2D Ti3C2 MXene embedded with Co(II)(OH)n nanoparticles as the cathode material for hybrid magnesium–lithium-ion batteries
Source abstract
Abstract
MXene, the 2D layered material, is intensively investigated for application in the energy storage field due to its multiple advantages of the high electrical conductivity, hydrophilicity and the plastic layer structure. Herein, a composite (M(II)(OH)n@Ti3C2) of Ti3C2 MXene matrices embedded with ultrafine M(II)(OH)n (M = Fe/Co/Ni) particles is in-situ prepared. M(II)(OH)n particles are tightly grown on the surface and between the interlayers of Ti3C2 MXene by strong Ti–O–Co covalent bonds. Co(II)(OH)n@Ti3C2 exhibits the remarkable performance in hybrid magnesium–lithium batteries (HMLBs) due to the redox capacitive contribution and “pillar effect” of Co(II)(OH)n particles between the interlayers of Ti3C2 MXene. It exhibits a promising reversible capacity and excellent cycling stability. Its reversible capacity maintains 81.1 mAh g−1 after 600 cycles at 100 mA g−1, and the coulombic efficiency is nearly 100%. Therefore, it is an effective strategy to enhance the electrochemical performance of HMLBs by increasing redox capacitance of MXene cathodes. The Co(II)(OH)n nanoparticles decorated Ti3C2 nanocomposite (M(II)(OH)n@Ti3C2) was successfully synthesized by three processing steps. The Co(II)(OH)n@Ti3C2 nanocomposite exhibits the superior performance in HMLBs due to the synergistic effect of the Co(II)(OH)n nanoparticles and the Ti3C2 matrix.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: MXene and MAX Phase Materials · Advancements in Battery Materials · Graphene research and applications
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (58)
Show source-provided references
1. Kim T, Song WT, Son D-Y, Ono LK, Qi YB (2019) Lithium-ion batteries: outlook on present, future, and hybridized technologies. J Mater Chem A 7:2942–296410.1039/C8TA10513H ↗
2. Wang QS, Jiang LH, Yu Y, Sun JH (2019) Progress of enhancing the safety of lithium ion battery from the electrolyte aspect. Nano Energy 55:93–11410.1016/j.nanoen.2018.10.035 ↗
3. Tang YK, Liu L, Zhao HY, Gao SS, Lv Y, Kong LB, Ma JH, Jia DZ (2017) Hybrid porous bamboo-like CNTs embedding ultrasmall LiCrTiO4 nanoparticles as high rate and long life anode materials for lithium ion batteries. Chem Commun 53:1033–103610.1039/C6CC08103G ↗
4. Canepa P, Sai Gautam G, Hannah DC, Malik R, Liu M, Gallagher KG, Persson KA, Ceder G (2017) Odyssey of multivalent cathode materials: open questions and future challenges. Chem Rev 117:4287–434110.1021/acs.chemrev.6b00614 ↗
5. Kim S-W, Seo D-H, Ma XH, Ceder G, Kang K (2012) Electrode materials for rechargeable sodium-ion batteries: potential alternatives to current lithium-ion batteries. Adv Energy Mater 2:710–72110.1002/aenm.201200026 ↗
6. Tan SS, Xiong FY, Wang JJ, An QY, Mai LQ (2020) Crystal regulation towards rechargeable magnesium battery cathode materials. Mater Horiz 7:1971–199510.1039/D0MH00315H ↗
7. Wang JJ, Tan SS, Zhang GB et al (2020) Fast and stable Mg2+ intercalation in a high voltage NaV2O2(PO4)2F/rGO cathode material for magnesium-ion batteries. Sci China Mater 63:1651–166210.1007/s40843-020-1311-1 ↗
8. Aurbach D, Lu Z, Schechter A et al (2000) Prototype system for rechargeable magnesium batteries. Nature 407:724–72710.1038/35037553 ↗
9. Aurbach D, Suresh GS, Levi E, Mitelman A, Mizrahi O, Chusid O, Brunelli M (2007) Progress in rechargeable magnesium battery technology. Adv Mater 19:4260–426710.1002/adma.200701495 ↗
10. Wang N, NuLi YN, Su SJ, Yang J, Wang JL (2017) Effects of binders on the electrochemical performance of rechargeable magnesium batteries. J Power Sources 341:219–22910.1016/j.jpowsour.2016.12.003 ↗
11. Yuan HC, Yang YY, NuLi YN, Yang J, Wang JL (2018) A conductive selenized polyacrylonitrile cathode in nucleophilic Mg2+/Li+ hybrid electrolytes for magnesium–selenium batteries. J Mater Chem A 6:17075–1708510.1039/C8TA04772C ↗
12. Aurbach D, Gofer Y, Lu Z et al (2001) A Short review on the comparison between Li battery systems and rechargeable magnesium battery technology. J Power Sources 97–98:28–3210.1016/S0378-7753(01)00585-7 ↗
13. Saha P, Datta MK, Velikokhatnyi OI, Manivannan A, Alman D, Kumta PN (2014) Rechargeable magnesium battery: Current status and key challenges for the future. Prog Mater Sci 66:1–8610.1016/j.pmatsci.2014.04.001 ↗
14. Wei L, Lian R, Zhao Y, Meng Y, He L, Yu Y, Chen G, Wei Y (2020) Experimental investigation and first-principles calculations of a Ni3Se4 cathode material for Mg-ion batteries. ACS Appl Mater Inter 12:9316–932110.1021/acsami.9b21540 ↗
15. Liu FF, Wang TT, Liu XB and Fan LZ (2020) Challenges and recent progress on key materials for rechargeable magnesium batteries, Adv Energy Mater 2000787–200080410.1002/aenm.202000787 ↗
16. Du AB, Zhang HR, Zhang ZH et al (2019) A crosslinked polytetrahydrofuran-borate-based polymer electrolyte enabling wide-working-temperature-range rechargeable magnesium batteries. Adv Mater 31:1805930–180593610.1002/adma.201805930 ↗
17. Muldoon J, Bucur CB, Gregory T (2017) Fervent hype behind magnesium batteries: an open call to synthetic chemists-electrolytes and cathodes needed. Angew Chem Int Ed 56:12064–1208410.1002/anie.201700673 ↗
18. Cheng YW, Choi DW, Han KS, Mueller KT, Zhang JG, Sprenkle VL, Liu J, Li GS (2016) Toward the design of high voltage magnesium–lithium hybrid batteries using dual-salt electrolytes. Chem Commun 52:5379–538210.1039/C6CC00986G ↗
19. Gao T, Han FD, Zhu YJ, Suo LM, Luo C, Xu K, Wang CS (2015) Hybrid Mg2+/Li+ battery with long cycle life and high rate capability. Adv Energy Mater 5:1401507–140151110.1002/aenm.201401507 ↗
20. Cho JH, Aykol M, Kim S, Ha JH, Wolverton C, Chung KY, Kim KB, Cho BW (2014) Controlling the intercalation chemistry to design high-performance dual-salt hybrid rechargeable batteries. J Am Chem Soc 136:16116–1611910.1021/ja508463z ↗
21. Meng Y, Wang DS, Wei YJ et al (2017) Competition between insertion of Li+ and Mg2+: An example of TiO2-B nanowires for Mg rechargeable batteries and Li+/Mg2+ hybrid-ion batteries. J Power Sources 346:134–14210.1016/j.jpowsour.2017.02.033 ↗
22. Su SJ, NuLi YN, Huang ZG, Miao Q, Yang J, Wang JL (2016) A high-performance rechargeable Mg2+/Li+ hybrid battery using one-dimensional mesoporous TiO2(B) nanoflakes as the cathode. ACS Appl Mater Inter 8:7111–711710.1021/acsami.6b00106 ↗
23. Pei CY, Xiong FY, Sheng JZ et al (2017) VO2 nanoflakes as the cathode material of hybrid magnesium–lithium-ion batteries with high energy density. ACS Appl Mater Inter 9:17061–17067
24. Yoo HD, Liang YL, Li YF, Yao Y (2015) High areal capacity hybrid magnesium–lithium-ion battery with 99.9% coulombic efficiency for large-scale energy storage. ACS Appl Mater Inter 7:7001–700710.1021/acsami.5b01206 ↗
25. Zhang Y, Xie JJ, Han YL, Li CL (2015) Dual-salt Mg-based batteries with conversion cathodes. Adv Funct Mater 25:7300–730810.1002/adfm.201503639 ↗
26. Naguib M, Kurtoglu M, Presser V et al (2011) Two-dimensional nanocrystals produced by exfoliation of Ti3AlC2. Adv Mater 23:4248–425310.1002/adma.201102306 ↗
27. Naguib M, Mashtalir O, Carle J, Presser V, Lu J, Hultman L, Gogotsi Y, Barsoum MW (2012) Two-dimensional transition metal carbides. ACS Nano 6:1322–133110.1021/nn204153h ↗
28. Ghidiu M, Lukatskaya MR, Zhao MQ, Gogotsi Y, Barsoum MW (2014) Conductive two-dimensional titanium carbide 'clay' with high volumetric capacitance. Nature 516:78–8110.1038/nature13970 ↗
29. Hou W, Yan W, Xing Zhong Y, Guang Ming Z, Jin Z, Xin W, Jia Wei C (2018) Clay-inspired MXene-based electrochemical devices and photo-electrocatalyst: State-of-the-art progresses and challenges. Adv Mater 30:1704561–170458810.1002/adma.201704561 ↗
30. Boota M, Gogotsi Y (2019) MXene-conducting polymer asymmetric pseudocapacitors. Adv Energy Mater 9:1802917–180292410.1002/aenm.201802917 ↗
31. Okubo M, Sugahara A, Kajiyama S, Yamada A (2018) MXene as a charge storage host. Acc Chem Res 51:591–59910.1021/acs.accounts.7b00481 ↗
32. Li Z, Wu Y (2019) 2D early transition metal carbides (MXenes) for catalysis. Small 15:1804736–180474510.1002/smll.201804736 ↗
33. Dong YF, Shi HD and Wu ZS (2020) Recent advances and promise of MXene‐based nanostructures for high‐performance metal ion batteries, Adv Funct Mater 2000706–200072910.1002/adfm.202000706 ↗
34. Tang H, Li WL, Pan LM et al (2019) A robust, freestanding MXene-sulfur conductive paper for long-lifetime Li–S batteries. Adv Funct Mater 29:1901907–190191610.1002/adfm.201901907 ↗
35. Xu M, Lei SL, Qi J et al (2018) Opening magnesium storage capability of two-dimensional MXene by intercalation of cationic surfactant. ACS Nano 12:3733–374010.1021/acsnano.8b00959 ↗
36. Zhao MQ, Xie XQ, Ren CE, Makaryan T, Anasori B, Wang GX, Gogotsi Y (2017) Hollow MXene spheres and 3D macroporous MXene frameworks for Na-ion storage. Adv Mater 29:1702410–170241610.1002/adma.201702410 ↗
37. Luo JM, Tao XY, Zhang J et al (2016) Sn4+ ion decorated highly conductive Ti3C2 MXene: Promising lithium-ion anodes with enhanced volumetric capacity and cyclic performance. ACS Nano 10:2491–249910.1021/acsnano.5b07333 ↗
38. Luo JM, Zhang WK, Yuan HD et al (2017) Pillared structure design of MXene with ultralarge interlayer spacing for high-performance lithium-ion capacitors. ACS Nano 11:2459–246910.1021/acsnano.6b07668 ↗
39. Zhang CF, Cui LF, Abdolhosseinzadeh S, Heier J (2020) Two-dimensional MXenes for lithium-sulfur batteries. InfoMat 2:613–63810.1002/inf2.12080 ↗
40. Meng JN, Zhang FF, Zhang L, Liu LY, Chen JT, Yang BJ, Yan XB (2020) Rolling up MXene sheets into scrolls to promote their anode performance in lithium-ion batteries. J Energy Chem 46:256–26310.1016/j.jechem.2019.10.008 ↗
41. Jiao L, Zhang C, Geng CN et al (2019) Capture and catalytic conversion of polysulfides by in situ built TiO2-MXene heterostructures for lithium–sulfur batteries. Adv Energy Mater 9:1900219–190022710.1002/aenm.201900219 ↗
42. Yu X, Yun S, Yeon JS, Bhattacharya P, Wang LB, Lee SW, Hu XL, Park HS (2018) Emergent pseudocapacitance of 2D nanomaterials. Adv Energy Mater 8:1702930–170296210.1002/aenm.201702930 ↗
43. Byeon A, Zhao MQ, Ren CE et al (2017) Two-dimensional titanium carbide MXene as a cathode material for hybrid magnesium/lithium-ion batteries. ACS Appl Mater Inter 9:4296–430010.1021/acsami.6b04198 ↗
44. Liu FF, Liu YC, Zhao XD, Liu KY, Yin HQ, Fan LZ (2020) Prelithiated V2C MXene: a high-performance electrode for hybrid magnesium/lithium-ion batteries by ion cointercalation. Small 16:1906076–190608410.1002/smll.201906076 ↗
45. Kim H, Choi WI, Jang Y et al (2018) Exceptional lithium storage in a Co(OH)2 anode: hydride formation. ACS Nano 12:2909–292110.1021/acsnano.8b00435 ↗
46. Li T, Nie XY (2018) One-step fast-synthesized foamlike amorphous Co(OH)2 flexible film on Ti foil by plasma-assisted electrolytic deposition as a binder-free anode of a high-capacity lithium-ion battery. ACS Appl Mater Inter 10:16943–1694610.1021/acsami.8b05482 ↗
47. Lukatskaya MR, Mashtalir O, Ren CE et al (2013) Cation intercalation and high volumetric capacitance of two-dimensional titanium carbide. Science 341:1502–150510.1126/science.1241488 ↗
48. Eftekhari-Bafrooei A, Nihonyanagi S, Borguet E (2012) Spectroscopy and dynamics of the multiple free OH species at an aqueous/hydrophobic interface. J Phys Chem C 116:21734–2174110.1021/jp210090h ↗
49. Hsieh CS, Campen RK, Okuno M, Backus EHG, Nagata Y, Bonn M (2013) Mechanism of vibrational energy dissipation of free OH groups at the air-water interface. P Natl Acad Sci USA 110:18780–1878510.1073/pnas.1314770110 ↗
50. Yang J, Liu HW, Martens WN, Frost RL (2010) Synthesis and characterization of cobalt hydroxide, cobalt oxyhydroxide, and cobalt oxide nanodiscs. J Phys Chem C 114:111–11910.1021/jp908548f ↗
51. Al-Abadleh HA, Grassian VH (2003) FT-IR study of water adsorption on aluminum oxide surfaces. Langmuir 19:341–34710.1021/la026208a ↗
52. Khataee A, Fazli A, Zakeri F, Joo SW (2020) Synthesis of a high-performance Z-scheme 2D/2D WO3@CoFe-LDH nanocomposite for the synchronic degradation of the mixture azo dyes by sonocatalytic ozonation process. J Ind Eng Chem 89:301–31510.1016/j.jiec.2020.05.026 ↗
53. Yang LM, Wang ZM, Zhao Y, Tian W, Xu YZ, Weng SF, Wu JG (2000) Complexation of trivalent lanthanide cations by inositols in the solid state: crystal structure and an FT-IR study of PrCl3·myo-inositol·9 H2O. Carbohydr Res 329:847–85310.1016/S0008-6215(00)00230-5 ↗
54. Rathee G, Awasthi A, Sood D, Tomar R, Tomar V, Chandra R (2019) A new biocompatible ternary layered double hydroxide adsorbent for ultrafast removal of anionic organic dyes. Sci Rep 9:16225–1623810.1038/s41598-019-52849-4 ↗
55. Peng QM, Guo JX, Zhang QR, Xiang JY, Liu BZ, Zhou AG, Liu RP, Tian YJ (2014) Unique lead adsorption behavior of activated hydroxyl group in two-dimensional titanium carbide. J Am Chem Soc 136:4113–411610.1021/ja500506k ↗
56. Feng ZZ, Yang J, NuLi YN, Wang JL (2008) Sol–gel synthesis of Mg1.03Mn0.97SiO4 and its electrochemical intercalation behavior. J Power Sources 184:604–60910.1016/j.jpowsour.2008.05.021 ↗
57. Miao XW, Chen ZY, Wang N, Nuli YN, Wang JL, Yang J, Hirano S-i (2017) Electrospun V2MoO8 as a cathode material for rechargeable batteries with Mg metal anode. Nano Energy 34:26–3510.1016/j.nanoen.2017.02.014 ↗
58. Deng XL, Wei ZX, Cui CY, Liu QH, Wang CY, Ma JM (2018) Oxygen-deficient anatase TiO2@C nanospindles with pseudocapacitive contribution for enhancing lithium storage. J Mater Chem A 6:4013–402210.1039/C7TA11301C ↗