DataVXJournal of Materials SciencePaper
journal article·2025-02

Melt-processed cast films of calcite reinforced starch/guar-gum biopolymer composites for packaging applications

Kshitij Madhu, Manoj Kumar Dhal, Arnab Banerjee, Vimal Katiyar, Amit Kumar

Journal of Materials Science· Volume 60· Issue 5
Publisher page
Bibliographic record

Abstract

No abstract is available for this record. The assistant can identify its topic from the title, but cannot infer the study’s results.

Source: Not provided · Quality: missing

Research context

Composites

OpenAlex topics: Nanocomposite Films for Food Packaging · biodegradable polymer synthesis and properties · Advanced Cellulose Research Studies

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (84)

Show source-provided references
1. Shuai C, Peng B, Feng P, Yu L, Lai R, Min A (2022) In situ synthesis of hydroxyapatite nanorods on graphene oxide nanosheets and their reinforcement in biopolymer scaffold. J Adv Res 35:13–24. https://doi.org/10.1016/j.jare.2021.03.00910.1016/j.jare.2021.03.009 ↗
2. Shuai C, Shi X, Wang K, Gu Y, Yang F, Feng P (2024) Ag-doped CNT/HAP nanohybrids in a PLLA bone scaffold show significant antibacterial activity. Biodes Manuf 7:105–120. https://doi.org/10.1007/s42242-023-00264-010.1007/s42242-023-00264-0 ↗
3. Banerjee A, Chah CN, Dhal MK, Madhu K, Dhobale KV, Rattan B et al (2024) Microenvironment of Landfill-Mined Soil-Like Fractions (LMSF): Evaluating the Polymer Composting Potential Using Metagenomics and Geoenvironmental Characterization. Int J Environ Res 18:1–16. https://doi.org/10.1007/s41742-024-00598-210.1007/s41742-024-00598-2 ↗
4. Banerjee A, Dhal MK, Madhu K, Chah CN, Rattan B, Katiyar V et al (2024) Landfill-mined soil-like fraction (LMSF) use in biopolymer composting: Material pre-treatment, bioaugmentation and agricultural prospects. Environ Pollut 355:124255. https://doi.org/10.1016/j.envpol.2024.12425510.1016/j.envpol.2024.124255 ↗
5. Dhal MK, Madhu K, Banerjee A, Prasannavenkadesan V, Kumar A, Katiyar V (2023) Polylactic acid/polycaprolactone/sawdust based biocomposites trays with enhanced compostability. Int J Biol Macromol. https://doi.org/10.1016/j.ijbiomac.2023.12697710.1016/j.ijbiomac.2023.126977 ↗
6. Shuai C, Yang W, Feng P, Peng S, Pan H (2021) Accelerated degradation of HAP/PLLA bone scaffold by PGA blending facilitates bioactivity and osteoconductivity. Bioact Mater 6:490–502. https://doi.org/10.1016/j.bioactmat.2020.09.00110.1016/j.bioactmat.2020.09.001 ↗
7. Fabunmi OO, Tabil LG, Chang PR, Panigrahi S (2013) Developing Biodegradable Plastics from starch. https://doi.org/10.13031/2013.2417910.13031/2013.24179 ↗
8. Bradshaw IJ, Kennedy JF (1985) Starch: Chemistry and technology, 2nd edition edited by R. L. Whistler, J. N. BeMiller and E. F. Paschall, Academic Press, Orlando, Florida, 1984. pp. 736, price £53.00. ISBN 0‐12‐746270‐8. Brit Polym J 17: 377–378. https://doi.org/10.1002/pi.498017041310.1002/pi.4980170413 ↗
9. Van Soest JJG, Essers P (1997) Influence of amylose-amylopectin ratio on properties of extruded starch plastic sheets. J Macromol Sci Pure Appl Chem 34:1665–1689. https://doi.org/10.1080/1060132970801003410.1080/10601329708010034 ↗
10. Xie F, Yu L, Su B, Liu P, Wang J, Liu H et al (2009) Rheological properties of starches with different amylose/amylopectin ratios. J Cereal Sci 49:371–377. https://doi.org/10.1016/j.jcs.2009.01.00210.1016/j.jcs.2009.01.002 ↗
11. Mondal K, Ghosh T, Bhagabati P, Katiyar V (2019) Sustainable nanostructured materials in food packaging. Dynamics of Advanced Sustainable Nanomaterials and Their Related Nanocomposites at the Bio-Nano Interface, Elsevier, pp 171–213. https://doi.org/10.1016/B978-0-12-819142-2.00008-210.1016/B978-0-12-819142-2.00008-2 ↗
12. Ren L, Yan X, Zhou J, Tong J, Su X (2017) Influence of chitosan concentration on mechanical and barrier properties of corn starch/chitosan films. Int J Biol Macromol 105:1636–1643. https://doi.org/10.1016/j.ijbiomac.2017.02.00810.1016/j.ijbiomac.2017.02.008 ↗
13. Liu W, Liu S, Wang Z, Dai B, Liu J, Chen Y et al (2019) Preparation and characterization of reinforced starch-based composites with compatibilizer by simple extrusion. Carbohydr Polym. https://doi.org/10.1016/j.carbpol.2019.11512210.1016/j.carbpol.2019.115122 ↗
14. Da Róz AL, Carvalho AJF, Gandini A, Curvelo AAS (2006) The effect of plasticizers on thermoplastic starch compositions obtained by melt processing. Carbohydr Polym 63:417–424. https://doi.org/10.1016/j.carbpol.2005.09.01710.1016/j.carbpol.2005.09.017 ↗
15. Bandsholm O (2016) Modification of starch properties. Trends Polym Sci 4:128–132
16. Teixeira EM, Da Róz AL, Carvalho AJF, Curvelo AAS (2007) The effect of glycerol/sugar/water and sugar/water mixtures on the plasticization of thermoplastic cassava starch. Carbohydr Polym 69:619–624. https://doi.org/10.1016/j.carbpol.2007.01.02210.1016/j.carbpol.2007.01.022 ↗
17. Jiugao Y, Ning W, Xiaofei M (2005) The effects of citric acid on the properties of thermoplastic starch plasticized by glycerol. Starch/Staerke 57:494–504. https://doi.org/10.1002/star.20050042310.1002/star.200500423 ↗
18. Shi R, Zhang Z, Liu Q, Han Y, Zhang L, Chen D et al (2007) Characterization of citric acid/glycerol co-plasticized thermoplastic starch prepared by melt blending. Carbohydr Polym 69:748–755. https://doi.org/10.1016/j.carbpol.2007.02.01010.1016/j.carbpol.2007.02.010 ↗
19. Zhou W, Zha D, Zhang X, Xu J, Guo B, Huang Y (2020) Ordered long polyvinyl alcohol fiber-reinforced thermoplastic starch composite having comparable mechanical properties with polyethylene and polypropylene. Carbohydr Polym. https://doi.org/10.1016/j.carbpol.2020.11691310.1016/j.carbpol.2020.116913 ↗
20. Hietala M, Mathew AP, Oksman K (2013) Bionanocomposites of thermoplastic starch and cellulose nanofibers manufactured using twin-screw extrusion. Eur Polym J 49:950–956. https://doi.org/10.1016/j.eurpolymj.2012.10.01610.1016/j.eurpolymj.2012.10.016 ↗
21. Müller CMO, Laurindo JB, Yamashita F (2011) Effect of nanoclay incorporation method on mechanical and water vapor barrier properties of starch-based films. Ind Crops Prod 33:605–610. https://doi.org/10.1016/j.indcrop.2010.12.02110.1016/j.indcrop.2010.12.021 ↗
22. Sun Q, Xi T, Li Y, Xiong L (2014) Characterization of corn starch films reinforced with CaCO3 nanoparticles. PLoS ONE. https://doi.org/10.1371/journal.pone.010672710.1371/journal.pone.0106727 ↗
23. Li T, Li R, Luo H, Peng L, Wang J, Li S et al (2024) Eggshell powder as a bio-filler for starch and gelatin: ternary biodegradable composite films manufactured by extrusion compression molding. Food Hydrocoll. https://doi.org/10.1016/j.foodhyd.2023.10963210.1016/j.foodhyd.2023.109632 ↗
24. Reddy N, Yang Y (2010) Citric acid cross-linking of starch films. Food Chem 118:702–711. https://doi.org/10.1016/j.foodchem.2009.05.05010.1016/j.foodchem.2009.05.050 ↗
25. Chen L, Imam SH, Gordon SH, Greene RV (1997) Starch-polyvinyl alcohol crosslinked film-performance and biodegradation. J Environ Polym Degrad 5:111–117. https://doi.org/10.1007/BF0276359410.1007/BF02763594 ↗
26. Alias NF, Ismail H (2021) Influence of filler loading on properties of polyvinyl alcohol and eggshell powder biocomposite. Polymer 45:191–199. https://doi.org/10.7317/pk.2021.45.2.19110.7317/pk.2021.45.2.191 ↗
27. Nandi S, Guha P (2021) Organic acid-compatibilized potato starch/guar gum blend films. Mater Chem Phys. https://doi.org/10.1016/j.matchemphys.2021.12471410.1016/j.matchemphys.2021.124714 ↗
28. Saberi B, Thakur R, Vuong QV, Chockchaisawasdee S, Golding JB, Scarlett CJ et al (2016) Optimization of physical and optical properties of biodegradable edible films based on pea starch and guar gum. Ind Crops Prod 86:342–352. https://doi.org/10.1016/j.indcrop.2016.04.01510.1016/j.indcrop.2016.04.015 ↗
29. Pokhrel S, Sigdel A, Lach R, Slouf M, Sirc J, Katiyar V et al (2021) Starch-based biodegradable film with poly(butylene adipate-co-terephthalate): preparation, morphology, thermal and biodegradation properties. J Macromol Sci Part A Pure Appl Chem 58:610–621. https://doi.org/10.1080/10601325.2021.192083810.1080/10601325.2021.1920838 ↗
30. Kim CH, Cho KY, Park JK (2001) Reactive blends of gelatinized starch and polycaprolactone-g-glycidyl methacrylate. J Appl Polym Sci 81:1507–1516. https://doi.org/10.1002/app.157910.1002/app.1579 ↗
31. Zhou X, Yang R, Wang B, Chen K (2019) Development and characterization of bilayer films based on pea starch/polylactic acid and use in the cherry tomatoes packaging. Carbohydr Polym. https://doi.org/10.1016/j.carbpol.2019.05.04210.1016/j.carbpol.2019.05.042 ↗
32. Basumatary IB, Mukherjee A, Katiyar V, Dutta J, Kumar S (2022) Chitosan-based active coating for pineapple preservation: Evaluation of antimicrobial efficacy and shelf-life extension. LWT. https://doi.org/10.1016/j.lwt.2022.11394010.1016/j.lwt.2022.113940 ↗
33. Dang KM, Yoksan R (2015) Development of thermoplastic starch blown film by incorporating plasticized chitosan. Carbohydr Polym 115:575–581. https://doi.org/10.1016/j.carbpol.2014.09.00510.1016/j.carbpol.2014.09.005 ↗
34. Dang KM, Yoksan R (2016) Morphological characteristics and barrier properties of thermoplastic starch/chitosan blown film. Carbohydr Polym 150:40–47. https://doi.org/10.1016/j.carbpol.2016.04.11310.1016/j.carbpol.2016.04.113 ↗
35. Veiga-Santos P, Oliveira LM, Cereda MP, Alves AJ, Scamparini ARP (2005) Mechanical properties, hydrophilicity and water activity of starch-gum films: effect of additives and deacetylated xanthan gum. Food Hydrocoll 19:341–349. https://doi.org/10.1016/j.foodhyd.2004.07.00610.1016/j.foodhyd.2004.07.006 ↗
36. Yoshimura M, Takaya T, Nishinari K (1999) Effects of xyloglucan on the gelatinization and retrogradation of corn starch as studied by rheology and differential scanning calorimetry. Food Hydrocoll. https://doi.org/10.1016/S0268-005X(98)00075-710.1016/S0268-005X(98)00075-7 ↗
37. Chiu PE, Lai LS (2010) Antimicrobial activities of tapioca starch/decolorized hsian-tsao leaf gum coatings containing green tea extracts in fruit-based salads, romaine hearts and pork slices. Int J Food Microbiol 139:23–30. https://doi.org/10.1016/j.ijfoodmicro.2010.01.01010.1016/j.ijfoodmicro.2010.01.010 ↗
38. Dai L, Long Z, Chen J, An X, Cheng D, Khan A et al (2017) Robust guar gum/cellulose nanofibrils multilayer films with good barrier properties. ACS Appl Mater Interfaces 9:5477–5485. https://doi.org/10.1021/acsami.6b1447110.1021/acsami.6b14471 ↗
39. Ghosh T, Katiyar V (2022) Nanochitosan functionalized hydrophobic starch/guar gum biocomposite for edible coating application with improved optical, thermal, mechanical, and surface property. Int J Biol Macromol 211:116–127. https://doi.org/10.1016/j.ijbiomac.2022.05.07910.1016/j.ijbiomac.2022.05.079 ↗
40. Azevedo JB, Lazarus B, Lobo RP Jr, Barbosa WT, Seixas LF, Barbosa JDV (2023) Influence of calcium carbonate concentration on the properties of polypropylene stretched flat tapes used in raffia packaging. J Bioeng Technol Health 6:1–9. https://doi.org/10.34178/jbth.v6i1.27110.34178/jbth.v6i1.271 ↗
41. Han L, Wang Y, Liu L, Xiang FM, Huang T, Zhou ZW (2010) Crystallization, mechanical and thermal properties of sorbitol derivatives nucleated polypropylene/calcium carbonate composites. Chin J Polym Sci (Engl Ed) 28:457–466. https://doi.org/10.1007/s10118-010-9051-810.1007/s10118-010-9051-8 ↗
42. La MFP, Morreale M, Scaffaro R, Tulone S (2013) Rheological and mechanical behavior of LDPE/calcium carbonate nanocomposites and microcomposites. J Appl Polym Sci 127:2544–2552. https://doi.org/10.1002/app.3787510.1002/app.37875 ↗
43. Vrsaljko D, Macut D, Kovačevic V (2015) Potential role of nanofillers as compatibilizers in immiscible PLA/LDPE Blends. J Appl Polym Sci. https://doi.org/10.1002/app.4141410.1002/app.41414 ↗
44. Ma F, Wang B, Leng X, Wang Y, Sun Z, Wang P et al (2022) Biodegradable PBAT/PLA/CaCO3 blowing films with enhanced mechanical and barrier properties: investigation of size and content of CaCO3 particles. Macromol Mater Eng. https://doi.org/10.1002/mame.20220013510.1002/mame.202200135 ↗
45. Swain SK, Dash S, Kisku SK, Singh RK (2014) Thermal and oxygen barrier properties of chitosan bionanocomposites by reinforcement of calcium carbonate nanopowder. J Mater Sci Technol 30:791–795. https://doi.org/10.1016/j.jmst.2013.12.01710.1016/j.jmst.2013.12.017 ↗
46. Li T, Li R, Luo H, Peng L, Wang J, Li S et al (2024) Eggshell powder as a bio-filler for starch and gelatin: ternary biodegradable composite films manufactured by extrusion compression molding. Food Hydrocoll 150:109632. https://doi.org/10.1016/j.foodhyd.2023.10963210.1016/j.foodhyd.2023.109632 ↗
47. Bootklad M, Kaewtatip K (2013) Biodegradation of thermoplastic starch/eggshell powder composites. Carbohydr Polym 97:315–320. https://doi.org/10.1016/j.carbpol.2013.05.03010.1016/j.carbpol.2013.05.030 ↗
48. Bourtoom T, Chinnan MS (2008) Preparation and properties of rice starch-chitosan blend biodegradable film. LWT. https://doi.org/10.1016/j.lwt.2007.10.01410.1016/j.lwt.2007.10.014 ↗
49. Syafri E, Kasim A, Abral H, Asben A (2017) Effect of precipitated calcium carbonate on physical, mechanical and thermal properties of cassava starch bioplastic composites. Int J Adv Sci Eng Inf Technol 7:1950–1956. https://doi.org/10.18517/ijaseit.7.5.129210.18517/ijaseit.7.5.1292 ↗
50. Garcia-Diaz S, Hernandez-Jaimes C, Escalona-Buendia HB, Bello-Perez LA, Vernon-Carter EJ, Alvarez-Ramirez J (2016) Effects of CaCO3 treatment on the morphology, crystallinity, rheology and hydrolysis of gelatinized maize starch dispersions. Food Chem 207:139–147. https://doi.org/10.1016/j.foodchem.2016.03.09510.1016/j.foodchem.2016.03.095 ↗
51. Fernández-Muñoz JL, Rojas-Molina I, González-Dávalos ML, Leal M, Valtierra ME, San Martín-Martinez E et al (2004) Study of calcium ion diffusion in components of maize kernels during traditional nixtamalization process. Cereal Chem 81:65–69. https://doi.org/10.1094/CCHEM.2004.81.1.6510.1094/CCHEM.2004.81.1.65 ↗
52. Boonkanon C, Phatthanawiwat K, Chuenchom L, Lamthornkit N, Taweekarn T, Wongniramaikul W et al (2021) Preparation and characterization of calcium cross-linked starch monolithic cryogels and their application as cost-effective green filters. Polymers. https://doi.org/10.3390/polym1322397510.3390/polym13223975 ↗
53. Sharanagat VS, Saxena DC, Kumar K, Kumar Y (eds) (2023) Starch: advances in modifications, technologies and applications. Springer. https://doi.org/10.1007/978-3-031-35843-210.1007/978-3-031-35843-2 ↗
54. Shankar S, Rhim JW (2016) Preparation of nanocellulose from micro-crystalline cellulose: The effect on the performance and properties of agar-based composite films. Carbohydr Polym 135:18–26. https://doi.org/10.1016/j.carbpol.2015.08.08210.1016/j.carbpol.2015.08.082 ↗
55. Pang J, Liu X, Zhang X, Wu Y, Sun R (2013) Fabrication of cellulose film with enhanced mechanical properties in ionic liquid 1-allyl-3-methylimidaxolium chloride (AmimCl). Materials 6:1270–1284. https://doi.org/10.3390/ma604127010.3390/ma6041270 ↗
56. Chong EWN, Abdul Khalil HPS, Ying TY, Tajarudin HA (2018) Preparation and characterization of red seaweed/calcium carbonate composite films. IOP Conf Ser Mater Sci Eng. https://doi.org/10.1088/1757-899X/368/1/01204110.1088/1757-899X/368/1/012041 ↗
57. Imani M, Dimic-Misic K, Kostic M, Barac N, Janackovic D, Uskokovic P et al (2022) Achieving a superhydrophobic, moisture, oil and gas barrier film using a regenerated cellulose-calcium carbonate composite derived from paper components or waste. Sustainability. https://doi.org/10.3390/su14161042510.3390/su141610425 ↗
58. Tarique J, Sapuan SM, Khalina A (2021) Effect of glycerol plasticizer loading on the physical, mechanical, thermal, and barrier properties of arrowroot (Maranta arundinacea) starch biopolymers. Sci Rep. https://doi.org/10.1038/s41598-021-93094-y10.1038/s41598-021-93094-y ↗
59. Rammak T, Boonsuk P, Kaewtatip K (2021) Mechanical and barrier properties of starch blend films enhanced with kaolin for application in food packaging. Int J Biol Macromol 192:1013–1020. https://doi.org/10.1016/j.ijbiomac.2021.10.08110.1016/j.ijbiomac.2021.10.081 ↗
60. Al-Hassan AA, Norziah MH (2012) Starch–gelatin edible films: water vapor permeability and mechanical properties as affected by plasticizers. Food Hydrocoll 26:108–117. https://doi.org/10.1016/J.FOODHYD.2011.04.01510.1016/J.FOODHYD.2011.04.015 ↗
61. Jafarzadeh S, Alias AK, Ariffin F, Mahmud S, Najafi A (2016) Preparation and characterization of bionanocomposite films reinforced with nano kaolin. J Food Sci Technol 53:1111–1119. https://doi.org/10.1007/s13197-015-2017-710.1007/s13197-015-2017-7 ↗
62. García MA, Martino MN, Zaritzky NE (2000) Microstructural characterization of plasticized starch-based films. Starch/Staerke 52:118–124. https://doi.org/10.1002/1521-379X(200006)52:4%3c118::AID-STAR118%3e3.0.CO;2-010.1002/1521-379X(200006)52:4<118::AID-STAR118>3.0.CO;2-0 ↗
63. Dome K, Podgorbunskikh E, Bychkov A, Lomovsky O (2020) Changes in the crystallinity degree of starch having different types of crystal structure after mechanical pretreatment. Polymers. https://doi.org/10.3390/polym1203064110.3390/polym12030641 ↗
64. de Oliveira Barros M, Mattos ALA, de Almeida JS, de Freitas Rosa M, de Brito ES (2023) Effect of ball-milling on starch crystalline structure, gelatinization temperature, and rheological properties: towards enhanced utilization in thermosensitive systems. Foods. https://doi.org/10.3390/foods1215292410.3390/foods12152924 ↗
65. Ungár T (2004) Microstructural parameters from X-ray diffraction peak broadening. Scr Mater 51:777–781. https://doi.org/10.1016/j.scriptamat.2004.05.00710.1016/j.scriptamat.2004.05.007 ↗
66. Holder CF, Schaak RE (2019) Tutorial on powder X-ray diffraction for characterizing nanoscale materials. ACS Nano 13:7359–7365. https://doi.org/10.1021/acsnano.9b0515710.1021/acsnano.9b05157 ↗
67. Wu H, Li T, Peng L, Wang J, Lei Y, Li S et al (2023) Development and characterization of antioxidant composite films based on starch and gelatin incorporating resveratrol fabricated by extrusion compression moulding. Food Hydrocoll. https://doi.org/10.1016/j.foodhyd.2023.10850910.1016/j.foodhyd.2023.108509 ↗
68. Xu B, Poduska KM (2014) Linking crystal structure with temperature-sensitive vibrational modes in calcium carbonate minerals. Phys Chem Chem Phys 16:17634–17639. https://doi.org/10.1039/c4cp01772b10.1039/c4cp01772b ↗
69. Elsaeed SM, Zaki EG, Omar WA, Ashraf Soliman A, Attia AM (2021) Guar gum-based hydrogels as potent green polymers for enhanced oil recovery in high-salinity reservoirs. ACS Omega 6:23421–23431. https://doi.org/10.1021/acsomega.1c0335210.1021/acsomega.1c03352 ↗
70. Zhang X, Jiang X, Jiang T, Gan L, Zhang X, Dai H (2012) The plasticizing mechanism and effect of calcium chloride on starch/poly(vinyl alcohol) films. Carbohydr Polym 90:1677–1684. https://doi.org/10.1016/j.carbpol.2012.07.05010.1016/j.carbpol.2012.07.050 ↗
71. Zhang S, Lin Z, Jiang G, Wang J, Wang DY (2018) Construction of chelation structure between Ca2+ and starch via reactive extrusion for improving the performances of thermoplastic starch. Compos Sci Technol 159:59–69. https://doi.org/10.1016/j.compscitech.2018.02.02710.1016/j.compscitech.2018.02.027 ↗
72. Sanyang ML, Sapuan SM, Jawaid M, Ishak MR, Sahari J (2016) Effect of plasticizer type and concentration on physical properties of biodegradable films based on sugar palm (arenga pinnata) starch for food packaging. J Food Sci Technol 53:326–336. https://doi.org/10.1007/s13197-015-2009-710.1007/s13197-015-2009-7 ↗
73. Dawam Abdu AH, Pudjirahar S, Karina M, Dwi Putri O, Fauziyyah RH (2018) Fabrication and characterization of sweet potato starch-based bioplastics plasticized with glycerol. J Biol Sci 19:57–64. https://doi.org/10.3923/jbs.2019.57.6410.3923/jbs.2019.57.64 ↗
74. Versino F, García MA (2014) Cassava (Manihot esculenta) starch films reinforced with natural fibrous filler. Ind Crops Prod 58:305–314. https://doi.org/10.1016/j.indcrop.2014.04.04010.1016/j.indcrop.2014.04.040 ↗
75. Saurabh CK, Gupta S, Bahadur J, Mazumder S, Variyar PS, Sharma A (2015) Mechanical and barrier properties of guar gum based nano-composite films. Carbohydr Polym 124:77–84. https://doi.org/10.1016/j.carbpol.2015.02.00410.1016/j.carbpol.2015.02.004 ↗
76. Carvalho AJF (2008) Starch: major sources, properties and applications as thermoplastic materials. Monom Polym Compos Renew Resour. https://doi.org/10.1016/B978-0-08-045316-3.00015-610.1016/B978-0-08-045316-3.00015-6 ↗
77. Zhang G, Verdugo-Escamilla C, Choquesillo-Lazarte D, García-Ruiz JM (2018) Thermal assisted self-organization of calcium carbonate. Nat Commun. https://doi.org/10.1038/s41467-018-07658-010.1038/s41467-018-07658-0 ↗
78. Paluch M, Ostrowska J, Tyński P, Sadurski W, Konkol M (2022) Structural and thermal properties of starch plasticized with glycerol/urea mixture. J Polym Environ 30:728–740. https://doi.org/10.1007/s10924-021-02235-x10.1007/s10924-021-02235-x ↗
79. Schlemmer D, Angélica RS, Sales MJA (2010) Morphological and thermomechanical characterization of thermoplastic starch/montmorillonite nanocomposites. Compos Struct 92:2066–2070. https://doi.org/10.1016/j.compstruct.2009.10.03410.1016/j.compstruct.2009.10.034 ↗
80. Lule ZC, Kim J (2021) Properties of economical and eco-friendly polybutylene adipate terephthalate composites loaded with surface treated coffee husk. Compos Part A Appl Sci Manuf. https://doi.org/10.1016/j.compositesa.2020.10615410.1016/j.compositesa.2020.106154 ↗
81. Ashok B, Naresh S, Reddy KO, Madhukar K, Cai J, Zhang L et al (2014) Tensile and thermal properties of poly(lactic acid)/eggshell powder composite films. Int J Polym Anal Charact 19:245–255. https://doi.org/10.1080/1023666X.2014.87963310.1080/1023666X.2014.879633 ↗
82. Li M, Liu P, Zou W, Yu L, Xie F, Pu H et al (2011) Extrusion processing and characterization of edible starch films with different amylose contents. J Food Eng 106:95–101. https://doi.org/10.1016/j.jfoodeng.2011.04.02110.1016/j.jfoodeng.2011.04.021 ↗
83. González Seligra P, Medina Jaramillo C, Famá L, Goyanes S (2016) Data of thermal degradation and dynamic mechanical properties of starch-glycerol based films with citric acid as crosslinking agent. Data Brief 7:1331–1334. https://doi.org/10.1016/j.dib.2016.04.01210.1016/j.dib.2016.04.012 ↗
84. Ferrari F, Greco A (2018) Thermal analysis of self-healing thermoplastic matrix nanocomposite from cyclic butylene terephthalate. J Therm Anal Calorim 134:567–574. https://doi.org/10.1007/s10973-018-7135-910.1007/s10973-018-7135-9 ↗