journal article·2019-05

Visible light photocatalytic conversion of CO2 in aqueous solution using 2D-structured carbon-based catalyst-coated β,γ-AgI nanocomposite

Pramila Murugesan, Sheeba Narayanan, Manickam Matheswaran

Journal of Materials Science· Volume 54· Issue 10
Publisher page

Abstract

Solar-light-driven carbon-based photocatalysts have been widely used for CO2 conversion reaction. In this work, silver iodide (AgI)-decorated 2D structure graphitic carbon nitride (GCN) composite was prepared using nitrogen-rich melamine precursor and the characterization results reveal that the mixture of hexagonal wurtzite and cubic phases of β,γ-AgI are incorporated on GCN surface. Consequently, the photoconversion of CO2 over AgI/GCN composite was tested under visible light irradiation in triethanolamine medium. The main products from CO2 conversion were methane, acetone and ethanol. Besides, the effects of metal AgI loading (0.5–1.5%), the amount of photocatalyst (1–4 g/L) and irradiation time for CO2 photoconversion were evaluated. Furthermore, the charge separation mechanism associated with the AgI/GCN composite for CO2 photoconversion was also discussed.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Advanced Photocatalysis Techniques · Gas Sensing Nanomaterials and Sensors · Copper-based nanomaterials and applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (57)

Show source-provided references
1. Herzog HJ (2011) Scaling up carbon dioxide capture and storage: from megatons to gigatons. Energy Econ 33:597–60410.1016/j.eneco.2010.11.004 ↗
2. Salehi-Khojin A, Jhong HRM, Rosen BA et al (2013) Nanoparticle silver catalysts that show enhanced activity for carbon dioxide electrolysis. J Phys Chem C 117:1627–163210.1021/jp310509z ↗
3. Inoue T, Fujishima A, Konishi S, Honda K (1979) Photoelectrocatalytic reduction of carbon dioxide in aqueous suspensions of semiconductor powders. Nature 277:637–63810.1038/277637a0 ↗
4. Yang Z, Li J, Cheng F et al (2015) BiOBr/protonated graphitic C3N4 heterojunctions: intimate interfaces by electrostatic interaction and enhanced photocatalytic activity. J Alloys Compd 634:215–22210.1016/j.jallcom.2015.02.103 ↗
5. Barrio J, Shalom M (2017) Photoactive carbon nitride from melamine hydrochloride supramolecular assembly. Mater Sci Semicond Process 73:78–8210.1016/j.mssp.2017.04.015 ↗
6. Zhang XS, Hu JY, Jiang H (2014) Facile modification of a graphitic carbon nitride catalyst to improve its photoreactivity under visible light irradiation. Chem Eng J 256:230–23710.1016/j.cej.2014.07.012 ↗
7. Xia P, Zhu B, Yu J et al (2016) Ultra-thin nanosheet assemblies of graphitic carbon nitride for enhanced photocatalytic CO2 reduction. J Mater Chem A 00:1–9
8. Cao J, Zhao Y, Lin H et al (2013) Ag/AgBr/g-C3N4: a highly efficient and stable composite photocatalyst for degradation of organic contaminants under visible light. Mater Res Bull 48:3873–388010.1016/j.materresbull.2013.05.120 ↗
9. Praus P, Svoboda L, Ritz M et al (2017) Graphitic carbon nitride: synthesis, characterization and photocatalytic decomposition of nitrous oxide. Mater Chem Phys 193:438–44610.1016/j.matchemphys.2017.03.008 ↗
10. Dong R, Tian B, Zeng C et al (2012) Ecofriendly synthesis and photocatalytic activity of uniform cubic Ag@AgCl plasmonic photocatalyst. J Phys Chem C 4:213–220
11. Zheng Y, Liu J, Liang JJ et al (2012) Graphitic carbon nitride materials: controllable synthesis and applications in fuel cells and photocatalysis. Energy Environ Sci 5:6717–673110.1039/c2ee03479d ↗
12. Sun Z, Wang H, Wu Z, Wang L (2018) g-C3N4 based composite photocatalysts for photocatalytic CO2 reduction. Catal Today 300:160–17210.1016/j.cattod.2017.05.033 ↗
13. Xu H, Zhao H, Song Y et al (2015) g-C3N4/Ag3PO4 composites with synergistic effect for increased photocatalytic activity under the visible light irradiation. Mater Sci Semicond Process 39:726–73410.1016/j.mssp.2015.04.013 ↗
14. Ohno T, Murakami N, Koyanagi T, Yang Y (2014) Photocatalytic reduction of CO2 over a hybrid photocatalyst composed of WO3 and graphitic carbon nitride (g-C3N4) under visible light. J CO2 Util 6:17–2510.1016/j.jcou.2014.02.002 ↗
15. He Y, Wang Y, Zhang L et al (2015) High-efficiency conversion of CO2 to fuel over ZnO/g-C3N4 photocatalyst. Appl Catal B Environ 168–169:1–8
16. Wang Y, Xu Y, Wang Y et al (2016) Synthesis of Mo-doped graphitic carbon nitride catalysts and their photocatalytic activity in the reduction of CO2 with H2O. Catal Commun 74:75–7910.1016/j.catcom.2015.10.029 ↗
17. Wang K, Li Q, Liu B et al (2015) Sulfur-doped g-C3N4 with enhanced photocatalytic CO2-reduction performance. Appl Catal B Environ 176–177:44–52
18. Cui L, Jiao T, Zhang Q et al (2015) Facile preparation of silver halide nanoparticles as visible light photocatalysts. Nanomater Nanotechnol 5:110.5772/60109 ↗
19. An C, Wang J, Liu J, Zhang Q (2014) Plasmonic enhancement of photocatalysis over Ag incorporated AgI hollow nanostructures. RSC Adv 4:2409–241310.1039/C3RA46527F ↗
20. Reddy DA, Lee S, Choi J et al (2015) Green synthesis of AgI-reduced graphene oxide nanocomposites: toward enhanced visible-light photocatalytic activity for organic dye removal. Appl Surf Sci 341:175–18410.1016/j.apsusc.2015.03.019 ↗
21. Cao J, Xu B, Luo B et al (2011) Preparation, characterization and visible-light photocatalytic activity of AgI/AgCl/TiO2. Appl Surf Sci 257:7083–708910.1016/j.apsusc.2011.03.046 ↗
22. Yi J, Huang L, Wang H et al (2015) AgI/TiO2 nanobelts monolithic catalyst with enhanced visible light photocatalytic activity. J Hazard Mater 284:207–21410.1016/j.jhazmat.2014.11.020 ↗
23. Vignesh K, Suganthi A, Rajarajan M, Sara SA (2012) Photocatalytic activity of AgI sensitized ZnO nanoparticles under visible light irradiation. Powder Technol 224:331–33710.1016/j.powtec.2012.03.015 ↗
24. Vignesh K, Suganthi A, Min B-K et al (2015) Designing of YVO4 supported β-AgI nano-photocatalyst with improved stability. RSC Adv 5:576–58510.1039/C4RA14291H ↗
25. Katsumata H, Hayashi T, Taniguchi M, Suzuki T (2015) AgI/AgPO4 hybrids with highly efficient visible-light driven photocatalytic activity. Mater Res Bull 63:116–12210.1016/j.materresbull.2014.11.040 ↗
26. Cui DH, Song XC, Zheng YF (2016) A novel AgI/BiOIO3 nanohybrid with improved visible-light photocatalytic activity. RSC Adv 6:71983–7198810.1039/C6RA14486A ↗
27. Xu H, Yan J, Xu Y et al (2013) Novel visible-light-driven AgX/graphite-like C3N4 (X = Br, I) hybrid materials with synergistic photocatalytic activity. Appl Catal B Environ 129:182–19310.1016/j.apcatb.2012.08.015 ↗
28. Zhang Z, Jiang D, Xing C et al (2015) Novel AgI-decorated β-Bi2O3 nanosheet heterostructured Z-scheme photocatalysts for efficient degradation of organic pollutants with enhanced performance. Dalton Trans 44:11582–1159110.1039/C5DT00298B ↗
29. Murugesan P, Narayanan S, Manickam M (2017) Experimental studies on photocatalytic reduction of CO2 using AgBr decorated g-C3N4 composite in TEA mediated system. J CO2 Util 22:250–26110.1016/j.jcou.2017.10.012 ↗
30. Wang H, Sun Z, Li Q et al (2016) Surprisingly advanced CO2 photocatalytic conversion over thiourea derived g-C3N4 with water vapor while introducing 200–420 nm UV light. J CO2 Util 14:143–15110.1016/j.jcou.2016.04.006 ↗
31. Tan LL, Ong WJ, Chai SP, Mohamed AR (2017) Photocatalytic reduction of CO2 with H2O over graphene oxide-supported oxygen-rich TiO2 hybrid photocatalyst under visible light irradiation: process and kinetic studies. Chem Eng J 308:248–25510.1016/j.cej.2016.09.050 ↗
32. Chen S, Pan B, Zeng L et al (2017) La2Sn2O7 enhanced photocatalytic CO2 reduction with H2O by deposition of Au co-catalyst. RSC Adv 7:14186–1419110.1039/C7RA00765E ↗
33. Zhai HS, Cao L, Xia XH (2013) Synthesis of graphitic carbon nitride through pyrolysis of melamine and its electrocatalysis for oxygen reduction reaction. Chin Chem Lett 24:103–10610.1016/j.cclet.2013.01.030 ↗
34. Yu JC, Yu J, Ho W et al (2002) Effects of F-doping on the photocatalytic activity and microstructures of nanocrystalline TiO2 powders. Chem Mater 14:3808–381610.1021/cm020027c ↗
35. Ong WJ, Putri LK, Tan LL et al (2016) Heterostructured AgX/g-C3N4 (X = Cl and Br) nanocomposites via a sonication-assisted deposition–precipitation approach: emerging role of halide ions in the synergistic photocatalytic reduction of carbon dioxide. Appl Catal B Environ 180:530–54310.1016/j.apcatb.2015.06.053 ↗
36. Lan Y, Qian X, Zhao C et al (2013) High performance visible light driven photocatalysts silver halides and graphitic carbon nitride (X = Cl, Br, I). J Colloid Interface Sci 395:75–8010.1016/j.jcis.2012.12.033 ↗
37. Akhundi A, Yangjeh AH (2016) Facile preparation of novel quaternary g-C3N4/Fe3O4/AgI/Bi2S3 nanocomposites: magnetically separable visible-light-driven photocatalysts with significantly enhanced activity. RSC Adv 6:106572–10658310.1039/C6RA12414C ↗
38. Alexander L, Klug HP (1950) Determination of crystallite size with the X-ray spectrometer. J Appl Phys 21:13710.1063/1.1699612 ↗
39. Zhang L, Chen X, Guan J et al (2013) Facile synthesis of phosphorus doped graphitic carbon nitride polymers with enhanced visible-light photocatalytic activity. Mater Res Bull 48:3485–349110.1016/j.materresbull.2013.05.040 ↗
40. Ma T, Bai J, Li C (2017) Facile synthesis of g-C3N4 wrapping on one-dimensional carbon fiber as a composite photocatalyst to degrade organic pollutants. Vaccum 145:47–5410.1016/j.vacuum.2017.08.027 ↗
41. Kong J-Z, Zhai H-F, Zhang W et al (2017) Visible light-driven photocatalytic performance of N-doped ZnO/g-C3N4 nanocomposites. Nanoscale Res Lett 12:52610.1186/s11671-017-2297-0 ↗
42. Jia L, Wang H, Dhawale D et al (2014) Highly ordered macro-mesoporous carbon nitride film for selective detection of acidic/basic molecules. Chem Commun 50:5976–597910.1039/C4CC02042A ↗
43. Feng Z, Zeng L, Chen Y et al (2017) In situ preparation of Z-scheme MoO3/g-C3N4 composite with high performance in photocatalytic CO2 reduction and RhB degradation. J Mater Res 32:3660–366810.1557/jmr.2017.271 ↗
44. Il’in EG, Parshakov AS, Teterin YA, Maslakov KI, Teterin AY (2017) Surface composition and morphology of a carbon matrix/Mo2C composite material. Inorg Mater 53:469–47610.1134/S0020168517050107 ↗
45. Zhang W, Hu Y, Ma L et al (2018) Progress and perspective of electrocatalytic CO2 reduction for renewable carbonaceous fuels and chemicals. Adv Sci 5:170027510.1002/advs.201700275 ↗
46. Chang X, Wang T, Gong J (2016) CO2 photo-reduction: insights into CO2 activation and reaction on surfaces of photocatalysts. Energy Environ Sci 9:2177–219610.1039/C6EE00383D ↗
47. Kinet Mech Cat R, Rahim Uddin M, Khan MR et al (2016) Photocatalytic reduction of CO2 into methanol over CuFe 2O4/TiO2 under visible light irradiation. React Kinet Mech Catal 10:1174–1181
48. Tseng I, Chang W, Wu JCS (2002) Photoreduction of CO2 using sol–gel derived titania and titania-supported copper catalysts. Appl Catal B Environ 37:37–4810.1016/S0926-3373(01)00322-8 ↗
49. Li S, Jiaxing Z, Wang X et al (2014) In situ ion exchange synthesis of strongly coupled Ag@AgCl/g-C3N4 porous nanosheets as plasmonic photocatalyst for highly efficient visible-light photocatalysis. Appl Mater Interfaces 6:22116–2212510.1021/am505528c ↗
50. Khalid NR, Ahmed E, Niaz NA et al (2017) Highly visible light responsive metal loaded N/TiO2 nanoparticles for photocatalytic conversion of CO2 into methane. Ceram Int 43:6771–677710.1016/j.ceramint.2017.02.093 ↗
51. Dean JA (1999) Handbook of chemistry, 15th edn. McGraw-Hill, New York
52. Karamian E, Sharifnia S (2016) On the general mechanism of photocatalytic reduction of CO2. J CO2 Util 16:194–20310.1016/j.jcou.2016.07.004 ↗
53. Zhang G, Su A, Qu J, Xu Y (2014) Synthesis of BiOI flower like hierarchical structures toward photocatalytic reduction of CO2 to CH4. Mater Res Bull 55:43–4710.1016/j.materresbull.2014.04.012 ↗
54. Maeda K, Sekizawa K, Ishitani O (2013) A polymeric-semiconductor–metal-complex hybrid photocatalyst for visible-light CO2 reduction. Chem Commun 49:1012710.1039/c3cc45532g ↗
55. Li H, Li C, Han L et al (2016) Photocatalytic reduction of CO2 with H2O on CuO/TiO2 catalysts. Energy Sour Part A Recover Util Environ Eff 38:420–42610.1080/15567036.2011.598910 ↗
56. Kaneco S, Kurimoto H, Ohta K, Mizuno T (1997) Photocatalytic reduction of CO2 using TiO2 powders in liquid CO2 medium. J Photochem Photobiol A 109:59–6310.1016/S1010-6030(97)00107-X ↗
57. Murugesan P, Narayanan S, Manickam M et al (2018) A direct Z-scheme plasmonic AgCl@g-C3N4 heterojunction photocatalyst with superior visible light CO2 reduction in aqueous medium. Appl Surf Sci 450:516–52610.1016/j.apsusc.2018.04.111 ↗