pyroelectric properties of 65PMN-35PT/P(VDF-TrFE) 0–3 composites. Compos Sci Technol 65:1107–1111. https://doi.org/10.1016/j.compscitech.2004.11.00610.1016/j.compscitech.2004.11.006 ↗
10. Jia N, Xing Q, Xia G, Sun J, Song R, Huang W (2015) Enhanced β-crystalline phase in poly(vinylidene fluoride) films by polydopamine-coated BaTiO3 nanoparticles. Mater Lett 139:212–215. https://doi.org/10.1016/j.matlet.2014.10.06910.1016/j.matlet.2014.10.069 ↗
11. Shrout TR, Zhang SJ (2007) Lead-free piezoelectric ceramics: alternatives for PZT? J Electroceram 19:111–124. https://doi.org/10.1007/s10832-007-9047-010.1007/s10832-007-9047-0 ↗
12. Simon-Seveyrat L, Hajjaji A, Emziane Y, Guiffard B, Guyomar D (2007) Re-investigation of synthesis of BaTiO3 by conventional solid-state reaction and oxalate coprecipitation route for piezoelectric applications. Ceram Int 33(1):35–40. https://doi.org/10.1016/j.ceramint.2005.07.01910.1016/j.ceramint.2005.07.019 ↗
13. Liu W, Wang J, Ke X, Li S (2017) Large piezoelectric performance of Sn doped BaTiO3 ceramics deviating from quadruple point. J Alloys Compd 712:1–6. https://doi.org/10.1016/j.jallcom.2017.04.01310.1016/j.jallcom.2017.04.013 ↗
14. Ali AI, Ahn CW, Kim YS (2013) Enhancement of piezoelectric and ferroelectric properties of BaTiO3 ceramics by aluminum doping. Ceram Int 39:6623–6629. https://doi.org/10.1016/j.ceramint.2013.01.09910.1016/j.ceramint.2013.01.099 ↗
15. Farahani A, Zarei-Hanzaki A, Abedi HR et al (2021) Polylactic acid piezo-biopolymers: chemistry structural evolution fabrication methods and tissue engineering applications. J Funct Biomater 12:1–33. https://doi.org/10.3390/jfb1204007110.3390/jfb12040071 ↗
16. Sappati KK, Bhadra S (2018) Piezoelectric polymer and paper substrates: a review. Sensors (Switzerland) 18:3605. https://doi.org/10.3390/s1811360510.3390/s18113605 ↗
17. Martins P, Lopes AC, Lanceros-Mendez S (2014) Electroactive phases of poly(vinylidene fluoride): determination processing and applications. Prog Polym Sci 39:683–706. https://doi.org/10.1016/j.progpolymsci.2013.07.00610.1016/j.progpolymsci.2013.07.006 ↗
18. Li M, Wondergem HJ, Spijkman MJ, Asadi K, Katsouras I, Blom PW, de Leeuw DM (2013) Revisiting the δ-phase of poly(vinylidene fluoride) for solution-processed ferroelectric thin films. Nat Mater 12(5):433–438. https://doi.org/10.1038/nmat357710.1038/nmat3577 ↗
19. Banerjee S, Bairagi S, Wazed Ali S (2021) A critical review on lead-free hybrid materials for next generation piezoelectric energy harvesting and conversion. Ceram Int 47:16402–16421. https://doi.org/10.1016/j.ceramint.2021.03.05410.1016/j.ceramint.2021.03.054 ↗
20. Bouhamed A, Jöhrmann N, Naifar S et al (2022) Collaborative filler network for enhancing the performance of BaTiO3/PDMS flexible piezoelectric polymer composite nanogenerators. Sensors 22:4181. https://doi.org/10.3390/s2211418110.3390/s22114181 ↗
21. Nunes-Pereira J, Sencadas V, Correia V, Cardoso VF, Han W, Rocha JG, Lanceros-Méndez S (2015) Energy harvesting performance of BaTiO3/poly(vinylidene fluoride-trifluoroethylene) spin coated nanocomposites. Compos Part B Eng 72:130–136. https://doi.org/10.1016/j.compositesb.2014.12.00110.1016/j.compositesb.2014.12.001 ↗
22. Kubin M, Makreski P, Zanoni M, Gasperini L, Selleri G, Fabiani D, Gualandi C, Bužarovska A (2023) Effects of nano-sized BaTiO3 on microstructural thermal mechanical and piezoelectric behavior of electrospun PVDF/BaTiO3 nanocomposite mats. Polym Test 126:108158. https://doi.org/10.1016/j.polymertesting.2023.10815810.1016/j.polymertesting.2023.108158 ↗
23. Köferstein R, Jäger L, Zenkner M, Ebbinghaus SG (2010) Phase transition and dielectric properties of BaTiO3 ceramics containing 10 mol% BaGeO3. Mater Chem Phys 119:118–122. https://doi.org/10.1016/j.matchemphys.2009.08.02610.1016/j.matchemphys.2009.08.026 ↗
24. Borkar H, Rao V, Tomar M, Gupta V, Kumar A (2018) Near room temperature bismuth and lithium co-substituted BaTiO3 relaxor ferroelectrics family. J Alloys Compd 737:821–828. https://doi.org/10.1016/j.jallcom.2017.12.17010.1016/j.jallcom.2017.12.170 ↗
25. Ataabadi MR, Jamshidi M (2023) Silane modification of TiO2 nanoparticles and usage in acrylic film for effective photocatalytic degradation of methylene blue under visible light. Sci Rep 13:7383. https://doi.org/10.1038/s41598-023-34463-710.1038/s41598-023-34463-7 ↗
26. Fathollahzadeh V, Khodaei M (2024) Enhanced piezoelectric response of PVDF by incorporating of BaTiO3 nanoparticles and surface treatment. J Mater Sci Mater Electron 35(2):107. https://doi.org/10.1007/s10854-023-11848-y10.1007/s10854-023-11848-y ↗
27. Sridhar R, Amith V, Aditya S, Gangadhar A, Vishnumurthy KA (2022) Electrospun PVDF/Cloisite-30B and PVDF/BaTiO3/graphene nanofiber mats for development of nanogenerators. J Indian Chem Soc 99(6):100501. https://doi.org/10.1016/j.jics.2022.10050110.1016/j.jics.2022.100501 ↗
28. Meng L, Yang C, Meng J et al (2019) In-situ fabricated anisotropic halide perovskite nanocrystals in polyvinylalcohol nanofibers: shape tuning and polarized emission. Nano Res 12:1411–1416. https://doi.org/10.1007/s12274-019-2353-410.1007/s12274-019-2353-4 ↗
29. Ghosh SK, Biswas A, Sen S et al (2016) Yb3+ assisted self-polarized PVDF based ferroelectretic nanogenerator: a facile strategy of highly efficient mechanical energy harvester fabrication. Nano Energy 30:621–629. https://doi.org/10.1016/j.nanoen.2016.10.04210.1016/j.nanoen.2016.10.042 ↗
30. Lin X, Yu F, Zhang X et al (2023) Wearable piezoelectric films based on MWCNT-BaTiO3/PVDF composites for energy harvesting sensing and localization. ACS Appl Nano Mater 6:11955–11965. https://doi.org/10.1021/acsanm.3c0179210.1021/acsanm.3c01792 ↗
31. Afsarimanesh N, Nag A, Eshrat e Alahi M et al (2022) A critical review of the recent progress on carbon nanotubes-based nanogenerators. Sens Actuators A Phys 344:113743. https://doi.org/10.1016/j.sna.2022.11374310.1016/j.sna.2022.113743 ↗
32. Han J, Wang Y, Ma Y, Wang C (2023) Enhanced energy harvesting performance of triboelectric nanogenerators via dielectric property regulation. ACS Appl Mater Interfaces 15:31795–31802. https://doi.org/10.1021/acsami.3c0479110.1021/acsami.3c04791 ↗
33. Iftekhar Uddin ASM, Lee D, Cho C, Kim B (2022) Impact of multi-walled CNT incorporation on dielectric properties of PVDF-BaTiO3 nanocomposites and their energy harvesting possibilities. Coatings 12:77. https://doi.org/10.3390/coatings1201007710.3390/coatings12010077 ↗
34. Silakaew K, Thongbai P (2019) Significantly improved dielectric properties of multiwall carbon nanotube-BaTiO3/PVDF polymer composites by tuning the particle size of the ceramic filler. RSC Adv 9:23498–23507. https://doi.org/10.1039/c9ra04933a10.1039/c9ra04933a ↗
35. Missaoui D, Bouhamed A, Jeder K, Njeh A, Donner W, Kassiba AH, Kanoun O (2023) Design and characterization of a PDMS/BCT/Multiwalled carbon nanotube nanocomposite as a piezoelectric energy harvester. ACS Appl Electron Mater 6(1):183–193. https://doi.org/10.1021/acsaelm.3c0100910.1021/acsaelm.3c01009 ↗
36. Bouhamed A, Professorship A, Shi Y et al (2019) Carbon nanotubes for high performance flexible piezoelectric polymer composite nanogenerators. NanofIM Sfax Tunis. https://doi.org/10.1109/NanofIM49467.2019.923347710.1109/NanofIM49467.2019.9233477 ↗
37. Hrabalova M, Gregorova A, Wimmer R, Sedlarik V, Machovsky M, Mundigler N (2010) Effect of wood flour loading and thermal annealing on viscoelastic properties of poly(lactic acid) composite films. J Appl Polym Sci 118(3):1534–1540. https://doi.org/10.1002/app.3250910.1002/app.32509 ↗
38. Yu H, Huang T, Lu M, Mao M, Zhang Q, Wang H (2013) Enhanced power output of an electrospun PVDF/MWCNTs-based nanogenerator by tuning its conductivity. Nanotechnol 24(40):405401. https://doi.org/10.1088/0957-4484/24/40/40540110.1088/0957-4484/24/40/405401 ↗
39. Lakra H, Aishwarya A, Mondal S et al (2025) Nanogenerators of acid-functionalized multiwalled carbon nanotubes incorporated poly(vinylidene fluoride) nanocomposites with enhanced piezoelectric performance towards bio-mechanical motion energy harvesting. Polym Compos. https://doi.org/10.1002/pc.2977410.1002/pc.29774 ↗
40. Kabir E, Khatun M, Nasrin L, Raihan MJ, Rahman M (2017) Pure β-phase formation in polyvinylidene fluoride (PVDF)-carbon nanotube composites. J Phys D Appl Phys 50(16):163002. https://doi.org/10.1088/1361-6463/AA5F8510.1088/1361-6463/AA5F85 ↗
41. Manna S, Nandi AK (2007) Piezoelectric β polymorph in poly(vinylidene fluoride)-functionalized multiwalled carbon nanotube nanocomposite films. J Phys Chem C 111:14670–14680. https://doi.org/10.1021/jp073102l10.1021/jp073102l ↗
42. Dang ZM, Wang L, Yin Y et al (2007) Giant dielectric permittivities in functionalized carbon-nanotube/ electroactive-polymer nanocomposites. Adv Mater 19:852–857. https://doi.org/10.1002/adma.20060070310.1002/adma.200600703 ↗
43. Satyanarayana M, Goud KY, Reddy KK et al (2019) Silver nanoparticles impregnated chitosan layered carbon nanotube as sensor interface for electrochemical detection of clopidogrel in-vitro. Mater Sci Eng C Mater Biol Appl 101:103–110. https://doi.org/10.1016/j.msec.2019.03.08310.1016/j.msec.2019.03.083 ↗
44. Musayeva N, Khalilova H, Izzatov B, Trevisi G, Ahmadova S, Alizada M (2023) Highly selective detection of hydrogen sulfide by simple Cu-CNTs nanocomposites. C 9(1):25. https://doi.org/10.3390/c901002510.3390/c9010025 ↗
45. Guluzade S, Musayeva N (2023) Room temperature detection of sulfur dioxide using functionalized carbon nanotubes. Dig J Nanomater Biostruct 18:1363–1370. https://doi.org/10.15251/DJNB.2023.184.136310.15251/DJNB.2023.184.1363 ↗
46. de Menezes BRC, Ferreira FV, Silva BC et al (2018) Effects of octadecylamine functionalization of carbon nanotubes on dispersion polarity and mechanical properties of CNT/HDPE nanocomposites. J Mater Sci 53:14311–14327. https://doi.org/10.1007/s10853-018-2627-310.1007/s10853-018-2627-3 ↗
47. Liu L, Li X, Gang Y, Cui X, Fan Bo, Dan Y, Fang J (2024) Self-powered piezoelectric sensor based on BaTiO3/MWCNTs/PVDF electrospun nanofibers for wireless alarm system. J Phys D Appl Phys 57(21):215501. https://doi.org/10.1088/1361-6463/ad2b1f10.1088/1361-6463/ad2b1f ↗
48. Lin B, Chen GD, He FA, Li Y, Yang Y, Shi Bo, Feng F-R, Chen S-Y, Lam K-H (2023) Preparation of MWCNTs/PVDF composites with high-content β form crystalline of PVDF and enhanced dielectric constant by electrospinning-hot pressing method. Diamond Relat Mater 131:109556. https://doi.org/10.1016/j.diamond.2022.10955610.1016/j.diamond.2022.109556 ↗
49. Cacciotti I, Valentini M, Raio M, Nanni F (2019) Design and development of advanced BaTiO3/MWCNTs/PVDF multi-layered systems for microwave applications. Compos Struct 224:111075. https://doi.org/10.1016/j.compstruct.2019.11107510.1016/j.compstruct.2019.111075 ↗
50. Du CH, Zhu BK, Xu YY (2007) Effects of stretching on crystalline phase structure and morphology of hard elastic PVDF fibers. J Appl Polym Sci 104:2254–2259. https://doi.org/10.1002/app.2563510.1002/app.25635 ↗
51. Cai X, Lei T, Sun D, Lin L (2017) A critical analysis of the α, β and γ phases in poly(vinylidene fluoride) using FTIR. RSC Adv 7:15382–15389. https://doi.org/10.1039/c7ra01267e10.1039/c7ra01267e ↗
52. Wu CM, Chou MH (2016) Polymorphism piezoelectricity and sound absorption of electrospun PVDF membranes with and without carbon nanotubes. Compos Sci Technol 127:127–133. https://doi.org/10.1016/j.compscitech.2016.03.00110.1016/j.compscitech.2016.03.001 ↗
53. Abbasipour M, Khajavi R, Yousefi AA, Yazdanshenas ME, Razaghian F (2017) The piezoelectric response of electrospun PVDF nanofibers with graphene oxide graphene and halloysite nanofillers: a comparative study. J Mater Sci Mater Electron 28(21):15942–15952. https://doi.org/10.1007/s10854-017-7491-410.1007/s10854-017-7491-4 ↗
54. Salam MA, Rahman QM (2018) Fundamentals of electrical circuit analysis. Springer Nature Singapore Private Ltd., Singapore. https://doi.org/10.1007/978-981-10-8624-310.1007/978-981-10-8624-3 ↗
55. Joshi S, Hegde GM, Nayak MM, Rajanna K (2013) A novel piezoelectric thin film impact sensor: application in non-destructive material discrimination. Sens Actuators A Phys 199:272–282. https://doi.org/10.1016/j.sna.2013.06.01010.1016/j.sna.2013.06.010 ↗
56. Priya S (2010) Criterion for material selection in design of bulk piezoelectric energy harvesters. IEEE Trans Ultrason Ferroelectr Freq Control 57:2610–2612. https://doi.org/10.1109/TUFFC.2010.173410.1109/TUFFC.2010.1734 ↗
57. Zhang B, Kang F, Tarascon JM, Kim JK (2016) Recent advances in electrospun carbon nanofibers and their application in electrochemical energy storage. Prog Mater Sci 76:319–380. https://doi.org/10.1016/j.pmatsci.2015.08.00210.1016/j.pmatsci.2015.08.002 ↗
58. Guan X, Zhang Y, Li H, Ou J (2013) PZT/PVDF composites doped with carbon nanotubes. Sens Actuators A Phys 194:228–231. https://doi.org/10.1016/j.sna.2013.02.00510.1016/j.sna.2013.02.005 ↗
59. Wu CM, Chou MH, Zeng WY (2018) Piezoelectric response of aligned electrospun polyvinylidene fluoride/carbon nanotube nanofibrous membranes. Nanomate 8:420. https://doi.org/10.3390/nano806042010.3390/nano8060420 ↗
60. Kim M, Kaliannagounder VK, Unnithan AR, Park CH, Kim CS, Ramachandra Kurup Sasikala A (2020) Development of In-Situ poled nanofiber based flexible piezoelectric nanogenerators for self-powered motion monitoring. Appl Sci 10(10):3493. https://doi.org/10.3390/app1010349310.3390/app10103493 ↗
61. Selvan RT, Jia CY, Jayathilaka WADM et al (2020) Enhanced piezoelectric performance of electrospun PVDF-MWCNT-Cu nanocomposites for energy harvesting application. NANO 15:2050049. https://doi.org/10.1142/S179329202050049610.1142/S1793292020500496 ↗
62. Labihi S, Chakhchaoui N, Eddiai A, El Achaby M, Meddad M, Cherkaoui O, Mazroui M (2023) Enhancement of piezoelectric β-polymorph formation and properties of graphene oxide and PZT-incorporated in PVDF-HFP matrix for energy harvesting applications. Polym Compos 44(4):2296–2304. https://doi.org/10.1002/pc.2724510.1002/pc.27245 ↗
63. Kulkarni ND, Saha A, Kumari P (2023) The development of a low-cost, sustainable bamboo-based flexible bio composite for impact sensing and mechanical energy harvesting applications. J Appl Polym Sci 140:1–13. https://doi.org/10.1002/app.5404010.1002/app.54040 ↗
64. Koç M, Tatardar F, Musayeva NN, Guluzade S, Sarı A, Paralı L (2024) The piezoelectric properties of three-phase electrospun PVDF/PZT/Multiwalled Carbone Nanotube composites for energy harvesting applications. J Alloys Compd 1003:175578. https://doi.org/10.1016/j.jallcom.2024.17557810.1016/j.jallcom.2024.175578 ↗