journal article·2025-03

Enhanced Pt/C and PtCu/C electrocatalysts for improved oxygen reduction reaction in proton-exchange membrane fuel cells

A. A. Alekseenko, K. O. Paperzh, A. S. Pavlets, S. V. Belenov, E. A. Moguchikh, A. K. Nevelskaya, Yu. A. Bayan, M. V. Danilenko, I. V. Pankov, V. E. Guterman

Journal of Materials Science· Volume 60· Issue 11
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OpenAlex topics: Electrocatalysts for Energy Conversion · Fuel Cells and Related Materials · Advanced battery technologies research

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References (70)

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1. Nørskov JK, Rossmeisl J, Logadottir A et al (2004) Origin of the overpotential for oxygen reduction at a fuel-cell cathode. J Phys Chem B 108:17886–17892. https://doi.org/10.1021/jp047349j10.1021/jp047349j ↗
2. Thompson ST, Papageorgopoulos D (2019) Platinum group metal-free catalysts boost cost competitiveness of fuel cell vehicles. Nat Catal 2:558–561. https://doi.org/10.1038/s41929-019-0291-x10.1038/s41929-019-0291-x ↗
3. Banham D, Ye S (2017) Current status and future development of catalyst materials and catalyst layers for proton exchange membrane fuel cells: an industrial perspective. ACS Energy Lett 2:629–638. https://doi.org/10.1021/acsenergylett.6b0064410.1021/acsenergylett.6b00644 ↗
4. Zhang L-L, Lu P-P, Yin M-M et al (2024) Black phosphorus nanodots-modified Pt/C electrocatalyst for methanol-tolerant oxygen reduction in direct methanol fuel cells. Rare Met. https://doi.org/10.1007/s12598-024-03039-310.1007/s12598-024-03039-3 ↗
5. Ramakrishnan S, Karuppannan M, Vinothkannan M et al (2019) Ultrafine Pt nanoparticles stabilized by MoS 2 /N-doped reduced graphene oxide as a durable electrocatalyst for alcohol oxidation and oxygen reduction reactions. ACS Appl Mater Interfaces 11:12504–12515. https://doi.org/10.1021/acsami.9b0019210.1021/acsami.9b00192 ↗
6. Sui S, Wang X, Zhou X et al (2017) A comprehensive review of Pt electrocatalysts for the oxygen reduction reaction: Nanostructure, activity, mechanism and carbon support in PEM fuel cells. J Mater Chem A Mater 5:1808–1825. https://doi.org/10.1039/C6TA08580F10.1039/C6TA08580F ↗
7. Kolluru S, Mahnot Jain G, Gollapudi D et al (2023) Recent developments in Pt-based alloy nanoparticles for oxygen reduction reaction in fuel cells. Mater Today Proc 92:764–770. https://doi.org/10.1016/j.matpr.2023.04.32010.1016/j.matpr.2023.04.320 ↗
8. Wu D, Shen X, Pan Y et al (2020) Platinum alloy catalysts for oxygen reduction reaction: advances, challenges and perspectives. ChemNanoMat 6:32–41. https://doi.org/10.1002/cnma.20190031910.1002/cnma.201900319 ↗
9. Gasteiger HA, Kocha SS, Sompalli B, Wagner FT (2005) Activity benchmarks and requirements for Pt, Pt-alloy, and non-Pt oxygen reduction catalysts for PEMFCs. Appl Catal B 56:9–35. https://doi.org/10.1016/j.apcatb.2004.06.02110.1016/j.apcatb.2004.06.021 ↗
10. Meier JC, Galeano C, Katsounaros I et al (2014) Design criteria for stable Pt/C fuel cell catalysts. Beilstein J Nanotechnol 5:44–67. https://doi.org/10.3762/bjnano.5.510.3762/bjnano.5.5 ↗
11. Garlyyev B, Kratzl K, Rück M et al (2019) Optimizing the size of platinum nanoparticles for enhanced mass activity in the electrochemical oxygen reduction reaction. Angew Chem Int Ed 58:9596–9600. https://doi.org/10.1002/anie.20190449210.1002/anie.201904492 ↗
12. Quinson J, Inaba M, Neumann S et al (2018) Investigating particle size effects in catalysis by applying a size-controlled and surfactant-free synthesis of colloidal nanoparticles in alkaline ethylene glycol: case study of the oxygen reduction reaction on Pt. ACS Catal 8:6627–6635. https://doi.org/10.1021/acscatal.8b0069410.1021/acscatal.8b00694 ↗
13. Xu S, Kim Y, Park J et al (2018) Extending the limits of Pt/C catalysts with passivation-gas-incorporated atomic layer deposition. Nat Catal 1:624–630. https://doi.org/10.1038/s41929-018-0118-110.1038/s41929-018-0118-1 ↗
14. Lim S, Kim S-I, Lee MS et al (2022) Effect of uniformity and surface morphology of Pt nanoparticles to enhance oxygen reduction reaction in polymer electrolyte membrane fuel cells. Int J Hydrogen Energy 47:29456–29466. https://doi.org/10.1016/j.ijhydene.2022.06.26410.1016/j.ijhydene.2022.06.264 ↗
15. Ma J, Tong X, Wang J et al (2019) Rare-earth metal oxide hybridized PtFe nanocrystals synthesized via microfluidic process for enhanced electrochemical catalytic performance. Electrochim Acta 299:80–88. https://doi.org/10.1016/j.electacta.2018.12.13210.1016/j.electacta.2018.12.132 ↗
16. Ma J, Wu Q, Zhang W et al (2022) Synergetic contribution of Co3+/Co2+ and FeNC in CoFe@CoFe2O4 toward efficient electrocatalysts for oxygen reduction reaction. Electrochim Acta 432:141224. https://doi.org/10.1016/j.electacta.2022.14122410.1016/j.electacta.2022.141224 ↗
17. Wang J, Ye H, Song Y (2018) In-situ reaction-growth of PtNiX nanocrystals on supports for enhanced electrochemical catalytic oxidation of ethanol via continuous flow microfluidic process. Electrochim Acta 278:149–155. https://doi.org/10.1016/j.electacta.2018.05.01310.1016/j.electacta.2018.05.013 ↗
18. Janssen M, Weber P, Oezaslan M (2023) Recent advances of various Pt-based catalysts for oxygen reduction reaction (ORR) in polymer electrolyte membrane fuel cells (PEMFCs). Curr Opin Electrochem 40:101337. https://doi.org/10.1016/j.coelec.2023.10133710.1016/j.coelec.2023.101337 ↗
19. Xiao Z, Wu H, Zhong H et al (2021) De-alloyed PtCu/C catalysts with enhanced electrocatalytic performance for the oxygen reduction reaction. Nanoscale 13:13896–13904. https://doi.org/10.1039/D1NR02820K10.1039/D1NR02820K ↗
20. Greeley J, Stephens IEL, Bondarenko AS et al (2009) Alloys of platinum and early transition metals as oxygen reduction electrocatalysts. Nat Chem 1:552–556. https://doi.org/10.1038/nchem.36710.1038/nchem.367 ↗
21. Stamenkovic V, Mun BS, Mayrhofer KJJ et al (2006) Changing the activity of electrocatalysts for oxygen reduction by tuning the surface electronic structure. Angew Chem Int Ed 45:2897–2901. https://doi.org/10.1002/anie.20050438610.1002/anie.200504386 ↗
22. Shin DY, Shin Y-J, Kim M-S et al (2021) Density functional theory–based design of a Pt-skinned PtNi catalyst for the oxygen reduction reaction in fuel cells. Appl Surf Sci 565:150518. https://doi.org/10.1016/j.apsusc.2021.15051810.1016/j.apsusc.2021.150518 ↗
23. Kong F, Ren Z, Norouzi Banis M et al (2020) Active and stable Pt–Ni alloy octahedra catalyst for oxygen reduction via near-surface atomical engineering. ACS Catal 10:4205–4214. https://doi.org/10.1021/acscatal.9b0513310.1021/acscatal.9b05133 ↗
24. Li C, Tan H, Lin J et al (2018) Emerging Pt-based electrocatalysts with highly open nanoarchitectures for boosting oxygen reduction reaction. Nano Today 21:91–105. https://doi.org/10.1016/j.nantod.2018.06.00510.1016/j.nantod.2018.06.005 ↗
25. Hou J, Yang M, Ke C et al (2020) Optimizing the structural design of a nanocomposite catalyst layer for PEM fuel cells for improving mass-specific power density. Nanoscale 12:13858–13878. https://doi.org/10.1039/D0NR02421J10.1039/D0NR02421J ↗
26. Lv H, Li D, Strmcnik D et al (2016) Recent advances in the design of tailored nanomaterials for efficient oxygen reduction reaction. Nano Energy 29:149–165. https://doi.org/10.1016/j.nanoen.2016.04.00810.1016/j.nanoen.2016.04.008 ↗
27. Ren P, Pei P, Li Y et al (2020) Degradation mechanisms of proton exchange membrane fuel cell under typical automotive operating conditions. Prog Energy Combust Sci 80:100859. https://doi.org/10.1016/j.pecs.2020.10085910.1016/j.pecs.2020.100859 ↗
28. Zhang J, Yuan Y, Gao L et al (2021) Stabilizing Pt-based electrocatalysts for oxygen reduction reaction: fundamental understanding and design strategies. Adv Mater. https://doi.org/10.1002/adma.20200649410.1002/adma.202006494 ↗
29. Ma J, Wang L, Deng Y et al (2021) Mass production of high-performance single atomic FeNC electrocatalysts via sequenced ultrasonic atomization and pyrolysis process. Sci China Mater 64:631–641. https://doi.org/10.1007/s40843-020-1464-610.1007/s40843-020-1464-6 ↗
30. Dicks AL (2006) The role of carbon in fuel cells. J Power Sources 156:128–141. https://doi.org/10.1016/j.jpowsour.2006.02.05410.1016/j.jpowsour.2006.02.054 ↗
31. Wang X, Li W, Chen Z et al (2006) Durability investigation of carbon nanotube as catalyst support for proton exchange membrane fuel cell. J Power Sources 158:154–159. https://doi.org/10.1016/j.jpowsour.2005.09.03910.1016/j.jpowsour.2005.09.039 ↗
32. Tong X, Cherif M, Zhang G et al (2021) N, P-codoped graphene dots supported on N-doped 3D graphene as metal-free catalysts for oxygen reduction. ACS Appl Mater Interfaces 13:30512–30523. https://doi.org/10.1021/acsami.1c0314110.1021/acsami.1c03141 ↗
33. Gribov EN, Kuznetsov AN, Voropaev IN et al (2016) Analysis of the corrosion kinetic of Pt/C catalysts prepared on different carbon supports under the “start-stop” cycling. Electrocatalysis 7:159–173. https://doi.org/10.1007/s12678-015-0294-610.1007/s12678-015-0294-6 ↗
34. Zhu J, Xiao M, Zhao X et al (2015) Strongly coupled Pt nanotubes/N-doped graphene as highly active and durable electrocatalysts for oxygen reduction reaction. Nano Energy 13:318–326. https://doi.org/10.1016/j.nanoen.2015.03.00210.1016/j.nanoen.2015.03.002 ↗
35. Gribov EN, Kuznetzov AN, Golovin VA et al (2014) Degradation of Pt/C catalysts in start-stop cycling tests. Russ J Electrochem. https://doi.org/10.1134/S102319351407005210.1134/S1023193514070052 ↗
36. Wang Y-Z, Ko T-H, Huang W-Y et al (2018) Preparation of Pt-catalyst by poly(p-phenylenediamine) nanocomposites assisted by microwave radiation for proton exchange membrane fuel cell. Polymers (Basel) 10:1388. https://doi.org/10.3390/polym1012138810.3390/polym10121388 ↗
37. Jukk K, Kongi N, Rauwel P et al (2016) Platinum nanoparticles supported on nitrogen-doped graphene nanosheets as electrocatalysts for oxygen reduction reaction. Electrocatalysis 7:428–440. https://doi.org/10.1007/s12678-016-0322-110.1007/s12678-016-0322-1 ↗
38. Chen Y, Wang J, Liu H et al (2011) Nitrogen doping effects on carbon nanotubes and the origin of the enhanced electrocatalytic activity of supported pt for proton-exchange membrane fuel cells. J Phys Chem C 115:3769–3776. https://doi.org/10.1021/jp108864y10.1021/jp108864y ↗
39. Roudbari MN, Ojani R, Raoof JB (2020) Nitrogen functionalized carbon nanotubes as a support of platinum electrocatalysts for performance improvement of ORR using fuel cell cathodic half-cell. Renew Energy 159:1015–1028. https://doi.org/10.1016/j.renene.2020.06.02810.1016/j.renene.2020.06.028 ↗
40. Mardle P, Ji X, Wu J et al (2020) Thin film electrodes from Pt nanorods supported on aligned N-CNTs for proton exchange membrane fuel cells. Appl Catal B 260:118031. https://doi.org/10.1016/j.apcatb.2019.11803110.1016/j.apcatb.2019.118031 ↗
41. Seo D-J, Kim M-R, Yang SY et al (2018) Nitrogen-doped carbon supported platinum catalyst via direct soft nitriding for high-performance polymer electrolyte membrane fuel cell. Int J Hydrogen Energy 43:17873–17879. https://doi.org/10.1016/j.ijhydene.2018.07.17310.1016/j.ijhydene.2018.07.173 ↗
42. Lee H-Y, Yu TH, Shin C-H et al (2023) Low temperature synthesis of new highly graphitized N-doped carbon for Pt fuel cell supports, satisfying DOE 2025 durability standards for both catalyst and support. Appl Catal B 323:122179. https://doi.org/10.1016/j.apcatb.2022.12217910.1016/j.apcatb.2022.122179 ↗
43. Danilenko MV, Guterman VE, Paperzh KO et al (2022) CO effect on the dynamics of platinum nucleation/growth under the liquid-phase synthesis of pt/c electrocatalysts. J Electrochem Soc 169:092501. https://doi.org/10.1149/1945-7111/ac8c0210.1149/1945-7111/ac8c02 ↗
44. https://www.fuelcellstore.com/ketjenblack-carbon-black-ec600jd
45. Nagai T, Jahn C, Jia H (2019) Improved accelerated stress tests for orr catalysts using a rotating disk electrode. J Electrochem Soc 166:F3111–F3115. https://doi.org/10.1149/2.0161907jes10.1149/2.0161907jes ↗
46. Alekseenko AA, Ashihina EA, Shpanko SP et al (2018) Application of CO atmosphere in the liquid phase synthesis as a universal way to control the microstructure and electrochemical performance of Pt/C electrocatalysts. Appl Catal B 226:608–615. https://doi.org/10.1016/j.apcatb.2018.01.01310.1016/j.apcatb.2018.01.013 ↗
47. Paperzh K, Alekseenko A, Safronenko O et al (2021) UV radiation effect on the microstructure and performance of electrocatalysts based on small Pt nanoparticles synthesized in the liquid phase. Colloid Interface Sci Commun 45:100517. https://doi.org/10.1016/j.colcom.2021.10051710.1016/j.colcom.2021.100517 ↗
48. Li X, Li G, Deng C et al (2023) Constructing ultrafine Pt nanoparticles anchored on N-doped porous carbon nanofibers for efficient and stable oxygen reduction reaction. Sci China Mater 66:3509–3519. https://doi.org/10.1007/s40843-023-2483-x10.1007/s40843-023-2483-x ↗
49. Harzer GS, Orfanidi A, El-Sayed H et al (2018) Tailoring Catalyst Morphology towards High Performance for Low Pt Loaded PEMFC Cathodes. J Electrochem Soc 165:F770–F779. https://doi.org/10.1149/2.0311810jes10.1149/2.0311810jes ↗
50. Zhou Y, Neyerlin K, Olson TS et al (2010) Enhancement of Pt and Pt-alloy fuel cell catalyst activity and durability via nitrogen-modified carbon supports. Energy Environ Sci 3:1437. https://doi.org/10.1039/c003710a10.1039/c003710a ↗
51. Paperzh K, Bayan Y, Gerasimov E et al (2024) High-performance electrocatalyst for PEMFC cathode: Combination of ultra-small platinum nanoparticles and N-doped carbon support. Carbon Trends 16:100383. https://doi.org/10.1016/j.cartre.2024.10038310.1016/j.cartre.2024.100383 ↗
52. Siburian R, Ali AMM, Sebayang K et al (2021) The loading effect of Pt clusters on Pt/graphene nano sheets catalysts. Sci Rep 11:2532. https://doi.org/10.1038/s41598-020-80472-110.1038/s41598-020-80472-1 ↗
53. Xue Q, Yang D, Jiang L et al (2021) Modifying carbon supports of catalyst for the oxygen reduction reaction in vehicle PEMFCs. Automot Innov 4:119–130. https://doi.org/10.1007/s42154-021-00149-x10.1007/s42154-021-00149-x ↗
54. Banerjee R, Liu Q, Tengco JMM, Regalbuto JR (2017) Detection of ambient oxidation of ultrasmall supported platinum nanoparticles with benchtop powder x-ray diffraction. Catal Letters 147:1754–1764. https://doi.org/10.1007/s10562-017-2060-210.1007/s10562-017-2060-2 ↗
55. Nagai T, Jahn C, Jia H (2019) Improved accelerated stress tests for ORR catalysts using a rotating disk electrode. J Electrochem Soc 166(7):F311110.1149/2.0161907jes ↗
56. Danilenko MV, Guterman VE, Novomlinskiy IN, Pankov IV (2023) The effect of a gas atmosphere on the formation of colloidal platinum nanoparticles in liquid phase synthesis. Colloid Polym Sci 301:433–443. https://doi.org/10.1007/s00396-023-05077-210.1007/s00396-023-05077-2 ↗
57. Kong D, Yuan W, Li C et al (2017) Synergistic effect of Nitrogen-doped hierarchical porous carbon/graphene with enhanced catalytic performance for oxygen reduction reaction. Appl Surf Sci 393:144–150. https://doi.org/10.1016/j.apsusc.2016.10.01910.1016/j.apsusc.2016.10.019 ↗
58. Jung WS, Popov BN (2017) Improved durability of Pt catalyst supported on N-doped mesoporous graphitized carbon for oxygen reduction reaction in polymer electrolyte membrane fuel cells. Carbon N Y 122:746–755. https://doi.org/10.1016/j.carbon.2017.07.02810.1016/j.carbon.2017.07.028 ↗
59. Garcia-Cardona J, Alcaide F, Brillas E et al (2021) Testing PtCu nanoparticles supported on highly ordered mesoporous carbons CMK3 and CMK8 as catalysts for low-temperature fuel cells. Catalysts 11:724. https://doi.org/10.3390/catal1106072410.3390/catal11060724 ↗
60. Caballero-Manrique G, Garcia-Cardona J, Brillas E et al (2020) Synthesis and evaluation of PtNi Electrocatalysts for CO and methanol oxidation in low temperature fuel cells. Catalysts 10:563. https://doi.org/10.3390/catal1005056310.3390/catal10050563 ↗
61. Shen Z, Tang J, Shen X (2024) Recent advances of PtCu alloy in electrocatalysis: innovations and applications. Catalysts 14:373. https://doi.org/10.3390/catal1406037310.3390/catal14060373 ↗
62. Pavlets AS, Alekseenko AA, Nikolskiy AV et al (2022) Effect of the PtCu/C electrocatalysts initial composition on their activity in the de-alloyed state in the oxygen reduction reaction. Int J Hydrogen Energy 47:30460–30471. https://doi.org/10.1016/j.ijhydene.2022.07.01410.1016/j.ijhydene.2022.07.014 ↗
63. Gatalo M, Jovanovič P, Petek U et al (2019) Comparison of Pt–Cu/C with benchmark Pt–Co/C: metal dissolution and their surface interactions. ACS Appl Energy Mater 2:3131–3141. https://doi.org/10.1021/acsaem.8b0214210.1021/acsaem.8b02142 ↗
64. Gan L, Heggen M, O’Malley R et al (2013) Understanding and controlling nanoporosity formation for improving the stability of bimetallic fuel cell catalysts. Nano Lett 13:1131–1138. https://doi.org/10.1021/nl304488q10.1021/nl304488q ↗
65. Gatalo M, Bele M, Ruiz-Zepeda F et al (2019) A double-passivation water-based galvanic displacement method for reproducible gram-scale production of high-performance platinum-alloy electrocatalysts. Angew Chem Int Ed 58:13266–13270. https://doi.org/10.1002/anie.20190356810.1002/anie.201903568 ↗
66. Garcia-Cardona J, Sirés I, Alcaide F et al (2020) Electrochemical performance of carbon-supported Pt(Cu) electrocatalysts for low-temperature fuel cells. Int J Hydrogen Energy 45:20582–20593. https://doi.org/10.1016/j.ijhydene.2020.02.03810.1016/j.ijhydene.2020.02.038 ↗
67. Garcia-Contreras MA, Gonzalez-Muñoz M (2021) Microwave-modified polyol synthesis of a PtCo electrocatalyst for the oxygen reduction reaction in acidic electrolyte. Int J Electrochem Sci 16:210750. https://doi.org/10.20964/2021.07.5310.20964/2021.07.53 ↗
68. Nassr ABAA, Sinev I, Pohl M-M et al (2014) Rapid microwave-assisted polyol reduction for the preparation of highly active PtNi/CNT electrocatalysts for methanol oxidation. ACS Catal 4:2449–2462. https://doi.org/10.1021/cs401140g10.1021/cs401140g ↗
69. Sun G-D, Cao Y-N, Hu M-Z et al (2023) Pyrrolic N-doped carbon catalysts for highly efficient electrocatalytic reduction of CO2 with superior CO selectivity over a wide potential window. Carbon N Y 214:118320. https://doi.org/10.1016/j.carbon.2023.11832010.1016/j.carbon.2023.118320 ↗
70. Gatalo M, Moriau L, Petek U et al (2019) CO-assisted ex-situ chemical activation of Pt-Cu/C oxygen reduction reaction electrocatalyst. Electrochim Acta 306:377–386. https://doi.org/10.1016/j.electacta.2019.03.15310.1016/j.electacta.2019.03.153 ↗