High-temperature steam oxidation behavior of an FeCrAl alloy with controlled addition of Mo
Source abstract
Abstract
The high-temperature steam oxidation behavior of Fe-13Cr-6Al-xMo (x = 1, 2, 3 or 4) is assessed from 1000 to 1300 °C. The oxidation film is dominated by α-Al2O3 with a nanolayer of Cr2O3 attached to the altered matrix. The oxidation behavior is thermodynamically driven and results in greater weight gain, and fast film growth is observed for the alloys at higher oxidation temperatures. Mo exerts an indirect effect on the oxidation behavior, with large-scale film deformation occurring by accelerating the lateral growth of the oxidation film. The high-temperature steam oxidation behavior of Fe–Cr-Al-Mo is not intrinsic and mainly depends on the oxidation temperature and surface film integrity, as evidenced by the diversity of weight gain curves.
Source: expertdata · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Nuclear Materials and Properties · High-Temperature Coating Behaviors · Thermal and Kinetic Analysis
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (63)
Show source-provided references
1. Hirano M, Yonomoto T, Ishigaki M, Watanabe N, Maruyama Y, Sibamoto Y, Watanabe T, Moriyama K (2012) Insights from review and analysis of the Fukushima Dai-ichi accident. J Nucl Sci Technol 49:1–1710.1080/18811248.2011.636538 ↗
2. Tanabe F (2012) Analyses of core melt and re-melt in the Fukushima Daiichi nuclear rectors. J Nucl Sci Technol 49:18–3610.1080/18811248.2011.636537 ↗
3. Ott LJ, Robb KR, Wang D (2014) Preliminary assessment of accident tolerant fuels on LWR performance during normal operation and under DB and BDB accident conditions. J Nucl Mater 448:520–53310.1016/j.jnucmat.2013.09.052 ↗
4. Field KG, Gussev MN, Yamamoto Y, Snead LL (2014) Deformation behavior of laser welds in high temperature oxidation resistant Fe-Cr-Al alloys for fuel cladding applications. J Nucl Mater 454:352–35810.1016/j.jnucmat.2014.08.013 ↗
5. Terrani KA, Zinkle SJ, Snead LL (2014) Advanced oxidation resistant iron based alloys for LWR fuel cladding. J Nucl Mater 448:420–43510.1016/j.jnucmat.2013.06.041 ↗
6. Tang C, Jianu A, Steinbrueck M, Grosse M, Weisenburger A, Seifert HJ (2018) Influence of composition and heating schedules on compatibility of FeCrAl alloys with high-temperature steam. J Nucl Mater 511:496–50710.1016/j.jnucmat.2018.09.026 ↗
7. Andresen PL, Dolley EJ, Huang S, Young-Jin Kim J, Charles, (2014) Ferritic alloys as accident tolerant fuel cladding material for light water reactors[R]. Gen Electr Glob Res Cent 2:1–74
8. Cheng B, Kim KJ, Chou P (2016) Improving accident tolerance of nuclear fuel with coated Mo-alloy cladding. Nucl Eng Technol 48:16–2510.1016/j.net.2015.12.003 ↗
9. Kim HG, Yang JH, Kim WJ, Koo YH (2016) Development status of accidenttolerant fuel for light water reactors in Korea. Nucl Eng Technol 48:1–1510.1016/j.net.2015.11.011 ↗
10. Duan Z, Yang H, Satoh Y, Murakami K, Kano K, Zhao Z, Shen J, Abe H (2017) Current status of materials development of nuclear fuel cladding tubes for light water reactors. Nucl Eng Des 316:131–15010.1016/j.nucengdes.2017.02.031 ↗
11. Tang C, Stueber M, Seifert HJ, Steinbrueck M (2017) Protective coatings on zirconiumbased alloys as accident-tolerant fuel (ATF) claddings. Corros Rev 35:141–16510.1515/corrrev-2017-0010 ↗
12. Zinkle SJ, Terrani KA, Gehin JC, Ott LJ, Snead LL (2014) Accident tolerant fuels for LWRs: a perspective. J Nucl Mater 448:374–37910.1016/j.jnucmat.2013.12.005 ↗
13. Badini C, Laurella F (2001) Oxidation of FeCrAl alloy: influence of temperature and atmosphere on scale growth rate and mechanism. Surf Coat Technol 135:291–29810.1016/S0257-8972(00)00989-0 ↗
14. Houngniou C, Chevalier S, Larpin JP (2006) High-temperature-oxidation behavior of iron–aluminide diffusion coatings. Oxid Met 65:409–43910.1007/s11085-006-9033-y ↗
15. Raiman SS, Field KG, Rebak RB, Yamamoto Y (2020) Hydrothermal corrosion of 2nd generation FeCrAl alloys for accident tolerant fuel cladding. J Nucl Mater 536:1522110.1016/j.jnucmat.2020.152221 ↗
16. Wallwork GR (1976) The oxidation of alloys. Rep Prog Phys 39:401–48510.1088/0034-4885/39/5/001 ↗
17. Pint BA, Terrani KA, Yamamoto Y, Snead LL (2015) Material selection for accident tolerant fuel cladding. Metall Mater Trans E 2(3):190–196
18. Zhong W, Mouche PA, Han X, Heuser BJ, Mandapaka KK, Was GS (2016) Performance of iron–chromium–aluminum alloy surface coatings on Zircaloy 2 under high-temperature steam and normal BWR operating conditions. J Nucl Mater 470:327–33810.1016/j.jnucmat.2015.11.037 ↗
19. Park DJ, Kim HG, Jung YI, Park JH, Yang JH, Koo YH (2016) Behavior of an improved Zr fuel cladding with oxidation resistant coating under loss-of-coolant accident conditions. J Nucl Mater 482:75–8210.1016/j.jnucmat.2016.10.021 ↗
20. Wang Y (2018) Oxidation resistance improvement of Zr-4 alloy in 1000 °C steam environment using ZrO2/FeCrAl bilayer coating. Surf Coat Technol 349:807–81510.1016/j.surfcoat.2018.05.005 ↗
21. Younker I, Fratoni M (2016) Neutronic evaluation of coating and cladding materials for accident tolerant fuels. Prog Nucl Energy 88:10–1810.1016/j.pnucene.2015.11.006 ↗
22. Park JY, Kim IH, Jung YI, Kim HG, Park DJ, Kim WJ (2013) Long-term corrosion behavior of CVD SiC in 360°C water and 400°C steam. J Nucl Mater 443(1):603–60710.1016/j.jnucmat.2013.07.058 ↗
23. Lyu Y, Du BH, Chen GQ, Zhao GD, Cheng Y, Zhou SB, Lv QR, Zhang XH, Han WB (2022) Microstructural regulation, oxidation resistance, and mechanical properties of Cf/SiC/SiHfBOC composites prepared by chemical vapor infiltration with precursor infiltration pyrolysis. J Adv Ceram 11:120–13510.1007/s40145-021-0521-y ↗
24. Maier BR, Garcia-Diaz BL, Hauch B, Olson LC, Sindelar RL, Sridharan K (2015) Cold spray deposition of Ti2AlC coatings for improved nuclear fuel cladding. J Nucl Mater 466:712–71710.1016/j.jnucmat.2015.06.028 ↗
25. Zhou AG, Liu Y, Li SB, Wang XH, Ying GB, Xia QX, Zhang PG (2021) From structural ceramics to 2D materials with multi-applications: a review on the development from MAX phases to MXenes. J Adv Ceram 10:1194–124210.1007/s40145-021-0535-5 ↗
26. Park JH, Kim HG, Park JY, Jung YI, Park DJ, Koo YH (2015) High temperature steam-oxidation behavior of arc ion plated Cr coatings for accident tolerant fuel claddings. Surf Coat Technol 280:256–25910.1016/j.surfcoat.2015.09.022 ↗
27. Dang XL, Zhao DL, Guo T, Fan XM, Xue JM, Ye F, Liu YS, Cheng LF (2022) Oxidation behaviors of carbon fiber reinforced multilayer SiC-Si3N4 matrix composites. J Adv Ceram 11:354–36410.1007/s40145-021-0539-1 ↗
28. Qiu BW, Wang J, Deng YB, Wang MJ, Wu YW, Qiu SZ (2020) A review on thermohydraulic and mechanical physical properties of SiC, FeCrAl, and Ti3SiC2 for ATF cladding. Nucl Eng Technol 52:1–1310.1016/j.net.2019.07.030 ↗
29. Maeda T, Ukai S, Hayashi S, Oono N, Shizukawa Y, Sakamoto K (2019) Effect of zirconium and oxygen on the oxidation of FeCrAl-ODS alloys under air and steam conditions up to 1500 °C. J Nucl Mater 516:317–32610.1016/j.jnucmat.2019.01.041 ↗
30. Huang XF, Wang H, Qiu SY, Zhang YY, He K, Wu BD (2020) Cold rolling & annealing process for nuclear-grade wrought FeCrAl cladding alloy to enhance the strength and ductility. J Mater Process Tech 277:11643410.1016/j.jmatprotec.2019.116434 ↗
31. Zhu H, Liu HY, Zhou JY, Dong Y, Li P, Chen LL, Yi J, Huang Q, Huang F, Ge FF (2020) Long-term oxidation resistance and deterioration mechanism of magnetron sputtered Cr-Al-Si-N coatings on zirconium alloys in 1200 °C steam atmosphere. Corros Sci 171:10860310.1016/j.corsci.2020.108603 ↗
32. Han XC, Wang Y, Peng SM, Zhang HB (2019) Oxidation behavior of FeCrAl coated Zry-4 under high temperature steam environment. Corros Sci 149:45–5310.1016/j.corsci.2019.01.004 ↗
33. Rebak RB, Gupta VK, Larsen M (2018) Oxidation characteristics of two FeCrAl alloys in air and steam from 800 °C to 1300 °C. JOM 70:1484–149210.1007/s11837-018-2979-9 ↗
34. Wu X, Kozlowski T, Hales JD (2015) Neutronics and fuel performance evaluation of accident tolerant FeCrAl cladding under normal operation conditions. Ann Nucl Energy 85:763–77510.1016/j.anucene.2015.06.032 ↗
35. Chen G, Wang H, Sun HY, Zhang YY, Cao P, Wang J (2021) Effect of Nb-doing on the mechanical properties and high-temperature steam oxidation of annealing FeCrAl fuel cladding alloys. Mater Sci Eng, A 803:14050010.1016/j.msea.2020.140500 ↗
36. Silva MJG, Herculano LFG (2015) Influence of Mo content on the phase evolution and corrosion behavior of model Fe-9Cr-xMo (x=5, 7 and 9 wt%) alloys. J Mater Res 30:1999–201510.1557/jmr.2015.157 ↗
37. Shi H, Fetzer R, Tang CC, Szabo DV, Schlabach S, Heinzel A, Weisenburger A, Muiller G (2021) The influence of Y and Nb addition on the corrosion resistance of Fe-Cr-Al-Ni model alloys exposed to oxygen containing molten Pb. Corros Sci 179:10915210.1016/j.corsci.2020.109152 ↗
38. Sun Z, Yamamoto Y (2017) Processability evaluation of a Mo-containing FeCrAl alloy for seamless thin-wall tube fabrication. Mater Sci Eng 700:554–56110.1016/j.msea.2017.06.036 ↗
39. Jonsson B, Berglund R, Magnusson J, Henning P, H€attestrand M (2004) High temperature properties of a new powder metallurgical FeCrAl alloy. Mater Sci Forum 464:455–46210.4028/www.scientific.net/MSF.461-464.455 ↗
40. Jonsson B, Lu Q, Chandrasekaran D, Berglund R, Rave F (2013) Oxidation and creep limited lifetime of kanthal APMT®, a dispersion strengthened FeCrAlMo alloy designed for strength and oxidation resistance at high temperatures. Oxid Metal 79(29):e39
41. Li N, Parker SS, Wood ES, Nelson AT (2018) Oxide morphology of a FeCrAl alloy, Kanthal APMT, following extended aging in air at 300 oC to 600 oC. Metall Mater Trans A 49A:2941–2951
42. Buscail H, Messki EI, Riffard F, Perrier S, Cueff R, Issartel C (2008) Role of molybdenum on the AISI 316L oxidation at 900 °C. J Mater Sci 43:6960–6966. https://doi.org/10.1007/s10853-008-2965-710.1007/s10853-008-2965-7 ↗
43. Safikhani A, Esmaillian M, Salmani MR, Aminfard M (2014) Effect of Ni-Mo addition on cyclic and isothermal oxidation resistance and electrical behavior of ferritic stainless steel for SOFCs interconnect. Int J Hydrog Energy 39:11210–1122310.1016/j.ijhydene.2014.05.122 ↗
44. Wang P, Qi W, Yang K, Qiao YJ, Wang XD, Zheng T, Bai CY, Zhang XH (2022) Systematic investigation of the high-temperature FeCrAl cladding alloy oxidation behavior in high-temperature steam. Corros Sci 207:11059510.1016/j.corsci.2022.110595 ↗
45. Parker SS, White J, Hosemann P, Nelson A (2018) Oxidation kinetics of ferritic alloys in high-temperature steam environments. J Mater 70:186–191
46. Naumenko D, Gleeson B, Wessel E, Singheiser L, Quadakkers WJ (2007) Correlation between the microstructure, growth mechanism, and growth kinetics of alumina scales on a FeCrAlY Alloy. Metall Mater Trans A 38A:2974–298110.1007/s11661-007-9342-z ↗
47. Pieraggi B (2005) Comments on “growth rates of alumina scales of Fe-Cr-Al alloys.” Oxid Met 64:397–40310.1007/s11085-005-8534-4 ↗
48. Wagner C (1952) Theoretical analysis of the diffusion processes determining the oxidation rate of alloys. J Electrochem Soc 99:369–38010.1149/1.2779605 ↗
49. Terrani KA, Pint BA, Kim YJ, Unocic KA, Yang Y, Silva CM, Rebak RB (2016) Uniform corrosion of FeCrAl alloys in LWR coolant environments. J Nucl Mater 479:36–4710.1016/j.jnucmat.2016.06.047 ↗
50. Chen GM, Yang HY, Sun HY, Wang F, Wang H, Kong QQ, An XG, Zhang YY, Wang J (2022) Exploring the high-temperature steam oxidation behaviors of the lean-Cr (7–10 wt%) FeCrAl alloys. Corros Sci 194:10992710.1016/j.corsci.2021.109927 ↗
51. Zhang WH, Qian Y, Sun RR, Lin XD, Yao MY, Qiu YL, Yang J, Cheng GG, Dong JX (2021) Oxidation characteristics of Fe22Cr5Al3Mo-xNb alloys in high temperature steam. Corros Sci 191:10972210.1016/j.corsci.2021.109722 ↗
52. Hong JM, Aramesh M, Shimoni O, Seo DH, Yick S, Grieg A, Charles C, Prawer S, Murphy AB (2016) Plasma catalytic synthesis of ammonia using functionalized-carbon coatings in an atmospheric-pressure non-equilibrium discharge. Plasm Chem Plasm Process 36:917–94010.1007/s11090-016-9711-8 ↗
53. Wu QL, Liu Y, Zhang ZH, Qi YM, Zhang CX, Zheng HT, Xu Y (2021) Oxidaiton behavior and high temperature tensile properties of Fe-9Cr-(Mo, Mo/Ni) alloys. Corros Sci 181:10924310.1016/j.corsci.2021.109243 ↗
54. Sadique SE, Mollah AH, Islam MS, Ali MM, Megat MHH, Basri S (2000) High temperature oxidation behavior of iron-chromium-aluminum alloys. Oxid Met 54:385–40010.1023/A:1004682316408 ↗
55. Airiskallio E, Nurmi E, Heinonen MH, Vayrynen IJ, Kokko K, Ropo M, Punkkinen MPJ, Pitkanen H, Alatalo M, Kollar J, Johansson B, Vitos L (2010) High temperature oxidation of Fe-Al and Fe-Cr-Al alloys: the role of Cr as a chemically active element. Corros Sci 52:3394–340410.1016/j.corsci.2010.06.019 ↗
56. Ardigo MR, Popa I, Chevalier S, Weber S, Heintz O, Vilasi M (2013) Effect of water vapor on the oxidation mechanisms of a commercial stanless steel for interconnet application in high temperature water vapor electrolysis. Oxid Met 79:495–50510.1007/s11085-012-9338-y ↗
57. Gotlind H, Liu F, Swensson JE, Harvarsson M, Johansson LG (2007) The effect of water vapor on the initial stages of oxidation of the FeCrAl alloy Kanthal AF at 900 °C. Oxid Met 67:251–26610.1007/s11085-007-9055-0 ↗
58. Liu F, Josefsson H, Svensson J-E, Johansson L-G, Halvarsson M (2005) TEM investigation of the base oxide formed on FeCrAl at 900°C in dry O2 and O2 + 40%H2O. Mater High Temp 22(n3–4):521–52610.3184/096034005782744119 ↗
59. Yun DW, Seo HS, Jun JH, Lee JM, Kim KY (2012) Molybdenum effect on oxidation resistance and electric conduction of ferritic stainless steel for SOFC interconnect. Int J Hydrog Energy 37:10328–1033610.1016/j.ijhydene.2012.04.013 ↗
60. Perez FJ, Otero E, Hierro MP, Gomez C, Pedraza F, Roman E (1998) High temperature corrosion protection of austenitic AISI 304 stainless steel by Si, Mo and Ce ion implantation. Surf Coat Technol 108–109:127–13110.1016/S0257-8972(98)00685-9 ↗
61. Park S, Seo S, Yoo Y, Jeong H, Jang H (2019) Effects of Cr W and Mo on the high temperature oxidation of Ni-based super alloys. Materials 12:2934–294510.3390/ma12182934 ↗
62. Qiao YJ, Wang P, Qi W, Du SY, Liu Z, Meng FP, Wang XD (2020) Mechanism of Al on FeCrAl steam oxidation behavior and molecular dynamics simulations. J Alloys Compd 828:15431010.1016/j.jallcom.2020.154310 ↗
63. Zheng XG, Young DJ (1994) High temperature corrosion of Cr2O3 forming alloys in CO-CO2-N2 atmospheres. Oxid Met 42:163–19010.1007/BF01052021 ↗