DataVXJournal of Materials SciencePaper
journal article·2025-05

Tuning the stable interlayer structure of SiOx-based anode materials for high-performance lithium-ion batteries

Junhui Zou, Ying Huang, Yangyang Xie, Xianping Du, Chen Chen, Jianghong Zhou, Zhao Bi, Xiaodie Xuan, Yuchen Guo, Yi Tang, Aibo Zhang, Chenhui Yang

Journal of Materials Science· Volume 60· Issue 20
Publisher page
Bibliographic record

Abstract

No abstract is available for this record. The assistant can identify its topic from the title, but cannot infer the study’s results.

Source: Not provided · Quality: missing

Research context

Energy storage

OpenAlex topics: Advancements in Battery Materials · Advanced Battery Materials and Technologies · Advanced Battery Technologies Research

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (70)

Show source-provided references
1. Chen S, Dai F, Cai M (2020) Opportunities and challenges of high-energy lithium metal batteries for electric vehicle applications. ACS Energy Lett 5:3140–3151. https://doi.org/10.1021/acsenergylett.0c0154510.1021/acsenergylett.0c01545 ↗
2. Sarma DD, Shukla AK (2018) Building better batteries: a travel back in time. ACS Energy Lett 3:2841–2845. https://doi.org/10.1021/acsenergylett.8b0196610.1021/acsenergylett.8b01966 ↗
3. Jin Y, Zhu B, Lu Z et al (2017) Challenges and recent progress in the development of Si anodes for lithium-ion battery. Adv Energy Mater 7:1–17. https://doi.org/10.1002/aenm.20170071510.1002/aenm.201700715 ↗
4. Luo W, Chen X, Xia Y et al (2017) Surface and interface engineering of silicon-based anode materials for lithium-ion batteries. Adv Energy Mater 7:1–28. https://doi.org/10.1002/aenm.20170108310.1002/aenm.201701083 ↗
5. Han J, Tang X, Ge S et al (2021) Si/C particles on graphene sheet as stable anode for lithium-ion batteries. J Mater Sci Technol 80:259–265. https://doi.org/10.1016/j.jmst.2020.11.05410.1016/j.jmst.2020.11.054 ↗
6. Ren H, Sun J, Yu R et al (2016) Controllable synthesis of mesostructures from TiO2 hollow to porous nanospheres with superior rate performance for lithium ion batteries. Chem Sci 7:793–798. https://doi.org/10.1039/c5sc03203b10.1039/c5sc03203b ↗
7. Liu H, Li W, Shen D et al (2015) Graphitic carbon conformal coating of mesoporous TiO2 hollow spheres for high-performance lithium ion battery anodes. J Am Chem Soc 137:13161–13166. https://doi.org/10.1021/jacs.5b0874310.1021/jacs.5b08743 ↗
8. Tang C, Liu Y, Xu C et al (2018) Ultrafine nickel-nanoparticle-enabled SiO2 hierarchical hollow spheres for high-performance lithium storage. Adv Funct Mater 28:1704561. https://doi.org/10.1002/adfm.20170456110.1002/adfm.201704561 ↗
9. Pei S, Guo J, He Z et al (2020) Porous Si-Cu3Si-Cu Microsphere@C core-shell composites with enhanced electrochemical lithium storage. Chem - A Eur J 26:6006–6016. https://doi.org/10.1002/chem.20190499510.1002/chem.201904995 ↗
10. Lee G, Kim S, Kim S, Choi J (2017) SiO2/TiO2 composite film for high capacity and excellent cycling stability in lithium-ion battery anodes. Adv Funct Mater 27:1703538. https://doi.org/10.1002/adfm.20170353810.1002/adfm.201703538 ↗
11. Wang S, Guan BY, Yu L, Lou XWD (2017) Rational design of three-layered TiO2@Carbon@MoS2 hierarchical nanotubes for enhanced lithium storage. Adv Mater 29:1–5. https://doi.org/10.1002/adma.20170272410.1002/adma.201702724 ↗
12. Yang S, Huang Y, Han G et al (2017) Synthesis and electrochemical performance of double shell SnO2@amorphous TiO2 spheres for lithium ion battery application. Powder Technol 322:84–91. https://doi.org/10.1016/j.powtec.2017.09.00410.1016/j.powtec.2017.09.004 ↗
13. Hwa Y, Kim WS, Yu BC et al (2013) Enhancement of the cyclability of a Si anode through Co3O4 coating by the sol-gel method. J Phys Chem C 117:7013–7017. https://doi.org/10.1021/jp401333v10.1021/jp401333v ↗
14. Liang J, Li X, Hou Z et al (2016) A deep reduction and partial oxidation strategy for fabrication of mesoporous Si anode for lithium ion batteries. ACS Nano 10:2295–2304. https://doi.org/10.1021/acsnano.5b0699510.1021/acsnano.5b06995 ↗
15. Zuo X, Zhu J, Müller-Buschbaum P, Cheng YJ (2017) Silicon based lithium-ion battery anodes: a chronicle perspective review. Nano Energy 31:113–143. https://doi.org/10.1016/j.nanoen.2016.11.01310.1016/j.nanoen.2016.11.013 ↗
16. Liu N, Wu H, McDowell MT et al (2012) A yolk-shell design for stabilized and scalable Li-ion battery alloy anodes. Nano Lett 12:3315–3321. https://doi.org/10.1021/nl301481410.1021/nl3014814 ↗
17. Wu H, Chan G, Choi JW et al (2012) Stable cycling of double-walled silicon nanotube battery anodes through solid-electrolyte interphase control. Nat Nanotechnol 7:310–315. https://doi.org/10.1038/nnano.2012.3510.1038/nnano.2012.35 ↗
18. Bae J, Kim DS, Yoo H et al (2016) High-performance Si/SiOx nanosphere anode material by multipurpose interfacial engineering with black TiO2-x. ACS Appl Mater Interfaces 8:4541–4547. https://doi.org/10.1021/acsami.5b1070710.1021/acsami.5b10707 ↗
19. Chen Y, Liu L, Xiong J et al (2015) Porous Si nanowires from cheap metallurgical silicon stabilized by a surface oxide layer for lithium ion batteries. Adv Funct Mater 25:6701–6709. https://doi.org/10.1002/adfm.20150320610.1002/adfm.201503206 ↗
20. Zhu J, Wang T, Fan F et al (2016) Atomic-scale control of silicon expansion space as ultrastable battery anodes. ACS Nano 10:8243–8251. https://doi.org/10.1021/acsnano.6b0452210.1021/acsnano.6b04522 ↗
21. Schmuelling G, Winter M, Placke T (2015) Investigating the Mg-Si binary system via combinatorial sputter deposition as high energy density anodes for lithium-ion batteries. ACS Appl Mater Interfaces 7:20124–20133. https://doi.org/10.1021/acsami.5b0538210.1021/acsami.5b05382 ↗
22. Zhao G, Meng Y, Zhang N, Sun K (2012) Electrodeposited Si film with excellent stability and high rate performance for lithium-ion battery anodes. Mater Lett 76:55–58. https://doi.org/10.1016/j.matlet.2012.02.06410.1016/j.matlet.2012.02.064 ↗
23. Li Z, Tang W, Yang Y et al (2022) Engineering prelithiation of polyacrylic acid binder: a universal strategy to boost initial coulombic efficiency for high-areal-capacity Si-based anodes. Adv Funct Mater 32:2206615. https://doi.org/10.1002/adfm.20220661510.1002/adfm.202206615 ↗
24. Zhou J, Lu Y, Yang L et al (2022) Sustainable silicon anodes facilitated via a double-layer interface engineering: Inner SiOx combined with outer nitrogen and boron co-doped carbon. Carbon Energy 4:399–410. https://doi.org/10.1002/cey2.17610.1002/cey2.176 ↗
25. Han D, Wang X, Ding W et al (2019) Phonon thermal conduction in a graphene-C3N heterobilayer using molecular dynamics simulations. Nanotechnol 30:075403. https://doi.org/10.1088/1361-6528/aaf48110.1088/1361-6528/aaf481 ↗
26. Li H, Peng J, Wu Z et al (2023) Constructing novel SiOx hybridization materials by a double-layer interface engineering for high-performance lithium-ion batteries. Chem Eng J 462:142172. https://doi.org/10.1016/j.cej.2023.14217210.1016/j.cej.2023.142172 ↗
27. Ouyang Q, Li G, Zhang X et al (2023) Towards high-capacity lithium ion batteries:constructing hollow-structured SiOx-based nanocube anode via a sequential coating strategy. Chem Eng J 460:141762. https://doi.org/10.1016/j.cej.2023.14176210.1016/j.cej.2023.141762 ↗
28. Xi F, Zhang Z, Hu Y et al (2021) PSi@SiOx/Nano-Ag composite derived from silicon cutting waste as high-performance anode material for Li-ion batteries. J Hazard Mater 414:125480. https://doi.org/10.1016/j.jhazmat.2021.12548010.1016/j.jhazmat.2021.125480 ↗
29. Han J, Wei W, Zhang C et al (2018) Engineering graphenes from the nano- to the macroscale for electrochemical energy storage. Electrochem Energy Rev 1:139–168. https://doi.org/10.1007/s41918-018-0006-z10.1007/s41918-018-0006-z ↗
30. Lim K, Lee J, Yang J et al (2014) Catalyst-free synthesis of Si-SiOx core-shell nanowire anodes for high-rate and high-capacity Lithium-Ion batteries. ACS Appl Mater Interfaces 9:6340–6345. https://doi.org/10.1021/am405618m10.1021/am405618m ↗
31. Hong F, Zhou R, Gao C et al (2023) Fabrication of porous SiOx/nanoSi@C composites with homogeneous silicon distribution for high-performance Li-ion battery anodes. J Alloys Compd 947:169511. https://doi.org/10.1016/j.jallcom.2023.16951110.1016/j.jallcom.2023.169511 ↗
32. Yuan T, Tang R, Xiao F et al (2023) Modifying SiO as a ternary composite anode material((SiOx/G/SnO2)@C) for lithium battery with high Li-ion diffusion and lower volume expansion. Electrochim Acta 439:141655. https://doi.org/10.1016/j.electacta.2022.14165510.1016/j.electacta.2022.141655 ↗
33. Zheng YQ, Yuan YF, Zhu M et al (2021) Triple-layered sandwich nanotube of carbon nanotube@TiO2 nanocrystalline@carbon with superior lithium storage performance. Mater Res Bull 133:111076. https://doi.org/10.1016/j.materresbull.2020.11107610.1016/j.materresbull.2020.111076 ↗
34. Ding M, Miao X, Cao L et al (2022) Core-shell nanostructured SiO2@a-TiO2@Ag composite with high capacity and safety for Li-ion battery anode. Mater Lett 308:131276. https://doi.org/10.1016/j.matlet.2021.13127610.1016/j.matlet.2021.131276 ↗
35. Xu C, Shen L, Zhang W et al (2023) Efficient implementation of kilogram-scale, high-capacity and long-life Si-C/TiO2 anodes. Energy Storage Mater 56:319–330. https://doi.org/10.1016/j.ensm.2023.01.02510.1016/j.ensm.2023.01.025 ↗
36. Yu R, Pan Y, Liu Y et al (2023) Constructing Sub 10 nm scale interfused TiO2/SiOx bicontinuous hybrid with mutual-stabilizing effect for lithium storage. ACS Nano 17:2568–2579. https://doi.org/10.1021/acsnano.2c1038110.1021/acsnano.2c10381 ↗
37. Zou J, Zhang S, Huang Y et al (2023) Co-doped SnS microsphere decorated carbon nanofiber flexible films for supercapacitor applications. J Alloys Compd 965:171400. https://doi.org/10.1016/j.jallcom.2023.17140010.1016/j.jallcom.2023.171400 ↗
38. Zhang S, Huang Y, Wang J et al (2023) Cu1.5Mn1.5O4 hollow sphere decorated Ti3C2Tx MXene for flexible all-solid-state supercapacitor and electromagnetic wave absorber. Carbon 209:118006. https://doi.org/10.1016/j.carbon.2023.118006.10.1016/j.carbon.2023.118006. ↗
39. Zhou N, Wu Y, Zhou Q et al (2019) Enhanced cycling performance and rate capacity of SiO anode material by compositing with monoclinic TiO2 (B). Appl Surf Sci 486:292–302. https://doi.org/10.1016/j.apsusc.2019.05.02510.1016/j.apsusc.2019.05.025 ↗
40. Xiao Z, Yu C, Lin X et al (2020) TiO2 as a multifunction coating layer to enhance the electrochemical performance of SiOx@TiO2@C composite as anode material. Nano Energy 77:105082. https://doi.org/10.1016/j.nanoen.2020.10508210.1016/j.nanoen.2020.105082 ↗
41. Zou J, Yuan S, Huang Y et al (2023) Design of SiOx/TiO2@C hierarchical structure for efficient lithium storage. Nanotechnology 34:455404. https://doi.org/10.1088/1361-6528/acee8310.1088/1361-6528/acee83 ↗
42. Zhang JJ, Wei Z, Huang T et al (2013) Carbon coated TiO2-SiO2 nanocomposites with high grain boundary density as anode materials for lithium-ion batteries. J Mater Chem A 1:7360–7369. https://doi.org/10.1039/c3ta11137g10.1039/c3ta11137g ↗
43. Zhang J, Li Y, Gao T et al (2018) Flower-shaped TiO2/C microspheres embedded with fish-scale-like MoS2 as anodes for lithium-ion batteries. Ceram Int 44:8550–8555. https://doi.org/10.1016/j.ceramint.2018.02.05910.1016/j.ceramint.2018.02.059 ↗
44. Chen X, Pang J, Zhou G, Sun B (2015) Synthesis and characterization of SiO2-PMMA-POEOMA structures and SiO2-TiO2 pomegranate-like hybrid microspheres for the photodecomposition of methyl orange. Colloids Surfaces A Physicochem Eng Asp 481:176–185. https://doi.org/10.1016/j.colsurfa.2015.04.04910.1016/j.colsurfa.2015.04.049 ↗
45. Jiang Y, Liu S, Ding Y et al (2020) Modification based on primary particle level to improve the electrochemical performance of SiOx-based anode materials. J Power Sources 467:228301. https://doi.org/10.1016/j.jpowsour.2020.22830110.1016/j.jpowsour.2020.228301 ↗
46. Xu K, Ben L, Li H, Huang X (2015) Silicon-based nanosheets synthesized by a topochemical reaction for use as anodes for lithium ion batteries. Nano Res 8:2654–2662. https://doi.org/10.1007/s12274-015-0772-410.1007/s12274-015-0772-4 ↗
47. Shi L, Wang W, Wang A et al (2016) Scalable synthesis of core-shell structured SiOx /nitrogen-doped carbon composite as a high-performance anode material for lithium-ion batteries. J Power Sources 318:184–191. https://doi.org/10.1016/j.jpowsour.2016.03.11110.1016/j.jpowsour.2016.03.111 ↗
48. Ren Y, Li M (2016) Facile synthesis of SiOx@C composite nanorods as anodes for lithium ion batteries with excellent electrochemical performance. J Power Sources 306:459–466. https://doi.org/10.1016/j.jpowsour.2015.12.06410.1016/j.jpowsour.2015.12.064 ↗
49. Liu Z, Zhao Y, He R et al (2019) Yolk@Shell SiOx/C microspheres with semi-graphitic carbon coating on the exterior and interior surfaces for durable lithium storage. Energy Storage Mater 19:299–305. https://doi.org/10.1016/j.ensm.2018.10.01110.1016/j.ensm.2018.10.011 ↗
50. Li Z, Zhao H, Lv P et al (2018) Watermelon-like structured SiOx–TiO2@C nanocomposite as a high-performance lithium-ion battery anode. Adv Funct Mater 28:1605711. https://doi.org/10.1002/adfm.20160571110.1002/adfm.201605711 ↗
51. Xu D, Chen W, Luo Y et al (2019) Amorphous TiO2 layer on silicon monoxide nanoparticles as stable and scalable core-shell anode materials for high performance lithium ion batteries. Appl Surf Sci 479:980–988. https://doi.org/10.1016/j.apsusc.2019.02.15610.1016/j.apsusc.2019.02.156 ↗
52. Kim SJ, Kim MC, Han SB et al (2016) 3D flexible Si based-composite (Si@Si3N4)/CNF electrode with enhanced cyclability and high rate capability for lithium-ion batteries. Nano Energy 27:545–553. https://doi.org/10.1016/j.nanoen.2016.08.01210.1016/j.nanoen.2016.08.012 ↗
53. Wang H, Gong Q, Huang H et al (2018) P-n heterostructured TiO2/NiO double-shelled hollow spheres for the photocatalytic degradation of papermaking wastewater. Mater Res Bull 107:397–406. https://doi.org/10.1016/j.materresbull.2018.08.01610.1016/j.materresbull.2018.08.016 ↗
54. Lu B, Ma B, Deng X et al (2018) Dual stabilized architecture of hollow Si@TiO2@C nanospheres as anode of high-performance Li-ion battery. Chem Eng J 351:269–279. https://doi.org/10.1016/j.cej.2018.06.10910.1016/j.cej.2018.06.109 ↗
55. Ren W, Zhang H, Guan C, Cheng C (2017) Ultrathin MoS2 Nanosheets@Metal organic framework-derived N-doped carbon nanowall arrays as sodium ion battery anode with superior cycling life and rate capability. Adv Funct Mater 27:1702116. https://doi.org/10.1002/adfm.20170211610.1002/adfm.201702116 ↗
56. Dou F, Weng Y, Chen G et al (2020) Volume expansion restriction effects of thick TiO2/C hybrid coatings on micro-sized SiOx anode materials. Chem Eng J 387:124106. https://doi.org/10.1016/j.cej.2020.12410610.1016/j.cej.2020.124106 ↗
57. Wang J, Huang Y, Gao Y et al (2022) The construction of carbon nanofiber composites modified by graphene/polypyrrole for flexible supercapacitors. J Energy Storage 51:104581. https://doi.org/10.1016/j.est.2022.10458110.1016/j.est.2022.104581 ↗
58. Li Z, Mi H, Liu L et al (2018) Nano-sized ZIF-8 anchored polyelectrolyte-decorated silica for nitrogen-rich hollow carbon shell frameworks toward alkaline and neutral supercapacitors. Carbon 136:176–186. https://doi.org/10.1016/j.carbon.2018.04.07510.1016/j.carbon.2018.04.075 ↗
59. Gong Q, Gao T, Huang H et al (2018) Double-shelled CeO2@C hollow nanospheres as enhanced anode materials for lithium-ion batteries. Inorg Chem Front 5:3197–3204. https://doi.org/10.1039/c8qi01068d10.1039/c8qi01068d ↗
60. Rehman S, Guo S, Hou Y (2016) Rational design of Si/SiO2@Hierarchical porous carbon spheres as efficient polysulfide reservoirs for high-performance Li-S battery. Adv Mater 28:3167–3172. https://doi.org/10.1002/adma.20150611110.1002/adma.201506111 ↗
61. Huang C, Zhao SX, Peng H et al (2018) Hierarchical porous Li4Ti5O12-TiO2 composite anode materials with pseudocapacitive effect for high-rate and low-temperature applications. J Mater Chem A 6:14339–14351. https://doi.org/10.1039/c8ta03172j10.1039/c8ta03172j ↗
62. Mahmood N, Tang T, Hou Y (2016) Nanostructured anode materials for lithium ion batteries: progress, challenge and perspective. Adv Energy Mater 6:1–22. https://doi.org/10.1002/aenm.20160037410.1002/aenm.201600374 ↗
63. Wang Y, Smarsly BM, Djerdj I (2010) Niobium doped TiO2 with mesoporosity and its application for lithium insertion. Chem Mater 22:6624–6631. https://doi.org/10.1021/cm102097710.1021/cm1020977 ↗
64. Xiao L, Cao M, Mei D et al (2013) Preparation and electrochemical lithium storage features of TiO2 hollow spheres. J Power Sources 238:197–202. https://doi.org/10.1016/j.jpowsour.2013.03.08110.1016/j.jpowsour.2013.03.081 ↗
65. Sahoo S, Kumar R, Joanni E et al (2022) Advances in pseudocapacitive and battery-like electrode materials for high performance supercapacitors. J Mater Chem A 10:13190–13240. https://doi.org/10.1039/d2ta02357a10.1039/d2ta02357a ↗
66. Wang P, Yan D, Wang C et al (2022) Study of the formation and evolution of solid electrolyte interface via in-situ electrochemical impedance spectroscopy. Appl Surf Sci 596:153572. https://doi.org/10.1016/j.apsusc.2022.15357210.1016/j.apsusc.2022.153572 ↗
67. Song G, Yi Z, Su F et al (2023) Boosting the low-temperature performance for Li-Ion batteries in LiPF6-based local high-concentration electrolyte. ACS Energy Lett 8:1336–1343. https://doi.org/10.1021/acsenergylett.2c0290310.1021/acsenergylett.2c02903 ↗
68. Liu T, Qu Y, Liu J et al (2021) Core-shell structured C@SiO2 hollow spheres decorated with nickel nanoparticles as anode materials for lithium-ion batteries. Small 17:2103673. https://doi.org/10.1002/smll.20210367310.1002/smll.202103673 ↗
69. Wei Z, Liu T, Zhang L, Yu J (2022) Sulfide-based nickel-plated fabrics for foldable quasi-solid-state supercapacitors. Energy Environ Mater 5:883–891. https://doi.org/10.1002/eem2.1220110.1002/eem2.12201 ↗
70. Xu L, Zhang L, Cheng B, Yu J (2019) Rationally designed hierarchical NiCo2O4–C@Ni(OH)2 core-shell nanofibers for high performance supercapacitors. Carbon 152:652–660. https://doi.org/10.1016/j.carbon.2019.06.06210.1016/j.carbon.2019.06.062 ↗