Synthesis and characterization of new anthracene-based semi-conducting materials
Source abstract
Abstract
Two soluble anthracene-based organic materials (BPA-An1 and BPA-An2) have been synthesized and characterized. The optical properties of these π-conjugated systems were investigated by UV–Visible absorption and photoluminescence (PL) spectroscopies. The optical gaps were estimated from the absorption onsets of the thin polymer films; their values were 3.01 and 2.76 eV for BPA-An1 and BPA-An2, respectively. The PL spectrum of BPA-An2 exhibits a blue emission both in dilute solution and thin film. BPA-An1 showed a blue photoluminescence in dilute solution; in solid film, π–π interactions influence its optical behavior and a green emission was observed. The HOMO and LUMO levels were estimated using cyclic voltammetry analysis. Single-layer devices of the (indium-tin oxide/anthracene-based material/aluminum) configuration have been elaborated and showed relatively low turn-on voltages of 6.2–5.5 V for BPA-An1 and BPA-An2, respectively.
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Research context
OpenAlex topics: Organic Electronics and Photovoltaics · Conducting polymers and applications · Organic Light-Emitting Diodes Research
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