New epoxy resin as a high-performance corrosion inhibitor for steel: experimental and theoretical investigations

1. Yang C, Ying T, Huang A, Huang J, Chen P, Chu PK, Zeng X (2025) Enhancing corrosion resistance of MAO coatings on Al alloy LY12 through in situ co-doping with zinc phosphate and cerium phosphate. Corros Commun 17:35–43. https://doi.org/10.1016/j.corcom.2024.10.00110.1016/j.corcom.2024.10.001 ↗

2. Boutaqqa O, Ettahiri W, Adardour M, Safir E, Alanazi AS, Naamane S, Rais Z, Baouid A, Wiedmer SK, Taleb M (2025) Synthesis and assessment of benzimidazole derivatives as effective corrosion inhibitors for mild steel in acidic environments: an experimental and theoretical approach. J Mol Struct. https://doi.org/10.1016/j.molstruc.2025.14328110.1016/j.molstruc.2025.143281 ↗

3. Aslam M, Rani A, Prajapat A, Khan J, Nand B, Pandey G, Verma C, AlFantazi A, Singh P (2025) A comprehensive review on pyrazole derivatives as corrosion inhibitors: Ligand properties, coordination bonding, and interfacial adsorption. Coord Chem Rev 538:216714. https://doi.org/10.1016/j.ccr.2025.21671410.1016/j.ccr.2025.216714 ↗

4. Singh AK, Singh M, Thakur S, Pani B, Kaya S, Ibrahimi BE, Marzouki R (2022) Adsorption study of N (-benzo[d]thiazol-2-yl)-1-(thiophene-2-yl) methanimine at mild steel/aqueous H2SO4 interface. Surf Interface 33:102169. https://doi.org/10.1016/j.surfin.2022.10216910.1016/j.surfin.2022.102169 ↗

5. Km S, Praveen BM, Devendra BK (2024) A review on corrosion inhibitors: types, mechanisms, electrochemical analysis, corrosion rate and efficiency of corrosion inhibitors on mild steel in an acidic environment. Results Surf Interfaces 16:100258. https://doi.org/10.1016/j.rsurfi.2024.10025810.1016/j.rsurfi.2024.100258 ↗

6. Du P, Xie Y, Qiang Y, Li X, Deng S (2025) Tobacco stem extract/KI as a sustainable synergistic inhibitor for the corrosion of steel in H₂SO₄ media: proposal and application of an advanced impedance parameter. Corros Sci 245:112676. https://doi.org/10.1016/j.corsci.2025.11267610.1016/j.corsci.2025.112676 ↗

7. Wang X, Yang J, Chen X (2024) 2-Benzylsulfanyl-1H-benzimidazole and its mixture as highly efficient corrosion inhibitors for carbon steel under dynamic supercritical CO2 flow conditions. Corros Sci 235:112170. https://doi.org/10.1016/j.corsci.2024.11217010.1016/j.corsci.2024.112170 ↗

8. Yang J, Zhao J, Guo X, Ran Y, Fu Z, Qian H, Ma L, Keil P, Mol A, Zhang D (2025) Combinatorial discovery and investigation of the synergism of green amino acid corrosion inhibitors: integrating high-throughput experiments and interpretable machine learning approach. Corros Sci 245:112675. https://doi.org/10.1016/j.corsci.2025.11267510.1016/j.corsci.2025.112675 ↗

9. Luo Z-G, Zhang Y, Wang H, Wan S, Song L-F, Liao B-K, Guo X-P (2024) Modified nano-lignin as a novel biomass-derived corrosion inhibitor for enhanced corrosion resistance of carbon steel. Corros Sci 227:111705. https://doi.org/10.1016/j.corsci.2023.11170510.1016/j.corsci.2023.111705 ↗

10. Farh HMH, Ben Seghier MEA, Zayed T (2023) A comprehensive review of corrosion protection and control techniques for metallic pipelines. Eng Fail Anal 143:106885. https://doi.org/10.1016/j.engfailanal.2022.10688510.1016/j.engfailanal.2022.106885 ↗

11. Arun KL, Udhayakumar M, Radhika N (2022) A comprehensive review on various ceramic nanomaterial coatings over metallic substrates: applications, challenges and future trends. J Bio- Tribo-Corros 9:11. https://doi.org/10.1007/s40735-022-00717-610.1007/s40735-022-00717-6 ↗

12. Fenker M, Balzer M, Kappl H (2014) Corrosion protection with hard coatings on steel: past approaches and current research efforts. Surf Coat Technol 257:182–205. https://doi.org/10.1016/j.surfcoat.2014.08.06910.1016/j.surfcoat.2014.08.069 ↗

13. Anadebe VC, Zamindar S, Harmayanti A, Thakur A, Nnaji N, Dagdag O, Verma C, Lgaz H, Gapsari F, Banerjee P, Barik RC, Alfantazi A, Ebenso EE (2025) Multifunctional 2D materials for corrosion resistance: Graphene, MXenes and next generation emerging nanostructures. Coord Chem Rev 544:216947. https://doi.org/10.1016/j.ccr.2025.21694710.1016/j.ccr.2025.216947 ↗

14. Martínez-Viademonte MP, Abrahami ST, Hack T, Burchardt M, Terryn H (2020) A review on anodizing of Aerospace Aluminum alloys for corrosion protection. Coatings 10:1106. https://doi.org/10.3390/coatings1011110610.3390/coatings10111106 ↗

15. Liu Y, Shi J (2024) Recent progress and challenges of using smart corrosion inhibitors in reinforced concrete structures. Constr Build Mater 411:134595. https://doi.org/10.1016/j.conbuildmat.2023.13459510.1016/j.conbuildmat.2023.134595 ↗

16. Aslam R, Mobin M, Zehra S, Aslam J (2022) A comprehensive review of corrosion inhibitors employed to mitigate stainless steel corrosion in different environments. J Mol Liq 364:119992. https://doi.org/10.1016/j.molliq.2022.11999210.1016/j.molliq.2022.119992 ↗

17. Huang Z, Wu Y, Shi M, Li L, Deng Z (2024) A novel Ti3SiC2-CaB6 modified Al-coated carbon fiber/boron phenolic resin ceramizable composite (ACF/BPRC) with excellent long-term oxidative corrosion resistance and high temperature load-bearing capacity. Corros Sci 227:111796. https://doi.org/10.1016/j.corsci.2023.11179610.1016/j.corsci.2023.111796 ↗

18. Verma C, Quraishi MA, Rhee KY (2022) Aqueous phase polymeric corrosion inhibitors: recent advancements and future opportunities. J Mol Liq 348:118387. https://doi.org/10.1016/j.molliq.2021.11838710.1016/j.molliq.2021.118387 ↗

19. Ou B, Wang Y, Lu Y (2021) A review on fundamentals and strategy of epoxy-resin-based anticorrosive coating materials. Polym Plast Technol Mater 60(6):601–625. https://doi.org/10.1080/25740881.2020.181931710.1080/25740881.2020.1819317 ↗

20. Anwar S, Li X (2024) A review of high-quality epoxy resins for corrosion-resistant applications. J Coat Technol Res 21:461–480. https://doi.org/10.1007/s11998-023-00865-510.1007/s11998-023-00865-5 ↗

21. Anene UA, Alpay SP (2025) First-principles modeling of interfacial adhesion strength of epoxy resins on copper surfaces. J Phys Chem C 129:3862–3871. https://doi.org/10.1021/acs.jpcc.4c0779210.1021/acs.jpcc.4c07792 ↗

22. El-Aouni N, Dagdag O, El-Amri A, Kim H, Berdimurodov E, Berisha A, Elbachiri A, Rafik M, Berdimuradov K (2024) Synthesis and evaluation of phosphoric ester pyrogallic acid hexaglycidyl ether as a green corrosion protective agent in the gas and oil industries. J Mater Sci 59:11057–11078. https://doi.org/10.1007/s10853-024-09813-z10.1007/s10853-024-09813-z ↗

23. Iravani D, Farhadian A, Sharifi R, Berisha A, Rahimi A, Shaabani A, Qiang Y, Javidparvar AA, Martyushev DA, Akbarinezhad E (2025) Fabrication of novel Arabic gum-grafted-polyurethanes as eco-friendly corrosion inhibitors for carbon steel in sour environments: surface analysis and inhibition mechanism. Corros Sci 246:112712. https://doi.org/10.1016/j.corsci.2025.11271210.1016/j.corsci.2025.112712 ↗

24. Peng SY, Jiang ZN, Li YR, Dong CF, Liu HF, Zhang GA (2025) A new exceptional imidazoline derivative corrosion inhibitor for carbon steel in supercritical CO2 environment. Corros Sci 245:112663. https://doi.org/10.1016/j.corsci.2024.11266310.1016/j.corsci.2024.112663 ↗

25. Dagdag O, Haldhar R, Kim S-C, Guo L, Gouri ME, Berdimurodov E, Hamed O, Jodeh S, Akpan ED, Ebenso EE (2023) Recent progress in epoxy resins as corrosion inhibitors: design and performance. J Adhes Sci Technol 37:923–944. https://doi.org/10.1080/01694243.2022.205534710.1080/01694243.2022.2055347 ↗

26. Rbaa M, Dohare P, Berisha A, Dagdag O, Lakhrissi L, Galai M, Lakhrissi B, Touhami ME, Warad I, Zarrouk A (2020) New epoxy sugar based glucose derivatives as eco friendly corrosion inhibitors for the carbon steel in 1.0 M HCl: experimental and theoretical investigations. J Alloys Compd 833:154949. https://doi.org/10.1016/j.jallcom.2020.15494910.1016/j.jallcom.2020.154949 ↗

27. Hsissou R, Benhiba F, Abbout S, Dagdag O, Benkhaya S, Berisha A, Erramli H, Elharfi A (2020) Trifunctional epoxy polymer as corrosion inhibition material for carbon steel in 1.0 M HCl: MD simulations, DFT and complexation computations. Inorg Chem Commun 115:107858. https://doi.org/10.1016/j.inoche.2020.10785810.1016/j.inoche.2020.107858 ↗

28. Damej M, Hsissou R, Berisha A, Azgaou K, Sadiku M, Benmessaoud M, Labjar N, El hajjaji S (2022) New epoxy resin as a corrosion inhibitor for the protection of carbon steel C38 in 1M HCl. experimental and theoretical studies (DFT, MC, and MD). J Mol Struct 1254:132425. https://doi.org/10.1016/j.molstruc.2022.13242510.1016/j.molstruc.2022.132425 ↗

29. El-kiri Z, Hmada A, Sayed R, Dakhsi K, Larioui A, Benhiba F, Hsissou R, Dkhireche N, Galai M, EbnTouhami M (2023) Correlation between experimental and theoretical approaches in the performance of new epoxy resin as an effective corrosion inhibitor for mild steel in acid pickling bath. J Mol Struct 1294:136466. https://doi.org/10.1016/j.molstruc.2023.13646610.1016/j.molstruc.2023.136466 ↗

30. Qin L, Lu S, Liu J, Wu Y, Ma Z, Mawignon FJ, Dong G (2022) Bionic non-smooth epoxy resin coating with corrosion inhibitor for drag-reduction and durability. Prog Org Coat 173:107176. https://doi.org/10.1016/j.porgcoat.2022.10717610.1016/j.porgcoat.2022.107176 ↗

31. Ding X, Wang Q, Xu X, Nie X, Xu X, Li J (2024) A novel epoxy resin composite coating containing polyaniline modified GO with triple anti-corrosion effects of barrier, passivation and corrosion inhibition. Prog Org Coat 194:108564. https://doi.org/10.1016/j.porgcoat.2024.10856410.1016/j.porgcoat.2024.108564 ↗

32. Benabida A, Aouni NE, Galai M, El Assyry A, Dagdag O, Cherkaoui M, El Harfi A, Zarrouk A (2021) The new organic molecule-based epoxy resin as an effective corrosion inhibitor for mild steel in sulfuric acid medium. Prot Met Phys Chem Surf 57:199–210. https://doi.org/10.1134/S207020512006005210.1134/S2070205120060052 ↗

33. Abouchane M, Hsissou R, Chraka A, Molhi A, Damej M, Tassaoui K, Berisha A, Seydou M, Elemine BO, Benmessaoud M (2024) Synthesis and characterization of new macromolecular epoxy resin as an effective corrosion inhibitor for C38 steel in 1 m HCl medium: electrochemical insights, surface morphological and computational approaches. J Bio-Tribo-Corros 10:21. https://doi.org/10.1007/s40735-024-00824-610.1007/s40735-024-00824-6 ↗

34. K. Dahmani, M. Khattabi, N. Errahmany, I. Saber, M. Galai, M. Cherkaoui, A.E. Magri, R. Hsissou, A. Hmada, M.E. Touhami, A.A. AlObaid, B.M. Al-Maswari, I. Warad, Synthesis, characterization and performance of ecofriendly epoxy resin as a highly efficient corrosion inhibition for mild steel in 1m HCl solution, J. Dispers. Sci. Technol. (2024). https://www.tandfonline.com/doi/abs/https://doi.org/10.1080/01932691.2024.2417675 (accessed 21 April 2025).10.1080/01932691.2024.2417675 ↗

35. Hsissou R, El Magri A, Ech-chihbi E, Hmada A, Saber I, Berisha A, Dkhireche N, Ouzebla D, Rbaa M, Benhiba F, Khamliche L (2025) Elaboration and investigation of formulated polymer composites as some potential anticorrosion coatings for brass surface in 3.5% NaCl solution: theoretical approaches. Can Metall Q 64(3):1333–135010.1080/00084433.2024.2399872 ↗

36. Verma C, Olasunkanmi LO, Akpan ED, Quraishi MA, Dagdag O, El Gouri M, Sherif E-SM, Ebenso EE (2020) Epoxy resins as anticorrosive polymeric materials: a review. React Funct Polym 156:104741. https://doi.org/10.1016/j.reactfunctpolym.2020.10474110.1016/j.reactfunctpolym.2020.104741 ↗

37. Elhaid M, El Khabchi M, Salghi R, Id El Mouden O, Elboughdiri N, Belkhaouda M, Chafiq M, Es-Sounni B, Bakhouch M, El YazidiMahariq MI, Chaouiki A, Kang J-H, Ko YG, Abboud M (2025) Improving the surface properties of steel alloy via benzothienopyran-based inhibitor for environmental functional material with excellent electrochemical stability. Process Saf Environ Prot 198:107119. https://doi.org/10.1016/j.psep.2025.10711910.1016/j.psep.2025.107119 ↗

38. Ferkous H, Guezane-Lakoud S, Sedik A, Boublia A, Delimi A, Kahlouche A, Boulechfar C, Dilgin Y, Halim KSA, Albrahim M, Benguerba Y (2025) Tailored α-hydroxyphosphonate derivatives: Green synthesis, spectroscopic characterization, DFT analysis, and high-efficiency corrosion protection for copper in acidic media. Sustain Mater Technol 43:e01282. https://doi.org/10.1016/j.susmat.2025.e0128210.1016/j.susmat.2025.e01282 ↗

39. Salim R, Salghi R, Ech-chihbi E, Elboughdiri N, Mouhib A, Mazoir N, Bakhouch M, Hammouti B, Chafiq M, Mahariq I, Chaouiki A, Kang J-H, Ko YG (2025) Eco-friendly strategy for enhancing the surface properties of C38 steel using quinazoline-based inhibitors: theoretical and experimental approach. J Mol Struct 1334:141902. https://doi.org/10.1016/j.molstruc.2025.14190210.1016/j.molstruc.2025.141902 ↗

40. Modwi MMY, Feng H, Hadi MK, Chen N, Hou J, Kamal E, Yang K (2025) Eco-friendly corrosion inhibitor of Q235 carbon steel in 1.0 M HCl by Isatin/Chitosan Schiff base. J Mol Struct 1321:139592. https://doi.org/10.1016/j.molstruc.2024.13959210.1016/j.molstruc.2024.139592 ↗

41. Chen Q-H, Zhou Z-Y, Feng M-T, He J-H, Xu Y-Q, Liao B-K (2025) Unraveling the inhibitive performance and adsorption behavior of expired compound glycyrrhizin tablets as an eco-friendly corrosion inhibitor for copper in acidic medium. J Taiwan Inst Chem Eng 168:105913. https://doi.org/10.1016/j.jtice.2024.10591310.1016/j.jtice.2024.105913 ↗

42. Chaouche R, Tiskar M, Larhlid I, Ihamdane R, Amri AE, Mansour AA, Hsissou R, Salghi R, Cheikhi N, Chaouch A, Habsaoui A (2025) Exploring of the Origanum compactum essential oil as an ecofriendly corrosion inhibitor for mild steel in 1M HCl environment: experimental, DFT, MD, DFTB and PDOS approaches. J Mol Struct 1327:141112. https://doi.org/10.1016/j.molstruc.2024.14111210.1016/j.molstruc.2024.141112 ↗

43. Abeng FE, Thakur A, Anadebe VC, Ebenso EE (2025) A comparative density functional theory (DFT) and molecular dynamics study on Natamycin and Cefmetazole as effective corrosion inhibitor for mild steel: electronic properties and adsorption behavior. Comput Theor Chem 1248:115200. https://doi.org/10.1016/j.comptc.2025.11520010.1016/j.comptc.2025.115200 ↗

44. El-Aouni N, Dagdag O, El AmriDkhireche AN, Kim H, Berdimurodov E, El BachiriBerisha AA, Rafik M, Berdimuradov K (2024) Investigation of a novel hexafunctional epoxy resin as an anti-corrosion agent for carbon steel in an HCl environment. Chem Pap 78:7505–7523. https://doi.org/10.1007/s11696-024-03609-w10.1007/s11696-024-03609-w ↗

45. El Amri A, Hmada A, El hajriEl Amri FA, Chafiq M, Chaouiki A, Ko YG, Boukhris S, Ebn-Touhami M, Dkhireche N (2025) Development of anti-corrosive layer on steel alloy using quinoline-based inhibitor: comprehensive experimental, characterization and DFT/DFTB perspectives. Mater Today Commun 44:112082. https://doi.org/10.1016/j.mtcomm.2025.11208210.1016/j.mtcomm.2025.112082 ↗

46. El Amri A, El-Aouni N, Dagdag O, El Amri A, Rachid I, Berisha A, Kim H, Haldhar R, Rafik M, Nik WBW, Touhami ME, Dkhireche N (2025) Assessment of a new epoxy resin for corrosion prevention of mild steel in HCl environment: experimental and theoretical analyses. Electrocatalysis 16:526–547. https://doi.org/10.1007/s12678-025-00933-x10.1007/s12678-025-00933-x ↗

47. El-Aouni N, Dagdag O, El-Amri A, Kim H, Haldhar R, Kim S-C, Dkhireche N, Elbachiri A, Berisha A, Rafik M (2024) Study of new phosphorus-sulfur epoxy polymer for CS anticorrosion in HCl solution: experimental and theoretical investigations. Mater Sci Eng, B 299:117011. https://doi.org/10.1016/j.mseb.2023.11701110.1016/j.mseb.2023.117011 ↗

48. Döner A, Yıldız R, Arslanhan S, Baran MF (2025) A comprehensive analysis of Arum dioscoridis plant leaf extract as a corrosion inhibitor for mild steel in 1 M HCl: synthesis, characterization, surface analysis observations, experimental and DFT studies. J Taiwan Inst Chem Eng 169:105955. https://doi.org/10.1016/j.jtice.2025.10595510.1016/j.jtice.2025.105955 ↗

49. Praveen BM, Jeevan Chakravarthy AS, Prasanna BM, Shabanbanu BK, Devendra MKP, Fasiulla (2025) Experimental and theoretical investigation of cyclohexanone derivative (CHD) as a corrosion inhibitor for mild steel in 1 M HCl. Sci Rep 15:720. https://doi.org/10.1038/s41598-024-83054-710.1038/s41598-024-83054-7 ↗

50. Abouelenein MG, Abdeen MM, El-Shamy OAA, Mohsen Q, Deyab MA (2025) Pyranopyrazole derivative, a new corrosion inhibitor designed for managing the corrosion problem of aluminum metal in alkaline solution. Electrochim Acta 514:145675. https://doi.org/10.1016/j.electacta.2025.14567510.1016/j.electacta.2025.145675 ↗

51. Xiong L, Wu M, Liu K, Ranliang Y, Cai M, Fan X, Zhu M (2025) Inhibition mechanism and warning performance of corrosion inhibitor and fluorescent indicator combinations on AA2024-T3. Prog Org Coat 203:109171. https://doi.org/10.1016/j.porgcoat.2025.10917110.1016/j.porgcoat.2025.109171 ↗

52. Zhao B, Luo Z, Yin N, Zhang Z, Zhang X, Zhou C, Wang S, Fang Z(, Zhou D, Wang T, Pan S (2024) Al3Zr nanophase-enabled anti-corrosion mechanisms in high-strength Al alloy by scalable micro-alloying design. J Mater Sci 59:12029–12049. https://doi.org/10.1007/s10853-024-09859-z10.1007/s10853-024-09859-z ↗

53. Cao H, Xiong Z, Guo H, Lu Z, Xu Z, Bai L (2024) Mechanical degradations of Fe–C alloys induced by stress corrosion in supercritical CO2 environments: a study based on molecular dynamics simulation and machine learning. J Mater Sci 59:17609–17624. https://doi.org/10.1007/s10853-024-10188-410.1007/s10853-024-10188-4 ↗

54. Rahimi A, Farhadian A, Berisha A, Shaabani A, Varfolomeev MA, Mehmeti V, Zhong X, Yousefzadeh S, Djimasbe R (2022) Novel sucrose derivative as a thermally stable inhibitor for mild steel corrosion in 15% HCl medium: an experimental and computational study. Chem Eng J 446:136938. https://doi.org/10.1016/j.cej.2022.13693810.1016/j.cej.2022.136938 ↗

55. Ibeji CU, Akintayo DC, Oluwasola HO, Akintemi EO, Onwukwe OG, Eziomume OM (2023) Synthesis, experimental and computational studies on the anti-corrosion performance of substituted Schiff bases of 2-methoxybenzaldehyde for mild steel in HCl medium. Sci Rep 13:3265. https://doi.org/10.1038/s41598-023-30396-310.1038/s41598-023-30396-3 ↗

56. El-Aouni N, Hsissou R, Safi Z, Abbout S, Benhiba F, El Azzaoui J, Haldhar R, Wazzan N, Guo L, Erramli H, Elharfi A, El Bachiri A, Rafik M (2021) Performance of two new epoxy resins as potential corrosion inhibitors for carbon steel in 1MHCl medium: combining experimental and computational approaches. Colloids Surf A Physicochem Eng Asp 626:127066. https://doi.org/10.1016/j.colsurfa.2021.12706610.1016/j.colsurfa.2021.127066 ↗

57. Dagdag O, Safi Z, Hsissou R, Erramli H, El Bouchti M, Wazzan N, Guo L, Verma C, Ebenso EE, El Harfi A (2019) Epoxy pre-polymers as new and effective materials for corrosion inhibition of carbon steel in acidic medium: computational and experimental studies. Sci Rep 9:11715. https://doi.org/10.1038/s41598-019-48284-010.1038/s41598-019-48284-0 ↗