journal article·2025-02

Solidification cracking in steel/copper alloy multi-material structures deposited by laser-based directed energy deposition

Zhao Zhao, Matteo Perini, Massimo Pellizzari

Journal of Materials Science· Volume 60· Issue 5
Publisher page

Abstract

This study investigates the susceptibility to solidification cracking in steel/copper alloy multi-material structures and identifies critical influencing factors. SS316L and H13 were deposited on copper-beryllium substrates using laser-based directed energy deposition. Solidification cracks were observed at the steel end, with a downward trend as the dilution ratio increased. Crack-free single-layer SS316L specimens were successfully deposited when the dilution ratio exceeded 44%. SS316L and H13 displayed similar cracking morphology and susceptibility, indicating that the cracking susceptibility of steel/copper alloy systems can be simplified to an Fe–Cu binary issue due to the limited impact of alloying elements. Thermodynamic calculations using the CALPHAD method reveal that Cu concentration in the steel predominantly influences cracking susceptibility through two metallurgical factors: (i) the solidification temperature range and (ii) the amount of peritectic liquid. Cracking susceptibility sharply increases when Cu concentration surpasses approximately 9 wt%, driven by the combination of a wide solidification temperature range and a limited terminal liquid quantity. Beyond this threshold, the cracking tendency continuously decreases as Cu concentration rises until reaching a crack-free region where Cu concentration is around 50 wt% or higher. A large solidification temperature range results in a long, narrow liquid channel at the final stages of solidification, which promotes crack formation. Conversely, a larger quantity of terminal liquid enhances the backfilling effect, facilitating crack healing and thus reducing the tendency for cracking. Furthermore, the solidification microstructure also affects cracking susceptibility. The cellular and columnar dendritic microstructure typical of low Cu concentrations increases cracking tendency, as thin, elongated intercellular and interdendritic films are weak and prone to crack initiation. However, at higher Cu concentrations, spinodal decomposition is more likely, producing a finely distributed, grid-like arrangement of Cu-rich phases within the steel matrix, which inhibits crack formation.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Additive Manufacturing Materials and Processes · High-Temperature Coating Behaviors · Aluminum Alloy Microstructure Properties

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (57)

Show source-provided references
1. Martin JH, Yahata BD, Hundley JM, Mayer JA, Schaedler TA, Pollock TM (2017) 3D printing of high-strength aluminium alloys. Nature 549:365–369. https://doi.org/10.1038/nature2389410.1038/nature23894 ↗
2. Liu K, Kou S (2019) Susceptibility of magnesium alloys to solidification cracking. Sci Technol Weld Joining 25:251–257. https://doi.org/10.1080/13621718.2019.168116010.1080/13621718.2019.1681160 ↗
3. Mondal B, Gao M, Palmer TA, DebRoy T (2022) Solidification cracking of a nickel alloy during high-power keyhole mode laser welding. J Mater Process Technol 305:117567. https://doi.org/10.1016/j.jmatprotec.2022.11757610.1016/j.jmatprotec.2022.117576 ↗
4. Lim S-H, Ryou K, Jang K, Choi WS, Lee HM, Choi P-P (2021) Hot cracking behavior of additively manufactured D2 steel. Mater Charact 178:111217. https://doi.org/10.1016/j.matchar.2021.11121710.1016/j.matchar.2021.111217 ↗
5. Brooks J, Thompson A (1991) Microstructural development and solidification cracking susceptibility of austenitic stainless steel welds. Int Mater Rev 36:16–44. https://doi.org/10.1179/imr.1991.36.1.1610.1179/imr.1991.36.1.16 ↗
6. Wang H, Chen L, Dovgyy B, Xu W, Sha A, Li X, Tang H, Liu Y, Wu H, Pham M-S (2021) Micro-cracking, microstructure and mechanical properties of Hastelloy-X alloy printed by laser powder bed fusion: as-built, annealed and hot-isostatic pressed. Addit Manuf 39:101853. https://doi.org/10.1016/j.addma.2021.10185310.1016/j.addma.2021.101853 ↗
7. DebRoy T, Wei HL, Zuback JS, Mukherjee T, Elmer JW, Milewski JO, Beese AM, Wilson-Heid A, De A, Zhang W (2018) Additive manufacturing of metallic components – Process, structure and properties. Prog Mater Sci 92:112–224. https://doi.org/10.1016/j.pmatsci.2017.10.00110.1016/j.pmatsci.2017.10.001 ↗
8. Rappaz M, Drezet J-M, Gremaud M (1999) A new hot-tearing criterion. Metall Mater Trans A 30:449–455. https://doi.org/10.1007/s11661-999-0334-z10.1007/s11661-999-0334-z ↗
9. Coniglio N, Cross CE (2009) Mechanisms for solidification crack initiation and growth in aluminum welding. Metall Mater Trans A 40:2718–2728. https://doi.org/10.1007/s11661-009-9964-410.1007/s11661-009-9964-4 ↗
10. Cross CE, Coniglio N, Schempp P, Mousavi M (2011) critical conditions for weld solidification crack growth. In: Böllinghaus T, Lippold J, Cross CE (eds) Hot Cracking Phenomena in Welds III. Springer, Berlin, Heidelberg, pp 25–4110.1007/978-3-642-16864-2_2 ↗
11. Wei HL, Mazumder J, DebRoy T (2015) Evolution of solidification texture during additive manufacturing. Sci Rep 5:16446. https://doi.org/10.1038/srep1644610.1038/srep16446 ↗
12. Kou S (2015) A criterion for cracking during solidification. Acta Mater 88:366–374. https://doi.org/10.1016/j.actamat.2015.01.03410.1016/j.actamat.2015.01.034 ↗
13. Suyitno WH, Kool LK (2009) Integrated approach for prediction of hot tearing. Metall Mater Trans A 40:2388–2400. https://doi.org/10.1007/s11661-009-9941-y10.1007/s11661-009-9941-y ↗
14. Kou S (2003) Solidification and liquation cracking issues in welding. JOM 55:37–42. https://doi.org/10.1007/s11837-003-0137-410.1007/s11837-003-0137-4 ↗
15. Clyne T, Wolf M, Kurz W (1982) The effect of melt composition on solidification cracking of steel, with particular reference to continuous casting. Metall Trans B 13:259–266. https://doi.org/10.1007/BF0266458310.1007/BF02664583 ↗
16. Easton MA, Gibson MA, Zhu S, Abbott TB (2014) A Priori hot-tearing indicator applied to die-cast magnesium-rare earth alloys. Metall Mater Trans A 45:3586–3595. https://doi.org/10.1007/s11661-014-2272-710.1007/s11661-014-2272-7 ↗
17. Benoit MJ, Mazur M, Easton MA, Brandt M (2021) Effect of alloy composition and laser powder bed fusion parameters on the defect formation and mechanical properties of Inconel 625. Int J Adv Manuf Technol 114:915–927. https://doi.org/10.1007/s00170-021-06957-z10.1007/s00170-021-06957-z ↗
18. Feenstra DR, Banerjee R, Fraser HL, Huang A, Molotnikov A, Birbilis N (2021) Critical review of the state of the art in multi-material fabrication via directed energy deposition. Curr Opin Solid State Mater Sci 25:100924. https://doi.org/10.1016/j.cossms.2021.10092410.1016/j.cossms.2021.100924 ↗
19. Spalding I (2007) Applied laser tooling. J Mod Opt 35(5):754–755. https://doi.org/10.1080/0950034881455081110.1080/09500348814550811 ↗
20. Brueckner F, Riede M, Müller M, Marquardt F, Willner R, Seidel A, Lopéz E, Leyens C, Beyer E (2018) Enhanced manufacturing possibilities using multi-materials in laser metal deposition. J Laser Appl 30(3):032308. https://doi.org/10.2351/1.504063910.2351/1.5040639 ↗
21. de Oliveira U, Ocelík V, De Hosson JTM (2005) Analysis of coaxial laser cladding processing conditions. Surf Coat Technol 197:127–136. https://doi.org/10.1016/j.surfcoat.2004.06.02910.1016/j.surfcoat.2004.06.029 ↗
22. Zhao Z, Perini M, Bosetti P, Pellizzari M (2022) Direct laser metal deposition of AISI H13 cladding on copper-beryllium alloy substrate through a stainless-steel buffer layer strategy. Steel Res Int 94:2200387. https://doi.org/10.1002/srin.20220038710.1002/srin.202200387 ↗
23. Li W, Karnati S, Kriewall C, Liou F, Newkirk J, Brown Taminger KM, Seufzer WJ (2017) Fabrication and characterization of a functionally graded material from Ti-6Al-4V to SS316 by laser metal deposition. Addit Manuf 14:95–104. https://doi.org/10.1016/j.addma.2016.12.00610.1016/j.addma.2016.12.006 ↗
24. Eliseeva OV, Kirk T, Samimi P, Malak R, Arróyave R, Elwany A, Karaman I (2019) Functionally Graded Materials through robotics-inspired path planning. Mater Des 182:107975. https://doi.org/10.1016/j.matdes.2019.10797510.1016/j.matdes.2019.107975 ↗
25. Weigl M, Schmidt M (2010) Influence of the feed rate and the lateral beam displacement on the joining quality of laser-welded copper-stainless steel connections. Phys Procedia 5:53–59. https://doi.org/10.1016/j.phpro.2010.08.02910.1016/j.phpro.2010.08.029 ↗
26. Tan C, Chew Y, Bi G, Wang D, Ma W, Yang Y, Zhou K (2021) Additive manufacturing of steel–copper functionally graded material with ultrahigh bonding strength. J Mater Sci Technol 72:217–222. https://doi.org/10.1016/j.jmst.2020.07.04410.1016/j.jmst.2020.07.044 ↗
27. Pogson S, Fox P, O’Neill W, Sutcliffe CJ (2004) The direct metal laser remelting of copper and tool steel powders. Mater Sci Eng A 386:453–459. https://doi.org/10.1016/j.msea.2004.08.01510.1016/j.msea.2004.08.015 ↗
28. Ostolaza M, Arrizubieta JI, Lamikiz A, Cortina M (2021) Functionally graded AISI 316L and AISI H13 manufactured by L-DED for die and mould applications. Appl Sci 11:771. https://doi.org/10.3390/app1102077110.3390/app11020771 ↗
29. Osipovich KS, Astafurova EG, Chumaevskii AV, Kalashnikov KN, Astafurov SV, Maier GG, Melnikov EV, Moskvina VA, Panchenko MY, Tarasov SY, Rubtsov VE, Kolubaev EA (2020) Gradient transition zone structure in “steel–copper” sample produced by double wire-feed electron beam additive manufacturing. J Mater Sci 55:9258–9272. https://doi.org/10.1007/s10853-020-04549-y10.1007/s10853-020-04549-y ↗
30. F.F. Noecker, J.N. DuPont (2002) Functionally graded copper: steel using laser engineered net shaping™ process. In: International Congress on Applications of Lasers & Electro-Optics. https://doi.org/10.2351/1.5066217.10.2351/1.5066217 ↗
31. Imran MK, Masood SH, Brandt M (2015) Direct metal deposition of H13 tool steel on copper alloy substrate: parametric investigation. Lasers Manuf Mater Process 2:242–260. https://doi.org/10.1007/s40516-015-0018-z10.1007/s40516-015-0018-z ↗
32. J. Greses, J.M. Sampedro, V. Climent, J.A. Ramos-de-Campos (2006) Laser deposition of stainless and tool steel on a copper-beryllium alloy for plastic injection mould improvement. In: International Congress on Applications of Lasers & Electro-Optics. https://doi.org/10.2351/1.5060809.10.2351/1.5060809 ↗
33. Chen J, Yang Y, Song C, Zhang M, Wu S, Wang D (2019) Interfacial microstructure and mechanical properties of 316L/CuSn10 multi-material bimetallic structure fabricated by selective laser melting. Mater Sci Eng A 752:75–8510.1016/j.msea.2019.02.097 ↗
34. Bennett JL, Liao H, Buergel T, Hyatt G, Ehmann K, Cao J (2021) Towards bi-metallic injection molds by directed energy deposition. Manuf Lett 27:78–81. https://doi.org/10.1016/j.mfglet.2021.01.00110.1016/j.mfglet.2021.01.001 ↗
35. Beal VE, Erasenthiran P, Hopkinson N, Dickens P, Ahrens CH (2006) The effect of scanning strategy on laser fusion of functionally graded H13/Cu materials. Int J Adv Manuf Technol 30:844–852. https://doi.org/10.1007/s00170-005-0130-x10.1007/s00170-005-0130-x ↗
36. Pellizzari M, Zhao Z, Bosetti P, Perini M (2022) Optimizing direct laser metal deposition of H13 cladding on CuBe alloy substrate. Surf Coat Technol 432:128084. https://doi.org/10.1016/j.surfcoat.2022.12808410.1016/j.surfcoat.2022.128084 ↗
37. Zhang W, Liao H, Hu Z, Zhang S, Chen B, Yang H, Wang Y, Zhu H (2021) Interfacial characteristics and mechanical properties of additive manufacturing martensite stainless steel on the Cu-Cr alloy substrate by directed energy deposition. J Mater Sci Technol 90:121–132. https://doi.org/10.1016/j.jmst.2021.03.00810.1016/j.jmst.2021.03.008 ↗
38. V. Beal, P. Erasenthiran, N. Hopkinson, P. Dickens, C. Ahrens (2004) Fabrication of x-graded H13 and Cu powder mix using high power pulsed Nd: YAG laser. In: 2004 International Solid Freeform Fabrication Symposium. https://doi.org/10.26153/tsw/6970.10.26153/tsw/6970 ↗
39. Noecker FF, DuPont JN (2006) Microstructural development and solidification cracking susceptibility of Cu deposits on steel: part I. J Mater Sci 42:495–509. https://doi.org/10.1007/s10853-006-1258-210.1007/s10853-006-1258-2 ↗
40. Noecker FF, DuPont JN (2006) Microstructural development and solidification cracking susceptibility of Cu deposits on steel: part II—use of a Ni interlayer. J Mater Sci 42:510–521. https://doi.org/10.1007/s10853-006-1259-110.1007/s10853-006-1259-1 ↗
41. Zhang X, Sun C, Pan T, Flood A, Zhang Y, Li L, Liou F (2020) Additive manufacturing of copper – H13 tool steel bi-metallic structures via Ni-based multi-interlayer. Addit Manuf 36:101474. https://doi.org/10.1016/j.addma.2020.10147410.1016/j.addma.2020.101474 ↗
42. Zhang X, Pan T, Chen Y, Li L, Zhang Y, Liou F (2021) Additive manufacturing of copper-stainless steel hybrid components using laser-aided directed energy deposition. J Mater Sci Technol 80:100–116. https://doi.org/10.1016/j.jmst.2020.11.04810.1016/j.jmst.2020.11.048 ↗
43. Ribeiro KS, Mariani FE, Coelho RT (2020) A study of different deposition strategies in direct energy deposition (DED) processes. Procedia Manuf 48:663–670. https://doi.org/10.1016/j.promfg.2020.05.15810.1016/j.promfg.2020.05.158 ↗
44. Sun L, Ren X, He J, Zhang Z (2021) A bead sequence-driven deposition pattern evaluation criterion for lowering residual stresses in additive manufacturing. Addit Manuf 48:102424. https://doi.org/10.1016/J.ADDMA.2021.10242410.1016/J.ADDMA.2021.102424 ↗
45. Mustafa H, Mezera M, Matthews DTA, Römer GRBE (2019) Effect of surface roughness on the ultrashort pulsed laser ablation fluence threshold of zinc and steel. Appl Surf Sci 488:10–21. https://doi.org/10.1016/j.apsusc.2019.05.06610.1016/j.apsusc.2019.05.066 ↗
46. Kou S (2002) Welding metallurgy, 2nd edn. John Wiley & Sons Inc., Hoboken, New Jersey10.1002/0471434027 ↗
47. Lippold JC, Kiser SD, DuPont JN (2011) Welding metallurgy and weldability of nickel-base alloys, 1st edn. John Wiley & Sons Inc., Hoboken, New Jersey
48. Svetlizky D, Das M, Zheng B, Vyatskikh AL, Bose S, Bandyopadhyay A, Schoenung JM, Lavernia EJ, Eliaz N (2021) Directed energy deposition (DED) additive manufacturing: Physical characteristics, defects, challenges and applications. Mater Today 49:271–295. https://doi.org/10.1016/j.mattod.2021.03.02010.1016/j.mattod.2021.03.020 ↗
49. Pinkerton AJ, Li L (2005) An analytical model of energy distribution in laser direct metal deposition. J Eng Manuf 218:363–374. https://doi.org/10.1243/09544050432305549810.1243/095440504323055498 ↗
50. Munitz A (1987) Liquid separation effects in Fe-Cu alloys solidified under different cooling rates. Metall Trans B 18:565–575. https://doi.org/10.1007/BF02654269/METRICS10.1007/BF02654269/METRICS ↗
51. Kurz W, Rappaz M, Trivedi R (2020) Progress in modelling solidification microstructures in metals and alloys. part II: dendrites from 2001 to 2018. Int Mater Rev 66:30–76. https://doi.org/10.1080/09506608.2020.175789410.1080/09506608.2020.1757894 ↗
52. Wang L, Wang N, Provatas N (2017) Liquid channel segregation and morphology and their relation with hot cracking susceptibility during columnar growth in binary alloys. Acta Mater 126:302–312. https://doi.org/10.1016/j.actamat.2016.11.05810.1016/j.actamat.2016.11.058 ↗
53. Guo J, Lu D, Zou J (2023) Investigation on solidification in Cu-20wt%Fe alloy through in situ observation. Metals 13:13030581. https://doi.org/10.3390/met1303058110.3390/met13030581 ↗
54. Ma D, Xu W, Ng SC, Li Y (2005) On secondary dendrite arm coarsening in peritectic solidification. Mater Sci Eng A 390:52–62. https://doi.org/10.1016/j.msea.2004.07.03210.1016/j.msea.2004.07.032 ↗
55. Peng P, Li X, Liu D, Su Y, Guo J, Fu H (2013) Secondary dendrite arm migration caused by temperature gradient zone melting in the directionally solidified Sn–40 at.% Mn peritectic alloy. J Mater Res 28:1196–1202. https://doi.org/10.1557/jmr.2013.7110.1557/jmr.2013.71 ↗
56. Shi RP, Wang CP, Wheeler D, Liu XJ, Wang Y (2013) Formation mechanisms of self-organized core/shell and core/shell/corona microstructures in liquid droplets of immiscible alloys. Acta Mater 61:1229–1243. https://doi.org/10.1016/j.actamat.2012.10.03310.1016/j.actamat.2012.10.033 ↗
57. Wu YH, Wang WL, Chang J, Wei B (2018) Evolution kinetics of microgravity facilitated spherical macrosegregation within immiscible alloys. J Alloys Compd 763:808–814. https://doi.org/10.1016/j.jallcom.2018.06.02210.1016/j.jallcom.2018.06.022 ↗