journal article·2011-11

Use of single wall carbon nanohorns in polymeric electrolyte fuel cells

Lúcia Brandão, Carolina Passeira, Daniele Mirabile Gattia, Adélio Mendes

Journal of Materials Science· Volume 46· Issue 22
Publisher page

Abstract

Single wall carbon nanohorns (SWNH), produced by AC arc discharge in air, were used as Pt and PtRu supports in polymer electrolyte membrane fuel cells (PEMFC). These electrocatalysts were compared with equivalent electrocatalysts supported on commercial carbon back. The SWNH were characterized by differential thermal analysis (DTA), TEM, SEM, and XRD. The produced SWNH were 84.5 wt% pure, containing 3 wt% of amorphous carbon and 12.5 wt% of graphitic carbon. SWNH were used as electrocatalyst supports and tested in the electrodes of two types of polymer electrolyte fuel cells: H2-fed PEMFC and direct methanol fuel cells (DMFC). The electrocatalyst nanoparticles anchored on both carbon supports were ca. 2.5 nm in diameter obtained by employing ethylene glycol as the reducing agent. The use of SWNH showed catalytic activities 60% higher than using carbon black as the electrocatalyst support in both types of fuel cells.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Fuel Cells and Related Materials · Electrocatalysts for Energy Conversion · Conducting polymers and applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (44)

Show source-provided references
1. Antolini E (2009) Appl Catal B 88:110.1016/j.apcatb.2008.09.030 ↗
2. Ocampo AL, Miranda-Hernandez M, Morgado J, Montoya JA, Sebastian PJ (2006) J Power Sources 160:91510.1016/j.jpowsour.2006.02.056 ↗
3. Li WZ, Wang X, Chen ZW, Waje M, Yan YS (2006) J Phys Chem B 110:1535310.1021/jp0623443 ↗
4. Sano N, Kimura Y, Suzuki T (2008) J Mater Chem 18:155510.1039/b717302d ↗
5. Brandão L, Mirabile Gattia D, Marazzi R, Vittori Antisari M, Licoccia S, Epifanio A, Traversa E, Mendes A (2010) Mater Sci Forum 638–642:110610.4028/www.scientific.net/MSF.638-642.1106 ↗
6. Mirabile Gattia D, Vittori Antisari M, Giorgi L, Marazzi R, Piscopiello E, Montone A, Bellitto S, Licoccia S, Traversa E (2009) J Power Sources 194:24310.1016/j.jpowsour.2009.04.058 ↗
7. Yoo E, Okata T, Akita T, Kohyama M, Nakamura J, Honma I (2009) Nano Lett 9:225510.1021/nl900397t ↗
8. Zhang MF, Yamaguchi T, Iijima S, Yudasaka M (2009) J Phys Chem C 113:1118410.1021/jp9037705 ↗
9. Mirabile Gattia D, Vittori Antisari M, Marazzi R (2007) Nanotechnology 18:7
10. Azami T, Kasuya D, Yuge R, Yudasaka M, Iijima S, Yoshitake T, Kubo Y (2008) J Phys Chem C 112:133010.1021/jp076365o ↗
11. Wang H, Chhowalla M, Sano N, Jia S, Amaratunga GAJ (2004) Nanotechnology 15:54610.1088/0957-4484/15/5/024 ↗
12. Sano N, Yasumura Y, Kimura Y, Toyoda A, Hirano K (2008) Trans Mat Res Soc Jap 33:66910.14723/tmrsj.33.669 ↗
13. Iijima S, Yudasaka M, Komi F, Takahashi K, James Adelene N (2005) Material for adsorbing gases, organic material, complex and bio related substance, comprises mono layer carbon nanohorn aggregate formed by aggregating mono layer carbon nanohorns in ball shape, JP2005021892-A
14. Kurungot S, Kurungott S (2007) Electrode catalyst for a solid polymer fuel cell, comprises a carbon nanohorn aggregate as a support, a catalytic metal supported on the carbon nanohorn aggregate support, and a polyelectrolyte applied to the aggregate support, WO2007105576-A2
15. Utsumi S, Honda H, Hattori Y, Kanoh H, Takahashi K, Sakai H, Abe M, Yudasaka M, Iijima S, Kaneko K (2007) J Phys Chem C 111:557210.1021/jp071273k ↗
16. Urita K, Seki S, Utsumi S, Noguchi D, Kanoh H, Tanaka H, Hattori Y, Ochiai Y, Aoki N, Yudasaka M, Iijima S, Kaneko K (2006) Nano Lett 6:132510.1021/nl060120q ↗
17. Yuge R, Ichihashi T, Miyawaki J, Yoshitake T, Iijima S, Yudasaka M (2009) J Phys Chem C 113:274110.1021/jp810121a ↗
18. Utsumi S, Miyawaki J, Tanaka H, Hattori Y, Itoi T, Ichikuni N, Kanoh H, Yudasaka M, Iijima S, Kaneko K (2005) J Phys Chem B 109:1431910.1021/jp0512661 ↗
19. Fan J, Yudasaka M, Miyawaki J, Ajima K, Murata K, Iijima S (2006) J Phys Chem B 110:158710.1021/jp0538870 ↗
20. Fan J, Yudasaka M, Kasuya D, Azami T, Yuge R, Imai H, Kubo Y, Iijima S (2005) J Phys Chem B 109:1075610.1021/jp050548y ↗
21. Azami T, Kasuya D, Yoshitake T, Kubo Y, Yudasaka M, Ichihashi T, Iijima S (2007) Carbon 45:136410.1016/j.carbon.2007.02.031 ↗
22. Whitney J, Sarkar S, Zhang JF, Shu CY, Dorn H, Rylander C, Campbell T, Geohegan D, Rylander MN (2009) In: 29th annual conference of the American-Society-for-Laser-Medicine and Surgery. Lasers in Surgery and Medicine, National Harbor, MD, p 3-3
23. Zhang M, Murakami T, Ajima K, Tsuchida K, Sandanayaka ASD, Ito O, Iijima S, Yudasaka M (2008) Proc Natl Acad Sci USA 105:1477310.1073/pnas.0801349105 ↗
24. Murakami T, Sawada H, Tamura G, Yudasaka M, Iijima S, Tsucbida K (2008) Nanomed 3:45310.2217/17435889.3.4.453 ↗
25. Sano N, Ohtsuki F (2007) J Electrostat 65:26310.1016/j.elstat.2006.09.002 ↗
26. Sano N, Kinugasa M, Otsuki F, Suehiro J (2007) Adv Powder Tech 18:45510.1163/156855207781389447 ↗
27. Suehiro J, Sano N, Zhou GB, Imakiire H, Imasaka K, Hara M (2006) J Electrostat 64:40810.1016/j.elstat.2005.11.001 ↗
28. Shi LH, Liu XQ, Niu WX, Li HJ, Han S, Chen J, Xu GB (2009) Biosens Bioelect 24:115910.1016/j.bios.2008.07.001 ↗
29. Sandanayaka ASD, Ito O, Zhang MF, Ajima K, Iijima S, Yudasaka M, Murakami T, Tsuchida K (2009) Adv Mat 21:436610.1002/adma.200901256 ↗
30. Liu XQ, Shi LH, Niu WX, Li HJ, Xu GB (2008) Biosens Bioelectron 23:188710.1016/j.bios.2008.02.016 ↗
31. Battiston S, Bolzan M, Fiameni S, Gerbasi R, Meneghetti M, Miorin E, Mortalo C, Pagura C (2009) Carbon 47:132110.1016/j.carbon.2009.01.016 ↗
32. Lacotte S, Garcia A, Decossas M, Al-Jamal WT, Li S, Kostarelos K, Muller S, Prato M, Dumortier H, Bianco A (2008) Adv Mat 20:242110.1002/adma.200702753 ↗
33. Ajima K, Murakami T, Mizoguchi Y, Tsuchida K, Ichihashi T, Iijima S, Yudasaka M (2008) ACS Nano 2:205710.1021/nn800395t ↗
34. Sahaym U, Norton MG (2008) J Mater Sci 43:5395. doi:https://doi.org/10.1007/s10853-008-2749-010.1007/s10853-008-2749-0 ↗
35. Huang Z, Liu XH, Li KX, Li DM, Luo YH, Li H, Song WB, Chen LQ, Meng QB (2007) Electrochem Commun 9:59610.1016/j.elecom.2006.10.028 ↗
36. Kosaka M, Kuroshima S, Yudasaka M, Yuge R (2009) Processing of carbon-nanohorn aggregate used for fuel-cell catalysts, involves opening hole which does not allow substance with diameter more than preset value to pass through, by heating aggregate in hydrogen-peroxide solution, JP2009190928-A
37. Yoshitake T, Shimakawa Y, Kuroshima S, Kimura H, Ichihashi T, Kubo Y, Kasuya D, Takahashi K, Kokai F, Yudasaka M, Iijima S (2002) Physica B 323:12410.1016/S0921-4526(02)00871-2 ↗
38. Kosaka M, Kuroshima S, Kobayashi K, Sekino S, Ichihashi T, Nakamura S, Yoshitake T, Kubo Y (2009) J Phys Chem C 113:866010.1021/jp8105293 ↗
39. Mirabile Gattia D, Vittori Antisari M, Marazzi R, Piscopiello E, Montone A (2008) In: Bandaru PR, Grego S, Kinloch I (eds) Symposium on nanotubes, nanowires, nanobelts and nanocoils held at the 2008 MRS fall meeting. Boston, MA, pp 49–54
40. Kasuya D, Yudasaka M, Takahashi K, Kokai F, Iijima S (2002) J Phys Chem B 106:494710.1021/jp020387n ↗
41. Bandow S, Kokai F, Takahashi K, Yudasaka M, Qin LC, Iijima S (2000) Chem Phys Lett 321:51410.1016/S0009-2614(00)00353-5 ↗
42. Garbarino S, Pereira A, Hamel C, Irissou E, Chaker M, Guay D (2010) J Phys Chem C 114:298010.1021/jp908724k ↗
43. Murata K, Kaneko K, Kokai F, Takahashi K, Yudasaka M, Iijima S (2000) Chem Phys Lett 331:1410.1016/S0009-2614(00)01152-0 ↗
44. Bekyarova E, Kaneko K, Yudasaka M, Kasuya D, Iijima S, Huidobro A, Rodriguez-Reinoso F (2003) J Phys Chem B 107:447910.1021/jp026737n ↗