Enhanced electrochemical energy storage devices utilizing a one-dimensional (1D) α-MnO2 nanocomposite encased in onion-like carbon
Source abstract
Abstract
Abstract This work describes the fabrication of a novel one-dimensional (1D) α-MnO2 nanorods encased in onion-like carbon (or) carbon nano-onions (OLC) via microwave irradiation techniques employing electrolytic manganese dioxide (EMD), which is especially beneficial for rapid ion and electron transfer, and great structural stability. The composite of α-MnO2 and OLC demonstrates exceptional performance as an electrode across various electrochemical energy storage systems, including zinc-ion batteries (ZIB), sodium-ion batteries (SIB), and supercapacitors (SC) than the pristine α-MnO2. In SIB systems, the composite exhibits a specific capacity of 266 mAh g−1 at initial cycle with 50% capacity retention over 500 cycles, whereas the pristine electrode delivers only 39% capacity retention. The rapid yet controlled charge transfer kinetics facilitated by OLC addition in the α-MnO2 matrix outperforms as the ZIB cathode with an excellent specific capacity of 476 mAh g−1 with 100% capacity retention, while the pristine sample exhibits 77.5% capacity retention. As a SC electrode, the α-MnO2/OLC composite exhibits better electrochemical properties such as rectangular behavior, increased specific capacitance (792 F g−1), excellent capacity retention at high current densities, and others. The higher surface area that could be offered by the OLC to the α-MnO2 matrix facilitates the improved electrochemistry in the pristine sample and this kind of modification can be a viable solution to overcome the limitations of α-MnO2 for electrochemical energy storage applications. It is important to note that the performance outputs of α-MnO2/OLC composite are far better than the regular carbon (graphite, graphene) in α-MnO2 electrodes. Further, OLC provided with high surface area and ordered morphology can play the role of conductivity booster, structural stabilizer, and electrochemical active material in all the energy storage applications which may give a significant research attention in near future.
Source: crossref · Quality: baseline
Research context
OpenAlex topics: Supercapacitor Materials and Fabrication · Advanced battery technologies research · Advancements in Battery Materials
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (100+)
Show source-provided references
1. Nithyadharseni P, Reddy MV, Fanny H, Adams S, Chowdari BVR (2015) Facile one-pot synthesis and Li-cycling properties of MnO2. RSC Adv 5:60552–6056110.1039/C5RA09278G ↗
2. Huang A, Zhou W, Wang A, Chen M, Tian Q, Chen J (2021) Molten salt synthesis of α- MnO2/Mn2O3 nanocomposite as a high-performance cathode material for aqueous zinc-ion batteries. J Energy Chem 54:475–48110.1016/j.jechem.2020.06.041 ↗
3. Song M, Tan H, Chao D, Fan HJ (2018) Recent advances in Zn-ion batteries. Adv Funct Mater 28:180256410.1002/adfm.201802564 ↗
4. Zeng X, Hao J, Wang Z, Mao J, Guo Z (2019) Recent Progress and perspective on aqueous Zn-based rechargeable batteries with mild aqueous electrolytes. Energy Storage Mater 20:410–43710.1016/j.ensm.2019.04.022 ↗
5. Konarov A, Voronina N, Jo JH, Bakenov Z, Sun YK, Myung ST (2018) Present and future perspective on electrode materials for rechargeable zinc-ion batteries. ACS Energy Lett 3:2620–264010.1021/acsenergylett.8b01552 ↗
6. Palaniyandy N (2020) Recent developments on layered 3d-transition metal oxide cathode materials for sodium-ion batteries. Curr Opin Electrochem 21:319–326. https://doi.org/10.1016/j.coelec.2020.03.02310.1016/j.coelec.2020.03.023 ↗
7. Lakshmi D, Palaniyandy N, Bohm S, Mamba BB (2023) Understanding the mechanisms of mixed-ion cathode materials for aqueous and non-aqueous lithium/sodium-ion batteries–A review. Curr Opin Electrochem 38:10121710.1016/j.coelec.2023.101217 ↗
8. Zhou YN, Xiao Z, Han D, Wang S, Chen J, Tang W, Yang M, Shao L, Shu C, Hua W, Zhou D, Wu Y (2023) Inhibition of the P3–O3 phase transition via local symmetry tuning in P3-type layered cathodes for ultra-stable sodium storage. J Mater Chem A 11:2618–262610.1039/D2TA09277H ↗
9. Worku Y, Palaniyandy N, Srinivasu Vallabhapurapu VS, Mamba BB (2023) Nanotechnology in advanced 2D and 3D nanostructured transition metal oxide based flexible supercapacitors: a review. Chem Electro Chem. https://doi.org/10.1002/celc.20230046310.1002/celc.202300463 ↗
10. Palaniyandy N, Kebede MA (2020) Sodium-ion battery anode materials and its future prospects and challenges. In: Kebede MA, Ezema FI (eds) Electrochemical devices for energy storage applications. CRC Press, pp 41–58
11. Molenda J, Milewska A, Zając W, Walczak K, Wolczko M, Komenda A, Tobola J (2023) Impact of O3/P3 phase transition on the performance of the NaxTi1/6Mn1/6Fe1/6Co1/6Ni1/6Cu1/6O2 cathode material for Na-ion batteries. J Mater Chem A 11(8):4248–426010.1039/D2TA08431G ↗
12. Pan Z, Zhang X, Xu S, Gu M, Rui X, Zhang X (2023) Chloride-doping, defect and interlayer engineering of copper sulfide for superior sodium-ion batteries. J Mater Chem A 11(8):4102–411010.1039/D2TA09612A ↗
13. Fan Y, Ye X, Yang X, Guan L, Chen C, Wang H, Ding X (2023) Zn/Ti/F synergetic-doped Na0.67Ni0.33Mn0.67O2 for sodium-ion batteries with high energy density. J Mater Chem A 11(7):3608–361510.1039/D2TA08315A ↗
14. Singh S, Singh D, Ahuja R, Fichtner M, Barpanda P (2023) Eldfellite NaV(SO4)2 as a versatile cathode insertion host for Li-ion and Na-ion batteries. J Mater Chem A 11(8):3975–398610.1039/D2TA03673H ↗
15. Yabuuchi N, Kubota K, Dahbi M, Komaba S (2014) Research development on sodium-ion batteries. Chem Rev 114:11636–1168210.1021/cr500192f ↗
16. Tatara R, Suzuki H, Hamada M, Kubota K, Kumakura S, Komaba S (2022) Application of P2-Na2/3Ni1/3Mn2/3O2 electrode to all-solid-state 3V sodium (-ion) polymer batteries. J Phys Chem C 126:20226–2023410.1021/acs.jpcc.2c06360 ↗
17. Kim EJ, Hosaka T, Kubota K, Tatara R, Kumakura S, Komaba S (2022) Effect of Cu substitution in P’2-and P2-type sodium manganese-based oxides. ACS Appl Energy Mater 5:12999–1301010.1021/acsaem.2c02581 ↗
18. Kumar PR, Kubota K, Igarashi D, Komaba S (2021) Enhanced electrochemical properties of KTiOPO4–rGO negative electrode for sodium and potassium ion batteries. J Phys Chem C 125:24823–2483010.1021/acs.jpcc.1c08339 ↗
19. Hameed AS, Ohara M, Kubota K, Komaba S (2021) A phosphite-based layered framework as a novel positive electrode material for Na-ion batteries. J Mater Chem A 9:5045–505210.1039/D0TA10517A ↗
20. Zhu L, Wang H, Sun D, Tang Y, Wang H-Y (2020) A comprehensive review on the fabrication, modification and applications of Na3V2(PO4)2F3 cathodes. J Mater Chem A 8:21387–2140710.1039/D0TA07872G ↗
21. Zhu C, Wu C, Chen C-C, Kopold P, van Aken PA, Maier J, Yu Y (2017) A high power-high energy Na3V2(PO4)2F3 sodium cathode: investigation of transport parameters. Rat Design Realiz Chem Mater 29:5207–5215
22. Kubota K, Fujitani N, Yoda Y, Kuroki K, Tokita Y, Komaba S (2021) Impact of Mg and Ti doping in O3 type NaNi1/2Mn1/2O2 on reversibility and phase transition during electrochemical Na intercalation. J Mater Chem A 9:12830–1284410.1039/D1TA01164B ↗
23. Kubota K, Miyazaki M, Jeong Kim E, Yoshida H, Barpanda P, Komaba S (2021) Structural change induced by electrochemical sodium extraction from layered O′3-NaMnO2. J Mater Chem A 9:26810–2681910.1039/D1TA05390F ↗
24. Chae MS, Elias Y, Aurbach D (2021) Tunnel-type sodium manganese oxide cathodes for sodium-ion batteries. ChemElectroChem 8:798–81110.1002/celc.202001323 ↗
25. Karbak M, Baazizi M, Sayah S, Lambert CA, Tison Y, Martinez H, Chafik T, Ghamouss F (2023) Unraveling high-performance oxygen-deficient amorphous manganese oxide as the cathode for advanced zinc ion batteries. J Mater Chem A 11:2634–264010.1039/D2TA07838D ↗
26. Shi M, Wang B, Chen C, Lang J, Yana C, Yanb XB (2020) 3D high-density MXene@MnO2 microflowers for advanced aqueous Zinc-Ion batteries. J Mater Chem A 8:24635–2464410.1039/D0TA09085A ↗
27. Chen C, Shi M, Zhao Y, Yang C, Zhao L, Yan C (2021) Al-Intercalated MnO2 cathode with reversible phase transition for aqueous Zn-Ion batteries. Chem Eng J 422:13037510.1016/j.cej.2021.130375 ↗
28. Zeng S, Song Y, Shi X, Xu W, Zheng D, Wang F, Xu C, Lu X (2022) Crystal form modulation enables high-performance manganese dioxide cathode for aqueous zinc ion battery. J Alloys Compd 913:16520710.1016/j.jallcom.2022.165207 ↗
29. Tong H, Li T, Liu J, Gong D, Xiao J, Shen L, Ding B, Zhang X (2021) Fabrication of the oxygen vacancy amorphous mno2/carbon nanotube as cathode for advanced aqueous Zinc-Ion batteries. Energy Technol 9:200076910.1002/ente.202000769 ↗
30. Xia X, Zhao Y, Zhao Y, Xu M, Liu W, Sun X (2022) Mo doping provokes two-electron reaction in MnO2 with ultrahigh capacity for aqueous zinc-ion batteries. Nano Res 16(2):2511–251810.1007/s12274-022-5057-0 ↗
31. Duan Q, Wang Y, Dong S, Yu DYW (2022) Facile electrode additive stabilizes the structure of electrolytic MnO2 for a mild aqueous rechargeable zinc-ion battery. J Power Sources 528:23119410.1016/j.jpowsour.2022.231194 ↗
32. Jing FY, Pei J, Zhou Y, Shang Y, Yao S, Liu S, Chen G (2022) High-performance reversible aqueous Zinc-Ion battery based on Zn2+ pre-intercalation alpha-manganese dioxide nanowires/carbon nanotubes. J Colloid Interface Sci 609:557–56510.1016/j.jcis.2021.11.064 ↗
33. Zhang Z, Li S, Wang X, Wen Z, Sun J (2021) Single-atom platinum implanted on manganese dioxide boosted the high-rate performance of cathodes for zinc-ion batteries. J Phys Chem C 125:26371–2637810.1021/acs.jpcc.1c08418 ↗
34. Wu B, Zhang G, Yan M, Xiong T, He P, He L, Xu X, Mai L (2018) Graphene scroll-coated α-MnO2 nanowires as high-performance cathode materials for aqueous Zn-ion battery. Small 14:170385010.1002/smll.201703850 ↗
35. Palaniyandy N, Kebede MA, Raju K, Ozoemena KI, Roux LL, Mathe MK, Jayaprakasam R (2019) α- MnO2 nanorod/onion-like carbon composite cathode material for aqueous zinc-ion battery. Mater Chem Phys 230:258–26610.1016/j.matchemphys.2019.03.069 ↗
36. Gao X, Wu H, Li W, Tian Y, Zhang Y, Wu H, Yang L, Zou G, Hou H, Ji X (2020) H+-insertion boosted α-MnO2 for an aqueous Zn-ion battery. Small 16:190584210.1002/smll.201905842 ↗
37. Alfaruqi MH, Islam S, Gim J, Song J, Kim S, Pham DT, Jo J, Xiu Z, Mathew V, Kim J (2016) A high surface area tunnel-type α- MnO2 nanorod cathode by a simple solvent-free synthesis for rechargeable aqueous zinc-ion batteries. Chem Phys Lett 650:64–6810.1016/j.cplett.2016.02.067 ↗
38. Iamprasertkun P, Krittayavathananon A, Seubsai A, Chanlek N, Kidkhunthod P, Sangthong W, Maensiri S, Yimnirun R, Nilmoung S, Pannopard P, Ittisanronnachai S, Kongpatpanich K, Limtrakul J, Sawangphruk M (2016) Charge storage mechanisms of manganese oxide nanosheets and N-doped reduced graphene oxide aerogel for high-performance asymmetric supercapacitors. Sci Rep 6:1–1210.1038/srep37560 ↗
39. Jayachandran M, Rose A, Maiyalagan T, Poongodi N, Vijayakumar T (2021) Effect of various aqueous electrolytes on the electrochemical performance of α- MnO2 nanorods as electrode materials for supercapacitor application. Electrochim Acta 366:13741210.1016/j.electacta.2020.137412 ↗
40. Shen C, Wang X, Li S, Wang JG, Zhang W, Kang F (2013) A high-energy-density micro supercapacitor of asymmetric MnO2 -carbon configuration by using micro-fabrication technologies. J Power Sources 234:302–30910.1016/j.jpowsour.2012.10.101 ↗
41. Hu CC, Hung CY, Chang KH, Yang YL (2011) A hierarchical nanostructure consisting of amorphous MnO2, Mn3O4 nanocrystallites, and single-crystalline MnOOH nanowires for supercapacitors. J Power Sources 196:847–85010.1016/j.jpowsour.2010.08.001 ↗
42. Zhao X, Hou Y, Wang Y, Yang L, Zhu L, Cao R, Sha Z (2017) Prepared MnO2 with different crystal forms as electrode materials for supercapacitors: experimental research from hydrothermal crystallization process to electrochemical performances. RSC Adv 7:4028610.1039/C7RA06369E ↗
43. Li M, Lei W, Yu Y, Yang W, Li J, Chen D, Xu S, Feng M, Li H (2018) High-performance asymmetric supercapacitors based on monodisperse MnO nanocrystals with high energy densities. Nanoscale 10:15926–1593110.1039/C8NR04541K ↗
44. Asbani B, Robert K, Roussel P, Brousse T, Lethien C (2021) Asymmetric micro-supercapacitors based on electrodeposited Ruo2 and sputtered VN films. Energy Storage Mater 37:207–21410.1016/j.ensm.2021.02.006 ↗
45. Nady JE, Shokry A, Khalil M, Ebrahim S, Elshaer AM, Anas M (2022) One-step electrodeposition of a polypyrrole/NiO nanocomposite as a supercapacitor electrode. Sci Rep 12:361110.1038/s41598-022-07483-y ↗
46. Ye TF, Wu HX, Shao YQ, Ye ZG, Li GY, Wang JJ, Chen K (2022) Study on the effect of graphene/carbon nanotubes on the enhanced capacitance of IrO2-ZnO-G(CNT)/Ti Electrodes. Energy Fuels 36:3259–327110.1021/acs.energyfuels.1c04037 ↗
47. Safari M, Mazloom J, Boustani K, Monemdjou A (2022) Hierarchical Fe2O3 hexagonal nanoplatelets anchored on SnO2 nanofibers for high-performance asymmetric supercapacitor device. Sci Rep 12:1491910.1038/s41598-022-18840-2 ↗
48. Tian M, Li R, Liu C, Long D, Cao G (2019) Aqueous Al-Ion supercapacitor with V2O5 mesoporous carbon electrodes. ACS Appl Mater Interfaces 11(17):15573–1558010.1021/acsami.9b02030 ↗
49. Shaheen I, Ahmad KS, Zequine C, Gupta RK, Thomas AG, Malik MA (2021) Facile ZnO-based nanomaterial and its fabrication as a supercapacitor electrode: synthesis, characterization and electrochemical studies. RSC Adv 11(38):23374–2338410.1039/D1RA04341B ↗
50. Rabani I, Yoo J, Kim H-S, Hussain S, Karuppasamy K, Seo YS (2021) Highly dispersive Co3O4 nanoparticles incorporated into cellulose nanofiber for high-performance flexible supercapacitor. Nanoscale 13(1):355–37010.1039/D0NR06982E ↗
51. Rabani I, Younus A, Patil S, Seo YS (2022) Fabrication of Fe3O4-incorporated MnO2 nanoflowers as electrodes for enhanced asymmetric supercapacitor performance. Dalton Trans 51:1419010.1039/D2DT01942F ↗
52. Ahamad T, Naushad M, Ubaidullah M, Alzaharani Y, Alshehri SM (2020) Birnessite-type manganese dioxide nanoparticles embedded with nitrogen-doped carbon for high-performance supercapacitor. J Energy Storage 32:10195210.1016/j.est.2020.101952 ↗
53. Li Z, Xiao D, Xu C, Li Z, Bi S, Xu H, Dou H, Zhang XG (2022) MnO2/carbon nanotube free-standing electrode recycled from spent manganese-oxygen battery as high-performance supercapacitor material. J Mater Sci 57:8818–882710.1007/s10853-022-07223-7 ↗
54. Palaniyandy N, Reddy MV, Mamba BB (2023) Unveiling the electrochemistry effect on microsphere and nanorod morphology of NaSn2(PO4)3 anode for lithium/sodium batteries. J Solid State Electrochem 27(2):427–438. https://doi.org/10.1007/s10008-022-05324-610.1007/s10008-022-05324-6 ↗
55. Lakshmi D, Diana MI, Manoj G, Jayapandi S, Nalini B, Selvin PC, Balraju P (2022) Influence of reducing agents in nanoparticle synthesis: SnO2-ZnO composite anode. Appl Organomet Chem. https://doi.org/10.1002/aoc.671410.1002/aoc.6714 ↗
56. Yue T, Shen B, Gao P (2022) Carbon material/MnO2 as conductive skeleton for supercapacitor electrode material: a review. Renew Sustain Energy Rev 158:11213110.1016/j.rser.2022.112131 ↗
57. Bhat TS, Jadhav SA, Beknalkar SA, Patil SS, Patil PS (2022) MnO2 core-shell type materials for high-performance supercapacitors: a short review. Inorg Chem Commun 141:10949310.1016/j.inoche.2022.109493 ↗
58. Kumar N, Gajraj V, Upadhyay S, Chetana S, Sankaranarayanan S, Hossain I, Joshi NC, Priyadarshi N, Sen A (2023) One-step fragmentation of a 2D MXene across the fine 1D MnO2 surface and its supercapacitance. CrystEngComm 25:72–8510.1039/D2CE01323A ↗
59. Mustaqeem M, Naikoo GA, Yarmohammadi M, Pedram MZ, Pourfarzad H, Dar RA, Taha SA, Hassan IU, Bhat MY, Chen YF (2022) Rational design of metal oxide-based electrode materials for high-performance supercapacitors–A review. J Energy Storage 55:10541910.1016/j.est.2022.105419 ↗
60. Abdelrahim AM, Abd El-Moghny MG, El-Shakre ME, El-Deab MS (2023) High mass loading MnO2/graphite felt electrode with marked stability over a wide potential window of 1.9 V for supercapacitor application. J Energy Storage 57:10621810.1016/j.est.2022.106218 ↗
61. McDonough JK, Gogotsi Y (2013) Carbon onions: synthesis and electrochemical applications. Electrochem Soc Interface 22:61–6610.1149/2.F05133if ↗
62. Zeiger M, Jäckel N, Mochalic VN, Presser V (2016) Review: carbon onions for electrochemical energy storage. J Mater Chem A 4:3172–319610.1039/C5TA08295A ↗
63. Lakshmi D, Diana MI, Jayapandi S, Selvin PC, Balraju P (2023) Deciphering the functionalization routes for SnO2 anodes. J Mater Sci 58:15471–15484. https://doi.org/10.1007/s10853-023-08986-310.1007/s10853-023-08986-3 ↗
64. Raju K, Han H, Velusamy DB, Jiang Q, Yang H, Nkosi FP, Palaniyandy N, Makgopa K, Bo Z, Ozoemena KI (2020) Rational design of 2D manganese phosphate hydrate nanosheets as pseudocapacitive electrodes. ACS Energy Lett 5:23–3010.1021/acsenergylett.9b02299 ↗
65. Li W, Zeng R, Sun Z, Tian D, Dou S (2014) Uncoupled surface spin induced exchange bias in α- MnO2 nanowires. Sci Rep 4:664110.1038/srep06641 ↗
66. Davoglio RA, Cabello G, Marco JF, Biaggio SR (2018) Synthesis and characterization of α- MnO2 nanoneedles for electrochemical supercapacitors. Electrochim Acta 261:428–43510.1016/j.electacta.2017.12.118 ↗
67. Palaniyandy N, Nkosi FP, Raju K, Ozoemena KI (2019) Conversion of electrolytic MnO2 to Mn3O4 nanowires for high-performance anode materials for lithium-ion batteries. J Electroanal Chem 833:79–9210.1016/j.jelechem.2018.11.002 ↗
68. Cheng J, Wang D, Wang B, Ning H, Zhang Y, Li Y, An J, Gao P (2020) Plasma-catalytic degradation of ciprofloxacin in aqueous solution over different MnO2 nanocrystals in a dielectric barrier discharge system. Chemosphere 253:12659510.1016/j.chemosphere.2020.126595 ↗
69. Hussain S, Amade R, Jover E, Bertran E (2013) Water plasma functionalized CNTs/MnO2 composites for supercapacitors. Sci World J. https://doi.org/10.1155/2013/83258110.1155/2013/832581 ↗
70. Yang Z, Lv J, Pang H, Yan W, Qian K, Guo T, Guo Z (2015) Facile Synthesis of coaxial CNTs/MnO x-carbon hybrid nanofibers and their greatly enhanced lithium storage performance. Sci Rep 5:1747310.1038/srep17473 ↗
71. Wei C, Xu C, Li B, Du H, Kang F (2012) Preparation and characterization of manganese dioxides with nano-sized tunnel structures for zinc ion storage. J Phys Chem Solids 73(12):1487–149110.1016/j.jpcs.2011.11.038 ↗
72. Makgopa K, Ejikeme PM, Jafta CJ, Raju K, Zeiger M, Presser V, Ozoemena KI (2015) A high-rate aqueous symmetric pseudocapacitor based on highly graphitized onion-like carbon/birnessite-type manganese oxide nanohybrids. J Mater Chem A 3:3480–349010.1039/C4TA06715K ↗
73. Su D, Ahn HJ, Wang G (2013) Hydrothermal synthesis of α- MnO2 and β- MnO2 nanorods as high-capacity cathode materials for sodium ion batteries. J Mater Chem A 1:4845–485010.1039/c3ta00031a ↗
74. Petnikota S, Srikanth VVSS, Nithyadharseni P, Reddy MV, Adams S, Chowdari BVR (2015) Sustainable graphenothermal reduction chemistry to obtain MnO nanonetwork supported exfoliated graphene oxide composite and its electrochemical characteristics. ACS Sustain Chem Eng 3:3205–321310.1021/acssuschemeng.5b00791 ↗
75. Wu W, Wang P, Lin L, Dai SF (2018) Manganese ore decomposition and carbon reduction in steelmaking. High Temp Mater Process (London) 37(8):741–74710.1515/htmp-2017-0042 ↗
76. Zhang X, Wang T, Jiang C, Zhang F, Li W, Tang Y (2016) Manganese dioxide/carbon nanotubes composite with optimized microstructure via room temperature solution approach for high-performance lithium-ion battery anodes. Electrochim Acta 187:465–47210.1016/j.electacta.2015.11.084 ↗
77. Zhou Y, Chen T, Zhang J, Liu Y, Ren P (2017) Amorphous MnO2 as cathode material for sodium-ion batteries. Chi J Chem 35:1294–129810.1002/cjoc.201600915 ↗
78. Su D, Ahn HJ, Wang G (2013) β-MnO2 nanorods with exposed tunnel structures as high-performance cathode materials for sodium-ion batteries. NPG Asia Mater 5:e7010.1038/am.2013.56 ↗
79. Biswal A, Chandra Tripathy BC, Sanjay K, Subbaiah T, Minakshi M (2015) Electrolytic manganese dioxide (EMD): a perspective on worldwide production, reserves and its role in electrochemistry. RSC Adv 5(72):58255–58283. https://doi.org/10.1039/C5RA05892A10.1039/C5RA05892A ↗
80. Minakshi Sundaram M, Biswal A, Mitchell DRG, Jones R, Fernandez C (2016) Correlation among physical and electrochemical behaviour of nanostructured electrolytic manganese dioxide from leach liquor and synthetic for aqueous asymmetric capacitor. Phys Chem Chem Phys 18(6):4711–4720. https://doi.org/10.1039/c5cp07141k10.1039/c5cp07141k ↗
81. Biswal SA, Tripathy BC, Subbaiah T, Meyrick D, Minakshi M (2015) Dual effect of anionic surfactants in the electrodeposited MnO2 trafficking redox ions for energy. J Electrochem Soc 162(1):A30–A3810.1149/2.0191501jes ↗
82. Zhang Y, Yang Y, Zhang Y, Zhang T, Ye M (2012) Heterogeneous oxidation of naproxen in the presence of α-MnO2 nanostructures with different morphologies. Appl Cat B 127:182–189. https://doi.org/10.1016/j.apcatb.2012.08.01410.1016/j.apcatb.2012.08.014 ↗
83. Yusof SN, Zain NK, Misnon II, Jose R (2018) Electrochemical evaluation of fluorinated MnO2 for supercapacitor application. MATEC Web Conf 150:02006. https://doi.org/10.1051/matecconf/20181500200610.1051/matecconf/201815002006 ↗
84. Pandit B, Rondiya SR, Dzade NY, Shaikh SF, Kumar N, Goda ES, Al-Kahtani AA, Mane RS, Mathur S, Salunkhe RR (2021) High stability and long cycle life of rechargeable sodium-ion battery using manganese oxide cathode: a combined density functional theory (DFT) and experimental study. ACS Appl Mater Interfaces 13:11433–1144110.1021/acsami.0c21081 ↗
85. Wang Z, Yan XD, Wang F, Xiong T, Balogun MS, Zhou H, Deng J (2021) Reduced graphene oxide thin layer induced lattice distortion in high crystalline MnO2 nanowires for high-performance sodium- and potassium-ion batteries and capacitors. Carbon 174:556–56610.1016/j.carbon.2020.12.071 ↗
86. Wang R, Liu Z, Zhao D, Xu J, Cao Y, Huang JH, Zhang J (2022) In situ micro-current collector of amorphous manganese dioxide as cathode material for sodium-ion batteries. Ionics 28:1211–121710.1007/s11581-021-04403-4 ↗
87. Wu L, Guo S, Pu X, Yue H, Li H, Li P, Li W, Cai K, Ding W, Li L, Zhang Y, Fa W, Yang C, Zheng Z, He WW, Cao Y (2022) Na0.91 MnO2 with an extended layer structure and excellent pseudocapacitive behavior as a cathode material for sodium-ion batteries. ACS Appl Energy Mater 5:4505–451210.1021/acsaem.1c04102 ↗
88. Li H, Liu A, Zhao S, Guo Z, Wang N, Ma T (2018) In Situ growth of a feather-like MnO2 nanostructure on carbon paper for high-performance rechargeable sodium-ion batteries. ChemElectroChem 5:3266–327210.1002/celc.201800830 ↗
89. Zhu CY, Fang GZ, Liang SQ, Chen ZX, Wang ZQ, Ma JY, Wang H, Tang B, Zheng XS, Zhou J (2020) Electrochemically induced cationic defect in MnO intercalation cathode for aqueous zinc-ion battery. Energy Storage Mater 24:394–40110.1016/j.ensm.2019.07.030 ↗
90. Wu BK, Zhang GB, Yan MY, Xiong TF, He P, He L, Xu X, Mai LQ (2018) Graphene scroll-coated α- MnO2 nanowires as high-performance cathode materials for aqueous Zn-Ion battery. Small 14:170385010.1002/smll.201703850 ↗
91. Liu MQ, Zhao Q, Liu H, Yang JL, Chen X, Yang LY, Cui YH, Huang WY, Zhao WG, Song A, Wang YT, Ding SX, Song YL, Qian GY, Chen HB, Pan F (2019) Tuning phase evolution of β- MnO2 during microwave hydrothermal synthesis for high-performance aqueous Zn ion battery. Nano Energy 64:10394210.1016/j.nanoen.2019.103942 ↗
92. Fang GZ, Zhu CY, Chen MH, Zhou J, Tang B, Cao XX, Zheng XS, Pan AQ, Liang SQ (2019) Suppressing manganese dissolution in potassium manganate with rich oxygen defects engaged high-energy-density and durable aqueous zinc-ion battery. Adv Funct Mater 29:180837510.1002/adfm.201808375 ↗
93. Liu XY, Yi J, Wu K, Jiang Y, Liu YY, Zhao B, Li WR, Zhang JJ (2020) Rechargeable Zn– MnO2 batteries: advances, challenges and perspectives. Nanotechnology 31:12200110.1088/1361-6528/ab5b38 ↗
94. Liu YZ, Chi XW, Han Q, Du YX, Huang JQ, Liu Y, Yang JH (2019) α- MnO2 nanofibers/carbon nanotubes hierarchically assembled microspheres: approaching practical applications of high-performance aqueous Zn-ion batteries. J Power Sources 443:22724410.1016/j.jpowsour.2019.227244 ↗
95. Alfaruqi MH, Islam S, Putro DY, Mathew V, Kim S, Jo J, Kim S, Sun YK, Kim K, Kim J (2018) Structural transformation and electrochemical study of layered MnO2 in rechargeable aqueous zinc-ion battery. Electrochim Acta 276:1–1110.1016/j.electacta.2018.04.139 ↗
96. Li N, Li GQ, Li CJ, Yang HC, Qin GW, Sun XD, Li F, Cheng H-M (2020) Bi-cation electrolyte for a 1.7 V aqueous Zn Ion battery. ACS Appl Mater Interfaces 12:13790–1379610.1021/acsami.9b20531 ↗
97. Zeng Y, Zhang X, Meng Y, Yu M, Yi J, Wu Y, Lu X, Tong Y (2017) Achieving ultrahigh energy density and long durability in a flexible rechargeable quasi-solid-state Zn– MnO2 battery. Adv Mater 29:170027410.1002/adma.201700274 ↗
98. Xiong T, Yu ZG, Wu H, Du Y, Xie Q, Chen J (2019) Defect engineering of oxygen-deficient manganese oxide to achieve high-performing aqueous zinc ion battery. Adv Energy Mater 9:180381510.1002/aenm.201803815 ↗
99. Yang SN, Zhang MS, Wu XW, Wu XS, Zeng FH, Li YT, Duan SY, Fan DH, Yang Y, Wu XM (2019) The excellent electrochemical performances of ZnMn2O4/Mn2O3: the composite cathode material for potential aqueous zinc ion batteries. J Electroanal Chem 832:69–7410.1016/j.jelechem.2018.10.051 ↗
100. Wang J, Jin J, Wang JG, Liu H, Wei C, Kang F (2019) Zinc ion stabilized MnO2 nanospheres for high capacity and long lifespan aqueous zinc-ion batteries. J Mater Chem A 7:13727–1373510.1039/C9TA03541A ↗