journal article·2019-03

Vertically standing ultrathin MoS2 nanosheet arrays on molybdenum foil as binder-free anode for lithium-ion batteries

Yifei Guo, Xingguo Qi, Xiuli Fu, Yongsheng Hu, Zhijian Peng

Journal of Materials Science· Volume 54· Issue 5
Publisher page

Abstract

Layered MoS2 nanostructures are outstanding anode materials for lithium-ion batteries due to their potentially high capacity. Here, we report a flexible binder-free anode for LIBs, which was fabricated from vertically standing ultrathin MoS2 nanosheet arrays grown directly on a molybdenum foil as the current collector. The self-supported MoS2 nanosheet arrays exhibit high specific capacity (1041 mAh g−1 at a current density of 0.1 A g−1), good cycling stability (maintained 84% of the initial capacity after 40 cycles) and outstanding rate performance. The excellent performance should be ascribed to the short ionic diffusion length, good contact between the electrode materials and current collector, and easy transportation of lithium ions. And it also arises from the nano-/microscale pores and extensively exposed edges that effectively accommodate for the volume change of MoS2 nanosheets during the charge–discharge processes.
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Research context

OpenAlex topics: Advancements in Battery Materials · MXene and MAX Phase Materials · Graphene research and applications

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References (41)

Show source-provided references
1. Liu D, Li W, Zheng Y, Cui Z, Yan X, Liu D, Wang J, Zhang Y, Lu H, Bai F, Guo J, Wu X (2018) In situ encapsulating α-MnS into N, S-codoped nanotube-like carbon as advanced anode material: α → β phase transition promoted cycling stability and superior Li/Na-storage performance in half/full cells. Adv Mater 30:170631710.1002/adma.201706317 ↗
2. Hou B, Wang Y, Guo J, Zhang Y, Ning Q, Yang Y, Li W, Zhang J, Wang X, Wu X (2018) A scalable strategy to develop advanced anode for sodium-ion batteries: commercial Fe3O4-derived Fe3O4@FeS with superior full-cell performance. ACS Appl Mater Inter 10:3581–358910.1021/acsami.7b16580 ↗
3. Wang Q, Xu J, Zhang W, Mao M, Wei Z, Wang L, Cui C, Zhu Y, Ma J (2018) Research progress on vanadium-based cathode materials for sodium ion batteries. J Mater Chem A 6:8815–883810.1039/C8TA01627E ↗
4. Wei Z, Wang L, Zhuo M, Ni W, Wang H, Ma J (2018) Layered tin sulfide and selenide anode materials for Li-and Na-ion batteries. J Mater Chem A 6:12185–1221410.1039/C8TA02695E ↗
5. Tan C, Zhang H (2015) Two-dimensional transition metal dichalcogenide nanosheet-based composites. Chem Soc Rev 44:2713–273110.1039/C4CS00182F ↗
6. Sharma S, Bhagat S, Singh J, Singh RC, Sharma S (2017) Excitation-dependent photoluminescence from WS2 nanostructures synthesized via top-down approach. J Mater Sci 52:11326–11336. https://doi.org/10.1007/s10853-017-1303-310.1007/s10853-017-1303-3 ↗
7. Zhao H, Fan H, Yang G, Lu L, Zheng C, Gao X, Wu T (2018) Integrated dynamic and steady state method and its application on the screening of MoS2 nanosheet-containing adsorbents for Hg-0 capture. Energy Fuels 32:5338–534410.1021/acs.energyfuels.8b00099 ↗
8. Xu S, Lei Z, Wu P (2015) Facile preparation of 3D MoS2/MoSe2 nanosheet-graphene networks as efficient electrocatalysts for the hydrogen evolution reaction. J Mater Chem A 3:16337–1634710.1039/C5TA02637G ↗
9. Nguyen TP, Choi S, Jeon JM, Kwon KC, Jang HW, Kim SY (2016) Transition metal disulfide nanosheets synthesized by facile sonication method for the hydrogen evolution reaction. J Phys Chem C 120:3929–393510.1021/acs.jpcc.5b12164 ↗
10. Bhandavat R, David L, Singh G (2013) Synthesis of surface-functionalized WS2 nanosheets and performance as Li-ion battery anodes. J Phys Chem Lett 3:1523–153010.1021/jz300480w ↗
11. Gao J, Li L, Tan J, Sun H, Li B, Idrobo JC, Singh CV, Lu TM, Koratkar N (2016) Vertically oriented arrays of ReS2 nanosheets for electrochemical energy storage and electrocatalysis. Nano Lett 16:3780–378710.1021/acs.nanolett.6b01180 ↗
12. Su L, Xiao Y, Han G (2017) Synthesis of highly active cobalt molybdenum sulfide nanosheets by a one-step hydrothermal method for use in dye-sensitized solar cells. J Mater Sci 52:13541–13551. https://doi.org/10.1007/s10853-017-1457-z10.1007/s10853-017-1457-z ↗
13. Choi K, Lee YT, Im S (2016) Two-dimensional van der Waals nanosheet devices for future electronics and photonics. Nano Today 11:626–64310.1016/j.nantod.2016.08.009 ↗
14. Han J, Xia H, Wu Y, Kong SN, Deivasigamani A, Xu R, Hui KM, Kang Y (2016) Single-layer MoS2 nanosheet grafted upconversion nanoparticles for near-infrared fluorescence imaging-guided deep tissue cancer phototherapy. Nanoscale 8:7861–786510.1039/C6NR00150E ↗
15. Gao M, Xu Y, Jiang J, Yu S (2013) Nanostructured metal chalcogenides: synthesis, modification, and applications in energy conversion and storage devices. Chem Soc Rev 42:2986–301710.1039/c2cs35310e ↗
16. Hwang H, Kim H, Cho J (2011) MoS2 nanoplates consisting of disordered graphene-like layers for high rate lithium battery anode materials. Nano Lett 11:4826–483010.1021/nl202675f ↗
17. Zhang P, Liu Y, Yan Y, Yu Y, Wang Q, Liu M (2018) High areal capacitance for lithium ion storage achieved by a hierarchical carbon/MoS2 aerogel with vertically aligned pores. ACS Appl Energy Mater 1:4814–482310.1021/acsaem.8b00897 ↗
18. Liu M, Liu Y, Tang B, Zhang P, Yan Y, Liu T (2017) 3D conductive network supported monolithic molybdenum disulfide nanosheets for high-performance lithium storage applications. Adv Mater Interfaces 4:160122810.1002/admi.201601228 ↗
19. Xiao J, Wang X, Yang X, Xun S, Liu G, Koech PK, Liu J, Lemmon JP (2011) Electrochemically induced high capacity displacement reaction of PEO/MoS2/graphene nanocomposites with lithium. Adv Funct Mater 21:2840–284610.1002/adfm.201002752 ↗
20. Liu Y, He X, Hanlon D, Harvey A, Khan U, Li Y, Coleman JN (2016) Electrical, mechanical, and capacity percolation leads to high-performance MoS2/nanotube composite lithium ion battery electrodes. ACS Nano 10:5980–599010.1021/acsnano.6b01505 ↗
21. Qu G, Cheng J, Wang Z, Wang B, Ye S (2016) Self-templated formation of tremella-like MoS2 with expanded spacing of (002) crystal planes for Li-ion batteries. J Mater Sci 51:4739–4747. https://doi.org/10.1007/s10853-015-9421-210.1007/s10853-015-9421-2 ↗
22. Xu Z, Shen X, Zhang Q, Li J, Kong L, Cao L, Huang J (2016) Synthesis of structurally stable 3D MoS2 architectures as high performance lithium-ion battery anodes. Part Part Syst Char 33:311–31510.1002/ppsc.201600047 ↗
23. Cao X, Shi Y, Shi W, Rui X, Yan Q, Kong J, Zhang H (2013) Preparation of MoS2-coated three-dimensional graphene networks for high-performance anode material in lithium-ion batteries. Small 9:3433–343810.1002/smll.201202697 ↗
24. Tian R, Wang W, Huang Y, Duan H, Guo Y, Kang H, Li H, Liu H (2016) 3D composites of layered MoS2 and graphene nanoribbons for high performance lithium-ion battery anodes. J Mater Chem A 4:13148–1315410.1039/C6TA04331C ↗
25. Xu W, Wang T, Wu S, Wang S (2017) N-doped carbon-coated MoS2 nanosheets on hollow carbon microspheres for high-performance lithium-ion batteries. J Alloy Compd 698:68–7610.1016/j.jallcom.2016.11.401 ↗
26. Li N, Liu Z, Gao Q, Li X, Wang R, Yan X, Li Y (2017) In situ synthesis of concentric C@MoS2 core–shell nanospheres as anode for lithium ion battery. J Mater Sci 52:13183–13191. https://doi.org/10.1007/s10853-017-1411-010.1007/s10853-017-1411-0 ↗
27. Jiang J, Li Y, Liu J, Huang X (2011) Building one-dimensional oxide nanostructure arrays on conductive metal substrates for lithium-ion battery anodes. Nanoscale 3:45–5810.1039/C0NR00472C ↗
28. Shen L, Uchaker E, Zhang X, Cao G (2012) Hydrogenated Li4Ti5O12 nanowire arrays for high rate lithium ion batteries. Adv Mater 24:6502–650610.1002/adma.201203151 ↗
29. Chen S, Xin Y, Zhou Y, Ma Y, Zhou H, Qi L (2014) Self-supported Li4Ti5O12 nanosheet arrays for lithium ion batteries with excellent rate capability and ultralong cycle life. Energy Environ Sci 7:1924–193010.1039/c3ee42646g ↗
30. Tang Y, Hong L, Wu Q, Li J, Hou G, Cao H, Wu L, Zheng G (2016) TiO2 (B) nanowire arrays on Ti foil substrate as three-dimensional anode for lithium-ion batteries. Electrochim Acta 195:27–3310.1016/j.electacta.2016.01.235 ↗
31. Zhang X, Qiao X, Shi W, Wu J, Jiang D, Tan P (2015) Phonon and Raman scattering of two-dimensional transition metal dichalcogenides from monolayer, multilayer to bulk material. Chem Soc Rev 44:2757–278510.1039/C4CS00282B ↗
32. Thripuranthaka M, Kashid RV, Sekhar Rout C, Late DJ (2014) Temperature dependent Raman spectroscopy of chemically derived few layer MoS2 and WS2 nanosheets. Appl Phys Lett 104:8191110.1063/1.4866782 ↗
33. Huang G, Chen T, Chen W, Wang Z, Chang K, Ma L, Huang F, Chen D, Lee JY (2013) Graphene-like MoS2/graphene composites: cationic surfactant-assisted hydrothermal synthesis and electrochemical reversible storage of lithium. Small 9:3693–370310.1002/smll.201300415 ↗
34. Pollak E, Salitra G, Baranchugov V, Aurbach D (2007) In situ conductivity, impedance spectroscopy, and ex situ Raman spectra of amorphous silicon during the Insertion/Extraction of lithium. J Phys Chem C 111:11437–1144410.1021/jp0729563 ↗
35. Yu X, Hu H, Wang Y, Chen H, Lou X (2015) Ultrathin MoS2 nanosheets supported on N-doped carbon nanoboxes with enhanced lithium storage and electrocatalytic properties. Angew Chemie Int Ed 54:7395–739810.1002/anie.201502117 ↗
36. Xu X, Fan Z, Yu X, Ding S, Yu D, Lou X (2017) A nanosheets-on-channel architecture constructed from MoS2 and CMK-3 for high-capacity and long-cycle-life lithium storage. Adv Energy Mater 4:140090210.1002/aenm.201400902 ↗
37. Fang X, Yu X, Liao S, Shi Y, Hu Y, Wang Z, Stucky GD, Chen L (2012) Lithium storage performance in ordered mesoporous MoS2 electrode material. Micropor Mesopor Mat 151:418–42310.1016/j.micromeso.2011.09.032 ↗
38. Guo B, Yu K, Fu H, Hua Q, Qi R, Li H, Song H, Guo S, Zhu Z (2015) Firework-shaped TiO2 microspheres embedded with few-layer MoS2 as an anode material for excellent performance lithium-ion batteries. J Mater Chem A 3:6392–640110.1039/C4TA06607C ↗
39. Yu H, Ma C, Ge B, Chen Y, Xu Z, Zhu C, Li C, Ouyang Q, Gao P, Li J (2013) Three-dimensional hierarchical architectures constructed by graphene/MoS2 nanoflake arrays and their rapid charging/discharging properties as lithium-ion battery anodes. Chem Eur J 19:5818–582310.1002/chem.201300072 ↗
40. Ding S, Zhang D, Chen J, Lou X (2012) Facile synthesis of hierarchical MoS2 microspheres composed of few-layered nanosheets and their lithium storage properties. Nanoscale 4:95–9810.1039/C1NR11552A ↗
41. Zhang K, Kim HJ, Shi X, Lee JT, Choi JM, Song MS, Park JH (2013) Graphene/acid coassisted synthesis of ultrathin MoS2 nanosheets with outstanding rate capability for a lithium battery anode. Inorg Chem 52:9807–981210.1021/ic400735f ↗