journal article·2020-08

Preparation of hyperelastic graphene/carboxymethyl cellulose composite aerogels by ambient pressure drying and its adsorption applications

Wenlong Xu, Shuang Chen, Yanan Zhu, Xiaoxiao Xiang, Yuqin Bo, Zimei Lin, Hao Wu, Huie Liu

Journal of Materials Science· Volume 55· Issue 24
Publisher page

Abstract

Three-dimensional porous graphene-based aerogels have become one of the most promising adsorbent materials for water pollution because of their unique structure and superhigh adsorption properties. However, most pore structures of graphene-based aerogels only have affinity for certain types of pollutants. This restricts the industrial application of graphene-based aerogels to a certain extent. In this study, superelastic graphene/carboxymethyl cellulose composite aerogels (SGA/CMC) were prepared under ambient pressure. And the effects of reducing agent dosage, prereduction time and pH value on the formation of aerogel were investigated. FTIR, XRD, XPS, Raman, SEM and microcomputer-controlled electronic universal testing machine were used to characterize the structure, stress–strain and micromorphology of SGA/CMC. The results show that SGA/CMC can not only adsorb the pure organic compound, but also the dye in water. The static adsorption rate of cyclohexane on water surface is 13.15 g g−1 s−1, and the removal rate of methylene blue in water can reach 99.7%. In addition, SGA/CMC shows high elasticity and fatigue resistance. After 500 cycles of cyclic compression at 80% strain, it can still recover to about 95% of the original height.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Aerogels and thermal insulation · Surface Modification and Superhydrophobicity · Supercapacitor Materials and Fabrication

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (48)

Show source-provided references
1. Lua AC, Guo J (2001) Microporous oil-palm-shell activated carbon prepared by physical activation for gas-phase adsorption. Langmuir 17:7112–711710.1021/la010290c ↗
2. Shi X, Ranellone RT, Sezer H, Lamie N, Zabilansky L, Stone K, Rangwala AS (2017) Influence of ullage to cavity size ratio on in-situ burning of oil spills in ice-infested water. Cold Reg Sci Technol 140:5–1310.1016/j.coldregions.2017.04.010 ↗
3. Chen Y, Lin J, Chen Z (2017) Remediation of water contaminated with diesel oil using a coupled process: biological degradation followed by heterogeneous Fenton-like oxidation. Chemosphere 183:286–29310.1016/j.chemosphere.2017.05.120 ↗
4. Punzi M, Anbalagan A, Borner RA, Svensson B-M, Jonstrup M, Mattiasson B (2015) Degradation of a textile azo dye using biological treatment followed by photo-Fenton oxidation: evaluation of toxicity and microbial community structure. Chem Eng J 270:290–29910.1016/j.cej.2015.02.042 ↗
5. Xu W-J, Zhang W-S, Li Y, Zhang S-L (2016) Adsorption of methyl orange dye from aqueous solutions by acrylic composite resin chemically modified with calcium lignosulphonate. Acta Polym Sin 3:307–314
6. Gong Z, Alef K, Wilke B-M, Li P (2007) Activated carbon adsorption of PAHs from vegetable oil used in soil remediation. J Hazard Mater 143:372–37810.1016/j.jhazmat.2006.09.037 ↗
7. Tofighy MA, Mohammadi T (2011) Adsorption of divalent heavy metal ions from water using carbon nanotube sheets. J Hazard Mater 185:140–14710.1016/j.jhazmat.2010.09.008 ↗
8. Peng W, Li H, Liu Y, Song S (2017) A review on heavy metal ions adsorption from water by graphene oxide and its composites. J Mol Liq 230:496–50410.1016/j.molliq.2017.01.064 ↗
9. Rahmani Z, Rashidi AM, Kazemi A, Samadi MT, Rahmani AR (2018) N-doped reduced graphene oxide aerogel for the selective adsorption of oil pollutants from water: isotherm and kinetic study. J Ind Eng Chem 61:416–42610.1016/j.jiec.2017.12.041 ↗
10. Liang Q, Luo H, Geng J, Chen J (2018) Facile one-pot preparation of nitrogen-doped ultra-light graphene oxide aerogel and its prominent adsorption performance of Cr(VI). Chem Eng J 338:62–7110.1016/j.cej.2017.12.145 ↗
11. Johra FT, Jung W-G (2018) Fabrication of reduced graphene oxide decorated with CuS nanoparticles and its activity toward the adsorption of Methylene Blue. J Serb Chem Soc 83:503–51310.2298/JSC170810117T ↗
12. Chen N, Pan Q (2013) Versatile fabrication of ultralight magnetic foams and application for oil-water separation. ACS Nano 7:6875–688310.1021/nn4020533 ↗
13. Ge J, Zhao H-Y, Zhu H-W, Huang J, Shi L-A, Yu S-H (2016) Advanced sorbents for oil-spill cleanup: recent advances and future perspectives. Adv Mater 28:10459–1049010.1002/adma.201601812 ↗
14. Shen Y, Zhu X, Zhu L, Chen B (2017) Synergistic effects of 2D graphene oxide nanosheets and 1D carbon nanotubes in the constructed 3D carbon aerogel for high performance pollutant removal. Chem Eng J 314:336–34610.1016/j.cej.2016.11.132 ↗
15. Liu Y, Zhan F, Wang B, Xie B, Sun Q, Jiang H, Li J, Sun X (2019) Three-dimensional composite catalysts for Al–O-2 batteries composed of CoMN2O4 nanoneedles supported on nitrogen-doped carbon nanotubes/graphene. ACS Appl Mater Interfaces 11:21526–2153510.1021/acsami.9b04861 ↗
16. Zhu P, Nair AS, Peng S, Yang S, Ramakrishna S (2016) Facile fabrication of TiO2-graphene composite with enhanced photovoltaic and photocatalytic properties by electrospinning (vol 4, p 581, 2012). ACS Appl Mater Interfaces 8:5051–505110.1021/acsami.5b12009 ↗
17. Garakani MA, Abouali S, Zhang B, Takagi CA, Xu Z-L, Huang J-Q, Huang J, Kim J-K (2014) cobalt carbonate/and cobalt oxide/graphene aerogel composite anodes for high performance Li-ion batteries. ACS Appl Mater Interfaces 6:18971–1898010.1021/am504851s ↗
18. Chen B, Bi H, Ma Q, Tan C, Cheng H, Chen Y, He X, Sun L, Lim T-T, Huang L, Zhang H (2017) Preparation of graphene-MoS2 hybrid aerogels as multifunctional sorbents for water remediation. Sci China-Mater 60:1102–110810.1007/s40843-017-9150-7 ↗
19. Kim T-W, Park S-J (2017) Synthesis of reduced graphene oxide/thorn-like titanium dioxide nanofiber aerogels with enhanced electrochemical performance for supercapacitor. J Coll Interface Sci 486:287–29510.1016/j.jcis.2016.10.007 ↗
20. Wang C, Yang S, Ma Q, Jia X, Ma P-C (2017) Preparation of carbon nanotubes/graphene hybrid aerogel and its application for the adsorption of organic compounds. Carbon 118:765–77110.1016/j.carbon.2017.04.001 ↗
21. Zhou G, Li F, Cheng H-M (2014) Progress in flexible lithium batteries and future prospects. Energy Environ Sci 7:1307–133810.1039/C3EE43182G ↗
22. Bai X, Zhai Y, Zhang Y (2011) Green approach to prepare graphene-based composites with high microwave absorption capacity. J Phys Chem C 115:11673–1167710.1021/jp202475m ↗
23. Rafiee MA, Rafiee J, Wang Z, Song H, Yu Z-Z, Koratkar N (2009) Enhanced mechanical properties of nanocomposites at low graphene content. ACS Nano 3:3884–389010.1021/nn9010472 ↗
24. Garcia-Bordeje E, Victor-Roman S, Sanahuja-Parejo O, Benito AM, Maser WK (2018) Control of the microstructure and surface chemistry of graphene aerogels via pH and time manipulation by a hydrothermal method. Nanoscale 10:3526–353910.1039/C7NR08732B ↗
25. Lin R, Li A, Lu L, Cao Y (2015) Preparation of bulk sodium carboxymethyl cellulose aerogels with tunable morphology. Carbohydr Polym 118:126–13210.1016/j.carbpol.2014.10.075 ↗
26. Huang Z-M, Liu X-Y, Wu W-G, Li Y-Q, Wang H (2017) Highly elastic and conductive graphene/carboxymethylcellulose aerogels for flexible strain-sensing materials. J Mater Sci 52:12540–12552. https://doi.org/10.1007/s10853-017-1374-110.1007/s10853-017-1374-1 ↗
27. Javier Salavagione H, Martinez G, Gomez MA (2009) Synthesis of poly(vinyl alcohol)/reduced graphite oxide nanocomposites with improved thermal and electrical properties. J Mater Chem 19:5027–503210.1039/b904232f ↗
28. Lu L, Sun H, Peng F, Jiang Z (2006) Novel graphite-filled PVA/CS hybrid membrane for pervaporation of benzene/cyclohexane mixtures. J Membr Sci 281:245–25210.1016/j.memsci.2006.03.041 ↗
29. Yadav M, Rhee KY, Park SJ (2014) Synthesis and characterization of graphene oxide/carboxymethylcellulose/alginate composite blend films. Carbohyd Polym 110:18–2510.1016/j.carbpol.2014.03.037 ↗
30. Yadav M, Rhee KY, Jung IH, Park SJ (2013) Eco-friendly synthesis, characterization and properties of a sodium carboxymethyl cellulose/graphene oxide nanocomposite film. Cellulose 20:687–69810.1007/s10570-012-9855-5 ↗
31. Chen J, Chi F, Huang L, Zhang M, Yao B, Li Y, Li C, Shi G (2016) Synthesis of graphene oxide sheets with controlled sizes from sieved graphite flakes. Carbon 110:34–4010.1016/j.carbon.2016.08.096 ↗
32. Peng L, Xu Z, Liu Z, Wei Y, Sun H, Li Z, Zhao X, Gao C (2015) An iron-based green approach to 1-h production of single-layer graphene oxide. Nat Commun 6:1–9
33. Wan C, Li J (2016) Graphene oxide/cellulose aerogels nanocomposite: preparation, pyrolysis, and application for electromagnetic interference shielding. Carbohydr Polym 150:172–17910.1016/j.carbpol.2016.05.051 ↗
34. Chen C, Zhu X, Chen B (2018) Covalently cross-linked graphene oxide aerogel with stable structure for high-efficiency water purification. Chem Eng J 354:896–90410.1016/j.cej.2018.08.034 ↗
35. Yan H, Bai J, Liao M, He Y, Liu Q, Liu J, Zhang H, Li Z, Wang J (2017) One-step synthesis of Co3O4/graphene aerogels and their all-solid-state asymmetric supercapacitor. Eur J Inorg Chem 2017:1143–115210.1002/ejic.201601202 ↗
36. Wang X, Li J, Luo Y, Huang M (2014) A novel ammonium perchlorate/graphene aerogel nanostructured energetic composite: preparation and thermal decomposition. Sci Adv Mater 6:530–53710.1166/sam.2014.1774 ↗
37. Xiao L, Wu D, Han S, Huang Y, Li S, He M, Zhang F, Feng X (2013) Self-assembled Fe2O3/graphene aerogel with high lithium storage performance. ACS Appl Mater Interfaces 5:3764–376910.1021/am400387t ↗
38. Wu C, Huang X, Wu X, Qian R, Jiang P (2013) Mechanically flexible and multifunctional polymer-based graphene foams for elastic conductors and oil-water separators. Adv Mater 25:5658–566210.1002/adma.201302406 ↗
39. Mu B, Li M (2018) Fabrication and thermal properties of tetradecanol/graphene aerogel form-stable composite phase change materials. Sci Rep 8:1–1410.1038/s41598-017-17765-5 ↗
40. Chen M, Li Z, Li J, Li J, Li Q, Zhang L (2017) The extraction of uranium using graphene aerogel loading organic solution. Talanta 166:284–29110.1016/j.talanta.2017.01.070 ↗
41. Chen W, Li S, Chen C, Yan L (2011) Self-assembly and embedding of nanoparticles by in situ reduced graphene for preparation of a 3D graphene/nanoparticle aerogel. Adv Mater 23:5679–568310.1002/adma.201102838 ↗
42. Qiu L, Huang B, He Z, Wang Y, Tian Z, Liu JZ, Wang K, Song J, Gengenbach TR, Li D (2017) Extremely low density and super-compressible graphene cellular materials. Adv Mater 29:170155310.1002/adma.201701553 ↗
43. Gao H-L, Zhu Y-B, Mao L-B, Wang F-C, Luo X-S, Liu Y-Y, Lu Y, Pan Z, Ge J, Shen W, Zheng Y-R, Xu L, Wang L-J, Xu W-H, Wu H-A, Yu S-H (2016) Super-elastic and fatigue resistant carbon material with lamellar multi-arch microstructure. Nat Commun 7:1–8
44. Huang H, Chen P, Zhang X, Lu Y, Zhan W (2013) Edge-to-edge assembled graphene oxide aerogels with outstanding mechanical performance and superhigh chemical activity. Small 9:1397–140410.1002/smll.201202965 ↗
45. Xu L, Xiao G, Chen C, Li R, Mai Y, Sun G, Yan D (2015) Superhydrophobic and superoleophilic graphene aerogel prepared by facile chemical reduction. J Mater Chem A 3:7498–750410.1039/C5TA00383K ↗
46. Dong X, Chen J, Ma Y, Wang J, Chan-Park MB, Liu X, Wang L, Huang W, Chen P (2012) Superhydrophobic and superoleophilic hybrid foam of graphene and carbon nanotube for selective removal of oils or organic solvents from the surface of water. Chem Commun 48:10660–1066210.1039/c2cc35844a ↗
47. Bi H, Xie X, Yin K, Zhou Y, Wan S, He L, Xu F, Banhart F, Sun L, Ruoff RS (2012) Spongy graphene as a highly efficient and recyclable sorbent for oils and organic solvents. Adv Funct Mater 22:4421–442510.1002/adfm.201200888 ↗
48. Zhao J, Ren W, Cheng H-M (2012) Graphene sponge for efficient and repeatable adsorption and desorption of water contaminations. J Mater Chem 22:20197–2020210.1039/c2jm34128j ↗