journal article·2023-10-24

Enhancement of Thermoelectric Performance of Single-Walled Carbon Nanotubes/Small Organic Molecule Hybrids by Fine-Tuning of the Alkyl Chain Length

Jae Gyu Jang, Tae-hoon Kim, Sung Hyun Kim, Jong-In Hong

ACS Applied Electronic Materials· Volume 5· Issue 10
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Abstract

We investigated the alkyl chain length effect of small organic molecules (SOMs) on the thermoelectric (TE) efficiency and transport properties of single-walled carbon nanotubes (SWCNTs)/SOM hybrids. The SWCNTs/DBOBI with an octyl tethering chain exhibited the greatest Seebeck coefficient (91.6 ± 5.3 μV/K) and power factor (182.6 ± 15.1 μW/mK 2 ), revealing semiconducting-dominant carrier transport. The FeCl 3 -doped SWCNTs/DBOBI exhibited a significantly enhanced power factor of 236.2 ± 12.3 μW/mK 2 and a ZT of 0.021 at room temperature. Our study provides clear guidelines for enhancing the TE efficiency of SWCNT-based hybrid materials by systematically varying the alkyl chain length of SOMs.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Advanced Thermoelectric Materials and Devices · Thermal properties of materials · Transition Metal Oxide Nanomaterials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Chemistry, Seoul National University, Seoul 08826, Korea

Department of Carbon Convergence Engineering, Wonkwang University, Iksan, Jeonbuk 54538, Korea

Funding

Ministry of Education · National Research Foundation of Korea

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