Facile synthesis of highly stable MOF-derived CoP-NP@C nanoarrays for asymmetric supercapacitors
Source abstract
Abstract
Nanostructured transition metal phosphides (TMPs) have emerged as an attractive material in energy storage domains, owing to their high electrical conductivity and easy redox properties. However, the low actual specific capacitance and weak cycling stability hinder its further application. In this paper, the hierarchical nanosheet of CoP nanoparticles embedded in a two-dimensional carbon skeleton (Co-NP@C) with flake-like ZIF-67 as its precursor was synthesized by facile carbonization and phosphorization and employed as positive electrodes for asymmetric supercapacitors. Due to the presence of carbon skeleton and nanoparticles, a stable structure and more reaction channels for the electrochemical reactions were created, leading to a remarkable improvement of the electrical properties of Co-NP@C. The Co-NP@C electrode presents the exceptional electrochemical performance of 540 F g−1 at 1.0 A g−1. Furthermore, an asymmetric symmetric supercapacitor with Co-NP@C cathode and reduced graphene oxide (RGO) anode achieves superior cycling stability (92.4% after 10, 000 cycles at 10 A g−1) and a high energy density of 20.22 Wh kg−1 at a power density of 649.93 W kg−1. This study offers a simplified method for guiding the design of MOF-derived phosphide electrode materials and provides additional opportunities for optimizing high-efficiency supercapacitors.
Source: expertdata · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Supercapacitor Materials and Fabrication · Electrocatalysts for Energy Conversion · Catalysis and Hydrodesulfurization Studies
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (38)
Show source-provided references
1. Du W, Wang XN, Zhan J, Sun XQ, Kang LT, Jiang FY, Zhang XY, Shao Q, Dong MY, Liu H, Murugadoss V, Guo ZH (2019) Biological cell template synthesis of nitrogen-doped porous hollow carbon spheres/MnO2 composites for high-performance asymmetric supercapacitors. Electrochim Acta 296:907–915. https://doi.org/10.1016/j.electacta.2018.11.07410.1016/j.electacta.2018.11.074 ↗
2. Chatterjee DP, Nandi AK (2021) A review on the recent advances in hybrid supercapacitors. J Mater Chem A 9:15880–15918. https://doi.org/10.1039/d1ta02505h10.1039/d1ta02505h ↗
3. Guo W, Yu C, Li SF, Qiu JS (2021) Toward commercial-level mass-loading electrodes for supercapacitors: opportunities, challenges and perspectives. Energy Environ Sci 14:576–601. https://doi.org/10.1039/d0ee02649b10.1039/d0ee02649b ↗
4. Yun Q, Li L, Hu Z, Lu Q, Chen B, Zhang H (2020) Layered transition metal dichalcogenide-based nanomaterials for electrochemical energy storage. Adv Mater 32:1903826. https://doi.org/10.1002/adma.20190382610.1002/adma.201903826 ↗
5. Song ZY, Miao L, Ruhlmann L, Lv YK, Zhu DZ, Li LC, Gan LH, Liu MX (2021) Self-Assembled Carbon Superstructures Achieving Ultra-Stable and Fast Proton-Coupled Charge Storage Kinetics. Adv Mater 33:2104148. https://doi.org/10.1002/adma.20210414810.1002/adma.202104148 ↗
6. Zheng Y, Xu J, Yang X, Zhang Y, Shang Y, Hu X (2018) Decoration NiCo2S4 nanoflakes onto Ppy nanotubes as core-shell heterostructure material for high-performance asymmetric supercapacitor. Chem Eng J 333:111–121. https://doi.org/10.1016/j.cej.2017.09.15510.1016/j.cej.2017.09.155 ↗
7. Tang Y, Liu Z, Guo W, Chen T, Qiao Y, Mu S, Zhao Y, Gao F (2016) Honeycomb-like mesoporous cobalt nickel phosphate nanospheres as novel materials for high performance supercapacitor. Electrochim Acta 190:118–125. https://doi.org/10.1016/j.electacta.2016.01.04210.1016/j.electacta.2016.01.042 ↗
8. Xiao LD, Qi HJ, Qu KQ, Shi C, Cheng Y, Sun Z, Yuan BN, Huang ZH, Pan D, Guo ZH (2021) Layer-by-layer assembled free-standing and flexible nanocellulose/porous Co3O4 polyhedron hybrid film as supercapacitor electrodes. Adv Compos Hybrid Mater 4:306–316. https://doi.org/10.1007/s42114-021-00223-210.1007/s42114-021-00223-2 ↗
9. Zhang LY, Cai PF, Wei ZH, Liu T, Yu JG, Al-Ghamdi AA, Wageh S (2021) Synthesis of reduced graphene oxide supported nickel-cobalt-layered double hydroxide nanosheets for supercapacitors. J Colloid Interface Sci 588:637–645. https://doi.org/10.1016/j.jcis.2020.11.05610.1016/j.jcis.2020.11.056 ↗
10. Li YX, Wang H, Shu T, Yuan JZ, Lu GG, Lin B, Gao Z, Wei FX, Ma CY, Qi JQ, Sui YW (2022) Two-dimensional hierarchical MoS2 lamella inserted in CoS2 flake as an advanced supercapacitor electrode. J Energy Storage 51:104299. https://doi.org/10.1016/j.est.2022.10429910.1016/j.est.2022.104299 ↗
11. Zhang X, Su D, Wu A, Yan H, Wang X, Wang D, Wang L, Tian C, Sun L, Fu H (2019) Porous NiCoP nanowalls as promising electrode with high-area and mass capacitance for supercapacitors. Sci China Mater 62:1115–1126. https://doi.org/10.1007/s40843-019-9405-810.1007/s40843-019-9405-8 ↗
12. Liu YJ, Zhang X, Matras-Postolek K, Yang P (2021) Ni2P nanosheets modified N-doped hollow carbon spheres towards enhanced supercapacitor performance. J Alloys Compd 854:157111. https://doi.org/10.1016/j.jallcom.2020.15711110.1016/j.jallcom.2020.157111 ↗
13. Shi JH, Qiu F, Yuan WB, Guo MM, Lu ZH (2021) Nitrogen-doped carbon-decorated yolk-shell CoP@FeCoP micro-polyhedra derived from MOF for efficient overall water splitting. Chem Eng J 403:126312. https://doi.org/10.1016/j.cej.2020.12631210.1016/j.cej.2020.126312 ↗
14. Theerthagiri J, Murthy AP, Lee SJ, Karuppasamy K, Arumugam SR, Yu Y, Hanafiah MM, Kim HS, Mittal V, Choi MY (2021) Recent progress on synthetic strategies and applications of transition metal phosphides in energy storage and conversion. Ceram Int. https://doi.org/10.1016/j.ceramint.2020.10.09810.1016/j.ceramint.2020.10.098 ↗
15. Li X, Elshahawy AM, Guan C, Wang J (2017) Metal phosphides and phosphates-based electrodes for electrochemical supercapacitors. Small 13:1701530. https://doi.org/10.1002/smll.20170153010.1002/smll.201701530 ↗
16. Sun M, Liu HJ, Qu JH, Li JH (2016) Earth-rich transition metal phosphide for energy conversion and storage. Adv Energy Mater 6:1600087. https://doi.org/10.1002/aenm.20160008710.1002/aenm.201600087 ↗
17. Oyama ST, Gott T, Zhao HY, Lee YK (2009) Transition metal phosphide hydroprocessing catalysts: A review. Catal Today 143:94–107. https://doi.org/10.1016/j.cattod.2008.09.01910.1016/j.cattod.2008.09.019 ↗
18. Zhang GQ, Li B, Liu MC, Yuan SK, Niu LY (2017) Liquid phase synthesis of cop nanoparticles with high electrical conductivity for advanced energy storage. J Nanomater 2017:9728591. https://doi.org/10.1155/2017/972859110.1155/2017/9728591 ↗
19. Han RX, Guan LX, Zhang S, Lin YF, Tao JG (2021) Boosted cycling stability of CoP nano-needles based hybrid supercapacitor with high energy density upon surface phosphorization. Electrochimica Acta 368:137690. https://doi.org/10.1016/j.electacta.2020.13769010.1016/j.electacta.2020.137690 ↗
20. Zhang XJ, Hou SJ, Ding ZB, Zhu G, Tang HR, Hou YC, Lu T, Pan LK (2020) Carbon wrapped CoP hollow spheres for high performance hybrid supercapacitor. J Alloys Compd 822:153578. https://doi.org/10.1016/j.jallcom.2019.15357810.1016/j.jallcom.2019.153578 ↗
21. Yang M, Jiang YM, Qu MJ, Qin YC, Wang Y, Shen W, He RX, Su W, Li M (2020) Strong electronic couple engineering of transition metal phosphides-oxides heterostructures as multifunctional electrocatalyst for hydrogen production. Appl Catal B-Environ 269:118803. https://doi.org/10.1016/j.apcatb.2020.11880310.1016/j.apcatb.2020.118803 ↗
22. Hu W, Chen L, Wu X, Du M, Song Y, Wu Z, Zheng Q (2021) Slight zinc doping by an ultrafast electrodeposition process boosts the cycling performance of layered double hydroxides for ultralong-life-span supercapacitors. ACS Appl Mater Interfaces 13:38346–38357. https://doi.org/10.1021/acsami.1c1038610.1021/acsami.1c10386 ↗
23. Liu CL, Bai Y, Wang J, Qiu ZM, Pang H (2021) Controllable synthesis of ultrathin layered transition metal hydroxide/zeolitic imidazolate framework-67 hybrid nanosheets for high-performance supercapacitors. J Mater Chem A 9:11201–11209. https://doi.org/10.1039/d1ta02065j10.1039/d1ta02065j ↗
24. Kumar S, Saeed G, Zhu L, Hui KN, Kim NH, Lee JH (2021) 0D to 3D carbon-based networks combined with pseudocapacitive electrode material for high energy density supercapacitor: a review. Chem Eng J 403:126352. https://doi.org/10.1016/j.cej.2020.12635210.1016/j.cej.2020.126352 ↗
25. Sun L, Xie ZB, Wu AP, Tian CG, Wang DX, Gu Y, Gao YC, Fu HG (2021) Hollow CoP spheres assembled from porous nanosheets as high-rate and ultra-stable electrodes for advanced supercapacitors. Journal of Materials Chemistry A 9:26226–26235. https://doi.org/10.1039/d1ta07566g10.1039/d1ta07566g ↗
26. Jia H, Li Q, Li C, Song Y, Zheng H, Zhao J, Zhang W, Liu X, Liu Z, Liu Y (2018) A novel three-dimensional hierarchical NiCo2O4/Ni2P electrode for high energy asymmetric supercapacitor. Chem Eng J 354:254–260. https://doi.org/10.1016/j.cej.2018.08.00810.1016/j.cej.2018.08.008 ↗
27. Yang Z, Cheng QH, Li WW, Li YJ, Yang C, Tao K, Han L (2021) Construction of 2D ZIF-derived hierarchical and hollow NiCo-LDH “nanosheet-on-nanosheet” arrays on reduced graphene oxide/Ni foam for boosted electrochemical energy storage. J Alloys Compd. https://doi.org/10.1016/j.jallcom.2020.15686410.1016/j.jallcom.2020.156864 ↗
28. Shu T, Wang H, Li Q, Feng ZP, Wei FX, Yao KX, Sun Z, Qi JQ, Sui YW (2021) Highly stable Co3O4 nanoparticles/carbon nanosheets array derived from flake-like ZIF-67 as an advanced electrode for supercapacitor. Chem Eng J 419:129631. https://doi.org/10.1016/j.cej.2021.12963110.1016/j.cej.2021.129631 ↗
29. Wang HF, Chen LY, Pang H, Kaskel S, Xu Q (2020) MOF-derived electrocatalysts for oxygen reduction, oxygen evolution and hydrogen evolution reactions. Chem Soc Rev 49:1414–1448. https://doi.org/10.1039/c9cs00906j10.1039/c9cs00906j ↗
30. Guo TT, Chen LY, Li YW, Shen K (2022) Controllable synthesis of ultrathin defect-rich LDH nanoarrays coupled with MOF-Derived Co-NC microarrays for efficient overall water splitting. Small 18:2107739. https://doi.org/10.1002/smll.20210773910.1002/smll.202107739 ↗
31. Xu L, Xi Y, Li W, Hua Z, Peng J, Hu J, Zhou J-J, Zhang P, Wang J, Wang W, Ding H, Wang W, Ji W, Yang Y, Xu X, Chen L, Li X (2022) 3D frame-like architecture of N-C-incorporated mixed metal phosphide boosting ultrahigh energy density pouch-type supercapacitors. Nano Energy 91:106630. https://doi.org/10.1016/j.nanoen.2021.10663010.1016/j.nanoen.2021.106630 ↗
32. Zhang X, Zhang L, Xu G, Zhao A, Zhang S, Zhao T (2020) Template synthesis of structure-controlled 3D hollow nickel-cobalt phosphides microcubes for high-performance supercapacitors. J Colloid Interface Sci 561:23–31. https://doi.org/10.1016/j.jcis.2019.11.11210.1016/j.jcis.2019.11.112 ↗
33. Zardkhoshoui AM, Ameri B, Davarani SSH (2021) alpha-MnS@Co3S4 hollow nanospheres assembled from nanosheets for hybrid supercapacitors. Chem Eng J 422:129953. https://doi.org/10.1016/j.cej.2021.12995310.1016/j.cej.2021.129953 ↗
34. He YY, Wang L, Dong CF, Li CC, Ding XY, Qian YT, Xu LQ (2019) In-situ rooting ZnSe/N-doped hollow carbon architectures as high-rate and long-life anode materials for half/full sodium-ion and potassium-ion batteries. Energy Storage Mater 23:35–45. https://doi.org/10.1016/j.ensm.2019.05.03910.1016/j.ensm.2019.05.039 ↗
35. Zhang MT, Ci SQ, Li H, Cai PW, Xu HM, Wen ZH (2017) Highly defective porous CoP nanowire as electrocatalyst for full water splitting. Int J Hydrogen Energy 42:29080–29090. https://doi.org/10.1016/j.ijhydene.2017.09.17110.1016/j.ijhydene.2017.09.171 ↗
36. Liao HB, Sun YM, Dai CC, Du YH, Xi SB, Liu F, Yu LH, Yang ZY, Hou YL, Fisher AC, Li SZ, Xu ZCJ (2018) An electron deficiency strategy for enhancing hydrogen evolution on CoP nano-electrocatalysts. Nano Energy 50:273–280. https://doi.org/10.1016/j.nanoen.2018.05.06010.1016/j.nanoen.2018.05.060 ↗
37. Liu WF, Gao HX, Zhang Z, Zheng YF, Wu YH, Fu XT, Su J, Gao YH (2022) CoP/Cu3P heterostructured nanoplates for high-rate supercapacitor electrodes. Chem Eng J. https://doi.org/10.1016/j.cej.2022.13535210.1016/j.cej.2022.135352 ↗
38. Manikandan R, Justin Raj C, Nagaraju G, Velayutham R, Moulton SE, Puigdollers J, Chul Kim B (2021) Selenium enriched hybrid metal chalcogenides with enhanced redox kinetics for high-energy density supercapacitors. Chem Eng J 414:128924. https://doi.org/10.1016/j.cej.2021.12892410.1016/j.cej.2021.128924 ↗