MOF-templated thermolysis for porous CuO/Cu2O@CeO2 anode material of lithium-ion batteries with high rate performance
Source abstract
Abstract
Novel porous CuO/Cu2O@CeO2 anode has been successfully synthesized from a Cu-based metal–organic framework (Cu-MOF) via a simple two-step pyrolysis method. The CeO2 protective layer greatly improves the electronic conductivity, can buffer the volume change and can provide pathways for electron transport and Li+ diffusion. The results demonstrate that the electrochemical performance of CuO/Cu2O anode can be significantly improved by the design. The CuO/Cu2O@CeO2 electrode delivers a large specific capacity of 473 mAh g−1 at 0.3 A g−1, and exhibits excellent rate capacity with 250 mAh g−1 at 2 A g−1 and good cyclic performance with a capacity of 592.3 mAh g−1 after 100 cycles at 0.2 A g−1.
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Research context
OpenAlex topics: Advancements in Battery Materials · Advanced Battery Materials and Technologies · Supercapacitor Materials and Fabrication
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