Phase transformation of the Ti-5553 titanium alloy subjected to rapid heating
Source abstract
Abstract
The a -> b phase transformation upon heating in the Ti-5553 alloy with lamellar-nodular bimodal microstructure was tracked in situ with high energy X-ray diffraction. Rapid heating at 10, 50 and 100 °C s-1 from room temperature to 1050 °C was tested. Phase transformation on heating was studied by a combined analysis of the microstructural features that provides estimates of mass fractions, mean lattice parameters and full width at half maximum for the two phases. In comparison with equilibrium conditions, the experimental mass fractions reveal a shift of the transformation domain toward high temperatures when the heating rate increases. Also, the dissolution of the a phase is largely impacted by its morphology, the transformation being faster for a lamellae. The combined analysis of mean lattice parameters and full width at half maximum suggests that the a -> b phase transformation on heating is diffusion controlled. The b phase therefore inherits the solute content of the adjacent parent a phase, leading to chemical heterogeneities in the b phase regardless of the heating rate.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Titanium Alloys Microstructure and Properties · Intermetallics and Advanced Alloy Properties · Metal and Thin Film Mechanics
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (56)
Show source-provided references
1. Lütjering G, Williams JC (2007) Titanium, 2nd edn. Springer, Berlin
2. Lütjering G (1998) Influence of processing on microstructure and mechanical properties of (α+β) titanium alloys. Mater Sci Eng A 243:32–45. https://doi.org/10.1016/S0921-5093(97)00778-810.1016/S0921-5093(97)00778-8 ↗
3. Banerjee D, Williams JC (2013) Perspectives on titanium science and technology. Acta Mater 61:844–879. https://doi.org/10.1016/j.actamat.2012.10.04310.1016/j.actamat.2012.10.043 ↗
4. Fomin A, Fomina M (2016) FEM modeling and experimental data of induction heating of titanium medical devices. In: 2016 57th international scientific conference on power and electrical engineering of Riga Technical University (RTUCON), pp 1–410.1109/RTUCON.2016.7763079 ↗
5. Markovsky PE, Semiatin SL (2011) Tailoring of microstructure and mechanical properties of Ti–6Al–4V with local rapid (induction) heat treatment. Mater Sci Eng A 528:3079–3089. https://doi.org/10.1016/j.msea.2010.12.00210.1016/j.msea.2010.12.002 ↗
6. Elmer JW, Palmer TA, Wong J (2003) In situ observations of phase transitions in Ti–6Al–4V alloy welds using spatially resolved X-ray diffraction. J Appl Phys 93:1941–1947. https://doi.org/10.1063/1.153746410.1063/1.1537464 ↗
7. Elmer JW, Palmer TA, Babu SS et al (2004) Phase transformation dynamics during welding of Ti–6Al–4V. J Appl Phys 95:8327–8339. https://doi.org/10.1063/1.173747610.1063/1.1737476 ↗
8. Rahman Rashid RA, Sun S, Wang G, Dargusch MS (2012) An investigation of cutting forces and cutting temperatures during laser-assisted machining of the Ti–6Cr–5Mo–5V–4Al beta titanium alloy. Int J Mach Tools Manuf 63:58–69. https://doi.org/10.1016/j.ijmachtools.2012.06.00410.1016/j.ijmachtools.2012.06.004 ↗
9. Ayed Y, Germain G, Ben Salem W, Hamdi H (2014) Experimental and numerical study of laser-assisted machining of Ti6Al4V titanium alloy. Finite Elem Anal Des 92:72–79. https://doi.org/10.1016/j.finel.2014.08.00610.1016/j.finel.2014.08.006 ↗
10. Elmer JW, Palmer TA, Babu SS, Specht ED (2005) In situ observations of lattice expansion and transformation rates of α and β phases in Ti–6Al–4V. Mater Sci Eng A 391:104–113. https://doi.org/10.1016/j.msea.2004.08.08410.1016/j.msea.2004.08.084 ↗
11. Barriobero-Vila P, Requena G, Buslaps T et al (2015) Role of element partitioning on the α–β phase transformation kinetics of a bi-modal Ti–6Al–6V–2Sn alloy during continuous heating. J Alloys Compd 626:330–339. https://doi.org/10.1016/j.jallcom.2014.11.17610.1016/j.jallcom.2014.11.176 ↗
12. Malinov S, Sha W, Voon CS (2002) In situ high temperature microscopy study of the surface oxidation and phase transformations in titanium alloys. J Microsc 207:163–168. https://doi.org/10.1046/j.1365-2818.2002.01055.x10.1046/j.1365-2818.2002.01055.x ↗
13. Semiatin SL, Obstalecki M, Payton EJ et al (2019) Dissolution of the alpha phase in Ti–6Al–4V during isothermal and continuous heat treatment. Metall Mater Trans A 50:2356–2370. https://doi.org/10.1007/s11661-019-05164-610.1007/s11661-019-05164-6 ↗
14. Dehmas M, Katemi R, Appolaire B, et al (2011) Dissolution kinetics of α phase in TA6V titanium alloy. In: Proceedings of the 12th World conference on titaninum, vol 1, pp 719–724
15. Ismail AI, Dehmas M, Aeby‐Gautier E, Appolaire B (2016) In-situ investigation of phase transformation kinetics in Ti–6Al–4V under rapid heating condition using high-energy synchrotron diffraction. In: Proceedings of the 13th World conference on titanium, pp 591–59810.1002/9781119296126.ch97 ↗
16. Callegari B, Aristizabal K, Suarez S et al (2020) In situ evaluation of the low-temperature aging response of Ti–5Al–5Mo–5V–3Cr alloy as influenced by starting microstructure. J Alloys Compd 835:155331. https://doi.org/10.1016/j.jallcom.2020.15533110.1016/j.jallcom.2020.155331 ↗
17. Settefrati A, Aeby-Gautier E, Appolaire B et al (2013) Low temperature transformations in β-metastable Ti 5553 titanium alloy. Mater Sci Forum 738–739:97–10210.4028/www.scientific.net/MSF.738-739.97 ↗
18. Aeby-Gautier E, Settefrati A, Bruneseaux F et al (2013) Isothermal α″ formation in β metastable titanium alloys. J Alloys Compd 577:S439–S443. https://doi.org/10.1016/j.jallcom.2012.02.04610.1016/j.jallcom.2012.02.046 ↗
19. Barriobero-Vila P, Requena G, Schwarz S et al (2015) Influence of phase transformation kinetics on the formation of α in a β-quenched Ti–5Al–5Mo–5V–3Cr–1Zr alloy. Acta Mater 95:90–101. https://doi.org/10.1016/j.actamat.2015.05.00810.1016/j.actamat.2015.05.008 ↗
20. Paiotti Marcondes Guimarães R, Callegari B, Warchomicka F et al (2020) In situ analysis of the phase transformation kinetics in the β-water-quenched Ti–5Al–5Mo–5V–3Cr–1Zr alloy during ageing after fast heating. Quantum Beam Sci 4:12. https://doi.org/10.3390/qubs401001210.3390/qubs4010012 ↗
21. Jones NG, Dashwood RJ, Jackson M, Dye D (2009) β phase decomposition in Ti–5Al–5Mo–5V–3Cr. Acta Mater 57:3830–3839. https://doi.org/10.1016/j.actamat.2009.04.03110.1016/j.actamat.2009.04.031 ↗
22. Thönnessen L (2017) Influence of heat treatment parameters on phase transformations in the near-beta titanium alloy Ti–1Al–8V5Fe. University of Wollongong thesis collection 2017
23. Charrier G, Dehmas M, Descoins M, et al (2016) Study of the elemental partitioning for different transformation conditions in the Ti-5553 alloy. In: Proceedings of the 13th World conference on titanium, pp 547–55210.1002/9781119296126.ch88 ↗
24. Nag S, Banerjee R, Hwang JY et al (2009) Elemental partitioning between α and β phases in the Ti–5Al–5Mo–5V–3Cr–0.5Fe (Ti-5553) alloy. Philos Mag 89:535–552. https://doi.org/10.1080/1478643080261315810.1080/14786430802613158 ↗
25. Callegari B, Campo L, Aristizabal K et al (2021) In situ assessment of isochronal phase transformations in a lamellar Ti–5Al–5Mo–5V–3Cr–1Zr alloy using synchrotron X-ray diffraction. J Alloys Compd 853:157105. https://doi.org/10.1016/j.jallcom.2020.15710510.1016/j.jallcom.2020.157105 ↗
26. Gridnev VN, Ivasishin OM, Markovskii PE (1985) Influence of heating rate on the temperature of the (α+β)→β-transformation of titanium alloys. Met Sci Heat Treat 27:43–48. https://doi.org/10.1007/BF0074188810.1007/BF00741888 ↗
27. Schneider CA, Rasband WS, Eliceiri KW (2012) NIH image to ImageJ: 25 years of image analysis. Nat Methods 9:671–675. https://doi.org/10.1038/nmeth.208910.1038/nmeth.2089 ↗
28. Schell N, King A, Beckmann F et al (2014) The high energy materials science beamline (HEMS) at PETRA III. Mater Sci Forum 772:57–6110.4028/www.scientific.net/MSF.772.57 ↗
29. Liss K-D, Bartels A, Schreyer A, Clemens H (2003) High-energy X-rays: a tool for advanced bulk investigations in materials science and physics. Textures Microstruct 35:219–252. https://doi.org/10.1080/0730330031000163495210.1080/07303300310001634952 ↗
30. Rietveld HM (1969) A profile refinement method for nuclear and magnetic structures. J Appl Crystallogr 2:65–71. https://doi.org/10.1107/S002188986900655810.1107/S0021889869006558 ↗
31. Toby BH (2006) R factors in Rietveld analysis: how good is good enough? Powder Diffr 21:67–70. https://doi.org/10.1154/1.217980410.1154/1.2179804 ↗
32. Rodriguez-Carjaval J (1990) FullProf: a program for Rietveld refinement and profile matching analysis. Abstracts of the satellite meeting on powder diffraction of the XV congress of the IUCr, Toulouse, France
33. Caglioti G, Paoletti A, Ricci FP (1958) Choice of collimators for a crystal spectrometer for neutron diffraction. Nucl Instrum 3:223–228. https://doi.org/10.1016/0369-643X(58)90029-X10.1016/0369-643X(58)90029-X ↗
34. Stephens PW (1999) Phenomenological model of anisotropic peak broadening in powder diffraction. J Appl Crystallogr 32:281–289. https://doi.org/10.1107/S002188989800600110.1107/S0021889898006001 ↗
35. Andersson J-O, Helander T, Höglund L et al (2002) Thermo-Calc & DICTRA, computational tools for materials science. Calphad 26:273–312. https://doi.org/10.1016/S0364-5916(02)00037-810.1016/S0364-5916(02)00037-8 ↗
36. Saunders N (1998) Titanium database. Thermotech Ltd., Guilford
37. Li X, Dippenaar R, Shiro A et al (2018) Lattice parameter evolution during heating of Ti–45Al–7.5Nb–0.25/0.5C alloys under atmospheric and high pressures. Intermetallics 102:120–131. https://doi.org/10.1016/j.intermet.2018.08.01110.1016/j.intermet.2018.08.011 ↗
38. Welsch G, Boyer R, Collings EW (1993) Materials properties handbook: titanium alloys. ASM International, Materials Park
39. Scherrer P (1912) Bestimmung der inneren Struktur und der Größe von Kolloidteilchen mittels Röntgenstrahlen. In: Zsigmondy R (ed) Kolloidchemie Ein Lehrbuch. Springer, Berlin, pp 387–40910.1007/978-3-662-33915-2_7 ↗
40. Patterson AL (1939) The Scherrer formula for X-ray particle size determination. Phys Rev 56:978–982. https://doi.org/10.1103/PhysRev.56.97810.1103/PhysRev.56.978 ↗
41. Ivasishin O, Flower HM (1986) The redistribution of alloying elements by rapid-heating solution treatment of an (α + β) titanium alloy. J Mater Sci 21:2519–2524. https://doi.org/10.1007/BF0111430010.1007/BF01114300 ↗
42. Carman A, Zhang LC, Ivasishin OM et al (2011) Role of alloying elements in microstructure evolution and alloying elements behaviour during sintering of a near-β titanium alloy. Mater Sci Eng A 528:1686–1693. https://doi.org/10.1016/j.msea.2010.11.00410.1016/j.msea.2010.11.004 ↗
43. Pawar RR, Deshpande VT (1968) The anisotropy of the thermal expansion of α-titanium. Acta Crystallogr A 24:316–317. https://doi.org/10.1107/S056773946800052510.1107/S0567739468000525 ↗
44. Jaffee RI (1958) The physical metallurgy of titanium alloys. Prog Met Phys 7:65–163. https://doi.org/10.1016/0502-8205(58)90004-210.1016/0502-8205(58)90004-2 ↗
45. Yan K, Carr DG, Kabra S et al (2011) In Situ characterization of lattice structure evolution during phase transformation of Zr–2.5Nb. Adv Eng Mater 13:882–886. https://doi.org/10.1002/adem.20100035010.1002/adem.201000350 ↗
46. Wiedemann KE, Shenoy RN, Unnam J (1987) Microhardness and lattice parameter calibrations of the oxygen solid solutions of unalloyed α-titanium and Ti–6Al–2Sn–4Zr–2Mo. Metall Trans A 18:1503–1510. https://doi.org/10.1007/BF0264666210.1007/BF02646662 ↗
47. Dobromyslov AV, Elkin VA (2003) Martensitic transformation and metastable ß-phase in binary titanium alloys with beta-metals of 4–6 periods. J Phys IV Proc 112:723–726. https://doi.org/10.1051/jp4:200398410.1051/jp4:2003984 ↗
48. Kabra S, Yan K, Carr DG et al (2013) Defect dynamics in polycrystalline zirconium alloy probed in situ by primary extinction of neutron diffraction. J Appl Phys 113:063513. https://doi.org/10.1063/1.479017710.1063/1.4790177 ↗
49. Williamson GK, Hall WH (1953) X-ray line broadening from filed aluminium and wolfram. Acta Metall 1:22–31. https://doi.org/10.1016/0001-6160(53)90006-610.1016/0001-6160(53)90006-6 ↗
50. Nath D, Singh F, Das R (2020) X-ray diffraction analysis by Williamson-Hall, Halder-Wagner and size—strain plot methods of CdSe nanoparticles—a comparative study. Mater Chem Phys 239:122021. https://doi.org/10.1016/j.matchemphys.2019.12202110.1016/j.matchemphys.2019.122021 ↗
51. Kale GB, Patil RV (1994) Chemical diffusion in titanium-molybdenum system. Mater Trans JIM 35:439–444. https://doi.org/10.2320/matertrans1989.35.43910.2320/matertrans1989.35.439 ↗
52. Hoffmann A, Livolant M, Roche R (1978) CASTEM: a system of finite element computer programs for elastic and inelastic analysis of mechanical structures of reactors. CEA Centre d’Etudes Nucleaires de Saclay
53. Wagner V, Baili M, Dessein G, Lallement D (2011) Experimental study of coated carbide tools behaviour: application for Ti-5-5-5-3 turning. Int J Mach Mach Mater 9:233. https://doi.org/10.1504/IJMMM.2011.03964910.1504/IJMMM.2011.039649 ↗
54. Baillieux J (2015) Effet de l’oxydation sur le comportement mécanique de structures minces en alliages de titane. PhD. thesis, CIRIMAT-ENSIACET
55. Bettaieb MB, Hoof TV, Pardoen T et al (2014) On the elasto-viscoplastic behavior of the Ti5553 alloy. Mater Sci Eng A 617:97–109. https://doi.org/10.1016/j.msea.2014.08.05510.1016/j.msea.2014.08.055 ↗
56. Rudnev V, Loveless DL, Cook R (2017) Handbook of induction heating, 2nd edn. CRC Press, New York10.1201/9781315117485 ↗