Relationship between the microstructures and Young’s modulus of 3D-networked porous carbon material
Source abstract
Abstract
Herein, we prepared 3D-networked porous carbon materials (TNPCs) (porosity ≈ 70%, average pore size ≈ 10 μm, density ≈ 0.37 g cm–3) composed of glassy carbon via pyrolysis of porous phenolic precursors. A compressive test for TNPCs shows that the Young’s moduli and compressive strength of TNPCs ranged from 0.7 to 1.5 GPa and 11 to 30 MPa, respectively, which increased with increasing pore diameter. Although these moduli could not be accurately predicted using conventional periodic unit cell models, the homogenized Young’s moduli predicted using a 3D image-based model acquired by X-ray computed tomography and focused ion beam scanning electron microscopy were in good agreement with the experimental values. These results indicate that the method can be used to reliably investigate the microstructures and evaluate the Young’s modulus using 3D image-based modeling.
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Research context
OpenAlex topics: Supercapacitor Materials and Fabrication · Catalytic Processes in Materials Science · Pickering emulsions and particle stabilization
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References (41)
Show source-provided references
1. Chuenchom L, Kraehnert R, Smarsly BM (2012) Recent progress in soft-templating of porous carbon materials. Soft Matter 8:10801–10812. https://doi.org/10.1039/c2sm07448f10.1039/c2sm07448f ↗
2. Ryoo R, Joo SH, Kruk M, Jaroniec M (2001) Ordered mesoporous carbons. Adv Mater 13:677–681. https://doi.org/10.1002/1521-4095(200105)13:9%3c677::AID-ADMA677%3e3.0.CO;2-C10.1002/1521-4095(200105)13:9<677::AID-ADMA677>3.0.CO;2-C ↗
3. Su F, Zhao XS, Wang Y et al (2005) Synthesis of graphitic ordered macroporous carbon with a three-dimensional interconnected pore structure for electrochemical applications. J Phys Chem B 109:20200–20206. https://doi.org/10.1021/jp054196710.1021/jp0541967 ↗
4. Stein A, Wang Z, Fierke MA (2009) Functionalization of porous carbon materials with designed pore architecture. Adv Mater 21:265–293. https://doi.org/10.1002/adma.20080149210.1002/adma.200801492 ↗
5. Inagaki M, Qiu J, Guo Q (2015) Carbon foam: preparation and application. Carbon N Y 87:128–152. https://doi.org/10.1016/j.carbon.2015.02.02110.1016/j.carbon.2015.02.021 ↗
6. Nagel B, Pusz S, Trzebicka B (2014) Review: tailoring the properties of macroporous carbon foams. J Mater Sci 49:1–17. https://doi.org/10.1007/s10853-013-7678-x10.1007/s10853-013-7678-x ↗
7. Kaneda Y, Inoue R, Kogo Y (2017) Development of fabrication procedure of porous carbon material with three dimensionally networked structure. Proc Mech Eng Congr Japan 2017:S0420104. https://doi.org/10.1299/jsmemecj.2017.s042010410.1299/jsmemecj.2017.s0420104 ↗
8. Wang C, Li D, Zhai T et al (2019) Direct conversion of waste tires into three-dimensional graphene. Energy Storage Mater 23:499–507. https://doi.org/10.1016/j.ensm.2019.04.01410.1016/j.ensm.2019.04.014 ↗
9. Wang C, Wang H, Dang B et al (2020) Ultrahigh yield of nitrogen doped porous carbon from biomass waste for supercapacitor. Renew Energy 156:370–376. https://doi.org/10.1016/j.renene.2020.04.09210.1016/j.renene.2020.04.092 ↗
10. Wang C, Wang H, Yang C et al (2020) A multilevel gradient structural carbon derived from naturally preprocessed biomass. Carbon N Y 168:624–632. https://doi.org/10.1016/j.carbon.2020.07.02010.1016/j.carbon.2020.07.020 ↗
11. Kubota Y, Fujita T, Kaneda Y et al (2018) Thermal protection performance of porous carbon ablators with three different matrices. J Spacecr Rockets 10:1–8. https://doi.org/10.2514/1.A3423410.2514/1.A34234 ↗
12. Inoue R, Li G, Kojo E, et al (2018) Experimental investigation and analysis of mechanical properties of three‐dimensionally networked porous carbon material. In: proceedings of the 12th pacific rim conference on ceramic and glass technology: ceramic transactions. pp 77–8410.1002/9781119494096.ch8 ↗
13. Maiti SK, Ashby MF, Gibson LJ (1984) Fracture toughness of brittle cellular solids. Scr Metall 18:213–217. https://doi.org/10.1016/0036-9748(84)90510-610.1016/0036-9748(84)90510-6 ↗
14. Ashby MF (2006) The properties of foams and lattices. Philos Trans R Soc A Math Phys Eng Sci 364:15–30. https://doi.org/10.1098/rsta.2005.167810.1098/rsta.2005.1678 ↗
15. Gibson LJ, Ashby MF (1999) Cellular solids: structure and properties. Cambridge University Press, Cambridge
16. Warren WE, Kraynik AK (1988) The linear elastic properties of open-cell foams. J Appl Mech 55:341–346. https://doi.org/10.1115/1.317368010.1115/1.3173680 ↗
17. Zhu HX, Knott JF, Mills NJ (1997) Analysis of the elastic properties of open-cell foams With Tetrakaidecahedral Cells. J Mech Phys Solids 45:319–34310.1016/S0022-5096(96)00090-7 ↗
18. Gan YX, Chen C, Shen YP (2005) Three-dimensional modeling of the mechanical property of linearly elastic open cell foams. Int J Solids Struct 42:6628–6642. https://doi.org/10.1016/j.ijsolstr.2005.03.00210.1016/j.ijsolstr.2005.03.002 ↗
19. Roberts AP, Garboczi EJ (2002) Elastic properties of model random three-dimensional open-cell solids. J Mech Phys Solids 50:33–55. https://doi.org/10.1016/S0022-5096(01)00056-410.1016/S0022-5096(01)00056-4 ↗
20. Zhu HX, Hobdell JR, Windle AH (2000) Effects of cell irregularity on the elastic properties of open-cell foams. Acta Mater 48:4893–4900. https://doi.org/10.1016/S1359-6454(00)00282-210.1016/S1359-6454(00)00282-2 ↗
21. Zhu HX, Windle AH (2002) Effects of cell irregularity on the high strain compression of open-cell foams. Acta Mater 50:1041–1052. https://doi.org/10.1016/S1359-6454(01)00402-510.1016/S1359-6454(01)00402-5 ↗
22. Xu S, Li J, Qiao G et al (2009) Pore structure control of mesoporous carbon monoliths derived from mixtures of phenolic resin and ethylene glycol. Carbon N Y 47:2103–2111. https://doi.org/10.1016/j.carbon.2009.03.06910.1016/j.carbon.2009.03.069 ↗
23. Kim BS, Chiba T, Inoue T (1993) A new time-temperature-transformation cure diagram for thermoset/thermoplastic blend: tetrafunctional epoxy/poly(ether sulfone). Polym (Guildf) 34:2809–2815. https://doi.org/10.1016/0032-3861(93)90125-T10.1016/0032-3861(93)90125-T ↗
24. Yamanaka K, Inoue T (1989) Structure development in epoxy resin modified with poly(ether sulphone). Polym (Guildf) 30:662–667. https://doi.org/10.1016/0032-3861(89)90151-110.1016/0032-3861(89)90151-1 ↗
25. Yamanaka K, Inoue T (1990) Phase separation mechanism of rubber-modified epoxy. J Mater Sci 25:241–245. https://doi.org/10.1007/BF0054421410.1007/BF00544214 ↗
26. Zhang J, Zhang H, Yan D et al (1997) Reaction-induced phase separation in rubber-modified epoxy resin. Sci China Ser B Chem 40:15–23. https://doi.org/10.1007/BF0288218310.1007/BF02882183 ↗
27. Inoue T (1995) Reaction-induced phase decomposition in polymer blends. Prog Polym Sci 20:119–15310.1016/0079-6700(94)00032-W ↗
28. Doerner MF, Nix WD (1986) A method for interpreting the data from depth-sensing indentation instruments. J Mater Res 1:601–609. https://doi.org/10.1557/jmr.1986.060110.1557/jmr.1986.0601 ↗
29. Brezny R, Green DJ (1990) The effect of cell size on the mechanical behavior of cellular materials. Acta Metall Mater 38:2517–2526. https://doi.org/10.1016/0956-7151(90)90263-G10.1016/0956-7151(90)90263-G ↗
30. Jurkiewicz K, Pawlyta M, Zygadło D et al (2018) Evolution of glassy carbon under heat treatment: correlation structure–mechanical properties. J Mater Sci 53:3509–3523. https://doi.org/10.1007/s10853-017-1753-710.1007/s10853-017-1753-7 ↗
31. Ko TH, Kuo WS, Chang YH (2001) Microstructural changes of phenolic resin during pyrolysis. J Appl Polym Sci 81:1084–1089. https://doi.org/10.1002/app.153010.1002/app.1530 ↗
32. Jenkins GM, Kawamura K (2011) Polymeric carbons carbon fibre, glass and char. Cambridge University Press, Cambridge
33. Tsyntsarski B, Petrova B, Budinova T et al (2010) Carbon foam derived from pitches modified with mineral acids by a low pressure foaming process. Carbon N Y 48:3523–3530. https://doi.org/10.1016/j.carbon.2010.05.04810.1016/j.carbon.2010.05.048 ↗
34. Chen C, Kennel EB, Stiller AH et al (2006) Carbon foam derived from various precursors. Carbon N Y 44:1535–1543. https://doi.org/10.1016/j.carbon.2005.12.02110.1016/j.carbon.2005.12.021 ↗
35. Narasimman R, Vijayan S, Prabhakaran K (2014) Carbon particle induced foaming of molten sucrose for the preparation of carbon foams. Mater Sci Eng B Solid-State Mater Adv Technol 189:82–89. https://doi.org/10.1016/j.mseb.2014.08.00710.1016/j.mseb.2014.08.007 ↗
36. Karthik M, Faik A, Blanco-Rodríguez P et al (2015) Preparation of erythritol-graphite foam phase change composite with enhanced thermal conductivity for thermal energy storage applications. Carbon N Y 94:266–276. https://doi.org/10.1016/j.carbon.2015.06.07510.1016/j.carbon.2015.06.075 ↗
37. Karthik M, Faik A, Doppiu S et al (2015) A simple approach for fabrication of interconnected graphitized macroporous carbon foam with uniform mesopore walls by using hydrothermal method. Carbon N Y 87:434–443. https://doi.org/10.1016/j.carbon.2015.02.06010.1016/j.carbon.2015.02.060 ↗
38. Wilson P, Vijayan S, Prabhakaran K (2018) Low-density microcellular carbon foams from sucrose by NaCl particle templating using glycerol as a plasticizing additive. J Mater Des 139:25–35. https://doi.org/10.1016/j.matdes.2017.10.06310.1016/j.matdes.2017.10.063 ↗
39. Kirca M, Gül A, Ekinci E et al (2007) Computational modeling of micro-cellular carbon foams. Finite Elem Anal Des 44:45–52. https://doi.org/10.1016/j.finel.2007.08.00810.1016/j.finel.2007.08.008 ↗
40. Storm J, Abendroth M, Zhang D, Kuna M (2013) Geometry dependent effective elastic properties of open-cell foams based on kelvin cell models. Adv Eng Mater 15:1292–1298. https://doi.org/10.1002/adem.20130014110.1002/adem.201300141 ↗
41. Zargarian A, Esfahanian M, Kadkhodapour J, Ziaei-Rad S (2014) Effect of solid distribution on elastic properties of open-cell cellular solids using numerical and experimental methods. J Mech Behav Biomed Mater 37:264–273. https://doi.org/10.1016/j.jmbbm.2014.05.01810.1016/j.jmbbm.2014.05.018 ↗