Combined effects of multi-interfacial furfurylation and densification on mechanical-physical performances of fast-growing poplar wood
Source abstract
Abstract
Upgrading low-quality wood with less consumption of modifier is demanded in sustainable development of wood industry. In this study, multi-interfacial furfurylation combined with densification was proposed to improve performances of wood. Different from traditional furfurylation, the multi-interfacial furfurylation comprised internal impregnation with 10% concentration furfuryl alcohol (FA) and surface coating with reused FA. After combined treatments, FA polymerized on wood surface, and also penetrated into cell lumina and cell walls. Some cell walls became closer and almost attached together. Wood mass increased by 12.6% and density reached 860 kg m−3. The set recovery of densified wood decreased by over 92% due to multi-interfacial furfurylation. On account of density increase and multi-interfacial interactions among FA from wood surface to inner parts principally, the mechanical properties were significantly improved with over 260% increase of flexural strength and 50% enhancement of impact toughness. Physical properties were improved indicated by reduction of surface wettability, dynamic moisture sorption and water absorption mainly due to hydrophobicity increase, accessible sorption site decrease, water-path block and accommodation reduction for water molecules. The results can help facilitate better application of low-quality wood for building more efficient and environmentally friendly material industry.
Source: expertdata · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Wood Treatment and Properties · Lignin and Wood Chemistry · Advanced Cellulose Research Studies
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (46)
Show source-provided references
1. Wang L, Toppinen A, Juslin H (2014) Use of wood in green building: a study of expert perspectives from the UK. J Clean Prod 65:350–361. https://doi.org/10.1016/j.jclepro.2013.08.02310.1016/j.jclepro.2013.08.023 ↗
2. Li K, Jin S, Zhou Y, Zhang FD, Zeng JD, Li JJ, Shi SQ, Li JZ (2022) Bioinspired dual-crosslinking strategy for fabricating soy protein-based adhesives with excellent mechanical strength and antibacterial activity. Compos B 240:109987. https://doi.org/10.1016/j.compositesb.2022.10998710.1016/j.compositesb.2022.109987 ↗
3. Milner H, Woodard A (2016) Sustainability of engineered wood products. Woodhead Publishing, Sawston, Cambridge10.1016/B978-0-08-100370-1.00008-1 ↗
4. Logging and Export Bans (2021) The Forest Legality Initiative, World resources institute. https://forestlegality.org/content/logging-and-exportbans. Accessed 28 Mar 2022
5. Cossalter C, Pye-Smith C (2003) Fast-wood forestry: myths and realities. Center for International Forestry Research, Jakarta
6. Qiu HB, Han YM, Fan DB, Li GY, Chu FX (2018) Progress in chemical modification of fast-growing wood. Mater Rev 32:2701–2708. https://doi.org/10.13466/j.cnki.lyzygl.2014.01.00110.13466/j.cnki.lyzygl.2014.01.001 ↗
7. Wang F, Zhang Z (2017) Catalytic transfer hydrogenation of furfural into furfuryl alcohol over magnetic γ-Fe2O3@HAP Catalyst. ACS Sustain Chem Eng 5:942–947. https://doi.org/10.1039/C9NJ04698D10.1039/C9NJ04698D ↗
8. Gong W, Chen C, Zhang Y, Zhou H, Wang H, Zhang H, Zhang Y, Wang G, Zhao H (2017) Efficient synthesis of furfuryl alcohol from H2-hydrogenation/transfer hydrogenation of furfural using sulfonate group modified Cu catalyst. ACS Sustain Chem Eng 5:2172–2180. https://doi.org/10.1021/acssuschemeng.6b0234310.1021/acssuschemeng.6b02343 ↗
9. Skrede I, Solbakken MH, Hess J, Fossdal CG, Hegnar O, Alfredsen G (2019) Wood modification by furfuryl alcohol caused delayed decomposition response in Rhodonia (Postia) placenta. Appl Environ Microbiol 85:e00338-e419. https://doi.org/10.1128/AEM.00338-1910.1128/AEM.00338-19 ↗
10. Li WJ, Liu MH, Wang HK, Yu Y (2020) Fabrication of highly stable and durable furfurylated wood materials. part i: process optimization. Holzforschung 74:1135–1146. https://doi.org/10.1515/hf-2019-028610.1515/hf-2019-0286 ↗
11. Lande S, Westin M, Schneider M (2004) Properties of furfurylated wood. Scand J For Res 19:22–30. https://doi.org/10.1080/028275804100191510.1080/0282758041001915 ↗
12. Pilgård A, De Vetter L, Van Acker J, Westin M (2010) Toxic hazard of leachates from furfurylated wood: comparison between two different aquatic organisms. Environ Toxicol Chem 29:1067–1071. https://doi.org/10.1002/etc.13210.1002/etc.132 ↗
13. Epmeier H (2004) Differently modified wood: comparison of some selected properties. Scand J For Res 19(5):31–37. https://doi.org/10.1080/0282758041001782510.1080/02827580410017825 ↗
14. Zheng BP, Bi CQ, Zhu RF, Sun JF, Wen XF, Chen FD, Liu Y, Gao JG (2015) Study on toughened furan resin chemically modified by poly(ethylene glycol)s. J Anhui Polytech Univer 30(1):40–43
15. Sejati PS, Imbert A, Christine GC, Dumarcay S, Fredon E, Masson E, Nandika D, Priadi T, Gérardi P, (2017) Tartaric acid catalyzed furfurylation of beech wood. Wood Sci Technol 51(2):379–394. https://doi.org/10.1007/s00226-016-0871-810.1007/s00226-016-0871-8 ↗
16. Zhang SY (2011) Chemical components effect on mechanical properties of wood cell wall. Chinese Academy of Forestry, Beijing
17. Pfriem A, Dietrich T, Buchelt B (2012) Furfuryl alcohol impregnation for improved plasticization and fixation during the densification of wood. Holzforschung 66(2):215–218. https://doi.org/10.1515/HF.2011.13410.1515/HF.2011.134 ↗
18. Navi P, Girardet F (2000) Effects of thermo-hydro-mechanical treatment on the structure and properties of wood. Holzforschung 54:287–293. https://doi.org/10.1515/HF.2000.04810.1515/HF.2000.048 ↗
19. Vorreiter L (1934) Lignostone, das neue Holzveredlungserzeugnis. Forftwiffenfchaftliches Centralblatt 56:533–542. https://doi.org/10.1007/BF0181921710.1007/BF01819217 ↗
20. Shams MI, Yano H, Endou K (2004) Compressive deformation of wood impregnated with low molecular weight phenol formaldehyde (PF) resin I: effects of pressing pressure and pressure holding. J Wood Sci 50:337–342. https://doi.org/10.1007/s10086-003-0570-610.1007/s10086-003-0570-6 ↗
21. Gabrielli C, Kamke FA (2010) Phenol-formaldehyde impregnation of densified wood for improved dimensional stability. Wood Sci Technol 44:95–10410.1007/s00226-009-0253-6 ↗
22. Schmitt CR (1974) Polyfurfuryl alcohol resins. J Macromol Sci: Part D—Rev Polym Process 3(2):121–158. https://doi.org/10.1080/0360255740854502510.1080/03602557408545025 ↗
23. Schneider MH (2002) Furan polymer impregnated wood. WO 02/060600 A1.
24. Hill CAS (2006) Wood modification: chemical, thermal and other processes. Wiley, Hoboken, Chichester10.1002/0470021748 ↗
25. Liu MH, Lyu SY, Cai LP, Peng LM, Tang J, Huang ZH, Lyu JX (2021) Performance improvement of radiata pine wood by combining impregnation of furfuryl alcohol resin and densification for making fretboard materials. Ind Crops Prod 172:11402910.1016/j.indcrop.2021.114029 ↗
26. Yang TT, Cao JZ, Mei CT, Ma EN (2022) Inhibiting wood-water interactions by hydrothermal hemicellulose extraction combined with furfurylation. Holzforschung 76(3):245–25510.1515/hf-2021-0078 ↗
27. Wang JM, Yang TT, Zhang SD, Cao JZ (2022) Application of polyvinyl alcohol (PVA) as a toughening agent in wood furfurylation. Holzforschung. https://doi.org/10.1515/hf-2021-014410.1515/hf-2021-0144 ↗
28. Acosta AP, Beltrame R, Missio AL, Amico S, de Delucis R, A, Gatto DA, (2022) Furfurylation as a post-treatment for thermally-treated wood. Biomass Convers Biorefin. https://doi.org/10.1007/s13399-022-02821-610.1007/s13399-022-02821-6 ↗
29. Thygesen LG, Barsberg S, Venas TM (2010) The fluorescence characteristics of furfurylated wood studied by fluorescence spectroscopy and confocal laser scanning microscopy. Wood Sci Technol 44(1):51–65. https://doi.org/10.1007/s00226-009-0255-410.1007/s00226-009-0255-4 ↗
30. Yang TT, Ma EN, Cao JZ (2019) Synergistic effects of partial hemicellulose removal and furfurylation on improving the dimensional stability of poplar wood tested under dynamic condition. Ind Crops Prod 139:111550. https://doi.org/10.1016/j.indcrop.2019.11155010.1016/j.indcrop.2019.111550 ↗
31. Sing KSW, Everett DH, Haul RAW, Moscou L, Pierotti RA, Rouquerol J, Siemieniewska T (1985) Reporting physisorption data for gas-solid systems. Pure Appl Chem 57:603–61910.1351/pac198557040603 ↗
32. Lu CW, Liu YP, Wang CP, Yong Q, Wang JF, Chu FX (2022) An integrated strategy to fabricate bio-based dual-cure and toughened epoxy thermosets with photothermal conversion property. Chem Eng J 433:13458210.1016/j.cej.2022.134582 ↗
33. Popescu CM, Hill CAS, Curling S, Ormondroyd G, Xie YJ (2014) The water vapour sorption behaviour of acetylated birch wood: how acetylation affects the sorption isotherm and accessible hydroxyl content. J Mater Sci 49:2362–2371. https://doi.org/10.1007/s10853-013-7937-x10.1007/s10853-013-7937-x ↗
34. Zhang FD, Xu CH, Li MY, Huang AM, Sun SQ (2014) Rapid identification of Pterocarpus santalinus and Dalbergia louvelii by FTIR and 2D correlation IR spectroscopy. J Mol Struct 1069:89–95. https://doi.org/10.1016/j.molstruc.2014.01.08510.1016/j.molstruc.2014.01.085 ↗
35. Pranger L, Tannenbaum R (2008) Biobased nanocomposites prepared by in situ polymerization of furfuryl alcohol with cellulose whiskers or montmorillonite clay. Macromolecules 41(22):8682–8687. https://doi.org/10.1021/ma802021310.1021/ma8020213 ↗
36. Ahmad EEM, Luyt AS, Djoković V (2013) Thermal and dynamic mechanical properties of biobased poly(furfuryl alcohol)/sisal whiskers nanocomposites. Polym Bull 70(4):1265–1276. https://doi.org/10.1007/s00289-012-0847-210.1007/s00289-012-0847-2 ↗
37. He L, Yu Y, Yu YS, Tian GL, Wang HK (2012) Stability and mechanical performance of furfurylated Chinese fir. China Wood Industry 26(3):22–28
38. Popescu MC, Froidevaux J, Navi P, Popescu CM (2013) Structural modifications of Tilia cordata wood during heat treatment investigated by FT-IR and 2D IR correlation spectroscopy. J Mol Struct 1033:176–186. https://doi.org/10.1016/j.molstruc.2012.08.03510.1016/j.molstruc.2012.08.035 ↗
39. Oishi SS, Rezende MC, Origo FD, Damiao AJ, Botelho EC (2013) Viscosity, pH, and moisture effect in the porosity of poly (furfuryl alcohol). J Appl Polym Sci 128:1680–1686. https://doi.org/10.1002/app.3833210.1002/app.38332 ↗
40. Kong LZ, Guan H, Wang XQ (2018) In situ polymerization of furfuryl alcohol with ammonium dihydrogen phosphate in poplar wood for improved dimensional stability and flame retardancy. ACS Sustain Chem Eng 6(3):3349–3357. https://doi.org/10.1021/acssuschemeng.7b0351810.1021/acssuschemeng.7b03518 ↗
41. Lande S, Westin M, Schneider M (2008) Development of modified wood products based on furan chemistry. Mol Cryst Liq Cryst 484(1):367–378. https://doi.org/10.1080/1542140080190145610.1080/15421400801901456 ↗
42. Liu MH, Lyu SY, Peng LM, Cai LP, Huang ZH, Lyu JX (2021) Improvement of toughness and mechanical properties of furfurylated wood by biosourced epoxidized soybean oil. ACS Sustain Chem Eng 9:8142–815510.1021/acssuschemeng.1c01358 ↗
43. Shen XS, Guo DK, Jiang P, Yang S, Li GY, Chu FX (2021) Water vapor sorption mechanism of furfurylated wood. J Mater Sci 56:11324–11334. https://doi.org/10.1007/s10853-021-06041-710.1007/s10853-021-06041-7 ↗
44. Papadopoulos AN, Hill CAS, Gkaraveli A (2003) Determination of surface area and pore volume of holocellulose and chemically modified wood flour using the nitrogen adsorption technique. Holz Roh-und Werkstoff 61(6):453–456. https://doi.org/10.1007/s00107-003-0430-510.1007/s00107-003-0430-5 ↗
45. Yin JP, Yuan TQ, Lu Y, Song KL, Li HY, Zhao GJ, Yin YF (2017) Effect of compression combined with steam treatment on the porosity, chemical composition and cellulose crystalline structure of wood cell walls. Carbohydr Polym 155:163–172. https://doi.org/10.1016/j.carbpol.2016.08.01310.1016/j.carbpol.2016.08.013 ↗
46. Yang TT, Zhang SD, Mei CT, Ma EN (2022) Performance improvement of poplar wood based on the synergies of furfurylation and polyethylene glycol. Holzforschung. https://doi.org/10.1515/hf-2022-008310.1515/hf-2022-0083 ↗