journal article·2022-03

Investigation of a novel poly (lactic acid) porous material toughened by thermoplastic polyurethane

Zecheng Wu, Zhijun Zhang, Wei Wei, Yanqing Yin, Chongxing Huang, Jiang Ding, Qingshan Duan

Journal of Materials Science· Volume 57· Issue 9
Publisher page

Abstract

Poly (lactic acid)/thermoplastic polyurethane (PLA/TPU) ductile fibrous porous material was obtained by electrospinning, which has better mechanical properties than pure PLA fibrous material. The effects of TPU on the morphology, hydrophobicity, thermal and mechanical properties of the porous fibrous material were studied. After adding TPU, the fiber diameter increased significantly. The static water contact angle of electrospinning fiber decreased as TPU increased. The addition of TPU reduced the crystallinity of the material, but the crystallinity built up over the rise of TPU. TPU substantially improved the toughness of the material, and the PLA/TPU strain energy can be enhanced by nearly 17 times. When the PLA/TPU mass ratio was 10, the maximum tensile strength could reach 9.2 MPa, and if the mass ratio is 20, it holds the highest elongation at break of 153.1%. The preparation of electrospun PLA ductile porous material would be a reliable foundation for broadening the application range of PLA fibrous material.
Source: expertdata · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: biodegradable polymer synthesis and properties · Electrospun Nanofibers in Biomedical Applications · Polymer composites and self-healing

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (35)

Show source-provided references
1. Lebreton L, Slat B, Ferrari F, Sainte-Rose B, Aitken J, Marthouse R, Hajbane S, Cunsolo S, Schwarz A, Levivier A, Noble K, Debeljak P, Maral H, Schoeneich-Argent R, Brambini R, Reisser J (2018) Evidence that the great pacific garbage patch is rapidly accumulating plastic. Sci Rep 8:4666. https://doi.org/10.1038/s41598-018-22939-w10.1038/s41598-018-22939-w ↗
2. Ragusa A, Svelato A, Santacroce C, Catalano P, Notarstefano V, Carnevali O, Papa F, Rongioletti MCA, Baiocco F, Draghi S, D’Amore E, Rinaldo D, Matta M, Giorgini E (2021) Plasticenta: first evidence of microplastics in human placenta. Environ Int 146:106274. https://doi.org/10.1016/j.envint.2020.10627410.1016/j.envint.2020.106274 ↗
3. Xu WH, Shen RZ, Yan YR, Gao J (2017) Preparation and characterization of electrospun alginate/PLA nanofibers as tissue engineering material by emulsion eletrospinning. J Mech Behav Biomed Mater 65:428–438. https://doi.org/10.1016/j.jmbbm.2016.09.01210.1016/j.jmbbm.2016.09.012 ↗
4. Shahriar SMS, Mondal J, Hasan MN, Revuri V, Lee DY, Lee Y-K (2019) Electrospinning nanofibers for therapeutics delivery. Nanomaterials 9:532. https://doi.org/10.3390/nano904053210.3390/nano9040532 ↗
5. Liu M, Hao X, Wang Y, Jiang Z, Zhang H (2020) A biodegradable core-sheath nanofibrous 3D hierarchy prepared by emulsion electrospinning for sustained drug release. J Mater Sci 55(35):16730–16743. https://doi.org/10.1007/s10853-020-05205-110.1007/s10853-020-05205-1 ↗
6. Takayama T, Todo M (2006) Improvement of impact fracture properties of PLA/PCL polymer blend due to LTI addition. J Mater Sci 41:4989–4992. https://doi.org/10.1007/s10853-006-0137-110.1007/s10853-006-0137-1 ↗
7. Nunez K, Rosales C, Perera R, Villarreal N, Pastor JM (2011) Nanocomposites of PLA/PP blends based on sepiolite. Polym Bull 67:1991–2016. https://doi.org/10.1007/s00289-011-0616-710.1007/s00289-011-0616-7 ↗
8. Hao YP, Yang HL, Pan HW, Ran XH, Zhang HL (2018) The effect of MBS on the heat resistant, mechanical properties, thermal behavior and rheological properties of PLA/EVOH blend. J Polym Res 25:1–9. https://doi.org/10.1007/s10965-018-1547-x10.1007/s10965-018-1547-x ↗
9. Zhang H-C, Huang J, Zhao P-F, Lu X (2020) Bio-based ethylene-co-vinyl acetate/poly (lactic acid) thermoplastic vulcanizates with enhanced mechanical strength and shape memory behavior. Polym Test 87:106537. https://doi.org/10.1016/j.polymertesting.2020.10653710.1016/j.polymertesting.2020.106537 ↗
10. Ferreira EDB, Luna CBB, Siqueira DD, Araujo EM, de Franca DC, Wellen RMR (2021) Annealing effect on Pla/Eva blends performance. J Polym Environ 35:1–14. https://doi.org/10.1007/s10924-021-02220-410.1007/s10924-021-02220-4 ↗
11. Aliotta L, Gigante V, Coltelli M-B, Lazzeri A (2021) Volume change during creep and micromechanical deformation orocesses in PLA-PBSA binary blends. Polymers 13:2379. https://doi.org/10.3390/polym1314237910.3390/polym13142379 ↗
12. Oztemur J, Yalcin-Enis I (2021) Development of biodegradable webs of PLA/PCL blends prepared via electrospinning:morphological, chemical, and thermal characterization. J Biomed Mater Res Part B 109:1844–1856. https://doi.org/10.1002/jbm.b.3484610.1002/jbm.b.34846 ↗
13. Gao WC, Wu W, Chen CZ, Zhao H, Liu Y, Li Q, Huang CX, Hu GH, Wang SF, Shi D, Zhang QC (2022) Design of a superhydrophobic strain sensor with a multilayer structure for human motion monitoring. ACS Appl Mater Interfaces 14(1):1874–1884. https://doi.org/10.1021/acsami.1c1756510.1021/acsami.1c17565 ↗
14. Dong K, Panahi-Sarmad M, Cui Z, Huang X, Xiao X (2021) Electro-induced shape memory effect of 4D printed auxetic composite using PLA/TPU/CNT filament embedded synergistically with continuous carbon fiber: A theoretical & experimental analysis. Compos B 220:108994. https://doi.org/10.1016/j.compositesb.2021.10899410.1016/j.compositesb.2021.108994 ↗
15. Boyacioglu S, Kodal M, Ozkoc G (2020) A comprehensive study on shape memory behavior of PEG plasticized PLA/TPU bio-blends. Eur Polym J 122:109372. https://doi.org/10.1016/j.eurpolymj.2019.10937210.1016/j.eurpolymj.2019.109372 ↗
16. Valenti S, Yousefzade O, Puiggalí J, Macovez R (2020) Phase-selective conductivity enhancement and cooperativity length in PLLA/TPU nanocomposite blends with carboxylated carbon nanotubes. Polymer 191:122279. https://doi.org/10.1016/j.polymer.2020.12227910.1016/j.polymer.2020.122279 ↗
17. Zhao XP, Ding Z, Lin Q, Peng SX, Fang PF (2017) Toughening of polylactide via in situ formation of polyurethane crosslinked elastomer during reactive blending. J Appl Polym Sci 134:44383. https://doi.org/10.1002/app.4438310.1002/app.44383 ↗
18. Zhang HC, Kang BH, Chen LS, Lu X (2020) Enhancing toughness of poly (lactic acid)/thermoplastic polyurethane blends via increasing interface compatibility by polyurethane elastomer prepolymer and its toughening mechanism. Polym Test 87:106521. https://doi.org/10.1016/j.polymertesting.2020.10652110.1016/j.polymertesting.2020.106521 ↗
19. Ma M, Wang XP, Liu K, Chen S, Shi YQ, He HW, Wang X (2020) Simultaneously enhanced fracture toughness and flame-retardant property of poly(l-lactic acid) via reactive blending with ammonium polyphosphate andin situformed polyurethane. Polym Int 69:985–994. https://doi.org/10.1002/pi.605310.1002/pi.6053 ↗
20. Fong H, Chun I, Reneker DH (1999) Beaded nanofibers formed during electrospinning. Polymer 40:4585–4592. https://doi.org/10.1016/s0032-3861(99)00068-310.1016/s0032-3861(99)00068-3 ↗
21. Yilmaz SS, Aytac A (2021) Poly(lactic acid)/polyurethane blend electrospun fibers: structural, thermal, mechanical and surface properties. Iran Polym J 30:873–883. https://doi.org/10.1007/s13726-021-00944-710.1007/s13726-021-00944-7 ↗
22. Zhao YY, Yang QB, Lu XF, Wang C, Wei Y (2005) Study on correlation of morphology of electrospun products of polyacrylamide with ultrahigh molecular weight. J Polym Sci Pt B-Polym Phys 43:2190–2195. https://doi.org/10.1002/polb.2050610.1002/polb.20506 ↗
23. Xu J, Zhang JH, Gao WQ, Liang HW, Wang HY, Li JF (2009) Preparation of chitosan/PLA blend micro/nanofibers by electrospinning. Mater Lett 63:658–660. https://doi.org/10.1016/j.matlet.2008.12.01410.1016/j.matlet.2008.12.014 ↗
24. Zhao XP, Xu M, Ding Z, Peng SX, Fang PF (2017) Reactive blending toughened PLA by in situ formation of polyurethane crosslinked elastomer. Polym Sci Ser B 59:437–442. https://doi.org/10.1134/s156009041704011x10.1134/s156009041704011x ↗
25. Fallahiarezoudar E, Ahmadipourroudposht M, Idris A, Yusof NM (2017) Optimization and development of maghemite (gamma-Fe2O3) filled poly-L-lactic acid (PLLA)/thermoplastic polyurethane (TPU) electrospun nanofibers using taguchi orthogonal array for tissue engineering heart valve. Mater Sci Eng C-Mater Biol Appl 76:616–627. https://doi.org/10.1016/j.msec.2017.03.12010.1016/j.msec.2017.03.120 ↗
26. Lin L, Deng C, Lin GP, Wang YZ (2015) Super toughened and high heat-resistant poly (Lactic Acid) (PLA)-based blends by enhancing Interfacial bonding and PLA phase crystallization. Ind Eng Chem Res 54:5643–5655. https://doi.org/10.1021/acs.iecr.5b0117710.1021/acs.iecr.5b01177 ↗
27. Raja M, Ryu SH, Shanmugharaj AM (2013) Thermal, mechanical and electroactive shape memory properties of polyurethane (PU)/poly (lactic acid) (PLA)/CNT nanocomposites. Eur Polym J 49:3492–3500. https://doi.org/10.1016/j.eurpolymj.2013.08.00910.1016/j.eurpolymj.2013.08.009 ↗
28. Li YJ, Shimizu H (2007) Toughening of polylactide by melt blending with a biodegradable poly(ether)urethane elastomer. Macromol Biosci 7:921–928. https://doi.org/10.1002/mabi.20070002710.1002/mabi.200700027 ↗
29. Su Z, Li Q, Liu Y, Hu G-H, Wu C (2009) Multiple melting behavior of poly (lactic acid) filled with modified carbon black. J Polym Sci Part B: Polym Phys 47(20):1971–1980. https://doi.org/10.1002/polb.2179010.1002/polb.21790 ↗
30. Lostocco MR, Huang SJ (1998) The hydrolysis of poly (lactic acid) poly (hexamethylene succinate) blends. Polym Degrad Stab 61:225–230. https://doi.org/10.1016/s0141-3910(97)00138-910.1016/s0141-3910(97)00138-9 ↗
31. Mustafa W, Azhar U, Tabassum S, Jamal M, Siddiqi SA, Tariq M, Muhammad N, Asif A, Chaudhry AA, Sharif F (2020) Doping and incorporation of hydroxyapatite in development of PU-PLA electrospun osteogenic membranes. J Polym Environ 28(11):2988–3002. https://doi.org/10.1007/s10924-020-01764-110.1007/s10924-020-01764-1 ↗
32. Oliaei E, Kaffashi B, Davoodi S (2016) Investigation of structure and mechanical properties of toughened poly (L-lactide)/thermoplastic poly (ester urethane) blends. J Appl Polym Sci 133:43104. https://doi.org/10.1002/app.4310410.1002/app.43104 ↗
33. Han JJ, Huang HX (2011) Preparation and characterization of biodegradable polylactide/thermoplastic polyurethane elastomer blends. J Appl Polym Sci 120:3217–3223. https://doi.org/10.1002/app.3333810.1002/app.33338 ↗
34. Feng F, Ye L (2010) Morphologies and mechanical properties of polylactide/thermoplastic polyurethane elastomer blends. J Appl Polym Sci 119:2778–2783. https://doi.org/10.1002/app.3286310.1002/app.32863 ↗
35. Imre B, Bedo D, Domjan A, Schon P, Vancso GJ, Pukanszky B (2013) Structure, properties and interfacial interactions in poly (lactic acid)/polyurethane blends prepared by reactive processing. Eur Polym J 49:3104–3113. https://doi.org/10.1016/j.eurpolymj.2013.07.00710.1016/j.eurpolymj.2013.07.007 ↗