journal article·2020-10

One-step photodeposition synthesis of TiO2 nanobelts/MoS2 quantum dots/rGO ternary composite with remarkably enhanced photocatalytic activity

Ying Lei, Pengwen Guo, Mengmeng Jia, Wei Wang, Juan Liu, Junyi Zhai

Journal of Materials Science· Volume 55· Issue 30
Publisher page

Abstract

Constructing a composite photocatalyst with distinct structures is an efficient mean to improve the charge transfer/separation ability and increase the active sites of TiO2-based photocatalyst. For the first time, we synthesized a TiO2 nanobelts/MoS2 quantum dots (QDs)/rGO (TiO2/MoS2/rGO) ternary photocatalyst via a facile one-step photodeposition method. TiO2 nanobelts provide photoinduced electrons that facilitate formation and self-assembling of MoS2 QDs and rGO. The TiO2/MoS2/rGO ternary composites present two different structures: One is a composite structure of graphene-wrapped TiO2 nanobelt/MoS2 QDs, and the other is composed of graphene-supported TiO2 nanobelts and MoS2 QDs. Both configurations facilitate the separation of photoinduced electron–hole pairs and charge transfer. The heterostructure of zero-dimensional MoS2 QDs, one-dimensional TiO2 nanobelts, and two-dimensional graphenes endows the photocatalyst with the integrated advantages of these nanomaterials with different dimensions and provides a substantial number of active sites for photocatalytic reactions. The TiO2/MoS2/rGO ternary composites degraded rhodamine B at a rate constant that is 8.72 times faster than that of pristine TiO2 nanobelt. This study presents a facile method to synthesize an inexpensive multi-composite photocatalyst with high efficiency for renewable energy production and environmental treatments.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Advanced Photocatalysis Techniques · 2D Materials and Applications · MXene and MAX Phase Materials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (49)

Show source-provided references
1. Yu H, Shi R, Zhao Y, Waterhouse GI, Wu LZ, Tung CH, Zhang T (2016) Smart utilization of carbon dots in semiconductor photocatalysis. Adv Mater 28:9454–947710.1002/adma.201602581 ↗
2. Xing Z, Zhang J, Cui J, Yin J, Zhao T, Kuang J, Xiu Z, Wan N, Zhou W (2018) Recent advances in floating TiO2-based photocatalysts for environmental application. Appl Catal B Environ 225:452–46710.1016/j.apcatb.2017.12.005 ↗
3. Asahi R, Morikawa T, Irie H, Ohwaki T (2014) Nitrogen-doped titanium dioxide as visible-light-sensitive photocatalyst: designs, developments, and prospects. Chem Rev 114:9824–985210.1021/cr5000738 ↗
4. Lan Y, Lu Y, Ren Z (2013) Mini review on photocatalysis of titanium dioxide nanoparticles and their solar applications. Nano Energy 2:1031–104510.1016/j.nanoen.2013.04.002 ↗
5. Zhang Y, Cui W, An W, Liu L, Liang Y, Zhu Y (2018) Combination of photoelectrocatalysis and adsorption for removal of bisphenol A over TiO2-graphene hydrogel with 3D network structure. Appl Catal B Environ 221:36–4610.1016/j.apcatb.2017.08.076 ↗
6. Zhang D, Lee C, Javed H, Yu P, Kim JH, Alvarez PJJ (2018) Easily recoverable, micrometer-sized TiO2 hierarchical spheres decorated with cyclodextrin for enhanced photocatalytic degradation of organic micropollutants. Environ Sci Technol 52:12402–1241110.1021/acs.est.8b04301 ↗
7. Hu X, Lu S, Tian J, Wei N, Song X, Wang X, Cui H (2019) The selective deposition of MoS2 nanosheets onto (101) facets of TiO2 nanosheets with exposed (001) facets and their enhanced photocatalytic H2 production. Appl Catal B Environ 241:329–33710.1016/j.apcatb.2018.09.051 ↗
8. Xiang Q, Yu J, Jaroniec M (2012) Synergetic effect of MoS2 and graphene as cocatalysts for enhanced photocatalytic H2 production activity of TiO2 nanoparticles. J Am Chem Soc 134:6575–657810.1021/ja302846n ↗
9. Kumar A, Kumar K, Krishnan V (2019) Sunlight driven methanol oxidation by anisotropic plasmonic Au nanostructures supported on amorphous titania: influence of morphology on photocatalytic activity. Mater Lett 245:45–4810.1016/j.matlet.2019.02.091 ↗
10. Kumar A, Sharma V, Kumar S, Kumar A, Krishnan V (2018) Towards utilization of full solar light spectrum using green plasmonic Au–TiOx photocatalyst at ambient conditions. Surf Interfaces 11:98–10610.1016/j.surfin.2018.03.005 ↗
11. Yang G, Chen D, Ding H, Feng J, Zhang JZ, Zhu Y, Hamid S, Bahnemann DW (2017) Well-designed 3D ZnIn2S4 nanosheets/TiO2 nanobelts as direct Z-scheme photocatalysts for CO2 photoreduction into renewable hydrocarbon fuel with high efficiency. Appl Catal B 219:611–61810.1016/j.apcatb.2017.08.016 ↗
12. Liu G, Xie S, Zhang Q, Tian Z, Wang Y (2015) Carbon dioxide-enhanced photosynthesis of methane and hydrogen from carbon dioxide and water over Pt-promoted polyaniline-TiO2 nanocomposites. Chem Commun 51:13654–1365710.1039/C5CC05113D ↗
13. Lu AH, Guo YJ, Liu J, Liu F, Wang CQ, Li N, Li QR (2004) Photocatalytic effect of nature and modified V-bearing rutile. Chin Sci Bull 49:2284–228710.1360/03wd0612 ↗
14. Zhang W, Xiao X, Zeng X, Li Y, Zheng L, Wan C (2016) Enhanced photocatalytic activity of TiO2 nanoparticles using SnS2/RGO hybrid as co-catalyst: DFT study and photocatalytic mechanism. J Alloys Compd 685:774–78310.1016/j.jallcom.2016.06.199 ↗
15. Zhou W, Yin Z, Du Y, Huang X, Zeng Z, Fan Z, Liu H, Wang J, Zhang H (2013) Synthesis of few-layer MoS2 nanosheet-coated TiO2 nanobelt heterostructures for enhanced photocatalytic activities. Small 9:140–14710.1002/smll.201201161 ↗
16. Chen K-N, Sari FNI, Ting J-M (2019) Multifunctional TiO2/polyacrylonitrile nanofibers for high efficiency PM2.5 capture, UV filter, and anti-bacteria activity. Appl Surf Sci 493:157–16410.1016/j.apsusc.2019.07.020 ↗
17. Purbarani ME, Sari FNI, Ting J-M (2019) The role of CoPi and nitrogen doping in enhancing photoelectrochemical hydrogen generation performance of mesoporous TiO2 beads. Surf Coat Technol 378:12507310.1016/j.surfcoat.2019.125073 ↗
18. Huang WC, Ting J-M (2017) Novel nitrogen-doped anatase TiO2 mesoporous bead photocatalysts for enhanced visible light response. Ceram Int 43:9992–999710.1016/j.ceramint.2017.05.012 ↗
19. Altomare M, Nguyen NT, Hejazi S, Schmuki P (2018) A cocatalytic electron-transfer cascade site-selectively placed on TiO2 nanotubes yields enhanced photocatalytic H2 evolution. Adv Funct Mater 28:170425910.1002/adfm.201704259 ↗
20. Quan Q, Xie S, Weng B, Wang Y, Xu YJ (2018) Revealing the double-edged sword role of graphene on boosted charge transfer versus active site control in TiO2 nanotube arrays@RGO/MoS2 heterostructure. Small 14:e170453110.1002/smll.201704531 ↗
21. Sopha H, Tesfaye AT, Zazpe R, Michalicka J, Dvorak F, Hromadko L, Krbal M, Prikryl J, Djenizian T, Macak JM (2019) ALD growth of MoS2 nanosheets on TiO2 nanotube supports. FlatChem 17:10013010.1016/j.flatc.2019.100130 ↗
22. Zhang X, Wang Y, Liu B, Sang Y, Liu H (2017) Heterostructures construction on TiO2 nanobelts: a powerful tool for building high-performance photocatalysts. Appl Catal B Environ 202:620–64110.1016/j.apcatb.2016.09.068 ↗
23. Duan Y, Luo J, Zhou S, Mao X, Shah MW, Wang F, Chen Z, Wang C (2018) TiO2-supported Ag nanoclusters with enhanced visible light activity for the photocatalytic removal of NO. Appl Catal B Environ 234:206–21210.1016/j.apcatb.2018.04.041 ↗
24. Li J-J, Cai S-C, Yu E-Q, Weng B, Chen X, Chen J, Jia H-P, Xu Y-J (2018) Efficient infrared light promoted degradation of volatile organic compounds over photo-thermal responsive Pt–rGO–TiO2 composites. Appl Catal B Environ 233:260–27110.1016/j.apcatb.2018.04.011 ↗
25. Zhang N, Yang MQ, Liu S, Sun Y, Xu YJ (2015) Waltzing with the versatile platform of graphene to synthesize composite photocatalysts. Chem Rev 115:10307–1037710.1021/acs.chemrev.5b00267 ↗
26. Tian H, Liu M, Zheng W (2018) Constructing 2D graphitic carbon nitride nanosheets/layered MoS2/graphene ternary nanojunction with enhanced photocatalytic activity. Appl Catal B Environ 225:468–47610.1016/j.apcatb.2017.12.019 ↗
27. Zhu M, Muhammad Y, Hu P, Wang B, Wu Y, Sun X, Tong Z, Zhao Z (2018) Enhanced interfacial contact of dopamine bridged melamine-graphene/TiO2 nano-capsules for efficient photocatalytic degradation of gaseous formaldehyde. Appl Catal B Environ 232:182–19310.1016/j.apcatb.2018.03.061 ↗
28. Chhabra T, Kumar A, Bahuguna A, Krishnan V (2019) Reduced graphene oxide supported MnO2 nanorods as recyclable and efficient adsorptive photocatalysts for pollutants removal. Vacuum 160:333–34610.1016/j.vacuum.2018.11.053 ↗
29. Tan LK, Liu B, Teng JH, Guo S, Low HY, Loh KP (2014) Atomic layer deposition of a MoS2 film. Nanoscale 6:10584–1058810.1039/C4NR02451F ↗
30. Motola M, Baudys M, Zazpe R, Krbal M, Michalička J, Rodriguez-Pereira J, Pavliňák D, Přikryl J, Hromádko L, Sopha H, Krýsa J, Macak JM (2019) 2D MoS2 nanosheets on 1D anodic TiO2 nanotube layers: an efficient co-catalyst for liquid and gas phase photocatalysis. Nanoscale 11:23126–2313110.1039/C9NR08753B ↗
31. Yuan Y-J, Ye Z-J, Lu H-W, Hu B, Li Y-H, Chen D-Q, Zhong J-S, Yu Z-T, Zou Z-G (2015) Constructing anatase TiO2 nanosheets with exposed (001) facets/layered MoS2 two-dimensional nanojunctions for enhanced solar hydrogen generation. ACS Catal 6:532–54110.1021/acscatal.5b02036 ↗
32. Liu H, Lv T, Zhu C, Su X, Zhu Z (2015) Efficient synthesis of MoS2 nanoparticles modified TiO2 nanobelts with enhanced visible-light-driven photocatalytic activity. J Mol Catal A Chem 396:136–14210.1016/j.molcata.2014.10.002 ↗
33. Alido JPM, Sari FNI, Ting J-M (2019) Synthesis of Ag/hybridized 1T–2H MoS2/TiO2 heterostructure for enhanced visible-light photocatalytic activity. Ceram Int 45:23651–2365710.1016/j.ceramint.2019.08.077 ↗
34. Islam SE, Hang DR, Chen CH, Sharma KH (2018) Facile and cost-efficient synthesis of quasi-0D/2D ZnO/MoS2 nanocomposites for highly enhanced visible-light-driven photocatalytic degradation of organic pollutants and antibiotics. Chemistry 24:9305–931510.1002/chem.201801397 ↗
35. Shi X, Fujitsuka M, Kim S, Majima T (2018) Faster electron injection and more active sites for efficient photocatalytic H2 evolution in g-C3N4/MoS2 hybrid. Small 14:170327710.1002/smll.201703277 ↗
36. Bian H, Ji Y, Yan J, Li P, Li L, Li Y, Liu S (2018) In situ synthesis of few-layered g-C3N4 with vertically aligned MoS2 loading for boosting solar-to-hydrogen generation. Small 14:170300310.1002/smll.201703003 ↗
37. Hui Z, Dong Y, Jiang P, Miao H, Wang GL, Zhang J (2015) In situ light-assisted preparation of MoS2 on graphitic C3N4 nanosheet for enhanced photocatalytic H2 production from water. J Mater Chem A 3:7375–738110.1039/C5TA00402K ↗
38. Shi L, He Z, Liu S (2018) MoS2 quantum dots embedded in g-C3N4 frameworks: a hybrid 0D–2D heterojunction as an efficient visible-light driven photocatalyst. Appl Surf Sci 457:30–4010.1016/j.apsusc.2018.06.132 ↗
39. Mei W, Chen C, Chen X, Liu X, Yang Z, Ding F, Chao Z, Liu T (2018) Low-temperature construction of MoS2 quantum dots/ZnO spheres and their photocatalytic activity under natural sunlight. J Colloid Interface Sci 530:714–72410.1016/j.jcis.2018.07.015 ↗
40. Wu D, Chen J, Ruan Y, Sun K, Zhang K, Xie W, Xie F, Zhao X, Wang X (2018) A novel sensitive and stable surface enhanced Raman scattering substrate based on a MoS2 quantum dot/reduced graphene oxide hybrid system. J Mater Chem C 6:12547–1255410.1039/C8TC05151H ↗
41. Saha A, Sinhamahapatra A, Kang TH, Ghosh SC, Yu JS, Panda AB (2017) Hydrogenated MoS2 QD-TiO2 heterojunction mediated efficient solar hydrogen production. Nanoscale 9:17029–1703610.1039/C7NR06526D ↗
42. Guo SN, Min YL, Fan JC, Xu QJ (2016) Stabilizing and improving solar H2 generation from Zn0.5Cd0.5S nanorods@MoS2/RGO hybrids via dual charge transfer pathway. ACS Appl Mater Interfaces 8:2928–293410.1021/acsami.5b06009 ↗
43. Xiang Q, Yu J, Jaroniec M (2011) Enhanced photocatalytic H2-production activity of graphene-modified titania nanosheets. Nanoscale 3:3670–367810.1039/c1nr10610d ↗
44. Wang C, Sun L, Zhang F, Wang X, Sun Q, Cheng Y, Wang L (2017) Formation of Mo–polydopamine hollow spheres and their conversions to MoO2/C and Mo2C/C for efficient electrochemical energy storage and catalyst. Small 13:170124610.1002/smll.201701246 ↗
45. Lv N, Li Y, Huang Z, Li T, Ye S, Dionysiou DD, Song X (2019) Synthesis of GO/TiO2/Bi2WO6 nanocomposites with enhanced visible light photocatalytic degradation of ethylene. Appl Catal B Environ 246:303–31110.1016/j.apcatb.2019.01.068 ↗
46. Kumar A, Reddy KL, Kumar S, Kumar A, Sharma V, Krishnan V (2018) Rational design and development of lanthanide-doped NaYF4@CdS–Au–RGO as quaternary plasmonic photocatalysts for harnessing visible–near-infrared broadband spectrum. ACS Appl Mater Interfaces 10:15565–1558110.1021/acsami.7b17822 ↗
47. Veeramalai CP, Li F, Guo T, Kim TW (2019) Highly flexible memristive devices based on MoS2 quantum dots sandwiched between PMSSQ layers. Dalton Trans 48:2422–242910.1039/C8DT04593C ↗
48. Yin W, Bai X, Zhang X, Zhang J, Gao X, Yu WW (2019) Multicolor light-emitting diodes with MoS2 quantum dots. Part Part Syst Char 36:180036210.1002/ppsc.201800362 ↗
49. Pu SY, Zhu RX, Ma H, Deng DL, Pei XJ, Qi F, Chu W (2017) Facile in-situ design strategy to disperse TiO2 nanoparticles on graphene for the enhanced photocatalytic degradation of rhodamine 6G. Appl Catal B 218:208–21910.1016/j.apcatb.2017.06.039 ↗