journal article·2020-09

Efficient polysulfide anchor: brain coral-like WS2 nanosheets

Man Xiong, Jingwen Qian, Kai Yang, Zihe Chen, Tao Mei, Jianying Wang, Jinhua Li, Li Yu, Xianbao Wang

Journal of Materials Science· Volume 55· Issue 26
Publisher page

Abstract

Controlling the inherent polysulfide shuttle process has been the key research topic to solve the irreversible capacity loss problem of Li–S battery. By skillfully designing, hierarchical brain coral-like WS2 nanosheets are synthesized. The novel structure is consisted of WS2 nanosheets arrayed along the same crystal plane, which expose a large number of adsorption active sites and enhance the adsorption of polysulfides. At the same time, the multilayer sheet structure has a large specific surface area and increases the sulfur loading. The brain coral-like WS2/S cathode exhibits excellent electrochemical properties, which delivers an initial discharge specific capacity of 1308 mAh g−1 at 0.1 C. And when cycles at 2 C, the discharge specific capacity is maintained at 721 mAh g−1 after 500 cycles, together with a low decay of 0.06% per cycle.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Advancements in Battery Materials · Advanced Battery Materials and Technologies · Advanced battery technologies research

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (47)

Show source-provided references
1. Evers S, Nazar LF (2013) New approaches for high energy density lithium–sulfur battery cathodes. Acc Chem Res 46(9):1135–114310.1021/ar3001348 ↗
2. Yin YX, Xin S, Guo YG, Wan LJ (2013) Lithium–sulfur batteries: electrochemistry, materials, and prospects. Angew Chem Int Ed Engl 52(50):1318610.1002/anie.201304762 ↗
3. Yao YX, Zhang XQ, Li BQ et al (2020) A compact inorganic layer for robust anode protection in lithium–sulfur batteries. InfoMat 2(2):379–38810.1002/inf2.12046 ↗
4. Chen L, Shaw LL (2014) Recent advances in lithium–sulfur batteries. J Power Sources 267:770–78310.1016/j.jpowsour.2014.05.111 ↗
5. Chen W, Lei T, Wu C et al (2018) Designing safe electrolyte systems for a high-stability lithium–sulfur battery. Adv Energy Mater 8:170234810.1002/aenm.201702348 ↗
6. Pang Q, Liang X, Kwok CY, Nazar LF (2015) The importance of chemical interactions between sulfur host materials and lithium polysulfides for advanced lithium–sulfur batteries. J Electrochem Soc 162(14):A2567–A257610.1149/2.0171514jes ↗
7. Nagao M, Imade Y, Narisawa H et al (2013) Reaction mechanism of all-solid-state lithium–sulfur battery with two-dimensional mesoporous carbon electrodes. J Power Sources 243:60–6410.1016/j.jpowsour.2013.05.037 ↗
8. Ji X, Nazar LF (2010) Advances in Li–S batteries. J Mater Chem 20(44):982110.1039/b925751a ↗
9. Lei T, Chen W, Hu Y et al (2018) A nonflammable and thermotolerant separator suppresses polysulfide dissolution for safe and long-cycle lithium–sulfur batteries. Adv Energy Mater 32:180244110.1002/aenm.201802441 ↗
10. Mikhaylik YV, Akridge JR (2004) Polysulfide shuttle study in the Li/S battery system. J Electrochem Soc 151(11):A1969–A197610.1149/1.1806394 ↗
11. Diao Y, Xie K, Xiong S, Hong X (2012) Analysis of polysulfide dissolved in electrolyte in discharge-charge process of Li–S battery. J Electrochem Soc 159(4):A421–A42510.1149/2.060204jes ↗
12. Zhang C, Wu HB, Yuan C, Guo Z, Lou XW (2012) Confining sulfur in double-shelled hollow carbon spheres for lithium–sulfur batteries. Angew Chem Int Ed 51(38):9592–959510.1002/anie.201205292 ↗
13. Chen W, Hu Y, Lv W et al (2019) Lithiophilic montmorillonite serves as lithium ion reservoir to facilitate uniform lithium deposition. Nat Commun 10:497310.1038/s41467-019-12952-6 ↗
14. Xin S, Gu L, Zhao NH et al (2012) Smaller sulfur molecules promise better lithium–sulfur batteries. J Am Chem Soc 134(45):18510–1851310.1021/ja308170k ↗
15. Duan B, Wang W, Wang A et al (2013) Carbyne polysulfide as a novel cathode material for lithium/sulfur batteries. J Mater Chem A 1(42):1326110.1039/c3ta12634j ↗
16. Xu K (2014) Electrolytes and interphases in Li-ion batteries and beyond. Chem Rev 114(23):11503–1161810.1021/cr500003w ↗
17. Li Z, Yuan L, Yi Z et al (2014) Insight into the electrode mechanism in lithium–sulfur batteries with ordered microporous carbon confined sulfur as the cathode. Adv Energy Mater 4:130147310.1002/aenm.201301473 ↗
18. Li BQ, Kong L, Zhao CX et al (2019) Expediting redox kinetics of sulfur species by atomic-scale electrocatalysts in lithium–sulfur batteries. InfoMat 1(4):533–54110.1002/inf2.12056 ↗
19. Zhou H, Wang D, Fu A et al (2018) Mesoporous carbon spheres with tunable porosity prepared by a template-free method for advanced lithium–sulfur batteries. Mate Sci and Eng B 227:9–1510.1016/j.mseb.2017.10.005 ↗
20. Sun X, Huang Y, Chen M, Wang Y, Gao X, Wang L (2018) Novel microporous carbon prepared from discarded clothes as host materials for high performance lithium–sulfur battery. Mater Lett 232:122–12510.1016/j.matlet.2018.08.112 ↗
21. Ma S, Wang L, Wang Y et al (2019) Palladium nanocrystals-imbedded mesoporous hollow carbon spheres with enhanced electrochemical kinetics for high performance lithium sulfur batteries. Carbon 143:878–88910.1016/j.carbon.2018.11.086 ↗
22. Liu J, Zhang W, Chen Y, Zhou P, Zhang K (2019) A novel biomimetic dandelion structure-inspired carbon nanotube coating with sulfur as a lithium–sulfur battery cathode. Nanotechnology 30(15):15540110.1088/1361-6528/aafe46 ↗
23. Benítez A, Caballero A, Morales J, Hassoun J, Rodríguez-Castellón E, Canales-Vázquez J (2019) Physical activation of graphene: an effective, simple and clean procedure for obtaining microporous graphene for high-performance Li/S batteries. Nano Res 12(4):759–76610.1007/s12274-019-2282-2 ↗
24. Zhao Q, Zhao K, Ji G et al (2019) High sulfur loading, rGO-linked and polymer binder-free cathodes based on rGO wrapped N, P-codoped mesoporous carbon as sulfur host for Li–S batteries. Chem Eng J 361:1043–105210.1016/j.cej.2018.12.153 ↗
25. Cavallo C, Agostini M, Genders JP, Abdelhamid ME, Matic A (2019) A free-standing reduced graphene oxide aerogel as supporting electrode in a fluorine-free Li2S8 catholyte Li–S battery. J Power Sources 416:111–11710.1016/j.jpowsour.2019.01.081 ↗
26. Kim J, Kang Y, Song S-W, Suk J (2019) Freestanding sulphur–graphene oxide/carbon composite paper as a stable cathode for high performance lithium–sulfur batteries. Electrochim Acta 299:27–3310.1016/j.electacta.2018.12.165 ↗
27. Lei T, Chen W, Lv W et al (2018) Inhibiting polysulfide shuttling with a graphene composite separator for highly robust lithium–sulfur batteries. Joule 2:209110.1016/j.joule.2018.07.022 ↗
28. Liu Q, Jiang Q, Jiang L et al (2018) Preparation of SnO2@rGO/CNTs/S composite and application for lithium–sulfur battery cathode material. App Surf Sci 462:393–39810.1016/j.apsusc.2018.08.038 ↗
29. Tu S, Zhao X, Cheng M, Sun P, He Y, Xu Y (2019) Uniform mesoporous MnO2 nanospheres as a surface chemical adsorption and physical confinement polysulfide mediator for lithium–sulfur batteries. ACS Appl Mater Interfaces 11(11):10624–1063010.1021/acsami.8b20044 ↗
30. Cui Z, Yao J, Mei T et al (2019) Strong lithium polysulfides chemical trapping of TiC–TiO2/S composite for long-cycle lithium–sulfur batteries. Electrochim Acta 298:43–5110.1016/j.electacta.2018.12.075 ↗
31. Zhu L, Yang C, Chen Y, Wang J, Wang C, Zhu X (2019) Lithium storage performance and mechanism of VS4/rGO as an electrode material associated with lithium–sulfur batteries. J Alloys Compd 785:855–86110.1016/j.jallcom.2019.01.253 ↗
32. Yuan Z, Peng HJ, Hou TZ et al (2016) Powering lithium–sulfur battery performance by propelling polysulfide redox at sulfiphilic hosts. Nano Lett 16(1):519–52710.1021/acs.nanolett.5b04166 ↗
33. Li T, Guo R, Luo Y et al (2018) Innovative N-doped graphene-coated WS2 nanosheets on graphene hollow spheres anode with double-sided protective structure for Li-ion storage. Electrochim Acta 290:128–14110.1016/j.electacta.2018.09.065 ↗
34. Xiao Z, Yang Z, Zhou L, Zhang L, Wang R (2017) Highly conductive porous transition metal dichalcogenides via water steam etching for high-performance lithium–sulfur batteries. ACS Appl Mater Interfaces 9(22):18845–1885510.1021/acsami.7b04232 ↗
35. Majumder S, Shao M, Deng Y, Chen G (2019) Two dimensional WS2/C nanosheets as a polysulfides immobilizer for high performance lithium–sulfur batteries. J Electrochem Soc 166(3):A5386–A539610.1149/2.0501903jes ↗
36. Lei T, Chen W, Huang J et al (2017) Multi-functional layered WS2 nanosheets for enhancing the performance of lithium–sulfur batteries. Adv Energy Mater 7(4):160184310.1002/aenm.201601843 ↗
37. Babu G, Masurkar N, Al Salem H, Arava LM (2017) Transition metal dichalcogenide atomic layers for lithium polysulfides electrocatalysis. J Am Chem Soc 139(1):171–17810.1021/jacs.6b08681 ↗
38. Huang S, Wang Y, Hu J et al (2018) Mechanism investigation of high-performance Li-polysulfide batteries enabled by tungsten disulfide nanopetals. ACS Nano 12(9):9504–951210.1021/acsnano.8b04857 ↗
39. Thangavel NK, Gopalakrishnan D, Arava LMR (2017) Understanding heterogeneous electrocatalysis of lithium polysulfide redox on Pt and WS2 surfaces. J Phys Chem C 121(23):12718–1272510.1021/acs.jpcc.7b01514 ↗
40. Fu X, Qian J, Qiao X, Tan P, Peng Z (2014) Nonlinear saturable absorption of vertically stood WS2 nanoplates. Opt Lett 39(22):6450–645310.1364/OL.39.006450 ↗
41. Sarma PV, Tiwary CS, Radhakrishnan S, Ajayan PM, Shaijumon MM (2018) Oxygen incorporated WS2 nanoclusters with superior electrocatalytic properties for hydrogen evolution reaction. Nanoscale 10(20):9516–952410.1039/C8NR00253C ↗
42. Liu S, Shen B, Niu Y, Xu M (2017) Fabrication of WS2-nanoflowers@rGO composite as an anode material for enhanced electrode performance in lithium-ion batteries. J Colloid Interface Sci 488:20–2510.1016/j.jcis.2016.10.083 ↗
43. Qin Z, Ouyang C, Zhang J et al (2017) 2D WS2 nanosheets with TiO2 quantum dots decoration for high-performance ammonia gas sensing at room temperature. Sens Actuators B Chem 253:1034–104210.1016/j.snb.2017.07.052 ↗
44. Feng C, Tang L, Deng Y et al (2020) Synthesis of branched WO3@W18O49 homojunction with enhanced interfacial charge separation and full-spectrum photocatalytic performance. Chem Eng J 389:12447410.1016/j.cej.2020.124474 ↗
45. Patel MU, Demir-Cakan R, Morcrette M, Tarascon JM, Gaberscek M, Dominko R (2013) Li–S battery analyzed by UV/Vis in operando mode. ChemSusChem 6(7):1177–1181. https://doi.org/10.1002/cssc.20130014210.1002/cssc.201300142 ↗
46. Yao J, Mei T, Cui Z, Yu Z, Xu K, Wang X (2017) Hollow carbon spheres with TiO2 encapsulated sulfur and polysulfides for long-cycle lithium–sulfur batteries. Chem Eng J 330:644–65010.1016/j.cej.2017.08.006 ↗
47. Cui Z, Mei T, Yao J et al (2018) Cabbage-like nitrogen-doped graphene/sulfur composite for lithium–sulfur batteries with enhanced rate performance. J Alloys Compd 753:622–62910.1016/j.jallcom.2018.04.234 ↗