journal article·2018-04

Efficient absorption of ibuprofen in aqueous solution using eco-friendly C3N4/soot composite

Riquan Liao, Ming Li, Weitao Li, Xiangfeng Lin, Dunyu Liu, Liang Wang

Journal of Materials Science· Volume 53· Issue 8
Publisher page

Abstract

The removal of ibuprofen (IBP) from wastewater is a hot topic in both academic and industrial fields. Herein, we reported a novel eco-friendly absorbent C3N4/soot composite via a simple one-step pyrolysis process, which had high adsorptive activity for the removal of IBP from wastewater. Adsorption kinetic and isotherm data of the adsorption process were investigated. The adsorption capacity at room temperature for low equilibrium concentration (10 mg/L) was as high as 104 mg/g, which was very similar to the maximum adsorption capacity (148.81 mg/g). The pseudo-first-order, pseudo-second-order, and the intraparticle diffusion models could best describe adsorption kinetics of IBP on 7 wt% C3N4/soot, and adsorption isotherm is well fitted to Langmuir model. Thermodynamic parameters (ΔH, ΔG, and ΔS) indicated that IBP adsorption on C3N4/soot composite was spontaneous and endothermic. Moreover, the potential adsorption mechanism of C3N4/soot composite for the adsorption of IBP was proposed. The 7 wt% C3N4/soot composite exhibited much higher adsorptive activity and still showed a relatively high adsorption stability even after five cycles, which were potentially suitable for high efficiency and low-cost water purification.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Advanced Photocatalysis Techniques · Covalent Organic Framework Applications · Gas Sensing Nanomaterials and Sensors

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (43)

Show source-provided references
1. Madhavan J, Grieser F, Ashokkumar M (2010) Combined advanced oxidation processes for the synergistic degradation of ibuprofen in aqueous environments. J Hazard Mater 178:202–20810.1016/j.jhazmat.2010.01.064 ↗
2. Musa KAK, Eriksson LA (2007) Theoretical study of ibuprofen phototoxicity. J Phys Chem B 111:13345–1335210.1021/jp076553e ↗
3. Liu JC, Lu GH, Xie ZX et al (2015) Occurrence, bioaccumulation and risk assessment of lipophilic pharmaceutically active compounds in the downstream rivers of sewage treatment plants. Sci Total Environ 511:54–6210.1016/j.scitotenv.2014.12.033 ↗
4. Camacho-Munoz D, Martin DJ, Santos JL et al (2010) Occurrence, temporal evolution and risk assessment of pharmaceutically active compounds in Donana Park (Spain). J Hazard Mater 183:602–60810.1016/j.jhazmat.2010.07.067 ↗
5. Santos JL, Aparicio I, Alonso E (2007) Occurrence and risk assessment of pharmaceutically active compounds in wastewater treatment plants. A case study: Seville city (Spain). Environ Int 33:596–60110.1016/j.envint.2006.09.014 ↗
6. Li J, Sun SY, Chen R et al (2017) Adsorption behavior and mechanism of ibuprofen onto BiOCl microspheres with exposed 001 facets. Environ Sci Pollut R 24:9556–956510.1007/s11356-017-8564-x ↗
7. Makila E, Kivela H, Shrestha N et al (2016) Influence of surface chemistry on ibuprofen adsorption and confinement in mesoporous silicon microparticles. Langmuir 32:13020–1302910.1021/acs.langmuir.6b03413 ↗
8. Lei ZD, Wang JJ, Wang L et al (2016) Efficient photocatalytic degradation of ibuprofen in aqueous solution using novel visible-light responsive graphene quantum dot/AgVO3 nanoribbons. J Hazard Mater 312:298–30610.1016/j.jhazmat.2016.03.044 ↗
9. Bahamon D, Carro L, Guri S et al (2017) Computational study of ibuprofen removal from water by adsorption in realistic activated carbons. J Colloid Interface Sci 498:323–33410.1016/j.jcis.2017.03.068 ↗
10. Sellaoui L, Guedidi H, Wjihi S et al (2017) Experimental and theoretical studies of adsorption of ibuprofen on raw and two chemically modified activated carbons: new physicochemical interpretations. RSC Adv 6:12363–1237310.1039/C5RA22302D ↗
11. Iovino P, Canzano S, Capasso S et al (2015) A modeling analysis for the assessment of ibuprofen adsorption mechanism onto activated carbons. Chem Eng J 277:360–36710.1016/j.cej.2015.04.097 ↗
12. Okamoto Y, Kishi Y, Ishigami T et al (2016) Chiral selective adsorption of ibuprofen on a liposome membrane. J Phys Chem B 120:2790–279510.1021/acs.jpcb.6b00840 ↗
13. Banerjee P, Das P, Zaman A et al (2016) Application of graphene oxide nanoplatelets for adsorption of ibuprofen from aqueous solutions: evaluation of process kinetics and thermodynamics. Process Saf Environ 101:45–5310.1016/j.psep.2016.01.021 ↗
14. Delgado LF, Charles P, Glucina K et al (2015) Adsorption of ibuprofen and atenolol at trace concentration on activated carbon. Sep Sci Technol 50:1487–149610.1080/01496395.2014.975360 ↗
15. Lu ZJ, MacFarlane JK, Gschwend PM (2016) Adsorption of organic compounds to diesel soot: frontal analysis and polyparameter linear free-energy relationship. Environ Sci Technol 50:285–29310.1021/acs.est.5b03605 ↗
16. Wang ZP, Yan XT, Bi XL et al (2014) Lanthanum-promoted copper-based hydrotalcites derived mixed oxides for NOx adsorption, soot combustion and simultaneous NOx-soot removal. Mater Res Bull 51:119–12710.1016/j.materresbull.2013.12.003 ↗
17. Fang LP, Borggaard OK, Marcussen H et al (2010) The pH-dependent adsorption of tributyltin to charcoals and soot. Environ Pollut 158:3642–364910.1016/j.envpol.2010.08.003 ↗
18. Nguyen TH, Ball WP (2006) Absorption and adsorption of hydrophobic organic contaminants to diesel and hexane soot. Environ Sci Technol 40:2958–296410.1021/es052121a ↗
19. Wang XC, Maeda K, Thomas A et al (2009) A metal-free polymeric photocatalyst for hydrogen production from water under visible light. Nat Mater 8:76–8010.1038/nmat2317 ↗
20. Lee EZ, Jun YS, Hong WH et al (2010) Cubic mesoporous graphitic carbon (IV) nitride: an all-in-one chemosensor for selective optical sensing of metal ions. Angew Chem Int Ed 49:9706–971010.1002/anie.201004975 ↗
21. Yang S, Feng X, Wang X et al (2011) Graphene-based carbon nitride nanosheets as efficient metal-free electrocatalysts for oxygen reduction reactions. Angew Chem Int Ed 50:5339–534310.1002/anie.201100170 ↗
22. Liu J, Li W, Duan L et al (2015) A graphene-like oxygenated carbon nitride material for improved cycle-life lithium/sulfur batteries. Nano Lett 15:5137–514210.1021/acs.nanolett.5b01919 ↗
23. Zhu B, Xia P, Ho W et al (2015) Isoelectric point and adsorption activity of porous g-C3N4. Appl Surf Sci 344:188–19510.1016/j.apsusc.2015.03.086 ↗
24. Haque E, Jun JW, Talapaneni SN et al (2010) Superior adsorption capacity of mesoporous carbon nitride with basic CN framework for phenol. J Mater Chem 20:10801–1080310.1039/c0jm02974b ↗
25. Park SS, Chu SW, Xue C et al (2011) Facile synthesis of mesoporous carbon nitrides using the incipient wetness method and the application as hydrogen adsorbent. J Mater Chem 21:10801–1080710.1039/c1jm10849b ↗
26. Lee SU, Jun YS, Lee EZ et al (2015) Selective silver ion adsorption onto mesoporous graphitic carbon nitride. Carbon 95:58–6410.1016/j.carbon.2015.08.012 ↗
27. Shen C, Chen C, Wen T et al (2015) Superior adsorption capacity of g-C3N4 for heavy metal ions from aqueous solutions. J Colloid Interface Sci 456:7–1410.1016/j.jcis.2015.06.004 ↗
28. Cai X, He J, Chen L et al (2017) A 2D-g-C3N4 nanosheet as an eco-friendly adsorbent for various environmental pollutants in water. Chemosphere 171:192–20110.1016/j.chemosphere.2016.12.073 ↗
29. Martin DJ, Qiu K, Shevlin SA et al (2014) Highly efficient photocatalytic H2 evolution from water using visible light and structure-controlled graphitic carbon nitride. Angew Chem Int Ed 53:9240–924510.1002/anie.201403375 ↗
30. Zhou YJ, Zhang LX, Liu JJ et al (2015) Brand new P-doped g-C3N4: enhanced photocatalytic activity for H2 evolution and Rhodamine B degradation under visible light. J Mater Chem A 3:3862–386710.1039/C4TA05292G ↗
31. Liu JY, Xu H, Xu YG et al (2017) Graphene quantum dots modified mesoporous graphite carbon nitride with significant enhancement of photocatalytic activity. Appl Catal B-Environ 207:429–43710.1016/j.apcatb.2017.01.071 ↗
32. He DL, Chen YF, Situ Y et al (2017) Synthesis of ternary g-C3N4/Ag/γ-FeOOH photocatalyst: an integrated heterogeneous Fenton-like system for effectively degradation of azo dye methyl orange under visible light. Appl Surf Sci 425:862–87210.1016/j.apsusc.2017.06.124 ↗
33. Hu SZ, Jin RR, Lu G et al (2014) The properties and photocatalytic performance comparison of Fe3+-doped g-C3N4 and Fe2O3/g-C3N4 composite catalysts. RSC Adv 4:24863–2486910.1039/c4ra03290j ↗
34. Yu WL, Chen JX, Shang TT et al (2017) Direct Z-scheme g-C3N4/WO3 photocatalyst with atomically defined junction for H2 production. Appl Catal B Environ 219:693–70410.1016/j.apcatb.2017.08.018 ↗
35. Staron A, Banach M, Kowalski Z et al (2016) Impact of waste soot on properties of coal-water suspensions. J Clean Prod 135:457–46710.1016/j.jclepro.2016.06.127 ↗
36. Yu WL, Xu DF, Peng TY (2015) Enhanced photocatalytic activity of g-C3N4 for selective CO2 reduction to CH3OH via facile coupling of ZnO: a direct Z-scheme mechanism. J Mater Chem A 3:19936–1994710.1039/C5TA05503B ↗
37. Qiu Y, Yu SM, Cheng LL et al (2013) Sorption of radiocobalt on acid-activated sepiolite: effects of pH, ionic strength, foreign ions, humic acid and temperature. J Radioanal Nucl Chem 295:1673–168110.1007/s10967-012-2195-y ↗
38. Zhao DL, Yang X, Zhang H et al (2010) Effect of environmental conditions on Pb(II) adsorption on β-MnO2. Chem Eng J 164:49–5510.1016/j.cej.2010.08.014 ↗
39. Gupta VK, Rastogi A, Nayak A (2010) Adsorption studies on the removal of hexavalent chromium from aqueous solution using a low cost fertilizer industry waste material. J Colloid Interface Sci 342:135–14110.1016/j.jcis.2009.09.065 ↗
40. Selim AQ, Mohamed EA, Mobarak M et al (2018) Cr(VI) uptake by a composite of processed diatomite with MCM-41: isotherm, kinetic and thermodynamic studies. Microporous Mesoporous Mater 260:84–9210.1016/j.micromeso.2017.10.041 ↗
41. Yang GD, Tang L, Zeng GM et al (2015) Simultaneous removal of lead and phenol contamination from water by nitrogen-functionalized magnetic ordered mesoporous carbon. Chem Eng J 259:854–86410.1016/j.cej.2014.08.081 ↗
42. Liu YY, Zeng GM, Tang L et al (2015) Highly effective adsorption of cationic and anionic dyes on magnetic Fe/Ni nanoparticles doped bimodal mesoporous carbon. J Colloid Interface Sci 448:451–45910.1016/j.jcis.2015.02.037 ↗
43. Jung C, Park J, Lim KH et al (2013) Adsorption of selected endocrine disrupting compounds and pharmaceuticals on activated biochars. J Hazard Mater 263:702–71010.1016/j.jhazmat.2013.10.033 ↗