Phosphorus-doped silicon nanoparticles as high performance LIB negative electrode
Source abstract
Abstract
Silicon is getting much attention as the promising next-generation negative electrode materials for lithium-ion batteries with the advantages of abundance, high theoretical specific capacity and environmentally friendliness. In this work, a series of phosphorus (P)-doped silicon negative electrode materials (P-Si-34, P-Si-60 and P-Si-120) were obtained by a simple heat treatment method, which can maintain the original nanoparticle morphology. The P-Si-60 material shows excellent discharge specific capacity, rate performance and cycling performance. The discharge specific capacity after 50 cycles remains > 2000 mAh g−1 with a capacity retention rate of 74.3%. The excellent electrochemical properties of P-Si-60 material can be attributed to the phosphorus doping without destroying the original particle morphology and nanostructure and the higher intrinsic electric conductivity. It will bring new thoughts for the further application of silicon negative electrode materials.
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Research context
OpenAlex topics: Advancements in Battery Materials · Supercapacitor Materials and Fabrication · Advanced battery technologies research
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (30)
Show source-provided references
1. Sun Y, Liu N, Cui Y (2016) Promises and challenges of nanomaterials for lithium-based rechargeable batteries. Nat Energy 1:16071. https://doi.org/10.1038/nenergy.2016.7110.1038/nenergy.2016.71 ↗
2. Osiak M, Geaney H, Armstrong E, O’Dwyer C (2014) Structuring materials for lithium-ion batteries: advancements in nanomaterial structure, composition, and defined assembly on cell performance. J Mater Chem A 2:9433–9460. https://doi.org/10.1039/c4ta00534a10.1039/c4ta00534a ↗
3. Andre D, Hain H, Lamp P, Maglia F, Stiaszny B (2017) Future high-energy density anode materials from an automotive. J Mater Chem 5:17174–17198. https://doi.org/10.1039/C7TA03108D10.1039/C7TA03108D ↗
4. Liu W, Song MS, Kong B, Cui Y (2017) Flexible and stretchable energy storage: recent advances and future perspectives. Adv Mater 29:1603436. https://doi.org/10.1002/adma.20160343610.1002/adma.201603436 ↗
5. Ashuri M, He Q, Shaw LL (2016) Silicon as a potential anode material for Li-ion batteries: where size, geometry and structure matter. Nanoscale 8:74–103. https://doi.org/10.1039/c5nr05116a10.1039/c5nr05116a ↗
6. Luo W et al (2017) Surface and interface engineering of silicon-based anode materials for lithium-ion batteries. Adv Energy Mater 7:1701083. https://doi.org/10.1002/aenm.20170108310.1002/aenm.201701083 ↗
7. Ogata K et al (2014) Revealing lithium-silicide phase transformations in nano-structured silicon-based lithium ion batteries via in situ NMR spectroscopy. Nat Commun 5:3217. https://doi.org/10.1038/ncomms421710.1038/ncomms4217 ↗
8. Tokur M, Aydin A, Cetinkaya T, Akbulut H (2017) Shoring up the lithium ion batteries with multi-component silicon yolk-shell anodes for grid-scale storage systems: experimental and computational mechanical studies. J Electrochem Soc 164:A2238–A2250. https://doi.org/10.1149/2.0401712jes10.1149/2.0401712jes ↗
9. Ma Y et al (2017) Facile synthesis of Si-C nanocomposites with yolk-shell structure as an anode for lithium-ion batteries. J Alloys Compd 704:599–606. https://doi.org/10.1016/j.jallcom.2017.02.08310.1016/j.jallcom.2017.02.083 ↗
10. Fang S, Tong Z, Nie P, Liu G, Zhang X (2017) Raspberry-like nanostructured silicon composite anode for high-performance lithium-ion batteries. ACS Appl Mater interfaces 9:18766–18773. https://doi.org/10.1021/acsami.7b0315710.1021/acsami.7b03157 ↗
11. Son Y et al (2018) Exploring critical factors affecting strain distribution in 1D silicon-based nanostructures for lithium-ion battery anodes. Adv Mater 30:e1705430. https://doi.org/10.1002/adma.20170543010.1002/adma.201705430 ↗
12. Paton KR et al (2014) Scalable production of large quantities of defect-free few-layer graphene by shear exfoliation in liquids. Nat Mater 13:624–630. https://doi.org/10.1038/nmat394410.1038/nmat3944 ↗
13. Kong MH, Noh JH, Byun DJ, Lee JK (2008) Electrochemical characteristics of phosphorus doped silicon and graphite composite for the anode materials of lithium secondary batteries. J Electroceram 23:376. https://doi.org/10.1007/s10832-008-9471-910.1007/s10832-008-9471-9 ↗
14. Minoru Fujii YY, Takase Y, Ninomiya K, Hayashi S (2004) Control of photoluminescence properties of Si nanocrystals by simultaneously doping n- and p-type impurities. Appl Phys Lett 85:1158. https://doi.org/10.1063/1.177995510.1063/1.1779955 ↗
15. Ooshida T, Otsuki M (2018) Two-tag correlations and nonequilibrium fluctuation-response relation in ageing single-file diffusion. J Phys Condens Matter 30:374001. https://doi.org/10.1088/1361-648X/aad4cc10.1088/1361-648X/aad4cc ↗
16. Legrain F, Manzhos S (2015) Aluminum doping improves the energetics of lithium, sodium, and magnesium storage in silicon: a first-principles study. J Power Sources 274:65–70. https://doi.org/10.1016/j.jpowsour.2014.10.03710.1016/j.jpowsour.2014.10.037 ↗
17. Chen J et al (2021) Self-supporting dual-confined porous Si@c-ZIF@carbon nanofibers for high-performance lithium-ion batteries. Chem Commun. https://doi.org/10.1039/D1CC04172J10.1039/D1CC04172J ↗
18. Gao M et al (2021) Self-supporting N, P doped Si/CNTs/CNFs composites with fiber network for high-performance lithium-ion batteries. J Alloys Compd 857:157554. https://doi.org/10.1016/j.jallcom.2020.15755410.1016/j.jallcom.2020.157554 ↗
19. Zhang C, Mahmood N, Yin H, Liu F, Hou Y (2013) Synthesis of phosphorus-doped graphene and its multifunctional applications for oxygen reduction reaction and lithium ion batteries. Adv Mater 25:4932–4937. https://doi.org/10.1002/adma.20130187010.1002/adma.201301870 ↗
20. Ette PM et al (2020) Nanocrystalline silicon embedded highly conducting phosphorus doped silicon thin film as high power lithium ion battery anode. Electrochim Acta 330:135318. https://doi.org/10.1016/j.electacta.2019.13531810.1016/j.electacta.2019.135318 ↗
21. Huang S, Cheong L-Z, Wang D, Shen C (2017) Nanostructured phosphorus doped silicon/graphite composite as anode for high-performance lithium-ion batteries. ACS Appl Mater Interfaces 9:23672–23678. https://doi.org/10.1021/acsami.7b0436110.1021/acsami.7b04361 ↗
22. Domi Y, Usui H, Shimizu M, Kakimoto Y, Sakaguchi H (2016) Effect of phosphorus-doping on electrochemical performance of silicon negative electrodes in lithium-ion batteries. ACS Appl Mater Interfaces 8:7125–7132. https://doi.org/10.1021/acsami.6b0038610.1021/acsami.6b00386 ↗
23. Jung C-Y et al (2015) Effects of phosphorous incorporation on the microstructure of Si nanoparticles as an anode material for lithium-ion battery. Thin Solid Films 587:142–149. https://doi.org/10.1016/j.tsf.2015.01.06810.1016/j.tsf.2015.01.068 ↗
24. Reyes Jimenez A et al (2017) A step toward high-energy silicon-based thin film lithium ion batteries. ACS Nano 11:4731–4744. https://doi.org/10.1021/acsnano.7b0092210.1021/acsnano.7b00922 ↗
25. Liu Y et al (2018) Interpenetrated 3D porous silicon as high stable anode material for Li-Ion battery. J Power Sources 406:167–175. https://doi.org/10.1016/j.jpowsour.2018.10.02810.1016/j.jpowsour.2018.10.028 ↗
26. Jeong M-G et al (2017) Self-rearrangement of silicon nanoparticles embedded in micro-carbon sphere framework for high-energy and long-life lithium-ion batteries. Nano Lett 17:5600–5606. https://doi.org/10.1021/acs.nanolett.7b0243310.1021/acs.nanolett.7b02433 ↗
27. Celotti G, Nobili D, Ostoja P (1974) Lattice parameter study of silicon uniformly doped with boron and phosphorus. J Mater Sci 9:821–828. https://doi.org/10.1007/BF0076180210.1007/BF00761802 ↗
28. Shenouda, A. Y. L., Hua-Kun (2010) Preparation, characterization, and electrochemical performance of Li2CuSnO4 and Li2CuSnSiO6 electrodes for lithium batteries (Research Online).10.1149/1.3479425 ↗
29. Shi L et al (2015) Si nanoparticles adhering to a nitrogen-rich porous carbon framework and its application as a lithium-ion battery anode material. J Mater Chem A 3:18190–18197. https://doi.org/10.1039/C5TA03974F10.1039/C5TA03974F ↗
30. Li R et al (2018) One-step synthesis of 3D sulfur/nitrogen dual-doped graphene supported nano silicon as anode for Li-ion batteries. Appl Surf Sci 433:367–373. https://doi.org/10.1016/j.apsusc.2017.10.06110.1016/j.apsusc.2017.10.061 ↗