Construction of an anionic porous framework via a post-synthesis strategy to regulate the adsorption behavior of organic pollutants
Source abstract
Abstract
This work reports an effective strategy to regulate the adsorption and separation performances in metal–organic frameworks. Through a covalent modification method, strongly acidic –SO3H groups were introduced into MIL-101-NH2 to modify the surface charge property. Based on the contrary electrostatic interactions, the resulting MIL-101-N-SO3H-A/B exhibited significantly reversed adsorption and separation performances for ionic pollutants. Moreover, the adsorptions of MB and MO in these MOFs can be fast achieved (equilibrium time < 20 min) and were not weakened obviously by coexisting inorganic salts. In addition, MIL-101-N-SO3H-B showed a high adsorption capacity of 443.3 mg g−1 for MB dye. Thus, this covalent modification strategy provides a guideline to design MOF-based adsorbents with optional adsorption performances.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Metal-Organic Frameworks: Synthesis and Applications · Covalent Organic Framework Applications · Adsorption and biosorption for pollutant removal
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (29)
Show source-provided references
1. Hu P, Zhao Z, Sun X, Muhammad Y, Li J, Chen S, Pang C, Liao T, Zhao Z (2019) Construction of crystal defect sites in N-coordinated UiO-66 via mechanochemical in-situ N-doping strategy for highly selective adsorption of cationic dyes. Chem Eng J 356:329–34010.1016/j.cej.2018.09.060 ↗
2. Wang C-C, Li J-R, Lv XL, Zhang YQ, Guo GS (2014) Photocatalytic organic pollutants degradation in metal-organic frameworks. Energy Environ Sci 7:2831–286710.1039/C4EE01299B ↗
3. Wang C, Xing F, Bai Y-L, Zhao Y, Li M-X, Zhu S (2016) Synthesis, structure of semi-rapid tetracarboxylate Cu(II) porous coordination polymers and their versatile high-efficiency catalytic dye degradation in neutral aqueous solution. Cryst Growth Des 16:2277–228810.1021/acs.cgd.6b00065 ↗
4. Li C, Xiong Z, Zhang J, Wu C (2015) The strengthening role of the amino group in metal-organic framework MIL-53(Al) for methylene blue and malachite green dye adsorption. J Chem Eng Data 60:3414–342210.1021/acs.jced.5b00692 ↗
5. Furukawa H, Cordova KE, O’Keeffe M, Yaghi OM (2013) The chemistry and applications of metal–organic frameworks. Science 341:123044410.1126/science.1230444 ↗
6. Wang Y, Zhang N, Chen D, Ma D, Liu G, Zou X, Chen Y, Shu R, Song Q, Lv W (2019) Facile synthesis of acid-modified UiO-66 to enhance the removal of Cr(VI) from aqueous solutions. Sci Total Environ 682:118–12710.1016/j.scitotenv.2019.04.407 ↗
7. Li J, Wang X, Zhao G, Chen C, Chai Z, Alsaedi A, Hayat T, Wang X (2018) Metal-organic framework-based materials: superior adsorbents for the capture of toxic and radioactive metal ions. Chem Soc Rev 47:2322–235610.1039/C7CS00543A ↗
8. Chen J, Gao Q, Zhang X, Liu Y, Wang P, Jiao Y, Yang Y (2019) Nanometer mixed-valence silver oxide enhancing adsorption of ZIF-8 for removal of iodide in solution. Sci Total Environ 646:634–64410.1016/j.scitotenv.2018.07.298 ↗
9. Guo J, Li J-J, Wang C-C (2019) Adsorptive removal of Cr(VI) from simulated wastewater in MOF BUC-17 ultrafine powder. J Environ Chem Eng 7:10290910.1016/j.jece.2019.102909 ↗
10. Zhao X, Zhao Y, Zheng M, Liu S, Xue W, Du G, Wang T, Gao X, Wang K, Hu J, Gao Z, Huang H (2019) Efficient separation of vitamins mixture in aqueous solution using a stable zirconium-based metal-organic framework. J Colloid Interface Sci 555:714–72110.1016/j.jcis.2019.08.024 ↗
11. Jiang D, Chen M, Wang H, Zeng G, Huang D, Chen M, Liu Y, Xue W, Wang Z (2019) The application of different typological and structural MOFs-based materials for the dyes adsorption. Coordin Chem Rev 380:471–48310.1016/j.ccr.2018.11.002 ↗
12. Xie L-H, Liu X-M, Li J-R (2018) Metal-organic frameworks for the capture of trace aromatic volatile organic compounds. Chemistry 4:1911–192710.1016/j.chempr.2018.05.017 ↗
13. Wang B, Lv X-L, Feng D, Xie L-H, Zhang J, Li M, Xie Y, Li J-R, Zhou H-C (2016) Highly stable Zr(IV)-based metal-organic frameworks for the detection and removal of antibiotics and organic explosives in water. J Am Chem Soc 138:6204–621610.1021/jacs.6b01663 ↗
14. Li T-T, Liu Y-M, Wang T, Wu Y-L, He Y-L, Yang R, Zheng S-R (2018) Regulation of the surface area and surface charge property of MOFs by multivariate strategy: synthesis, characterization, selective dye adsorption and separation. Micropor Mesopor Mater 272:101–10810.1016/j.micromeso.2018.06.023 ↗
15. Hahm H, Kim S, Ha H, Jung S, Kim Y, Yoon M, Kim M (2015) Charged functional groups effects on metal-organic framework for selective organic dye adsorptions. CrystEngComm 17:8418–842210.1039/C5CE01512J ↗
16. Luo X-P, Fu S-Y, Du Y-M, Guo J-Z, Li B (2017) Adsorption of methylene blue and malachite green from aqueous solution by sulfonic acid group modified MIL-101. Micropor Mesopor Mater 237:268–27410.1016/j.micromeso.2016.09.032 ↗
17. Haque E, Lee JE, Jang IT, Hwang YK, Chang J-S, Jegal J, Jhung SH (2010) Adsorptive removal of methyl orange from aqueous solution with metal-organic frameworks, porous chromium-benzenedicarboxylates. J Hazard Mater 181:535–54210.1016/j.jhazmat.2010.05.047 ↗
18. Zhao X, Wang K, Gao Z, Gao H, Xie Z, Du X, Huang H (2017) Reversing the dye adsorption and separation performance of metal-organic frameworks via introduction of –SO3H groups. Ind Eng Chem Res 56:4496–450110.1021/acs.iecr.7b00128 ↗
19. Mao C, Kudla RA, Zuo F, Zhao X, Mueller LJ, Bu X, Peng P (2014) Anion stripping as a general method to create cationic porous framework with mobile anions. J Am Chem Soc 136:7579–758210.1021/ja5030723 ↗
20. Lin Y, Kong C, Chen L (2012) Direct synthesis of amine-functionalized MIL-101(Cr) nanoparticles and application for CO2 capture. RSC Adv 2:6417–741910.1039/c2ra20641b ↗
21. Ko N, Choi PG, Hong J, Yeo M, Sung S, Cordova KE, Park HJ, Yang JK, Kim J (2015) Tailoring the water adsorption properties of MIL-101 metal-organic frameworks by partial functionalization. J Mater Chem A 3:2057–206410.1039/C4TA04907A ↗
22. Li B, Zhang Y, Krishna R, Yao K, Han Y, Wu Z, Ma D, Shi Z, Pham T, Space B, Liu J, Thallapally PK, Liu J, Chrzanowski M, Ma S (2014) Introduction of π-complexation into porous aromatic framework for highly selective adsorption of ethylene over ethane. J Am Chem Soc 136:8654–866010.1021/ja502119z ↗
23. Lin S, Song Z, Che G, Ren A, Li P, Liu C, Zhang J (2014) Adsorption behavior of metal-organic frameworks for methylene blue from aqueous solution. Micropor Mesopor Mater 193:27–3410.1016/j.micromeso.2014.03.004 ↗
24. Sharma Uma YC (2010) Optimization of parameters for adsorption of methylene blue on a low-cost activated carbon. J Chem Eng Data 55:435–43910.1021/je900408s ↗
25. Huang X-X, Qiu L-G, Zhang W, Yuan Y-P, Jiang X, Xie A-J, Shen Y-H, Zhu J-F (2012) Hierarchically mesostructured MIL-101 metal-organic frameworks: supramolecular template-directed synthesis and accelerated adsorption kinetics for dye removal. CysEngComm 14:1613–161710.1039/C1CE06138K ↗
26. Zhang W, Yang J-M, Yang R-N, Yang B-C, Quan S, Jiang X (2019) Effect of free carboxylic acid groups in UiO-66 analogues on the adsorption of dyes from water: Plausible mechanisms for adsorption and gate-opening behavior. J Mol Liq 283:160–16610.1016/j.molliq.2019.03.100 ↗
27. Haque E, Jun JW, Jhung SH (2011) Adsorptive removal of methyl orange and methylene blue from aqueous solution with a metal-organic framework material, iron terephthalate (MOF-235). J Hazard Mater 185:507–51110.1016/j.jhazmat.2010.09.035 ↗
28. Ma J, Jia Y, Jing Y, Yao Y, Sun J (2012) Kinetics and thermodynamics of methylene blue adsorption by cobalt-hectorite composite. Dyes Pigments 93:1441–144610.1016/j.dyepig.2011.08.010 ↗
29. Zhao X, Zhao H, Dai W, Wei Y, Wang Y, Zhang Y, Zhi L, Huang H, Gao Z (2018) A metal-organic framework with large 1-D channels and rich –OH sites for high-efficiency chloramphenicol removal from water. J Colloid Interface Sci 526:28–3410.1016/j.jcis.2018.04.095 ↗