Reduced graphene oxide enhanced magnetic nanocomposites for removal of carbamazepine
Source abstract
Abstract
Ferrite, as a kind of common magnetic adsorbent, always tend to reuniting and lead to the poor performance for removing contaminant in aqueous. Meanwhile, reduced graphene oxide (rGO), a high-efficiency adsorbent used for water treatment, is hydrophobic and easy to stack because of the Van der Waals force, resulting in the low adsorption capacity. Herein, we prepare the magnetic CoFe2O4/rGO nanocomposites to solve the reuniting of CoFe2O4 and stacking of rGO simultaneously. The rGO nanosheets can improve the dispersion of CoFe2O4 nanoparticles. As sorbent, the adsorption behaviors of carbamazepine on the nanocomposites can be fitted well by the Langmuir and pseudo-second-order kinetic models. In addition, the CoFe2O4/rGO nanocomposites show enhanced adsorption performance than that of the pure CoFe2O4 nanoparticles, and the loading of rGO can affect their adsorption performance. The adsorption of carbamazepine on CoFe2O4/rGO is exothermic and mainly controlled by π–π interaction and hydrogen bond interaction. Furthermore, the CoFe2O4/rGO can be used to remove other organic pollutants simultaneously. Finally, the nanocomposites can be collected by external magnet, and the regenerated nanocomposites still showed a high adsorption capacity retention (90%) after five cycles.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Graphene and Nanomaterials Applications · Nanomaterials for catalytic reactions · Pharmacological Effects and Toxicity Studies
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (47)
Show source-provided references
1. Yi X, Tran NH, Yin T, He Y, Gin KY (2017) Removal of selected PPCPs, EDCs, and antibiotic resistance genes in landfill leachate by a full-scale constructed wetlands system. Water Res 121:46–6010.1016/j.watres.2017.05.008 ↗
2. Archer E, Petrie B, Kasprzyk-Hordern B, Wolfaardt GM (2017) The fate of pharmaceuticals and personal care products (PPCPs), endocrine disrupting contaminants (EDCs), metabolites and illicit drugs in a WWTW and environmental waters. Chemosphere 174:437–44610.1016/j.chemosphere.2017.01.101 ↗
3. Hahn J, Szoboszlay S, Krifaton C, Kovacs KJ, Ferenczi S, Kriszt B (2016) Development of a combined method to assess the complex effect of atrazine on sex steroid synthesis in H295R cells. Chemosphere 154:507–51410.1016/j.chemosphere.2016.03.119 ↗
4. Kim Y, Joo H, Her N, Yoon Y, Sohn J, Kim S, Yoon J (2015) Simultaneously photocatalytic treatment of hexavalent chromium (Cr(VI)) and endocrine disrupting compounds (EDCs) using rotating reactor under solar irradiation. J Hazard Mater 288:124–13310.1016/j.jhazmat.2015.02.021 ↗
5. Sakkas VA, Islam MA, Stalikas C, Albanis TA (2010) Photocatalytic degradation using design of experiments: a review and example of the Congo red degradation. J Hazard Mater 175:33–4410.1016/j.jhazmat.2009.10.050 ↗
6. Braun JM (2017) Early-life exposure to EDCs: role in childhood obesity and neurodevelopment. Nat Rev Endocrinol 13:161–17310.1038/nrendo.2016.186 ↗
7. Guo R, Du Y, Zheng F, Wang J, Wang Z, Ji R, Chen J (2017) Bioaccumulation and elimination of bisphenol A (BPA) in the alga Chlorella pyrenoidosa and the potential for trophic transfer to the rotifer Brachionus calyciflorus. Environ Pollut 227:460–46710.1016/j.envpol.2017.05.010 ↗
8. Teng M, Qi S, Zhu W, Wang Y, Wang D, Dong K, Wang C (2018) Effects of the bioconcentration and parental transfer of environmentally relevant concentrations of difenoconazole on endocrine disruption in zebrafish (Danio rerio). Environ Pollut 233:208–21710.1016/j.envpol.2017.10.063 ↗
9. Tan W, Xi B, Wang G, Jiang J, He X, Mao X, Gao R, Huang C, Zhang H, Li D, Jia Y, Yuan Y, Zhao X (2017) Increased electron-accepting and decreased electron-donating capacities of soil humic substances in response to increasing temperature. Environ Sci Technol 51:3176–318610.1021/acs.est.6b04131 ↗
10. Zhang S, Gitungo SW, Axe L, Raczko RF, Dyksen JE (2017) Biologically active filters—an advanced water treatment process for contaminants of emerging concern. Water Res 114:31–4110.1016/j.watres.2017.02.014 ↗
11. Miralles-Cuevas S, Oller I, Aguera A, Llorca M, Sanchez Perez JA, Malato S (2017) Combination of nanofiltration and ozonation for the remediation of real municipal wastewater effluents: acute and chronic toxicity assessment. J Hazard Mater 323:442–45110.1016/j.jhazmat.2016.03.013 ↗
12. Bakr AR, Rahaman MS (2017) Removal of bisphenol A by electrochemical carbon-nanotube filter: influential factors and degradation pathway. Chemosphere 185:879–88710.1016/j.chemosphere.2017.07.082 ↗
13. Li C, Dong F, Crittenden JC, Luo F, Chen X, Zhao T (2017) Kinetics and mechanism of 17beta-estradiol chlorination in a pilot-scale water distribution systems. Chemosphere 178:73–7910.1016/j.chemosphere.2017.03.039 ↗
14. Velo-Gala I, Pirán-Montaño JA, Rivera-Utrilla J, Sánchez-Polo M, Mota AJ (2017) Advanced Oxidation Processes based on the use of UVC and simulated solar radiation to remove the antibiotic tinidazole from water. Chem Eng J 323:605–61710.1016/j.cej.2017.04.102 ↗
15. Xiao P, Wang P, Li H, Li Q, Shi Y, Wu XL, Lin H, Chen J, Wang X (2018) New insights into bisphenols removal by nitrogen-rich nanocarbons: synergistic effect between adsorption and oxidative degradation. J Hazard Mater 345:123–13010.1016/j.jhazmat.2017.11.001 ↗
16. Capar G, Yetis U, Yilmaz L (2007) The most effective pre-treatment to nanofiltration for the recovery of print dyeing wastewaters. Desalination 212:103–11310.1016/j.desal.2006.09.020 ↗
17. Nistico R, Celi LR, Bianco Prevot A, Carlos L, Magnacca G, Zanzo E, Martin M (2018) Sustainable magnet-responsive nanomaterials for the removal of arsenic from contaminated water. J Hazard Mater 342:260–26910.1016/j.jhazmat.2017.08.034 ↗
18. Cai K, Shen W, Ren B, He J, Wu S, Wang W (2017) A phytic acid modified CoFe2O4 magnetic adsorbent with controllable morphology, excellent selective adsorption for dyes and ultra-strong adsorption ability for metal ions. Chem Eng J 330:936–94610.1016/j.cej.2017.08.009 ↗
19. Chen R, Wang W, Zhao X, Zhang Y, Wu S, Li F (2014) Rapid hydrothermal synthesis of magnetic CoxNi1–xFe2O4 nanoparticles and their application on removal of Congo red. Chem Eng J 242:226–23310.1016/j.cej.2013.12.016 ↗
20. Zhao X, Wang W, Zhang Y, Wu S, Li F, Liu JP (2014) Synthesis and characterization of gadolinium doped cobalt ferrite nanoparticles with enhanced adsorption capability for Congo Red. Chem Eng J 250:164–17410.1016/j.cej.2014.03.113 ↗
21. Wu X, Ding Z, Song N, Li L, Wang W (2016) Effect of the rare-earth substitution on the structural, magnetic and adsorption properties in cobalt ferrite nanoparticles. Ceram Int 42:4246–425510.1016/j.ceramint.2015.11.100 ↗
22. Nassar MY, Khatab M (2016) Cobalt ferrite nanoparticles via a template-free hydrothermal route as an efficient nano-adsorbent for potential textile dye removal. RSC Adv 6:79688–7970510.1039/C6RA12852A ↗
23. Singh C, Goyal A, Singhal S (2014) Nickel-doped cobalt ferrite nanoparticles: efficient catalysts for the reduction of nitroaromatic compounds and photo-oxidative degradation of toxic dyes. Nanoscale 6:7959–797010.1039/C4NR01730G ↗
24. Borgohain C, Senapati KK, Sarma KC, Phukan P (2012) A facile synthesis of nanocrystalline CoFe2O4 embedded one-dimensional ZnO hetero-structure and its use in photocatalysis. J Mol Catal A Chem 363–364:495–50010.1016/j.molcata.2012.07.032 ↗
25. Oyetade OA, Nyamori VO, Martincigh BS, Jonnalagadda SB (2015) Effectiveness of carbon nanotube–cobalt ferrite nanocomposites for the adsorption of rhodamine B from aqueous solutions. RSC Adv 5:22724–2273910.1039/C4RA15446K ↗
26. Zhao Y, Ma X, Xu P, Wang H, Liu Y, He A (2018) Elemental mercury removal from flue gas by CoFe2O4 catalyzed peroxymonosulfate. J Hazard Mater 341:228–23710.1016/j.jhazmat.2017.07.047 ↗
27. Xie A, Dai J, Cui J, Lang J, Wei M, Dai X, Li C, Yan Y (2017) Novel graphene oxide-confined nanospace directed synthesis of glucose-based porous carbon nanosheets with enhanced adsorption performance. ACS Sustain Chem Eng 5:11566–1157610.1021/acssuschemeng.7b02917 ↗
28. Pham CD, Chang J, Zurbuchen MA, Chang JP (2017) Magnetic properties of CoFe2O4 thin films synthesized by radical-enhanced atomic layer deposition. ACS Appl Mater Interfaces 9:36980–3698810.1021/acsami.7b08097 ↗
29. Song W, Yang T, Wang X, Sun Y, Ai Y, Sheng G, Hayat T, Wang X (2016) Experimental and theoretical evidence for competitive interactions of tetracycline and sulfamethazine with reduced graphene oxides. Environ Sci Nano 3:1318–132610.1039/C6EN00306K ↗
30. Jin Z, Wang X, Sun Y, Ai Y, Wang X (2015) Adsorption of 4-n-nonylphenol and bisphenol-A on magnetic reduced graphene oxides: a combined experimental and theoretical studies. Environ Sci Technol 49:9168–917510.1021/acs.est.5b02022 ↗
31. Minitha CR, Lalitha M, Jeyachandran YL, Senthilkumar L, Rajendra Kumar RT (2017) Adsorption behaviour of reduced graphene oxide towards cationic and anionic dyes: co-action of electrostatic and π–π interactions. Mater Chem Phys 194:243–25210.1016/j.matchemphys.2017.03.048 ↗
32. Gupta K, Khatri OP (2017) Reduced graphene oxide as an effective adsorbent for removal of malachite green dye: plausible adsorption pathways. J Colloid Interface Sci 501:11–2110.1016/j.jcis.2017.04.035 ↗
33. Guo X, Mei N (2014) Assessment of the toxic potential of graphene family nanomaterials. J Food Drug Anal 22:105–11510.1016/j.jfda.2014.01.009 ↗
34. Xu Y, Bai H, Lu G, Li C, Shi G (2008) Flexible graphene films via the filtration of water-soluble noncovalent functionalized graphene sheets. J Am Chem Soc 130:5856–585710.1021/ja800745y ↗
35. Kumbhar VS, Jagadale AD, Shinde NM, Lokhande CD (2012) Chemical synthesis of spinel cobalt ferrite (CoFe2O4) nano-flakes for supercapacitor application. Appl Surf Sci 259:39–4310.1016/j.apsusc.2012.06.034 ↗
36. Chen D, Li L, Guo L (2011) An environment-friendly preparation of reduced graphene oxide nanosheets via amino acid. Nanotechnology 22:32560110.1088/0957-4484/22/32/325601 ↗
37. Basirun WJ, Sookhakian M, Baradaran S, Mahmoudian MR, Ebadi M (2013) Solid-phase electrochemical reduction of graphene oxide films in alkaline solution. Nanoscale Res Lett 8:39710.1186/1556-276X-8-397 ↗
38. Zhang XJ, Wang GS, Cao WQ, Wei YZ, Liang JF, Guo L, Cao MS (2014) Enhanced microwave absorption property of reduced graphene oxide (RGO)-MnFe2O4 nanocomposites and polyvinylidene fluoride. ACS Appl Mater Interfaces 6:7471–747810.1021/am500862g ↗
39. Chen D, Chen C, Shen W, Quan H, Chen S, Xie S, Luo X, Guo L (2017) MOF-derived magnetic porous carbon-based sorbent: synthesis, characterization, and adsorption behavior of organic micropollutants. Adv Powder Technol 28:1769–177910.1016/j.apt.2017.04.018 ↗
40. Álvarez-Torrellas S, Peres JA, Gil-Álvarez V, Ovejero G, García J (2017) Effective adsorption of non-biodegradable pharmaceuticals from hospital wastewater with different carbon materials. Chem Eng J 320:319–32910.1016/j.cej.2017.03.077 ↗
41. Chen C, Chen D, Xie S, Quan H, Luo X, Guo L (2017) Adsorption behaviors of organic micropollutants on zirconium metal-organic framework UiO-66: analysis of surface interactions. ACS Appl Mater Interfaces 9:41043–4105410.1021/acsami.7b13443 ↗
42. Liu Z, Zhou X, Chen X, Dai C, Zhang J, Zhang Y (2013) Biosorption of clofibric acid and carbamazepine in aqueous solution by agricultural waste rice straw. J Environ Sci 25:2384–239510.1016/S1001-0742(12)60324-6 ↗
43. Misra T, Mitra S, Sen S (2018) Adsorption studies of carbamazepine by green-synthesized magnetic nanosorbents. Nanotechnol Environ Eng 3:1–1210.1007/s41204-018-0040-4 ↗
44. Bui TX, Choi H (2009) Adsorptive removal of selected pharmaceuticals by mesoporous silica SBA-15. J Hazard Mater 168:602–60810.1016/j.jhazmat.2009.02.072 ↗
45. Chen D, Xie S, Chen C, Quan H, Hua L, Luo X, Guo L (2017) Activated biochar derived from pomelo peel as a high-capacity sorbent for removal of carbamazepine from aqueous solution. RSC Adv 7:54969–5497910.1039/C7RA10805B ↗
46. Nisticò R (2017) Magnetic materials and water treatments for a sustainable future. Res Chem Intermed 43:6911–694910.1007/s11164-017-3029-x ↗
47. Mathew DS, Juang R-S (2007) An overview of the structure and magnetism of spinel ferrite nanoparticles and their synthesis in microemulsions. Chem Eng J 129:51–6510.1016/j.cej.2006.11.001 ↗