journal article·2017-03

Ionic liquid microemulsion-assisted synthesis and improved photocatalytic activity of ZnIn2S4

Ai-Li Wang, Li Chen, Jia-Xi Zhang, Wan-Chun Sun, Peng Guo, Cong-Ying Ren

Journal of Materials Science· Volume 52· Issue 5
Publisher page

Abstract

This paper reported the fabrication of high-performance ZnIn2S4 photocatalysts using ionic liquid microemulsion-mediated hydrothermal method under facile conditions. The influences of reaction temperature and aging time on the catalytic properties of the specimens were investigated. The crystal phase, optical property, and morphological structure of the obtained catalysts were characterized using X-ray diffraction, UV–visible spectrometer, electronic microscope, and N2 adsorption–desorption techniques. The results indicated that all of the ZnIn2S4 samples prepared by this method consisted of the hexagonal phase and exhibited excellent photoresponse capability and photocatalytic performance. The sample prepared at 60 °C with an aging time of 6 h showed the best photocatalytic performance, and the corresponding degradation rate of methyl orange was measured as 98.5% after 10 min. The current study highlights an efficient and environmental method for the formulation of high-performance ZnIn2S4.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Advanced Photocatalysis Techniques · TiO2 Photocatalysis and Solar Cells · Copper-based nanomaterials and applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (27)

Show source-provided references
1. Fang F, Chen L, Chen Y, Wu L (2010) Synthesis and photocatalysis of ZnIn2S4 nano/micropeony. J Phys Chem C 114:2393–239710.1021/jp910291p ↗
2. Tan C, Zhu G, Hojamberdiev M, Lokesh KS, Luo X, Jin L, Zhou J, Liu P (2014) Adsorption and enhanced photocatalytic activity of the 0001 faceted Sm-doped ZnIn2S4 microspheres. J Hazard Mater 278:572–58310.1016/j.jhazmat.2014.06.019 ↗
3. Islam SU, Mohammad F (2015) High-energy radiation induced sustainable coloration and functional finishing of textile materials. Ind Eng Chem Res 54:3727–374510.1021/acs.iecr.5b00524 ↗
4. Kale MJ, Avanesian T, Christopher P (2014) Direct photocatalysis by plasmonic nanostructures. ACS Catal 4:116–12810.1021/cs400993w ↗
5. Jung HS, Hong YJ, Li Y, Cho J, Kim YJ, Yi GC (2008) Photocatalysis using GaN nanowires. ACS Nano 2:637–64210.1021/nn700320y ↗
6. Yang Y, Wu Q, Guo Y, Hu C, Wang E, Mol J (2005) Efficient degradation of dye pollutants on nanoporous polyoxotungstate–anatase composite under visible-light irradiation. J Mol Catal A 225:203–21210.1016/j.molcata.2004.08.031 ↗
7. Wang B, Gu D, Ji Lmand WuH (2016) Photocatalysis: a novel approach to efficient demulsification. Catal Commun 75:83–8610.1016/j.catcom.2015.12.008 ↗
8. Pruden AL, Ollis DF (1983) Photoassisted heterogeneous catalysis: the degradation of trichloroethylene in water. J Catal 82:404–41710.1016/0021-9517(83)90207-5 ↗
9. Mills A, Hunte SL (1997) Photomineralization of 4-chlorophenol sensitized by titanium dioxide: a study of the initial kinetics of carbon dioxide photogeneration. J Photochem Photobiol A 108:1–3510.1016/S1010-6030(97)00118-4 ↗
10. Huang M, Xu C, Wu Z, Huang Y, Lin J, Wu J (2008) Photocatalytic discolorization of methyl orange solution by Pt modified TiO2 loaded on natural zeolite. Dyes Pigments 77:327–33410.1016/j.dyepig.2007.01.026 ↗
11. Jing J, Feng J, Li W, Yu W (2013) Low-temperature synthesis of water-dispersible anatase titanium dioxide nanoparticles for photocatalysis. J Colloid Interface Sci 396:90–9410.1016/j.jcis.2012.12.075 ↗
12. Ding K, Wang D, Yang P, Cheng X (2016) Synthesis of anatase titanium dioxide nanocaps via hydrofluoric acid etching towards enhanced photocatalysis. Mater Res Bull 74:311–31810.1016/j.materresbull.2015.10.047 ↗
13. Sriram MA, McMichael PH, Waghray A, Kumta PN, Misture S, Wang XL (1998) Chemical synthesis of the high-pressure cubic-spinel phase of ZnIn2S4. J Mater Sci 33:4333–4339. doi: 10.1023/A:100442462949810.1023/A:1004424629498 ↗
14. Li M, Su J, Guo L (2008) Preparation and characterization of ZnIn2S4 thin films deposited by spray pyrolysis for hydrogen production. Int J Hydrog Energy 33:2891–289610.1016/j.ijhydene.2008.04.008 ↗
15. Ye L, Fu J, Xu Z, Yuan R, Li Z (2014) Facile One-Pot Solvothermal method to synthesize sheet-on-Sheet reduced graphene oxide (RGO)/ZnIn2S4 nanocomposites with superior photocatalytic performance. ACS Appl Mater Interfaces 6:3483–349010.1021/am5004415 ↗
16. Shang L, Zhou C, Bian T, Yu H, Wu LZ, Tung CH, Zhang T (2013) Facile synthesis of hierarchical ZnIn2S4 submicrospheres composed of ultrathin mesoporous nanosheets as a highly efficient visible-light-driven photocatalyst for H2 production. J Mater Chem A 1:4552–455810.1039/c3ta01685d ↗
17. Antonietti M, Kuang D, Smarsly B, Zhou Y (2004) Ionic liquids for the convenient synthesis of functional nanoparticles and other inorganic nanostructures. Angew Chem Int Ed 43:4988–499210.1002/anie.200460091 ↗
18. Li Z, Jia Z, Luan Y, Mu T (2008) Ionic liquids for synthesis of inorganic nanomaterials. Curr Opin Solid State Mater Sci 12:1–810.1016/j.cossms.2009.01.002 ↗
19. Gao YA, Han SB, Han BX, Li GZ, Shen D, Li ZH, Du JM, Hou WG, Zhang GY (2005) TX-100/water/1-butyl-3-methylimidazolium hexafluorophosphate microemulsions. Langmuir 21:5681–568410.1021/la0500880 ↗
20. Capek I (2004) Preparation of metal nanoparticles in water-in-oil (w/o) microemulsions. Adv Colloid Interface Sci 110:49–7410.1016/j.cis.2004.02.003 ↗
21. Warisnoicharoen W, Lansley A, Lawrence M (2000) Nonionic oil-in-water microemulsions: the effect of oil type on phase behavior. Int J Pharm 198:7–2710.1016/S0378-5173(99)00406-8 ↗
22. Shen S, Zhao L, Guo L (2008) Cetyltrimethylammoniumbromide (CTAB)-assisted hydrothermal synthesis of ZnIn2S4 as an efficient visible-light-driven photocatalyst for hydrogen production. Int J Hydrog Energy 33:4501–451010.1016/j.ijhydene.2008.05.043 ↗
23. Chen Z, Li D, Xiao G, He Y, Xu YJ (2012) Microwave-assisted hydrothermal synthesis of marigold-like ZnIn2S4 microspheres and their visible light photocatalytic activity. J Solid State Chem 186:247–25410.1016/j.jssc.2011.12.006 ↗
24. Chen Z, Li D, Zhang W, Shao Y, Chen T, Sun M, Fu X (2009) Photocatalytic degradation of dyes by ZnIn2S4 microspheres under visible light irradiation. J Phys Chem C 113:4433–444010.1021/jp8092513 ↗
25. Wodka D, Bielanska E, Socha RP, Elzbieciak-Wodka M, Gurgul J, Nowak P, Warszyński P, Kumakiri I (2010) Photocatalytic activity of titanium dioxide modified by silver nanoparticles. ACS Appl Mater Interface 2:1945–195310.1021/am1002684 ↗
26. Shen S, Guo P, Zhao L, Du Y, Guo L (2011) Insights into photoluminescence property and photocatalytic activity of cubic and rhombohedral ZnIn2S4. J Solid State Chem 184:2250–225610.1016/j.jssc.2011.06.033 ↗
27. Gou X, Cheng F, Shi Y, Zhang L, Peng S, Chen J, Shen P (2006) Shape-controlled synthesis of ternary chalcogenide ZnIn2S4 and CuIn(S, Se)2 nano-/microstructures via facile solution route. J Am Chem Soc 128:7222–722910.1021/ja0580845 ↗