journal article·2016-11

Encapsulating 8-hydroxyquinoline in graphene oxide-stabilized polystyrene containers and its anticorrosion performance

Sneha Daradmare, Mamata Pradhan, V. S. Raja, Smrutiranjan Parida

Journal of Materials Science· Volume 51· Issue 22
Publisher page

Abstract

We report the formation of encapsulated graphene oxide/polystyrene (GO/PS) containers via Pickering emulsion polymerization of oil-in-water emulsions stabilized by GO sheets. Without further functionalization, the as-synthesized GO sheets were used for emulsion stabilization to minimize the process step. A one-step process was developed to encapsulate 8-Hydroxyquinoline (8-HQ) in GO/PS containers. FT-IR study confirmed the encapsulation. The inhibiting effect of 8-HQ was found to affect the kinetics of the emulsion polymerization and shift the polymerization temperature to a higher value. A detailed study of stability, size, and morphology of encapsulated containers (PS/GO) was carried out as a function of GO-to-oil ratio and oil volume fraction in the formulation, to optimize the process parameters. A possible mechanism for the formation of GO/PS containers at various GO-to-oil ratios was discussed. The corrosion inhibition performance of 8-HQ-encapsulated containers was studied in an epoxy coating. These encapsulated containers induced long-term anticorrosive property to the coating. The use of cost-effective materials and a scalable method used in this work can be utilized to prepare environmentally friendly coatings for large-area applications.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Pickering emulsions and particle stabilization · Advanced Polymer Synthesis and Characterization · Surface Modification and Superhydrophobicity

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

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