Evaluation of iron-based hybrid materials for heavy metal ions removal
Source abstract
Abstract
The article presents in detail the results of the sorption of heavy metal ions such as Cu(II), Zn(II), Cd(II), and Zn(II) in the presence of ethylenediamine-N,N′-disuccinic acid as well as chromium(VI) on Purolite Arsen Xnp and Lewatit FO36. Factors affecting the sorption equilibrium (sorbent dose, contact time, temperature, pH, and the presence of interfering ions) were studied. To compare the surface morphologies of the studied ion exchangers, scans using atomic force microscope were also recorded, and attenuated total reflectance infrared spectroscopy was applied to establish the adsorption mechanism. The main parameters affecting sorption are initial concentration of the solution, pH, and phase contact time. Temperature has only a slight influence. The kinetic data were fitted using the pseudo-first-order and pseudo-second-order models. In the case of Cr(VI) adsorption, the equilibriums on Purolite Arsen Xnp and Lewatit FO36 were established within 60 min, in the case of Cu(II) and Zn(II) within 30–40 min and for Cd(II) and Pb(II) even less than 30 min. Moreover, it was found that the effectiveness of adsorption in the case of Cr(VI), Cu(II), Zn(II), Cd(II), and Pb(II) on Purolite ArsenXnp was higher than that on Lewatit FO36.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Adsorption and biosorption for pollutant removal · Extraction and Separation Processes · Radioactive element chemistry and processing
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (43)
Show source-provided references
1. Barceloux DG (1999) Chromium. J Toxicol Clin Toxicol 37:173–19410.1081/CLT-100102418 ↗
2. Clifford DA, Ghurye GL (2002) Metal-oxide adsorption, ion exchange and coagulation-microfiltration for arsenic removal from water. In: Frankenberger WT (ed) Environmental chemistry of arsenic. Marcel Dekker, New York, pp 217–245
3. Clifford DA, Ghurye GL, Tripp AR (1999) Development of an anion exchange process for arsenic removal from water. In: Chappell WR, Abernathy CO, Calderon RL (eds) Arsenic exposure and health effects. Elsevier Science, Oxford, pp 379–38710.1016/B978-008043648-7/50043-1 ↗
4. Cumbal L, Greenleaf J, Leun D, SenGupta AK (2003) Polymer supported inorganic nanoparticles: characterization and environmental applications. React Funct Polym 54:167–18010.1016/S1381-5148(02)00192-X ↗
5. Cumbal L, SenGupta AK (2005) Arsenic removal using polymer supported hydrated iron(III) oxide nanoparticles: role of Donnan membrane effect. Environ Sci Technol 39:6508–651510.1021/es050175e ↗
6. Elangovan R, Philip L, Chandraraj K (2008) Biosorption of hexavalent and trivalent chromium by palm flower (Borassus aethiopum). Chem Eng J 141:99–11110.1016/j.cej.2007.10.026 ↗
7. US EPA (2000) Arsenic removal from drinking water by ion exchange and activated alumina plants. Prepared by Battelle under contract 68-C7-0008 for EPA ORD
8. Mohan D, Pittman ChU Jr (2007) Arsenic removal from water/wastewater using adsorbents: a critical review. J Hazard Mater 142:1–5310.1016/j.jhazmat.2007.01.006 ↗
9. Hua M, Zhang S, Pan B, Zhang W, Lv L, Zhang Q (2012) Heavy metal removal from water/wastewater by nanosized metal oxides: a review. J Hazard Mater 211–212:317–33110.1016/j.jhazmat.2011.10.016 ↗
10. Kołodyńska D (2011) Organic–inorganic composite materials as sorbents and ion-exchangers used in environmental protection. In: Inamuddin (ed) Advanced organic–inorganic composites: materials, devices and allied applications. Nova Science Publishers, New York, pp 69–130
11. Qiu H, Zhang S, Pan B, Zhang W, Lv L (2012) Effect of sulfate on Cu(II) sorption to polymer-supported nano-iron oxides: behavior and XPS study. J Colloid Interface Sci 366:37–4310.1016/j.jcis.2011.09.070 ↗
12. Sarkar S, Blaney LM, Gupta A, Ghosh D, SenGupta AK (2008) Arsenic removal from groundwater and its safe containment in a rural environment: validation of a sustainable approach. Environ Sci Technol 49:4268–427310.1021/es702556t ↗
13. Brochure of Purolite International Ltd. 2011
14. Lanxess (2007) Engineering information, arsenic separation from ground water using Lewatit FO 36 ion exchange/iron oxide hybrids system, Leverkusen
15. Langmuir I (1916) The constitution and fundamental properties of solids and liquids. J Am Chem Soc 38:2221–229510.1021/ja02268a002 ↗
16. Freundlich HFM (1906) Über die adsorption in Lösungen. Z Phys Chem 57:385–470
17. Lagergren S (1898) Zur Theorie der sogenannten Adsorption gelöster Stoffe. Kungliga Svenska Vetenskapsakademiens Handlingar 24:1–39
18. Blanchard G, Maunaye M, Martin G (1984) Removal of heavy metals from waters by means of natural zeolites. Water Res 18:1501–150710.1016/0043-1354(84)90124-6 ↗
19. Ho YS, McKay G (1998) Sorption of dye from aqueous solution by peat. Chem Eng J 70:115–12410.1016/S0923-0467(98)00076-1 ↗
20. Juang R, Wu W (2002) Adsorption of sulphate and copper(II) on goethite in relation to the changes of zeta potentials. J Colloid Interface Sci 249:22–2910.1006/jcis.2002.8240 ↗
21. Boukhalfa Ch (2010) Sulfate removal from aqueous solutions by hydrous iron oxide in the presence of heavy metals and competitive anions. Macroscopic and spectroscopic analyses. Desalination 250:428–43210.1016/j.desal.2009.09.070 ↗
22. Chardichai P, Ritchie GSP (1992) The effect of pH on zinc adsorption by a lateritic soil in the presence of citrate and oxalate. J Soil Sci 43:713–728
23. Christophi ChA, Axe L (2000) Competition of Cd, Cu, and Pb adsorption on goethite. J Environ Eng 126:66–7410.1061/(ASCE)0733-9372(2000)126:1(66) ↗
24. Jaworska JS, Schowaneck D, Feitzel TCJ (1999) Environmental risk assessment for trisodium [S,S]-ethylene diaminedisuccinate, a biodegradable chelator used in detergent applications. Chemosphere 38:3597–362510.1016/S0045-6535(98)00573-6 ↗
25. Loonen H, Lindgren F, Hansen B, Karcher W, Niemelä J, Hiromatsu K, Takatsuki M, Peijnenburg W, Rorije E, Struijs J (1999) Prediction of biodegradability from chemical structure: modeling of ready biodegradation test data. Environ Toxicol Chem 18:1763–176810.1002/etc.5620180822 ↗
26. Tandy S, Ammann A, Schulin R, Nowack B (2006) Biodegradation and speciation of residual S,S-ethylenediaminedisuccinic acid (EDDS) in soil solution left after soil washing. Environ Pollut 142:191–19910.1016/j.envpol.2005.10.013 ↗
27. Elliot HA, Huang CP (1981) Adsorption characteristics of some Cu(II) complexes on aluminosilicates. Water Res 15:849–85510.1016/0043-1354(81)90139-1 ↗
28. Kołodyńska D (2011) Application of strongly basic anion exchangers for removal of heavy metals in the presence of green chelating agent. Chem Eng J 168:994–100710.1016/j.cej.2011.01.073 ↗
29. McBride MB (1989) Reactions controlling heavy metal solubility in soils. Adv Soil Sci 10:1–5610.1007/978-1-4613-8847-0_1 ↗
30. Perelomov LV, Pinskiy DL, Violante A (2011) Effect of organic acids on the adsorption of copper, lead, and zinc by goethite. Eur Soil Sci 44:22–2810.1134/S1064229311010091 ↗
31. Ali MA, Dzombak DA (1996) Interactions of copper, organic acids, and sulfate in goethite suspensions. Geochim Cosmochim Acta 60:5045–505310.1016/S0016-7037(96)00311-0 ↗
32. Lee SM, Laldawngliana C, Tiwari D (2012) Iron oxide nano-particles-immobilized-sand material in the treatment of Cu(II), Cd(II) and Pb(II) contaminated waste waters. Chem Eng J 195–196:103–111
33. Mahmoud ME, Abdelwahab MS, Fathallah EM (2013) Design of novel nano-sorbents based on nano-magnetic iron oxide-bound-nano-silicon oxide-immobilized-triethylenetetramine for implementation in water treatment of heavy metals. Chem Eng J 223:318–32710.1016/j.cej.2013.02.097 ↗
34. Gong J, Chen L, Zeng G, Long F, Deng J, Niu Q, He X (2012) Shellac-coated iron oxide nanoparticles for removal of cadmium(II) ions from aqueous solution. J Environ Sci 24:1165–117310.1016/S1001-0742(11)60934-0 ↗
35. Karami H (2013) Heavy metal removal from water by magnetite nanorods. Chem Eng J 219:209–21610.1016/j.cej.2013.01.022 ↗
36. Tan Y, Chen M, Hao Y (2012) High efficient removal of Pb(II) by amino-functionalized Fe3O4 magnetic nano-particles. Chem Eng J 191:104–11110.1016/j.cej.2012.02.075 ↗
37. Roy A, Bhattacharya J (2012) Removal of Cu(II), Zn(II) and Pb(II) from water using microwave-assisted synthesized maghemite nanotubes. Chem Eng J 211–212:493–50010.1016/j.cej.2012.09.097 ↗
38. Mahapatra A, Mishra BG, Hota G (2013) Electrospun Fe2O3–Al2O3 nanocomposite fibers as efficient adsorbent for removal of heavy metal ions from aqueous solution. J Hazard Mater 258–259:116–12310.1016/j.jhazmat.2013.04.045 ↗
39. Kołodyńska D (2010) Biodegradable complexing agents as an alternative to chelators in sorption of heavy metal ions. Desalination Water Treat Sci Eng 16:146–15510.5004/dwt.2010.1050 ↗
40. Kołodyńska D (2011) Green complexing agent EDDS in removal of heavy metal ions on strongly basic anion exchangers. Desalination 280:44–5710.1016/j.desal.2011.06.060 ↗
41. Kołodyńska D (2011) The chelating agents of a new generation as an alternative to conventional chelators for heavy metal ions removal from different waste waters. In: RY Ning (ed) Expanding issues in desalination. InTech Publishers, ISBN 978-953-307-326-2, pp 339–37110.5772/21180 ↗
42. Kowalczyk M, Hubicki Z, Kołodyńska D (2013) Modern hybrid sorbents: new ways of heavy metal removal from waters. Chem Eng Process 70:55–6510.1016/j.cep.2013.05.007 ↗
43. Grčman H, Vodnik D, Velikonja-Bolta Š, Leštan D (2003) Ethylenediaminedissuccinate as a new chelate for environmentally safe enhanced lead phytoextraction. J Environ Qual 32:500–50610.2134/jeq2003.5000 ↗