journal article·2021-10

Ca-modified Al–Mg–Sc alloy with high strength at elevated temperatures due to a hierarchical microstructure

Haiquan Du, Shasha Zhang, Bingyi Zhang, Xuewei Tao, Zhengjun Yao, Nikolay Belov, Sybrand van der Zwaag, Zili Liu

Journal of Materials Science· Volume 56· Issue 28
Publisher page

Abstract

Al-Mg alloys are normally prone to lose part of their yield and tensile strength at high temperatures due to insufficient thermal stability of the microstructure. Here, we present a Ca-modified Al–Mg–Sc alloy demonstrating high strength at elevated temperatures. The microstructure contains Al4Ca phases distributed as a network along the grain boundary and Al3(Sc,Zr) nano-particles dispersed within the grains. The microstructure evolution and age-hardening analysis indicate that the combination of an Al4Ca network and Sc-rich nano-particles leads to excellent thermal stability even upon aging at 300 °C. The tensile strength of the alloy for temperatures up to 250 °C is significantly improved by an aging treatment and is comparable with the commercial heat-resistant aluminum alloys, i.e., A356 and A319. At a high temperature of 300 °C, the tensile strength is superior to the above-mentioned commercial alloys, even more so when expressed as the specific strength due to the low density of Ca-modified Al–Mg–Sc alloy. The excellent high-temperature strength results from a synergistic effect of solid solution strengthening, grain boundary strengthening and nanoparticle order strengthening.
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Research context

OpenAlex topics: Aluminum Alloy Microstructure Properties · Aluminum Alloys Composites Properties · Microstructure and mechanical properties

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