Formulation and characterization of polysaccharide beads for controlled release of plant growth regulators
Source abstract
Abstract
Owing to their chemical, physical, and functional characteristics, polysaccharides are considered to be the most versatile natural polymers. As a result, their properties have been exploited in various fields of research in the biomedical, pharmaceutical, cosmetic, food, and agricultural industries. A property of special interest is their ability to form systems or materials with unique physicochemical characteristics, such as hydrogels and micro- and nanoparticles for controlled release of active compounds. In the present study, polysaccharide beads formulated from alginate, cellulose powder, cellulose nanocrystals, starch, and xylan were reinforced with kaolin and surface-modified with polyethylenimine (PEI), a positively charged polyelectrolyte. Addition of kaolin improved the mechanical strength of the beads. Modification of the surface of the beads with PEI facilitated better control of the release rate of the plant growth regulator, phenylacetic acid (PAA). The physical properties of the beads were characterized by optical and scanning electron microscopy, and their mechanical strength was determined by an Instron 5565 Tensile Testing Machine. Cumulative release of PAA was measured by UV–Vis spectroscopy.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Polymer-Based Agricultural Enhancements · Pesticide and Herbicide Environmental Studies · Plant Surface Properties and Treatments
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (26)
Show source-provided references
1. McCrink-Goode M (2014) Pollution: a global threat. Environ Int 68:162–17010.1016/j.envint.2014.03.023 ↗
2. Bajpai AK, Giri A (2003) Water sorption behavior of highly swelling (carboxymethylcellulose-g-polyacrylamide) hydrogels and release of potassium nitrate as agrochemical. Carbohydr Polym 53:271–27910.1016/S0144-8617(03)00071-7 ↗
3. Abhilash PC, Singh N (2009) Pesticide use and application: an Indian scenario. J Hazard Mater 165:1–1210.1016/j.jhazmat.2008.10.061 ↗
4. van der Werf HMG (1996) Assessing the impact of pesticides on the environment. Agric Ecosyst Environ 60(2–3):81–9610.1016/S0167-8809(96)01096-1 ↗
5. Arias-Estévez M, López-Periago E, Martínez-Carballo E, Simal-Gándara J, Mejuto JC, Garcia-Rio L (2008) The mobility and degradation of pesticides in soils and the pollution of groundwater resources. Agric Ecosyst Environ 123(4):247–26010.1016/j.agee.2007.07.011 ↗
6. Bai C, Zhang S, Huang L, Wang H, Wang W, Ye Q (2015) Starch-based hydrogel loading with carbendazim for controlled-release and water absorption. Carbohydr Polym 125:376–38310.1016/j.carbpol.2015.03.004 ↗
7. Roy A, Singh SK, Bajpai J, Bajpai AK (2014) Controlled pesticides release from biodegradable polymers. Cent Eur J Chem 12:453–46910.2478/s11532-013-0405-2 ↗
8. Kumar S, Chauhan N, Gopal M, Kumar R, Dilbaghi N (2015) Development and evaluation of alginate–chitosan nanocapsules for controlled release of acetamiprid. Int J Biol Macromol 81:631–63710.1016/j.ijbiomac.2015.08.062 ↗
9. Campos EVR, de Oliveira JZ, Fraceto LF, Singh B (2015) Polysaccharides as safer release systems for agrochemicals. Agron Sustain Dev 35:47–6610.1007/s13593-014-0263-0 ↗
10. Kashyap PL, Xiang X, Heiden P (2015) Chitosan nanoparticle based delivery systems for sustainable agriculture. Int J Biol Macromol 77:36–5110.1016/j.ijbiomac.2015.02.039 ↗
11. Aouada FA, de Moura MR, Orts WJ, Mattoso LHC (2010) Polyacrylamide and methylcellulose hydrogel as delivery vehicle for the controlled release of paraquat pesticide. J Mater Sci 45:4977–4985. doi: 10.1007/s10853-009-4180-610.1007/s10853-009-4180-6 ↗
12. Bortolin A, Aouada FA, de Moura MR, Ribeiro C, Longo E, Mattoso LHC (2012) Application of polysaccharide hydrogels in adsorption and controlled-extended release of fertilizers processes. J Appl Polym Sci 123:2291–229810.1002/app.34742 ↗
13. Jamnongkan T, Kaewpirom S (2010) Potassium release kinetics and water retention of controlled-release fertilizers based on chitosan hydrogels. J Polym Environ 18:413–42110.1007/s10924-010-0228-6 ↗
14. Ferreira Almeida P, Almeida AJ (2004) Cross-linked alginate-gelatine beads: a new matrix for controlled release of pindolol. J Control Release 97:431–43910.1016/j.jconrel.2004.03.015 ↗
15. Zhong K, Lin ZT, Zheng XL, Jiang GB, Fang YS (2013) Starch derivative-based superabsorbent with integration of water-retaining and controlled release fertilizers. Carbohydr Polym 92:1367–137610.1016/j.carbpol.2012.10.030 ↗
16. Quinones JP, García YC, Curiel H, Covas CP (2010) Microspheres of chitosan for controlled delivery of brassinosteroids with biological activity as agrochemicals. Carbohydr Polym 80:915–92110.1016/j.carbpol.2010.01.006 ↗
17. Sopena F, Cabrera A, Maqueda C, Morillo E (2005) Controlled release of the herbicide norflurazon into water from ethylcellulose formulations. J Agric Food Chem 53:3540–354710.1021/jf048007d ↗
18. Isiklan N (2007) Controlled release study of carbaryl insecticide from calcium alginate and nickel alginate hydrogel beads. J Appl Polym Sci 105:718–72510.1002/app.26078 ↗
19. Kenawy NR, Sakran MA (1996) Controlled release formulations of agrochemicals from calcium alginate. Ind Eng Chem Res 35:3726–372910.1021/ie950448m ↗
20. Kulkarni AR, Soppimath KS, Aminabhavi TM, Dave AM, Mehta MH (2000) Glutaraldehyde crosslinked sodium alginate beads containing liquid pesticide for soil application. J Control Release 63:97–10510.1016/S0168-3659(99)00176-5 ↗
21. Singh B, Sharma DK, Kumar R, Gupta A (2010) Controlled release of thiram from neem-alginate-clay based delivery systems to manage environmental and health hazards. Appl Clay Sci 47:384–39110.1016/j.clay.2009.12.001 ↗
22. Pepperman AB, Kuan JCW (1995) Controlled release formulations of alachlor based on calcium alginate. J Control Release 34:17–2310.1016/0168-3659(94)00111-7 ↗
23. Cho AR, Chun YG, Kim BK, Park DJ (2014) Preparation of alginate-CaCl2 microspheres as resveratrol carriers. J Mater Sci 49:4612–4619. doi: 10.1007/s10853-014-8163-x10.1007/s10853-014-8163-x ↗
24. Peretz S, Anghel DF, Vasilescu E, Florea-Spiroiu M, Stoian C, Zgherea G (2015) Synthesis, characterization and adsorption properties of alginate porous beads. Polym Bull 72:3169–318210.1007/s00289-015-1459-4 ↗
25. Guilherme MR, Aouada FA, Fajardo AR, Martins AF, Paulino AT, Davi MFT, Rubira AF, Muniz EC (2015) Superabsorbent hydrogels based on polysaccharides for application in agriculture as soil conditioner and nutrient carrier: a review. Eur Polym J 72:365–38510.1016/j.eurpolymj.2015.04.017 ↗
26. Paques JP, van der Linden E, van Rijn CJM, Sagis LMC (2014) Preparation methods of alginate nanoparticles. Adv Colloid Interfac 209:163–17110.1016/j.cis.2014.03.009 ↗