Phase transition and magnetocaloric effect in particulate Fe-Rh alloys
Source abstract
Abstract
Micro-sized particles of FexRh100−x (x = 50, 48, 45, 40, and 35) binary alloys were synthesized by a solid-phase reduction method and their structural properties, magnetic properties and cytotoxicity have been characterized. From X-ray diffraction results, the Fe50Rh50 alloy is in a single chemically ordered α′ phase while the face-centered cubic disordered γ phase arises and increases with Rh content when x is smaller than 50. The magnetization behavior of the alloys demonstrates that the α′ phase consists of ferromagnetic and antiferromagnetic components due to the nonuniformity of elements in the particulate alloys. The maximal magnetic entropy change and the relative refrigeration capacity of the Fe50Rh50 particles reach 9.7 J/kg K and 230 J/kg, respectively, with a 0–3 T magnetic field change. Despite its moderate magnetic entropy among the first-order transition materials, Fe50Rh50 microparticles are promising for biomedical applications due to its large relative cooling power and low cytotoxicity.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Magnetic and transport properties of perovskites and related materials · Shape Memory Alloy Transformations · High Entropy Alloys Studies
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (31)
Show source-provided references
1. Nikitin SA, Myalikgulyev G, Tishin AM, Annaorazov MP, Asatryan KA, Tyurin AL (1990) The magnetocaloric effect in Fe49Rh51 compound. Phys Lett A 148(6–7):363–366. https://doi.org/10.1016/0375-9601(90)90819-A10.1016/0375-9601(90)90819-A ↗
2. Algarabel PA, Ibarra MR, Marquina C, Del Moral A, Galibert J, Iqbal M, Askenazy S (1995) Giant room-temperature magnetoresistance in the FeRh alloy. Appl Phys Lett 66(22):3061–3063. https://doi.org/10.1063/1.11427810.1063/1.114278 ↗
3. Lu W, Wang Y, Yan B, Suzuki T (2010) Magnetic properties and first-order magnetic phase transition in single crystal FeRh thin film. J Mater Sci 45(18):4919–4923. https://doi.org/10.1007/s10853-010-4206-010.1007/s10853-010-4206-0 ↗
4. Barua R, Jiménez-Villacorta F, Lewis LH (2014) Towards tailoring the magnetocaloric response in FeRh-based ternary compounds. J Appl Phys 115(17):17A903. https://doi.org/10.1063/1.485497510.1063/1.4854975 ↗
5. Barua R, Jiang X, Jimenez-Villacorta F, Shield JE, Heiman D, Lewis LH (2013) Tuning the magnetostructural phase transition in FeRh nanocomposites. J Appl Phys 113(2):023910. https://doi.org/10.1063/1.477428210.1063/1.4774282 ↗
6. Ko HYY, Suzuki T (2007) Synthesis and magnetic properties of self-organized FeRh nanoparticles. J Appl Phys 101(9):09J103. https://doi.org/10.1063/1.271128510.1063/1.2711285 ↗
7. Ko HYY, Suzuki T, Nam NT, Phuoc NN, Cao J, Hirotsu Y (2008) Magnetic and structural characterizations on nanoparticles of FePt, FeRh and their composites. J Magn Magn Mater 320(22):3120–3123. https://doi.org/10.1016/j.jmmm.2008.08.08910.1016/j.jmmm.2008.08.089 ↗
8. Ko HYY, Suzuki T, Phuoc NN, Cao J (2008) Fabrication and characterization of FeRh nanoparticles. J Appl Phys 103(7):07D508. https://doi.org/10.1063/1.283244010.1063/1.2832440 ↗
9. Jia Z, Harrell JW, Misra RDK (2008) Synthesis and magnetic properties of self-assembled FeRh nanoparticles. Appl Phys Lett 93(2):022504. https://doi.org/10.1063/1.295295610.1063/1.2952956 ↗
10. Barua R, Jimenez-Villacorta F, Shield JE, Heiman D, Lewis LH (2013) Nanophase stability in a granular FeRh-Cu system. J Appl Phys 113(17):17B523. https://doi.org/10.1063/1.480074210.1063/1.4800742 ↗
11. Rajkumar DM, Manivel Raja M, Gopalan R, Chandrasekaran V (2008) Magnetocaloric effect in high-energy ball-milled Gd5Si2Ge2 and Gd5Si2Ge2/Fe nanopowders. J Magn Magn Mater 320(8):1479. https://doi.org/10.1016/j.jmmm.2007.12.00510.1016/j.jmmm.2007.12.005 ↗
12. Feng J, Geutjens R, Thang NV, Li J, Guo X, Kéri A, Basak S, Galbács G, Biskos G, Nirschl H, Zandbergen HW, Brück E, Schmidt-Ott A (2018) Magnetic phase transition in spark-produced ternary LaFeSi nanoalloys. ACS Appl Mater Interfaces 10(7):6073. https://doi.org/10.1021/acsami.7b1544110.1021/acsami.7b15441 ↗
13. Sánchez-Valdés CF, Gimaev RR, López-Cruz M, Llamazares JS, Zverev VI, Tishin AM, Pecharsky VK (2020) The effect of cooling rate on magnetothermal properties of Fe49Rh51. J Magn Magn Mater 498:166130. https://doi.org/10.1016/j.jmmm.2019.16613010.1016/j.jmmm.2019.166130 ↗
14. Tishin AM, Spichkin YI, Zverev VI, Egolf PW (2016) A review and new perspectives for the magnetocaloric effect: new materials and local heating and cooling inside the human body. Int J Refrig 68:177–186. https://doi.org/10.1016/j.ijrefrig.2016.04.02010.1016/j.ijrefrig.2016.04.020 ↗
15. Tishin AM (2016) Patent EP 1897590 B1
16. Zverev VI, Pyatakov AP, Shtil AA, Tishin AM (2018) Novel applications of magnetic materials and technologies for medicine. J Magn Magn Mater 459:182–186. https://doi.org/10.1016/j.jmmm.2017.11.03210.1016/j.jmmm.2017.11.032 ↗
17. Ohtani Y, Hatakeyama I (1994) Features of broad magnetic transition in FeRh thin film. J Magn Magn Mater 131(3):339–344. https://doi.org/10.1016/0304-8853(94)90278-x10.1016/0304-8853(94)90278-x ↗
18. Fan R, Tong A, Li X, Gao X, Mei L, Zhou L, Zhang X, You C, Guo G (2015) Enhanced antitumor effects by docetaxel/LL37-loaded thermosensitive hydrogel nanoparticles in peritoneal carcinomatosis of colorectal cancer. Int J Nanomed 10:7291–7305. https://doi.org/10.2147/IJN.S8906610.2147/IJN.S89066 ↗
19. Suzuki I, Koike T, Itoh M, Taniyama T, Sato T (2009) Stability of ferromagnetic state of epitaxially grown ordered FeRh thin films. J Appl Phys 105(7):07E501. https://doi.org/10.1063/1.305438610.1063/1.3054386 ↗
20. Maat S, Thiele JU, Fullerton EE (2005) Temperature and field hysteresis of the antiferromagnetic-to-ferromagnetic phase transition in epitaxial FeRh films. Phys Rev B 72(21):214432. https://doi.org/10.1103/PhysRevB.72.21443210.1103/PhysRevB.72.214432 ↗
21. Makhlouf SA, Nakamura T, Shiga M (1994) Structure and magnetic properties of FeAl1−xRhx alloys. J Magn Magn Mater 135(3):257–264. https://doi.org/10.1016/0304-8853(94)90355-710.1016/0304-8853(94)90355-7 ↗
22. Zakharov AI, Kadomtseva AM, Levitin RZ, Ponyatovskii EG (1964) Magnetic and magnetoelastic properties of a metamagnetic iron-rhodium alloy. Sov Phys JETP 19:1348–1353
23. Okamoto H (2011) Fe-Rh (iron-rhodium). J Phase Equilib Diffus 32(5):472. https://doi.org/10.1007/s11669-011-9934-610.1007/s11669-011-9934-6 ↗
24. Barua R, Jiménez-Villacorta F, Lewis LH (2013) Predicting magnetostructural trends in FeRh-based ternary systems. Appl Phys Lett 103(10):102407. https://doi.org/10.1063/1.482058310.1063/1.4820583 ↗
25. Cao J, Nam NT, Inoue S, Ko HYY, Phuoc NN, Suzuki T (2008) Magnetization behaviors for FeRh single crystal thin films. J Appl Phys 103(7):07F501. https://doi.org/10.1063/1.282881210.1063/1.2828812 ↗
26. Chirkova A, Bittner F, Nenkov K, Baranov NV, Schultz L, Nielsch K, Woodcock TG (2017) The effect of the microstructure on the antiferromagnetic to ferromagnetic transition in FeRh alloys. Acta Mater 131:31–38. https://doi.org/10.1016/j.actamat.2017.04.00510.1016/j.actamat.2017.04.005 ↗
27. Liu M, Benzo P, Tang H, Castiella M, Warot-Fonrose B, Tarrat N, Gatel C, Respaud M, Morillo J, Casanove MJ (2016) Magnetism and morphology in faceted B2-ordered FeRh nanoparticles. EPL (Europhys Lett) 116(2):27006. https://doi.org/10.1209/0295-5075/116/2700610.1209/0295-5075/116/27006 ↗
28. Zverev VI, Saletsky AM, Gimaev RR, Tishin AM, Miyanaga T, Staunton JB (2016) Influence of structural defects on the magnetocaloric effect in the vicinity of the first order magnetic transition in Fe50.4Rh49.6. Appl Phys Lett 108(19):192405. https://doi.org/10.1063/1.494935510.1063/1.4949355 ↗
29. Pecharsky VK, Gschneidner KA Jr (1999) Magnetocaloric effect from indirect measurements: magnetization and heat capacity. J Appl Phys 86(1):565–575. https://doi.org/10.1063/1.37076710.1063/1.370767 ↗
30. Wang F, Chen YF, Wang GJ, Sun JR, Shen BG (2003) Large magnetic entropy change and magnetic properties in La(Fe1−xMnx)11.7Si1.3Hy compounds. Chin. Phys. 12(8):911. https://doi.org/10.1088/1009-1963/12/8/31710.1088/1009-1963/12/8/317 ↗
31. XXII U, XVII N (1990) Toxicity classification in US Pharmacopeia. I. United States Pharmacopeial Convection, 2069