journal article·2023-04Open access

Influence of wood pretreatment, hardwood and softwood extractives on the compressive strength of fly ash-based geopolymer composite

Bright Asante, Jörn Appelt, Libo Yan, Andreas Krause

Journal of Materials Science· Volume 58· Issue 13

Abstract

Abstract This paper investigated the specific compressive strength (specific strength) of fly ash-based geopolymer composites with four hardwood extractives and two softwood extractives, as well as specific wood extractives. Additionally, the effect of the portion of pine wood (i.e., sapwood and heartwood) and wood pretreatment with NaOH were considered. Geopolymer paste (with extractives) and geopolymer wood composites (GWCs) were cured at 60 °C for 24 h. The samples were stored in a climate chamber (20 °C, 65% RH) for 7 days before finally testing under compression. From the results, the specific strengths of geopolymers with hardwood extractives were not significantly affected. However, geopolymers containing pine extractives showed the most significant reduction in specific strength. There were no significant differences in the specific strengths of geopolymers containing polyphenols and resin acid. Generally, geopolymers containing fatty acids recorded the lowest specific strengths. There was no difference between the GWCs with untreated sapwood and heartwood. However, the wood pretreatment led to a 21% and 10% increase in the specific strengths of GWCs with sapwood and heartwood, respectively. The findings of this study form the basis for improved GWCs production and a wide range of applications for green composite materials.
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Research context

OpenAlex topics: Concrete and Cement Materials Research · Innovative concrete reinforcement materials · Recycling and utilization of industrial and municipal waste in materials production

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References (51)

Show source-provided references
1. Sarmin SN (2016) The influence of different wood aggregates on the properties of geopolymer composites. KEM 723:74–79. https://doi.org/10.4028/www.scientific.net/KEM.723.7410.4028/www.scientific.net/KEM.723.74 ↗
2. Shaikh FUA (2013) Review of mechanical properties of short fibre reinforced geopolymer composites. Constr Build Mater 43:37–49. https://doi.org/10.1016/j.conbuildmat.2013.01.02610.1016/j.conbuildmat.2013.01.026 ↗
3. Bakharev T (2005) Resistance of geopolymer materials to acid attack. Cem Concr Res 35(4):658–670. https://doi.org/10.1016/j.cemconres.2004.06.00510.1016/j.cemconres.2004.06.005 ↗
4. Ryu GS, Lee YB, Koh KT, Chung YS (2013) The mechanical properties of fly ash-based geopolymer concrete with alkaline activators. Constr Build Mater 47:409–418. https://doi.org/10.1016/j.conbuildmat.2013.05.06910.1016/j.conbuildmat.2013.05.069 ↗
5. Shehab HK, Eisa AS, Wahba AM (2016) Mechanical properties of fly ash based geopolymer concrete with full and partial cement replacement. Constr Build Mater 126:560–565. https://doi.org/10.1016/j.conbuildmat.2016.09.05910.1016/j.conbuildmat.2016.09.059 ↗
6. Zhao Q, Nair B, Rahimian T, Balaguru P (2007) Novel geopolymer based composites with enhanced ductility. J Mater Sci 42(9):3131–3137. https://doi.org/10.1007/s10853-006-0527-410.1007/s10853-006-0527-4 ↗
7. Giancaspro J, Papakonstantinou C, Balaguru P (2009) Mechanical behavior of fire-resistant biocomposite. Compos Part B: Eng 40(3):206–211. https://doi.org/10.1016/j.compositesb.2008.11.00810.1016/j.compositesb.2008.11.008 ↗
8. Giancaspro JW, Papakonstantinou CG, Balaguru PN (2010) Flexural response of inorganic hybrid composites with E-glass and carbon fibers. J Eng Mater Technol 132(2):1. https://doi.org/10.1115/1.400067010.1115/1.4000670 ↗
9. Ye H, Zhang Y, Yu Z, Mu J (2018) Effects of cellulose, hemicellulose, and lignin on the morphology and mechanical properties of metakaolin-based geopolymer. Constr Build Mater 173:10–16. https://doi.org/10.1016/j.conbuildmat.2018.04.02810.1016/j.conbuildmat.2018.04.028 ↗
10. Zhengtian L, Moslemi AA (1985) Influence of chemical additives on the hydration characteristics of western larch wood cement water mixtures. For Prod J 35(7):37–43
11. Moslemi AA, Garcia J, Hofstrand AD (1983) Effect of various treatments and additives on woodeportland cementewater systems. Wood Fiber Sci 15(2):164–176
12. Lee A, Short PH (1989) Pretreating hardwood for cement-bonded excelsior board. For Prod J 39(10):68–70
13. Alberto M, Mougel E, Zoulalian A (2000) Compatibility of some tropical hardwoods species with Portland cement using isothermal calorimetry. For Prod J 50(9):83–88
14. Quiroga A, Marzocchi V, Rintoul I (2016) Influence of wood treatments on mechanical properties of wood–cement composites and of Populus Euroamericana wood fibers. Compos Part B: Eng 84:25–32. https://doi.org/10.1016/j.compositesb.2015.08.06910.1016/j.compositesb.2015.08.069 ↗
15. Jorge FC, Pereira C, Ferreira JMF (2004) Wood-cement composites: a review. Holz Roh Werkst 62(5):370–377. https://doi.org/10.1007/s00107-004-0501-210.1007/s00107-004-0501-2 ↗
16. Asante B, Schmidt G, Teixeira R, Krause A, Savastano Junior H (2021) Influence of wood pretreatment and fly ash particle size on the performance of geopolymer wood composite. Eur J Wood Prod 79(3):597–609. https://doi.org/10.1007/s00107-021-01671-910.1007/s00107-021-01671-9 ↗
17. Volf I, Ignat I, Neamtu M, Popa V (2014) Thermal stability, antioxidant activity, and photo-oxidation of natural polyphenols. Chem Pap 68(1):121–129. https://doi.org/10.2478/s11696-013-0417-610.2478/s11696-013-0417-6 ↗
18. Rowell RM (2013) Handbook of wood chemistry and wood composites, 2nd edn. Taylor & Francis, Boca Raton
19. Cabangon RJ, Eusebio DA, Soriano FP, Cunningham RB, Donnelly C, Evans PD (2000) Effect of post-harvest storage on the suitability of Acacia mangium for the manufacture of wood-wool cement boards. In: Wood-cement composites in the Asia-Pacific region, Canberra, Australia, pp 97–104
20. Asante B, Ye H, Nopens M, Schmidt G, Krause A (2022) Influence of wood moisture content on the hardened state properties of geopolymer wood composites. Compos Part A: Appl Sci Manuf 152:1. https://doi.org/10.1016/j.compositesa.2021.10668010.1016/j.compositesa.2021.106680 ↗
21. Asante B, Sirviö JA, Li P, Lavola A, Julkunen-Tiitto R, Haapala A, Liimatainen H (2020) Adsorption of bark derived polyphenols onto functionalized nanocellulose: equilibrium modeling and kinetics. AIChE J 66(2):1. https://doi.org/10.1002/aic.1682310.1002/aic.16823 ↗
22. Baar J, Paschova Z, Cermak P, Wimmer R (2019) Color changes of various wood species in response to moisture. Wood Fiber Sci 51(2):1–1310.22382/wfs-2019-014 ↗
23. Hon DN-S, Minemura N (2001) Color and discoloration, 2nd edn. Marcel Dekker, New York
24. Pandey KK (2005) A note on the influence of extractives on the photo-discoloration and photo-degradation of wood. Polym Degrad Stab 87(2):375–379. https://doi.org/10.1016/j.polymdegradstab.2004.09.00710.1016/j.polymdegradstab.2004.09.007 ↗
25. Sandoval-Torres S, Jomaa W, Marc F, Puiggali J-R (2010) Causes of color changes in wood during drying. For Stud China 12:167–175. https://doi.org/10.1007/s11632-010-0404-810.1007/s11632-010-0404-8 ↗
26. Bhatia L, Johri S (2016) FTIR analysis and optimization of simultaneous saccharification and fermentation parameters for sustainable production of ethanol from peels of ananas cosmosus by Mucor indicus MTCC 4349. Waste Biomass Valor 7(3):427–438. https://doi.org/10.1007/s12649-015-9462-410.1007/s12649-015-9462-4 ↗
27. Zhong L, Shi T, Guo L (2010) Preparation and morphology of porous SiO2 ceramics derived from fir flour templates. J Serb Chem Soc 75(3):385–394. https://doi.org/10.2298/JSC090410010Z10.2298/JSC090410010Z ↗
28. Barman DN, Haque MA, Hossain MM, Paul SK, Yun HD (2020) Deconstruction of pine wood (pinus sylvestris) recalcitrant structure using alkali treatment for enhancing enzymatic saccharification evaluated by congo red. Waste Biomass Valor 11(5):1755–1764. https://doi.org/10.1007/s12649-018-00547-z10.1007/s12649-018-00547-z ↗
29. Redzuan MS, Paridah MT, Anwar UM, Juliana AH, Lee SH, Norwahyuni MY (2019) Effects of surface pretreatment on wettability of Acacia mangium wood. JTFS 31(2):249–258. https://doi.org/10.26525/jtfs2019.31.2.24925810.26525/jtfs2019.31.2.249258 ↗
30. Sarmin SN, Rahman WMNWA, Mohd Yunus NY, Ahmad N (2020) Determination of the bond strength of wood veneer and geopolymer matrix by means of a pull-out test. MSF 981:162–168. https://doi.org/10.4028/www.scientific.net/MSF.981.16210.4028/www.scientific.net/MSF.981.162 ↗
31. Routa J, Brännström H, Anttila P, Mäkinen M, Jänis J, Asikainen A (2017) Wood extractives of Finnish pine, spruce and birch—availability and optimal sources of compounds A literature review. Natural resources and bioeconomy studies 73/2017. Natural Resources Institute Finland (Luke), Finland, Helsinki
32. Holmbom B (1999) Extractives. In: Sjöström E, Alen R (eds) Analytical methods in wood chemistry pulping and papermaking. Springer, Germany, pp 125–14810.1007/978-3-662-03898-7_5 ↗
33. Bali G, Meng X, Deneff JI, Sun Q, Ragauskas AJ (2015) The effect of alkaline pretreatment methods on cellulose structure and accessibility. Chemsuschem 8(2):275–279. https://doi.org/10.1002/cssc.20140275210.1002/cssc.201402752 ↗
34. Hassan NS, Badri KH (2014) Lignin recovery from alkaline hydrolysis and glycerolysis of oil palm fiber. In: AIP Publishing LLC, pp 433–43810.1063/1.4895236 ↗
35. Bertaud F, Holmbom B (2004) Chemical composition of earlywood and latewood in Norway spruce heartwood, sapwood and transition zone wood. Wood Sci Technol 38:245–256. https://doi.org/10.1007/s00226-004-0241-910.1007/s00226-004-0241-9 ↗
36. Uprichard JM, Lloyd JA (1980) Influence of tree age on the chemical composition of radiate pine. N Z J For Sci 10(3):551–557
37. Ingram LL, Templeton MC, McGraw GW, Hemingway RW (2000) Knot, heartwood, and sapwood extractives related to VOCs from drying southern pine lumber. J Wood Chem Technol 20(4):415–439. https://doi.org/10.1080/0277381000935189210.1080/02773810009351892 ↗
38. Wan G, Frazier CE (2019) Pine extractives strongly affect lignin thermochemical pathways. ACS Sustain Chem Eng 7(21):17999–18004. https://doi.org/10.1021/acssuschemeng.9b0483310.1021/acssuschemeng.9b04833 ↗
39. Martínez-Inigo MJ, Immerzeel P, Gutierrez A, Del Río JC, Sierra-Alvarez R (1999) Biodegradability of Extractives in Sapwood and Heartwood from Scots Pine by Sapstain and White-Rot Fungi. Holzforschung 53(3):247–252. https://doi.org/10.1515/HF.1999.04210.1515/HF.1999.042 ↗
40. Turtola S, Manninen AM, Holopainen JK, Levula T, Raitio H, Kainulainen P (2002) Secondary metabolite concentrations and terpene emissions of Scots pine xylem after long-term forest fertilization. J Environ Qual 31:1694–1701. https://doi.org/10.2134/jeq2002.169410.2134/jeq2002.1694 ↗
41. Arshadi M, Backlund I, Geladi P, Bergsten U (2013) Comparison of fatty and resin acid composition in boreal lodgepole pine and Scots pine for biorefinery applications. Ind Crops Prod 49:535–541. https://doi.org/10.1016/j.indcrop.2013.05.03810.1016/j.indcrop.2013.05.038 ↗
42. Doczekalska B, Zborowska M (2010) Wood chemical composition of selected fast growing species treated with naoh part i: structural substances. Wood Res 55(1):41–48
43. Huang Z, Yan N (2013) Characterization of major components in barks from five canadian tree species. Wood Fiber Sci 46(2):167–174
44. Back EL, Allen LH (2000) Pitch control, wood resin and deresination. Tappi, Atlanta, Ga
45. Tugrul Albayrak A, Yasar M, Gurkaynak MA, Gurgey I (2005) Investigation of the effects of fatty acids on the compressive strength of the concrete and the grindability of the cement. Cem Concr Res 35(2):400–404. https://doi.org/10.1016/j.cemconres.2004.07.03110.1016/j.cemconres.2004.07.031 ↗
46. Shill SK, Al-Deen S, Ashraf M, Hutchison W (2020) Resistance of fly ash based geopolymer mortar to both chemicals and high thermal cycles simultaneously. Constr Build Mater 239:1. https://doi.org/10.1016/j.conbuildmat.2019.11788610.1016/j.conbuildmat.2019.117886 ↗
47. Shill SK, Al-Deen S, Ashraf M, Garcez EO, Subhani M, Hossain MM (2022) Resistance of geopolymer, epoxy and cement mortar to hydrocarbon-based synthetic engine lubricant, hydraulic fluid, jet fuel and elevated temperatures. Constr Mater 2(1):15–26. https://doi.org/10.3390/constrmater201000210.3390/constrmater2010002 ↗
48. Sandermann W, Preusser HJ, Schweers W (1960) The effect of wood extractives on the setting of cement-bonded wood materials. Holzforschung 14(3):70–7710.1515/hfsg.1960.14.3.70 ↗
49. Biblis EL, Lo CF (1968) Sugars and other wood extractives: Effect on setting of southern pine cement mixtures. For Prod J 18(8):28–34
50. Fischer F, Wienhaus O, Ryssel M, Olbrecht J (1974) The water soluble carbohydrates of wood and their influence on the production of light weight wood wool boards. Holztechnologie 15(1):12–19
51. Liu Z, Moslemi AA (1985) Influence of chemical additives on the hydration characteristics of western larch wood-cementwater mixtures. For Prod J 7(7/8):37–43