Effect of fiber orientation in gelled poly(vinylidene fluoride) electrospun membranes for Li-ion battery applications
Source abstract
Abstract
Battery separators based on electrospun membranes of poly(vinylidene fluoride) (PVDF) have been prepared in order to study the effect of fiber alignment on the performance and characteristics of the membrane. The prepared membranes show an average fiber diameter of ~272 nm and a degree of porosity of ~87 %. The gel polymer electrolytes are prepared by soaking the membranes in the electrolyte solution. The alignment of the fibers improves the mechanical properties for the electrospun membranes. Further, the microstructure of the membrane also plays an important role in the ionic conductivity, being higher for the random electrospun membrane due to the lower tortuosity value. Independently of the microstructure, both membranes show good electrochemical stability up to 5.0 V versus Li/Li+. These results show that electrospun membranes based on PVDF are appropriate for battery separators in lithium-ion battery applications, the random membranes showing a better overall performance.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Advancements in Battery Materials · Advanced Battery Materials and Technologies · Advanced Battery Technologies Research
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (54)
Show source-provided references
1. Pistoia G, Nazri G-A (eds) (2003) Lithium batteries, science and technology. Springer Science, New York
2. Scrosati B, Garche J (2010) J Power Sources 195(9):241910.1016/j.jpowsour.2009.11.048 ↗
3. Rydh CJ, Sandén BA (2005) Energy Convers Manag 46(11–12):195710.1016/j.enconman.2004.10.003 ↗
4. Kang B, Ceder G (2009) Nature 458(7853):19010.1038/nature07853 ↗
5. Yoshio M, Brodd RJ, Kozawa A (2009) Lithium-ion batteries: science and technologies. Springer, New York10.1007/978-0-387-34445-4 ↗
6. Arico AS, Bruce P, Scrosati B, Tarascon J-M, van Schalkwijk W (2005) Nat Mater 4(5):36610.1038/nmat1368 ↗
7. Yang M, Hou J (2012) Membranes 2(3):36710.3390/membranes2030367 ↗
8. Cheng F, Liang J, Tao Z, Chen J (2011) Adv Mater 23(15):169510.1002/adma.201003587 ↗
9. Missan HPS, Sekhon SS (2005) J Mater Sci 40(14):3771. doi: 10.1007/s10853-005-3317-510.1007/s10853-005-3317-5 ↗
10. Balbuena PB, Wang Y (eds) (2004) Lithium-ion batteries: solid–electrolyte interphase. Imperial College Press, London
11. Hikmet RAM (2001) In: Buschow KHJ, Cahn Robert W, Merton CF et al (eds) Encyclopedia of materials: science and technology. Elsevier, Oxford, p 653410.1016/B0-08-043152-6/01155-4 ↗
12. Arora P, Zhang Z (2004) Chem Rev 104(10):441910.1021/cr020738u ↗
13. Xu K (2004) Chem Rev 104(10):430310.1021/cr030203g ↗
14. Park M, Zhang X, Chung M, Less GB, Sastry AM (2010) J Power Sources 195(24):790410.1016/j.jpowsour.2010.06.060 ↗
15. Stephen AM (2006) Eur Polym J 42(1):2110.1016/j.eurpolymj.2005.09.017 ↗
16. Millet P, Andolfatto F, Durand R (1995) J Appl Electrochem 25(3):233
17. Chung YS, Yoo SH, Kim CK (2009) Ind Eng Chem Res 48(9):434610.1021/ie900096z ↗
18. Venugopal G, Moore J, Howard J, Pendalwar S (1999) J Power Sources 77(1):3410.1016/S0378-7753(98)00168-2 ↗
19. Costa CM, Tamano Machiavello MN, Gomez Ribelles JL et al (2013) J Mater Sci 48(9):3494. doi: 10.1007/s10853-013-7141-z10.1007/s10853-013-7141-z ↗
20. Kang Y, Kim HJ, Kim E, Oh B, Cho JH (2001) J Power Sources 92(1–2):25510.1016/S0378-7753(00)00546-2 ↗
21. Costa CM, Silva MM, Lanceros-Mendez S (2013) RSC Adv. doi: 10.1039/C3RA40732B
22. Costa CM, Rodrigues LC, Sencadas V, Silva MM, Rocha G, Lanceros-Méndez S (2012) J Membr Sci 407–408(8):19310.1016/j.memsci.2012.03.044 ↗
23. Yang XQ, Lee HS, Hanson L, McBreen J, Okamoto Y (1995) J Power Sources 54(2):19810.1016/0378-7753(94)02066-C ↗
24. Nishikawa O, Sugimoto T, Nomura S, Doyama K, Miyatake K, Uchida H, Watanabe M (2004) Electrochim Acta 50(2–3):66710.1016/j.electacta.2003.12.069 ↗
25. Kim JR, Choi SW, Jo SM, Lee WS, Kim BC (2004) Electrochim Acta 50(1):6910.1016/j.electacta.2004.07.014 ↗
26. Li Z, Shan F, Wei J, Yang J, Li X, Wang X (2008) J Solid State Electrochem 12(12):162910.1007/s10008-008-0540-4 ↗
27. Abraham KM, Jiang Z, Carroll B (1997) Chem Mater 9(9):197810.1021/cm970075a ↗
28. Sylla S, Sanchez JY, Armand M (1992) Electrochim Acta 37(9):169910.1016/0013-4686(92)80141-8 ↗
29. Cui W-W, Tang D-Y, Gong Z-l, Guo Y-D (2012) J Mater Sci 47(17):6276. doi: 10.1007/s10853-012-6547-310.1007/s10853-012-6547-3 ↗
30. Srinivasan G, Reneker DH (1995) Polym Int 36(2):19510.1002/pi.1995.210360210 ↗
31. Saunier J, Alloin F, Sanchez JY, Maniguet L (2004) J Polym Sci B 42(12):230810.1002/polb.20099 ↗
32. Nakajima T, Groult H (2005) Fluorinated materials for energy conversion. Elsevier, Amsterdam
33. Kim JR, Choi SW, Jo SM, Lee WS, Kim BC (2005) J Electrochem Soc 152(2):A29510.1149/1.1839531 ↗
34. Gao K, Hu X, Dai C, Yi T (2006) Mater Sci Eng B 131(1–3):10010.1016/j.mseb.2006.03.035 ↗
35. Ding Y, Zhang P, Long Z, Jiang Y, Xu F, Di W (2008) Sci Technol Adv Mater 9(1):01500510.1088/1468-6996/9/1/015005 ↗
36. Alcoutlabi M, Lee H, Watson JV et al (2013) J Mater Sci 48(6):2690. doi: 10.1007/s10853-012-7064-010.1007/s10853-012-7064-0 ↗
37. Choi SW, Kim JR, Ahn YR, Jo SM, Cairns EJ (2006) Chem Mater 19(1):10410.1021/cm060223+ ↗
38. Croce F, Focarete ML, Hassoun J, Meschini I, Scrosati B (2011) Energy Environ Sci 4(3):92110.1039/c0ee00348d ↗
39. Ribeiro C, Sencadas V, Ribelles JLG, Lanceros-Méndez S (2010) Soft Mater 8(3):27410.1080/1539445X.2010.495630 ↗
40. California A, Cardoso VF, Costa CM, Sencadas V, Botelho G, Gómez-Ribelles JL, Lanceros-Mendez S (2011) Eur Polym J 47(12):244210.1016/j.eurpolymj.2011.10.005 ↗
41. Brett AMCFO, Brett CMA (1996) Electroquímica: princípios, métodos e aplicações. Livraria Almedina, Coimbra
42. Raghavan P, Manuel J, Zhao X, Kim D-S, Ahn J-H, Nah C (2011) J Power Sources 196(16):674210.1016/j.jpowsour.2010.10.089 ↗
43. Karabelli D, Leprêtre JC, Alloin F, Sanchez JY (2011) Electrochim Acta 57(1):9810.1016/j.electacta.2011.03.033 ↗
44. Quartarone E, Mustarelli P, Magistris A (2002) J Phys Chem B 106(42):1082810.1021/jp0139843 ↗
45. Sheidaei A, Xiao X, Huang X, Hitt J (2011) J Power Sources 196(20):872810.1016/j.jpowsour.2011.06.026 ↗
46. Kim CS, Oh SM (2001) Electrochim Acta 46(9):132310.1016/S0013-4686(00)00727-1 ↗
47. Krevelen DW, Te Nijenhuis K (2009) Properties of polymers: their correlation with chemical structure; their numerical estimation and prediction from additive group contributions. Elsevier, Amsterdam
48. Chang B-Y, Park S-M (2010) Annu Rev Anal Chem 3(1):20710.1146/annurev.anchem.012809.102211 ↗
49. Cole K (1941) J Chem Phys 9(4):34110.1063/1.1750906 ↗
50. Saunier J, Alloin F, Sanchez JY, Caillon G (2003) J Power Sources 119–121(1–2):45410.1016/S0378-7753(03)00197-6 ↗
51. Rajendran S, Sivakumar P (2008) Physica B 403(4):50910.1016/j.physb.2007.06.012 ↗
52. Gray FM (1997) Polymer electrolytes. Royal Society of Chemistry, Cambridge
53. Aurbach D, Daroux M, Faguy P, Yeager E (1991) J Electroanal Chem 297(1):22510.1016/0022-0728(91)85370-5 ↗
54. Bard AJ, Faulkner LR (2001) Electrochemical methods: fundamentals and applications. Wiley, New York