H3PW12O40-doped pyromellitic diimide prepared via thermal transformation as an efficient visible-light photocatalyst
Source abstract
Abstract
We prepared the H3PW12O40-doped pyromellitic diimide (PMDI) photocatalysts via thermal transformation using urea phosphotungstate and pyromellitic dianhydride as precursors (UPWPI) and calcination of PMDI with phosphotungstic acid directly (UPIPW). The influences of the strategies on the morphology, light absorption, and visible-light photocatalytic degradation efficiency of H3PW12O40-doped PMDI are systematically investigated by various characterization methods. By comparing the structure of UPWPI and UPIPW, the adoption of urea phosphotungstate as precursors can promote the separation of PMDI into small particles and the inclusion of phosphotungstic acid. Moreover, the visible-light (λ > 420 nm) absorption efficiency of UPWPI is also enhanced compared with that of UPIPW because of the improved photogenerated electron transfer efficiency between PMDI and HPW. With a catalyst dosage of 100 mg and the degradation time of 3 h, the photocatalytic degradation efficiency of imidacloprid on UPWPI was 97.12% and the degradation rate constant was 0.93 h−1.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Polyoxometalates: Synthesis and Applications · Advanced Photocatalysis Techniques · Sulfur-Based Synthesis Techniques
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (36)
Show source-provided references
1. Zhang N, Li X, Ye H, Chen S, Ju H, Liu D, Lin Y, Ye W, Wang C, Xu Q, Zhu J, Song L, Jiang J, Xiong Y (2016) Oxide defect engineering enables to couple solar energy into oxygen activation. J Am Chem Soc 138:8928–8935. https://doi.org/10.1021/jacs.6b0462910.1021/jacs.6b04629 ↗
2. Jia G, Wang Y, Cui X, Yang Z, Liu L, Zhang H, Wu Q, Zheng L, Zheng W (2019) Asymmetric embedded benzene ring enhances charge transfer of carbon nitride for photocatalytic hydrogen generation. Appl Catal B Environ 258:117959. https://doi.org/10.1016/j.apcatb.2019.11795910.1016/j.apcatb.2019.117959 ↗
3. Zhou C, Zeng Z, Zeng G, Huang D, Xiao R, Cheng M, Zhang C, Xiong W, Lai C, Yang Y, Wang W, Yi H, Li B (2019) Visible-light-driven photocatalytic degradation of sulfamethazine by surface engineering of carbon nitride: properties, degradation pathway and mechanisms. J Hazard Mater 380:120815. https://doi.org/10.1016/j.jhazmat.2019.12081510.1016/j.jhazmat.2019.120815 ↗
4. Zhang Z, Zhao W, Ma B, Ding Y (2010) The epoxidation of olefins catalyzed by a new heterogeneous polyoxometalate-based catalyst with hydrogen peroxide. Catal Commun 12:318–322. https://doi.org/10.1016/j.catcom.2010.09.02610.1016/j.catcom.2010.09.026 ↗
5. Yue Z-C, Shen L-X, Wu H-H, Li X-H, Niu Y-Y (2013) pH-dependent assembly of metal–organic hybrid compounds based on octamolybdates and a new flexible multidentate ligand. CrystEngComm 15:9938–9948. https://doi.org/10.1039/c3ce41223g10.1039/c3ce41223g ↗
6. Tan C, Feng R (2017) Self-assembly morphology and packing structures depend on the ‘head’ of organic cations anchored on polyoxometalate anions in hybrids. Supramol Chem 29:634–642. https://doi.org/10.1080/10610278.2017.130145110.1080/10610278.2017.1301451 ↗
7. Cai Z-X, Song X-H, Chen Y-Y, Wang Y-R, Chen X (2016) 3D nitrogen-doped graphene aerogel: a low-cost, facile prepared direct electrode for H2O2 sensing. Sens Actuators B Chem 222:567–573. https://doi.org/10.1016/j.snb.2015.08.09410.1016/j.snb.2015.08.094 ↗
8. Ran J, Ma TY, Gao G, Du X-W, Qiao SZ (2015) Porous P-doped graphitic carbon nitride nanosheets for synergistically enhanced visible-light photocatalytic H2 production. Energy Environ Sci 8:3708–3717. https://doi.org/10.1039/c5ee02650d10.1039/c5ee02650d ↗
9. Kofuji Y, Ohkita S, Shiraishi Y, Sakamoto H, Tanaka S, Ichikawa S, Hirai T (2016) Graphitic carbon nitride doped with biphenyl diimide: efficient photocatalyst for hydrogen peroxide production from water and molecular oxygen by sunlight. ACS Catal 6:7021–7029. https://doi.org/10.1021/acscatal.6b0236710.1021/acscatal.6b02367 ↗
10. Weon S, Choi W (2016) TiO2 nanotubes with open channels as deactivation-resistant photocatalyst for the degradation of volatile organic compounds. Environ Sci Technol 50:2556–2563. https://doi.org/10.1021/acs.est.5b0541810.1021/acs.est.5b05418 ↗
11. Rengifo-Herrera JA, Blanco M, Wist J, Florian P, Pizzio LR (2016) TiO2 modified with polyoxotungstates should induce visible-light absorption and high photocatalytic activity through the formation of surface complexes. Appl Catal B Environ 189:99–109. https://doi.org/10.1016/j.apcatb.2016.02.03310.1016/j.apcatb.2016.02.033 ↗
12. Larumbe S, Monge M, Gómez-Polo C (2015) Comparative study of (N, Fe) doped TiO2 photocatalysts. Appl Surf Sci 327:490–497. https://doi.org/10.1016/j.apsusc.2014.11.13710.1016/j.apsusc.2014.11.137 ↗
13. Li K, Yan L, Zeng Z, Luo S, Luo X, Liu X, Guo H, Guo Y (2014) Fabrication of H3PW12O40-doped carbon nitride nanotubes by one-step hydrothermal treatment strategy and their efficient visible-light photocatalytic activity toward representative aqueous persistent organic pollutants degradation. Appl Catal B Environ 156–157:141–152. https://doi.org/10.1016/j.apcatb.2014.03.01010.1016/j.apcatb.2014.03.010 ↗
14. Meng J, Wang X, Yang X, Hu A, Guo Y, Yang Y (2019) Enhanced gas-phase photocatalytic removal of aromatics over direct Z-scheme-dictated H3PW12O40/g-C3N4 film-coated optical fibers. Appl Catal B Environ 251:168–180. https://doi.org/10.1016/j.apcatb.2019.03.06310.1016/j.apcatb.2019.03.063 ↗
15. Zhang Y, Zheng D, Chen SG (2017) Synthesis and photocatalytic properties of H3PW12O40/TiO2 composite nanotubes. J Nanosci Nanotechnol 17:6967–6969. https://doi.org/10.1166/jnn.2017.1452110.1166/jnn.2017.14521 ↗
16. Tan C (2017) Self-assembly and morphology change of four organic-polyoxometalate hybrids with different solid structures from 2D lamellar to 3D hexagonal forms. J Mol Struct 1130:276–283. https://doi.org/10.1016/j.molstruc.2016.10.02810.1016/j.molstruc.2016.10.028 ↗
17. Li J, Zhang C, Jiang P, Leng Y (2017) Cross-linked chitosan supporting polyoxometalates catalyst with adjustable redox property for H2O2-based oxidation reactions. Catal Commun 94:13–17. https://doi.org/10.1016/j.catcom.2017.01.02810.1016/j.catcom.2017.01.028 ↗
18. Meng P, Huang J, Liu X (2019) In-situ solid phase thermal transformation of self-assembled melamine phosphotungstates produce efficient visible light photocatalysts. J Colloid Interface Sci 551:208–218. https://doi.org/10.1016/j.jcis.2019.05.00510.1016/j.jcis.2019.05.005 ↗
19. Darwish WM, Darwish AM, Al-Ashkar EA (2016) Indium(III) phthalocyanine eka-conjugated polymer as high-performance optical limiter upon nanosecond laser irradiation. High Perform Polym 28:651–659. https://doi.org/10.1177/095400831559361610.1177/0954008315593616 ↗
20. Kacprzak K (2003) Rapid and convenient microwave-assisted synthesis of aromatic imides and N-Hydroxymethylimides. Synth Commun 33:1499–1507. https://doi.org/10.1081/scc-12001876810.1081/scc-120018768 ↗
21. Liao X, Huang Y, Zhou Y, Liu H, Cai Y, Lu S, Yao Y (2019) Homogeneously dispersed HPW/graphene for high efficient catalytic oxidative desulfurization prepared by electrochemical deposition. Appl Surf Sci 484:917–924. https://doi.org/10.1016/j.apsusc.2019.04.15610.1016/j.apsusc.2019.04.156 ↗
22. Tian M (2015) The preparation and characterization of AM/2-EHA copolymer as profile control agent. Adv Mater Res 1083:15–20. https://doi.org/10.4028/www.scientific.net/AMR.1083.1510.4028/www.scientific.net/AMR.1083.15 ↗
23. Nakanishi F, Hasegawa M, Takahashi H (1973) Aliphatic poly(amido acids) and polyimides with cyclobutane ring in the main chain. Polymer 14:440–444. https://doi.org/10.1016/0032-3861(73)90010-410.1016/0032-3861(73)90010-4 ↗
24. Avramidou KV, Zaccheria F, Karakoulia SA, Triantafyllidis KS, Ravasio N (2017) Esterification of free fatty acids using acidic metal oxides and supported polyoxometalate (POM) catalysts. Mol Catal 439:60–71. https://doi.org/10.1016/j.mcat.2017.06.00910.1016/j.mcat.2017.06.009 ↗
25. Xiong Z, Wang Z, Muthu M, Zhang Y (2019) Construction of an in-situ Fenton-like system based on a g-C3N4 composite photocatalyst. J Hazard Mater 373:565–571. https://doi.org/10.1016/j.jhazmat.2019.03.11410.1016/j.jhazmat.2019.03.114 ↗
26. Li Y, Fang Y, Cao Z, Li N, Chen D, Xu Q, Lu J (2019) Construction of g-C3N4/PDI@MOF heterojunctions for the highly efficient visible light-driven degradation of pharmaceutical and phenolic micropollutants. Appl Catal B Environ 250:150–162. https://doi.org/10.1016/j.apcatb.2019.03.02410.1016/j.apcatb.2019.03.024 ↗
27. Maciá-Agulló JA, Cazorla-Amorós D, Linares-Solano A, Wild U, Su DS, Schlögl R (2005) Oxygen functional groups involved in the styrene production reaction detected by quasi in situ XPS. Catal Today 102–103:248–253. https://doi.org/10.1016/j.cattod.2005.02.02310.1016/j.cattod.2005.02.023 ↗
28. Li J, Luo L, Tan W, Wang H, Yang M, Jiang F, Yang W (2019) The comparative study of two reusable phosphotungstic acid salts/reduced graphene oxides composites with enhanced photocatalytic activity. Environ Sci Pollut Res Int 26:34248–34260. https://doi.org/10.1007/s11356-018-4047-y10.1007/s11356-018-4047-y ↗
29. Ilbeygi H, Kim IY, Kim MG, Cha W, Kumar PSM, Park DH, Vinu A (2019) Highly crystalline mesoporous phosphotungstic acid: a high-performance electrode material for energy-storage applications. Angew Chem Int Ed Engl 58:10849–10854. https://doi.org/10.1002/anie.20190122410.1002/anie.201901224 ↗
30. Wang J-F, Shi T-F, Zhuang Z-T, Gao Q-Q, Zhang Y-M (2018) Effect of the itinerant electron density on the magnetization and Curie temperature of Sr2FeMoO6 ceramics. RSC Adv 8:29071–29077. https://doi.org/10.1039/c8ra05755a10.1039/c8ra05755a ↗
31. Meng P, Huang J, Liu X (2019) Extended light absorption and enhanced visible-light photocatalytic degradation capacity of phosphotungstate/polyimide photocatalyst based on intense interfacial interaction and alternate stacking structure. Appl Surf Sci 465:125–135. https://doi.org/10.1016/j.apsusc.2018.09.14110.1016/j.apsusc.2018.09.141 ↗
32. Panneri S, Thomas M, Ganguly P, Nair BN, Mohamed AP, Warrier KGK, Hareesh US (2017) C3N4 anchored ZIF 8 composites: photo-regenerable, high capacity sorbents as adsorptive photocatalysts for the effective removal of tetracycline from water. Catal Sci Technol 7:2118–2128. https://doi.org/10.1039/C7CY00348J10.1039/C7CY00348J ↗
33. Liu X, Xu J, Ni Z, Wang R, You J, Guo R (2019) Adsorption and visible-light-driven photocatalytic properties of Ag3PO4/WO3 composites: a discussion of the mechanism. Chem Eng J 356:22–33. https://doi.org/10.1016/j.cej.2018.09.00110.1016/j.cej.2018.09.001 ↗
34. Di J, Xia J, Li X, Ji M, Xu H, Chen Z, Li H (2016) Constructing confined surface carbon defects in ultrathin graphitic carbon nitride for photocatalytic free radical manipulation. Carbon 107:1–10. https://doi.org/10.1016/j.carbon.2016.05.02810.1016/j.carbon.2016.05.028 ↗
35. Li Y, Jin R, Li G, Liu X, Yu M, Xing Y, Shi Z (2018) Preparation of phenyl group functionalized g-C3N4 nanosheets with extended electron delocalization for enhanced visible-light photocatalytic activity. New J Chem 42:6756–6762. https://doi.org/10.1039/C8NJ00298C10.1039/C8NJ00298C ↗
36. Wang SS, Yang GY (2015) Recent advances in polyoxometalate-catalyzed reactions. Chem Rev 115:4893–4962. https://doi.org/10.1021/cr500390v10.1021/cr500390v ↗