journal article·2018-08

Self-assembly and performances of wrinkled rGO@carbon fiber with embedded SnO2 nanoparticles as anode materials for structural lithium-ion battery

Huagen Li, Shubin Wang, Mengjie Feng, Jiping Yang, Boming Zhang

Journal of Materials Science· Volume 53· Issue 16
Publisher page

Abstract

To meet the requirements for the mechanical and electrochemical performance for carbon fiber-based (CF-based) composite electrode materials in the structural lithium-ion batteries application, better CF-based composite is urgently needed. Herein, we report a novel hierarchical structure formed by wrinkled reduced graphene oxide/tin oxide (rGO/SnO2) coating wrapping on the surface of CF for the first time via a facile self-assembly approach and subsequent annealing treatment. Although the mass ratio of rGO/SnO2 coating in this composite is only about 12.8%, it exhibits excellent tensile strength which is up to 5.01 GPa and cycling stability including a high reversible capacity of 369 mAh g−1 at 100 mA g−1, which increases 230% than that of the CF. Besides, the morphology of this composite after 100 cycles is firstly observed to further confirm it still maintains a layered and fibrous structure. The excellent properties may benefit from the design of hierarchical hybrid rGO/SnO2 coating and the synergistic effects of SnO2, rGO and CF.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Advancements in Battery Materials · Graphene research and applications · Supercapacitor Materials and Fabrication

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References (29)

Show source-provided references
1. Liu Y, Kumar S (2012) Recent progress in fabrication, structure, and properties of carbon fibers. Polym Rev 52:234–25810.1080/15583724.2012.705410 ↗
2. Botelhoa EC, Silvac RA, Pardinia LC, Rezend MC (2006) A review on the development and properties of continuous fiber/epoxy/aluminum hybrid composites for aircraft structures. Mater Res 9:247–25610.1590/S1516-14392006000300002 ↗
3. Guo M, Yi X, Liu G, Liu L (2014) Simultaneously increasing the electrical conductivity and fracture toughness of carbon–fiber composites by using silver nanowiresloaded interleaves. Compos Sci Technol 97:27–3310.1016/j.compscitech.2014.03.020 ↗
4. Asp L, Greenhalgh E (2014) Structural power composites. Compos Sci Technol 101:41–6110.1016/j.compscitech.2014.06.020 ↗
5. Ping L, Sherman E, Jacobsen A (2009) Design and fabrication of multifunctional structural batteries. J Power Sources 189:646–65010.1016/j.jpowsour.2008.09.082 ↗
6. Jacques E, Kjell MH, Zenkert D (2013) Expansion of carbon fibres induced by lithium intercalation for structural electrode applications. Carbon 59:246–25410.1016/j.carbon.2013.03.015 ↗
7. Jacques E, Kjell MH, Zenkert D (2014) The effect of lithium-intercalation on the mechanical properties of carbon fibres. Carbon 68:725–73310.1016/j.carbon.2013.11.056 ↗
8. Hagberg J, Leijonmarck S, Lindbergh G (2016) High precision coulometry of commercial PAN-based carbon fibers as electrodes in structural batteries. J Electrochem Soc 163:A1790–A179710.1149/2.0041609jes ↗
9. Kjell MH, Jacques E, Dan Z (2011) PAN-based carbon fiber negative electrodes for structural lithium-ion batteries. J Electrochem Soc 158:A1455–A146010.1149/2.053112jes ↗
10. Feng M, Wang S, Yang J, Zhang B (2016) Core–shell rGO/SnO2@CF with wrinkled surface used as structural anode material: high tensile strength and electrochemical stability. J Mater Chem A 4:18524–1853110.1039/C6TA07865F ↗
11. Han QG, Yi Z, Wang FX, Wu Y, Wang LM (2017) Preparation of bamboo carbon fiber and sandwich-like bamboo carbon fiber@SnO2@ carbon composites and their potential application in structural lithium-ion battery anodes. J Alloys Compd 709:227–23310.1016/j.jallcom.2017.03.141 ↗
12. Wang FX, Han QG, Yi Z, Geng D, Li X, Wang Z, Wang LM (2017) Synthesis and performances of carbon fiber@Co3O4 based on metal organic frameworks as anode materials for structural lithium-ion battery. J Electroanal Chem 807:196–20210.1016/j.jelechem.2017.10.039 ↗
13. Feng M, Wang S, Yu Y (2016) The H3PO4/H2SO4/HNO3 chemical functionalization optimized performances of functionalized carbon fibers via preventing fibers from over-oxidation. J Electrochem Soc 163:A2225–A223110.1149/2.0481610jes ↗
14. Jiang SH, Yue WB, Gao ZQ, Ren Y, Ma H, Zhao XH, Liu YL, Yang XJ (2013) Graphene-encapsulated mesoporous SnO2 composites as high performance anodes for lithium-ion batteries. J Mater Sci 48:3870–3876. https://doi.org/10.1007/s10853-013-7189-910.1007/s10853-013-7189-9 ↗
15. Tang JJ, Yang J, Zhou LM, Xie J, Chen GH, Zhou XY (2014) Layer-by-layer self-assembly of a sandwich-like graphene wrapped SnOx@ graphene composite as an anode material for lithium ion batteries. J Mater Chem A 2:6292–629510.1039/C4TA00495G ↗
16. Tang JJ, Yang J, Zhou XY, Yao HM, Zhou LM (2015) A porous graphene/carbon nanowire hybrid with embedded SnO2 nanocrystals for high performance lithium ion storage. J Mater Chem A 3:23844–2385110.1039/C5TA06859B ↗
17. Zhu Y, Murali S, Cai W (2010) Graphene and graphene oxide: Synthesis, properties, and applications. Adv Mater 22:3906–392410.1002/adma.201001068 ↗
18. Bai T, Zhou HC, Zhou XY, Liao QC, Chen SM, Yang J (2017) N-doped carbon-encapsulated MnO@graphene nanosheet as high-performance anode material for lithium-ion batteries. J Mater Sci 52:11608–11619. https://doi.org/10.1007/s10853-017-1247-710.1007/s10853-017-1247-7 ↗
19. Wu TH, Tu FY, Liu SQ, Zhuang SX, Jin GH, Pan CY (2014) MnO nanorods on graphene as an anode material for high capacity lithium ion batteries. J Mater Sci 49:1861–1867. https://doi.org/10.1007/s10853-013-7874-810.1007/s10853-013-7874-8 ↗
20. Wu YL, Chen YL, Lin J, Chu RX, Zheng J, Wu CQ, Guo H (2017) Three-dimensional tin dioxide-graphene composite nanofiber membrane as binder-free anode for high-performance lithium-ion batteries. J Mater Sci 52:8097–8106. https://doi.org/10.1007/s10853-017-1017-610.1007/s10853-017-1017-6 ↗
21. Zhang XQ, Fan XY, Yan C, Li HZ, Zhu YD, Li XT, Yu LP (2012) Interfacial microstructure and properties of carbon fiber composites modified with graphene oxide. ACS Appl Mater Interfaces 4:1543–155210.1021/am201757v ↗
22. Hummers W, Offeman R (1958) Preparation of graphitic oxide. J Am Chem Soc 80:1339. https://doi.org/10.1021/ja01539a01710.1021/ja01539a017 ↗
23. Dahn J, Zheng T, Liu Y (1995) Mechanisms for lithium insertion in carbonaceous materials. Science 270:590–59310.1126/science.270.5236.590 ↗
24. Kudin KN, Ozbas B, Schniepp HC, Prud’homme RK, Aksay IA, Car R (2008) Raman spectra of graphite oxide and functionalized graphene sheets. Nano Lett 8:36–4110.1021/nl071822y ↗
25. Han W, Zhao G, Zhang X, Zhou S (2015) Graphene oxide grafted carbon fiber reinforced siliconborocarbonitride ceramics with enhanced thermal stability. Carbon 95:157–16510.1016/j.carbon.2015.08.028 ↗
26. Chen L, Wu P, Wang H, Ye Y, Xu B, Cao GP, Zhou YM, Lu TH, Yang YS (2014) Highly loaded SnO2/mesoporous carbon nanohybrid with well-improved lithium storage capability. J Power Sources 247:178–18310.1016/j.jpowsour.2013.08.059 ↗
27. Liang JF, Wei W, Zhong D, Yang QL, Li LD, Guo L (2012) One-step in situ synthesis of SnO2/graphene nanocomposites and its application as an anode material for Li-ion batteries. ACS Appl Mater Interfaces 4:454–45910.1021/am201541s ↗
28. Jin YH, Min KM, Seo SD, Shim HW, Kim DW (2011) Enhanced Li storage capacity in 3 nm diameter SnO2 nanocrystals firmly anchored on multiwalled carbon nanotubes. J Phys Chem C 115:22062–2206710.1021/jp208021w ↗
29. Wang HK, Wang JK, Cao DX, Gu HY, Li BB, Lu X, Han XG, Rogach AL, Niu CM (2017) Honeycomb-like carbon nanoflakes as a host for SnO2 nanoparticles allowing enhanced lithium storage performance. J Mater Chem A 5:6817–682410.1039/C7TA00772H ↗