journal article·2019-08

Multi-walled carbon nanotube-reinforced boron carbide matrix composites fabricated via ultra-high-pressure sintering

Bing Wang, Yuan Wang, Yun Zhou, Fugang Qi, Qiujie Ding, Junyu Li, Xiaoping OuYang, Lixin Liu

Journal of Materials Science· Volume 54· Issue 16
Publisher page

Abstract

To well preserve the fine structure of MWCNTs in the fabrication of ceramic matrix composites, an ultra-high-pressure sintering method is employed here. The effects of the MWCNTs on the microstructure and properties of the composites are investigated. The B4C-MWCNTs composites are prepared under the pressure of 4.5 GPa at a low sintering temperature of 1300 °C for 10 min. The results indicate that the densification method is beneficial to protect MWCNTs from destruction and create a good interfacial combination between the MWCNTs and the matrix. The indentation crack length of the B4C-MWCNTs composites decreases and the electrical conductivity increases continuously with the increase of MWCNTs additive amount, reaching the optimum values at 5 vol% MWCNTs addition. The microstructural observations indicate that the reinforcement mechanism of the composites is mainly the crack branching, crack deflection, bridging, and pullout of MWCNTs. This finding provides a promising approach for producing more robust ceramics with CNTs reinforcing.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Boron and Carbon Nanomaterials Research · Advanced ceramic materials synthesis · Aluminum Alloys Composites Properties

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (34)

Show source-provided references
1. Thévenot F (1990) Boron carbide—a comprehensive review. J Eur Ceram Soc 6(4):205–22510.1016/0955-2219(90)90048-K ↗
2. Domnich V, Reynaud S, Haber RA, Manish C (2011) Boron carbide: structure, properties, and stability under stress. J Am Ceram Soc 94(11):3605–362810.1111/j.1551-2916.2011.04865.x ↗
3. Yamada S, Hirao K, Yamauchi Y, Kanzaki S (2003) High strength B4C–TiB2 composites fabricated by reaction hot-pressing. J Eur Ceram Soc 23(7):1123–113010.1016/S0955-2219(02)00274-1 ↗
4. Stoto T, Housseau N, Zuppiroli L, Kryger B (1990) Swelling and microcracking of boron carbide subjected to fast neutron irradiations. J Appl Phys 68(7):3198–320610.1063/1.346370 ↗
5. Kobayashi T, Yoshida K, Yano T (2013) Microstructure, mechanical and thermal properties of B4C/CNT composites with Al additive. J Nucl Mater 440(1):524–52910.1016/j.jnucmat.2013.02.061 ↗
6. Ipek M, Zeytin S, Bindal C (2011) An evaluation of Al2O3–ZrO2 composites produced by coprecipitation method. J Alloys Compd 509(2):486–48910.1016/j.jallcom.2010.09.073 ↗
7. Sarkar S, Das PK (2012) Microstructure and physicomechanical properties of pressureless sintered multiwalled carbon nanotube/alumina nanocomposites. Ceram Int 38(1):423–43210.1016/j.ceramint.2011.07.023 ↗
8. Iijima S (1991) Helical microtubules of graphitic carbon. Nature 354:5610.1038/354056a0 ↗
9. Ruoff RS (2018) Strong bundles based on carbon nanotubes. Nat Nanotechnol 13(7):533–53410.1038/s41565-018-0184-1 ↗
10. Hanzel O, Sedláček J, Šajgalík P (2014) New approach for distribution of carbon nanotubes in alumina matrix. J Eur Ceram Soc 34(7):1845–185110.1016/j.jeurceramsoc.2014.01.020 ↗
11. Jiang D, Thomson K, Kuntz J, Ager J, Mukherjee A (2007) Effect of sintering temperature on a single-wall carbon nanotube-toughened alumina-based nanocomposite. Scr Mater 56(11):959–96210.1016/j.scriptamat.2007.02.007 ↗
12. Inam F, Yan H, Reece MJ, Peijs T (2010) Structural and chemical stability of multiwall carbon nanotubes in sintered ceramic nanocomposite. Adv Appl Ceram 109(4):240–24710.1179/174367509X12595778633336 ↗
13. Gallardo-López A, Poyato R, Morales-Rodríguez A, Fernández-Serrano A, Muñoz A, Domínguez-Rodríguez A (2014) Hardness and flexural strength of single-walled carbon nanotube/alumina composites. J Mater Sci 49(20):7116–7123. https://doi.org/10.1007/s10853-014-8419-510.1007/s10853-014-8419-5 ↗
14. Liu L, Li X, He Q, Xu L, Cao X, Peng X, Meng C, Wang W, Zhu W, Wang Y (2018) Sintering dense boron carbide without grain growth under high pressure. J Am Ceram Soc 101(3):1289–129710.1111/jace.15282 ↗
15. Zhao Z, Yang Z, Hu Y, Li J, Fan X (2013) Multiple functionalization of multi-walled carbon nanotubes with carboxyl and amino groups. Appl Surf Sci 276:476–48110.1016/j.apsusc.2013.03.119 ↗
16. Zhan GD, Mukherjee AK (2004) Carbon nanotube reinforced alumina-based ceramics with novel mechanical, electrical, and thermal properties. Int J Appl Ceram Technol 1(2):161–17110.1111/j.1744-7402.2004.tb00166.x ↗
17. Mohammad K, Saheb N (2016) Molecular level mixing: an approach for synthesis of homogenous hybrid ceramic nanocomposite powders. Powder Technol 291:121–13010.1016/j.powtec.2015.12.012 ↗
18. Bocanegra-Bernal MH, Dominguez-Rios C, Echeberria J, Reyes-Rojas A, Garcia-Reyes A, Aguilar-Elguezabal A (2016) Spark plasma sintering of multi-, single/double- and single-walled carbon nanotube-reinforced alumina composites: Is it justifiable the effort to reinforce them? Ceram Int 42(1, Part B):2054–206210.1016/j.ceramint.2015.09.060 ↗
19. Rul S, Lefevre-schlick F, Capria E, Laurent Ch, Peigney A (2003) Percolation of single-walled carbon nanotubes in ceramic matrix nanocomposites. Acta Mater 52:1061–106710.1016/j.actamat.2003.10.038 ↗
20. Poyato R, Vasiliev AL, Padture NP, Tanaka H, Nishimura T (2006) Aqueous colloidal processing of single-wall carbon nanotubes and their composites with ceramics. Nanotechnology 17:1770–177710.1088/0957-4484/17/6/038 ↗
21. Li Q, Dong L, Fang J, Xiong C (2010) Property–structure relationship of nanoscale ionic materials based on multiwalled carbon nanotubes. ACS Nano 4(10):5797–580610.1021/nn101542v ↗
22. Liu L, Wang Y, Li X, Xu L, Cao X, Wang Y, Wang Z, Meng C, Zhu W, Ouyang X, Sglavo V (2016) Enhancing toughness in boron carbide with reduced graphene oxide. J Am Ceram Soc 99(1):257–26410.1111/jace.13943 ↗
23. Sedlák R, Kovalčíková A, Múdra E, Rutkowski P, Dubiel A, Girman V, Bystrický R, Dusza J (2017) Boron carbide/graphene platelet ceramics with improved fracture toughness and electrical conductivity. J Eur Ceram Soc 37(12):3773–378010.1016/j.jeurceramsoc.2017.04.061 ↗
24. Stobinski L, Lesiak B, Kövér L, Tóth J, Biniak S, Trykowski G, Judek J (2010) Multiwall carbon nanotubes purification and oxidation by nitric acid studied by the FTIR and electron spectroscopy methods. J Alloys Compd 501(1):77–8410.1016/j.jallcom.2010.04.032 ↗
25. Kuila BK, Park K, Dai L (2010) Soluble P3HT-grafted carbon nanotubes: synthesis and photovoltaic application. Macromolecules 43(16):6699–670510.1021/ma100917p ↗
26. Wang FF, Li N, Tian D, Xia GF, Xiao N (2010) Efficient synthesis of fullerenol in anion form for the preparation of electrodeposited films. ACS Nano 4(10):5565–557210.1021/nn100485g ↗
27. Vartapetyan RS, Voloshchuk A, Shumilina E (1993) The critical size of clusters of water molecules on a carbon surface. Russ Chem Bull 42(1):46–4810.1007/BF00699971 ↗
28. Fan J, Zhao D, Wu M, Xu Z, Song J (2006) Preparation and microstructure of multi-wall carbon nanotubes-toughened Al2O3 composite. J Am Ceram Soc 89(2):750–75310.1111/j.1551-2916.2005.00774.x ↗
29. Kovalčíková A, Balázsi C, Dusza J, Tapasztó O (2012) Mechanical properties and electrical conductivity in a carbon nanotube reinforced silicon nitride composite. Ceram Int 38(1):527–53310.1016/j.ceramint.2011.07.038 ↗
30. Kang S-Z, D-e Yin, Li X, Mu J (2011) A facile preparation of multiwalled carbon nanotubes modified with hydroxyl groups and their high dispersibility in ethanol. Colloid Surface A 384(1–3):363–36710.1016/j.colsurfa.2011.04.036 ↗
31. Chen Y, Feng Y, Wang Y, Mo F, Qian G, Yu D, Liu W, Zhang X (2017) Well-dispersed carbon nanotubes for greatly enhanced mechanical properties of alumina-based composites. Refract Ind Ceram 58(2):188–19310.1007/s11148-017-0079-y ↗
32. Zhang X, Zhang Z, Wen R, Wang G, Zhang X, Mu J, Che H, Wang W (2018) Comparisons of the densification, microstructure and mechanical properties of boron carbide sintered by hot pressing and spark plasma sintering. Ceram Int 44(2):2615–261910.1016/j.ceramint.2017.10.230 ↗
33. Ghobadi H, Ebadzadeh T, Sadeghian Z, Barzegar-Bafrooei H, Nemati A (2017) Microwave-assisted sintering of Al2O3-MWCNT nanocomposites. Ceram Int 43(8):6105–610910.1016/j.ceramint.2017.02.003 ↗
34. Zhan G-D, Kuntz JD, Garay JE, Mukherjee AK (2003) Electrical properties of nanoceramics reinforced with ropes of single-walled carbon nanotubes. Appl Phys Lett 83(6):1228–123010.1063/1.1600511 ↗