journal article·2018-09

Structural evolution of vertically oriented graphene nanosheet templating Ni–Co hydroxide as pseudocapacitive electrode

Pingge He, Boyun Huang, Qun Huang, Tengfei Chen, Qiangqing Zhang

Journal of Materials Science· Volume 53· Issue 17
Publisher page

Abstract

High-performance pseudocapacitive electrode with vertically oriented graphene nanosheet (GN) templating Ni–Co hydroxide (NCH) is fabricated through a facial electrodeposition way. The structural evolution of electrodes after cyclic voltammetry treatment at different scan rates (from 5 to 500 mV s−1) and its impact on the electrodes’ electrochemical performance are for the first time systematically investigated. The results reveal that the NCH/GN hybrid electrode exhibits ultrahigh electrochemical stability that the electrochemical properties of hybrid electrodes are not affected by the different rate-scanning treatments. GN grown on carbon cloth (CC) as nanotemplate for NCH pseudocapacitive material creates a rapid channel for ion/charge transfer between the electrolyte and electrode, and the robust interfacial bonding of hybrid structure is prerequisite for the high performance stability. Furthermore, asymmetric supercapacitor devices consisting of NCH/GN/CC as positive electrode and GN/CC as negative electrode were fabricated and electrochemically treated as well, further demonstrating the ultrahigh electrochemical stability of such NCH/GN/CC hybrid structures at various scan rates.
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Research context

OpenAlex topics: Supercapacitor Materials and Fabrication · Conducting polymers and applications · Advanced battery technologies research

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