journal article·2021-01

Rational design of FeCo imbedded 3D porous carbon microspheres as broadband and lightweight microwave absorbers

Yue Guo, Qiaozhi Sun, Kai Song, Jiawei Ding, Chunsheng Shi, Fang He

Journal of Materials Science· Volume 56· Issue 3
Publisher page

Abstract

With the aim to obtain microwave (MW) absorber possessing simultaneous light weight and broad absorption bandwidth, FeCo imbedded 3D porous carbon network microspheres (3DC@FeCo) were synthesized via spray-drying followed by calcination processes. 3DC@FeCo exhibits 3D porous carbon microspheres structure with submicrometer-sized macropores. The FeCo imbedded carbon structure not only restrains the growth and agglomeration of FeCo nanoparticles, but also effectively introduces polarization and suppresses the skin effect from FeCo. In addition, the 3D porous carbon microspheres provide more channels which enhance the multiple reflection for microwave. The microwave absorption performance of 3DC@FeCo can be adjusted through changing the carbonization temperature, and the sample after carbonized at 630 °C (3DC@FeCo-630) shows the best microwave absorption property. It is worth mentioning that there is only 21.8 wt% FeCo in 3DC@FeCo, indicating that the 3DC@FeCo microspheres proposed in this study are one kind of lightweight microwave absorbers. The minimum reflection loss (RL) value of 3DC@FeCo-630 is − 47.4 dB at 6.35 GHz and the effective absorption bandwidth (RL < − 10 dB) can reach up 5.66 GHz (12.08–17.74 GHz) with the matching thickness of only 2.7 mm. The excellent microwave absorption ability can be attributed to favorable impedance matching, strong dielectric loss, magnetic loss, FeCo imbedded carbon and unique 3D porous structure. 3DC@FeCo microspheres as broadband and lightweight microwave absorbers exhibit a promising prospect applied in complex electromagnetic environments.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Electromagnetic wave absorption materials · Advanced Antenna and Metasurface Technologies · Metamaterials and Metasurfaces Applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (55)

Show source-provided references
1. He J-Z, Wang X-X, Zhang Y-L, Cao M-S (2016) Small magnetic nanoparticles decorating reduced graphene oxides to tune the electromagnetic attenuation capacity. J Mater Chem C 4(29):7130–714010.1039/C6TC02020H ↗
2. Wei S, Wang X, Zhang B, Yu M, Zheng Y, Wang Y, Liu J (2017) Preparation of hierarchical core–shell C@NiCo2O4@Fe3O4 composites for enhanced microwave absorption performance. Chem Eng J 314:477–48710.1016/j.cej.2016.12.005 ↗
3. Zeng M, Cao Q, Liu J, Guo B, Hao X, Liu Q, Liu X, Sun X, Zhang X, Yu R (2020) Hierarchical cobalt selenides as highly efficient microwave absorbers with tunable frequency response. ACS Appl Mater Interfaces 12(1):1222–123110.1021/acsami.9b15172 ↗
4. Zhao B, Shao G, Fan B, Zhao W, Zhang S, Guan K, Zhang R (2015) In situ synthesis of novel urchin-like ZnS/Ni3S2@Ni composite with a core–shell structure for efficient electromagnetic absorption. J Mater Chem C 3(41):10862–1086910.1039/C5TC02063H ↗
5. Gao S, Zhang Y, Xing H, Li H (2020) Controlled reduction synthesis of yolk–shell magnetic@void@C for electromagnetic wave absorption. Chem Eng J 387:12414910.1016/j.cej.2020.124149 ↗
6. Shu R, Zhang J, Guo C, Wu Y, Wan Z, Shi J, Liu Y, Zheng M (2020) Facile synthesis of nitrogen-doped reduced graphene oxide/nickel–zinc ferrite composites as high-performance microwave absorbers in the X-band. Chem Eng J 384:12326610.1016/j.cej.2019.123266 ↗
7. Shu R, Wu Y, Zhang J, Wan Z, Li X (2020) Facile synthesis of nitrogen-doped cobalt/cobalt oxide/carbon/reduced graphene oxide nanocomposites for electromagnetic wave absorption. Compos Part B Eng 193:10802710.1016/j.compositesb.2020.108027 ↗
8. Ding X, Huang Y, Li S, Zhang N, Wang J (2016) FeNi3 nanoalloy decorated on 3D architecture composite of reduced graphene oxide/molybdenum disulfide giving excellent electromagnetic wave absorption properties. J Alloys Compd 689:208–21710.1016/j.jallcom.2016.07.312 ↗
9. Huang L, Li J, Li Y, He X, Yuan Y (2019) Lightweight and flexible hybrid film based on delicate design of electrospun nanofibers for high-performance electromagnetic interference shielding. Nanoscale 11(17):8616–862510.1039/C9NR02102G ↗
10. Yang Y, Xu C, Xia Y, Wang T, Li F (2010) Synthesis and microwave absorption properties of FeCo nanoplates. J Alloys Compd 493(1–2):549–55210.1016/j.jallcom.2009.12.153 ↗
11. Li G, Xie T, Yang S, Jin J, Jiang J (2012) Microwave absorption enhancement of porous carbon fibers compared with carbon nanofibers. J Phys Chem C 116(16):9196–920110.1021/jp300050u ↗
12. Kuang D, Hou L, Wang S, Luo H, Deng L, Mead JL, Huang H, Song M (2019) Large-scale synthesis and outstanding microwave absorption properties of carbon nanotubes coated by extremely small FeCo–C core–shell nanoparticles. Carbon 153:52–6110.1016/j.carbon.2019.06.105 ↗
13. Wu N, Qiao J, Liu J, Du W, Xu D, Liu W (2017) Strengthened electromagnetic absorption performance derived from synergistic effect of carbon nanotube hybrid with Co@C beads. Adv Compos Hybrid Mater 1(1):149–15910.1007/s42114-017-0008-z ↗
14. Mohamadi M, Kowsari E, Haddadi-Asl V, Yousefzadeh M (2019) Fabrication, characterization and electromagnetic wave absorption properties of covalently modified reduced graphene oxide based on dinuclear cobalt complex. Compos Part B-Eng 162:569–57910.1016/j.compositesb.2019.01.032 ↗
15. Zhang N, Liu X, Huang Y, Wang M, Li S, Zong M, Liu P (2019) Novel nanocomposites of cobalt ferrite covalently-grafted on graphene by amide bond as superior electromagnetic wave absorber. J Colloid Interface Sci 540:218–22710.1016/j.jcis.2019.01.025 ↗
16. Li D, Zhang B, Liu W, Liang X, Ji G (2017) Tailoring the input impedance of FeCo/C composites with efficient broadband absorption. Dalton Trans 46(43):14926–1493310.1039/C7DT02840G ↗
17. Liu Z, Zhao N, Shi C, He F, Liu E, He C (2019) Synthesis of three-dimensional carbon networks decorated with Fe3O4 nanoparticles as lightweight and broadband electromagnetic wave absorber. J Alloys Compd 776:691–70110.1016/j.jallcom.2018.10.303 ↗
18. Huang B, Yue J, Wei Y, Huang X, Tang X, Du Z (2019) Enhanced microwave absorption properties of carbon nanofibers functionalized by FeCo coatings. Appl Surf Sci 483:98–10510.1016/j.apsusc.2019.03.301 ↗
19. Li X, Feng J, Du Y, Bai J, Fan H, Zhang H, Peng Y, Li F (2015) One-pot synthesis of CoFe2O4/graphene oxide hybrids and their conversion into FeCo/graphene hybrids for lightweight and highly efficient microwave absorber. J Mater Chem A 3(10):5535–554610.1039/C4TA05718J ↗
20. Zeng S, Yao Y, Feng W, Zhang H, Peng S (2020) Constructing a 3D interconnected Fe@graphitic carbon structure for a highly efficient microwave absorber. J Mater Chem C 8(4):1326–133410.1039/C9TC05615G ↗
21. He G, Duan Y, Pang H (2020) Microwave absorption of crystalline Fe/MnO@C nanocapsules embedded in amorphous carbon. Nano-Micro Lett. 12(1):1–1610.1007/s40820-019-0337-2 ↗
22. Liu L, He N, Wu T, Hu P, Tong G (2019) Co/C/Fe/C hierarchical flowers with strawberry-like surface as surface plasmon for enhanced permittivity, permeability, and microwave absorption properties. Chem Eng J 355:103–10810.1016/j.cej.2018.08.131 ↗
23. Zhao Y, Liu L, Han J, Wu W, Tong G (2017) Effective modulation of electromagnetic characteristics by composition and size in expanded graphite/Fe3O4 nanoring composites with high Snoek’s limit. J Alloys Compd 728:100–11110.1016/j.jallcom.2017.08.238 ↗
24. Zhang X, Ji G, Liu W, Quan B, Liang X, Shang C, Cheng Y, Du Y (2015) Thermal conversion of an Fe3O4@metal–organic framework: a new method for an efficient Fe–Co/nanoporous carbon microwave absorbing material. Nanoscale 7(30):12932–1294210.1039/C5NR03176A ↗
25. Qin J, Wang T, Liu D, Liu E, Zhao N, Shi C, He F, Ma L, He C (2018) A top-down strategy toward SnSb in-plane nanoconfined 3D N-doped porous graphene composite microspheres for high performance Na-ion battery anode. Adv Mater 30(9):170467010.1002/adma.201704670 ↗
26. Qin J, Zhang X, Zhao N, Shi C, Liu E-Z, Li J, He C (2015) In situ preparation of interconnected networks constructed by using flexible graphene/Sn sandwich nanosheets for high-performance lithium-ion battery anodes. J Mater Chem A 3(46):23170–2317910.1039/C5TA06550J ↗
27. Chung H-C, Lin Y-T, Lin S-Y, Ho C-H, Chang C-P, Lin M-F (2016) Magnetoelectronic and optical properties of nonuniform graphene nanoribbons. Carbon 109:883–89510.1016/j.carbon.2016.08.091 ↗
28. Sun X, He J, Li G, Tang J, Wang T, Guo Y, Xue H (2013) Laminated magnetic graphene with enhanced electromagnetic wave absorption properties. J Mater Chem C 1(4):765–77710.1039/C2TC00159D ↗
29. Golchinvafa S, Masoudpanah SM, Jazirehpour M (2019) Magnetic and microwave absorption properties of FeCo/CoFe2O4 composite powders. J Alloys Compd 809:15174610.1016/j.jallcom.2019.151746 ↗
30. Xu J, Sun L, Qi X, Wang Z, Fu Q, Pan C (2019) A novel strategy to enhance the multiple interface effect using amorphous carbon packaged hydrogenated TiO2 for stable and effective microwave absorption. J Mater Chem C 7(20):6152–616010.1039/C9TC00483A ↗
31. Fang J, Liu T, Chen Z, Wang Y, Wei W, Yue X, Jiang Z (2016) A wormhole-like porous carbon/magnetic particles composite as an efficient broadband electromagnetic wave absorber. Nanoscale 8(16):8899–890910.1039/C6NR01863G ↗
32. Zhu T, Shen W, Wang X, Song Y-F, Wang W (2019) Paramagnetic CoS2@MoS2 core–shell composites coated by reduced graphene oxide as broadband and tunable high-performance microwave absorbers. Chem Eng J 378:12215910.1016/j.cej.2019.122159 ↗
33. Zare Y, Shams MH, Jazirehpour M (2017) Tuning microwave permittivity coefficients for enhancing electromagnetic wave absorption properties of FeCo alloy particles by means of sodium stearate surfactant. J Alloys Compd 717:294–30210.1016/j.jallcom.2017.05.043 ↗
34. Deng L, Han M (2007) Microwave absorbing performances of multiwalled carbon nanotube composites with negative permeability. Appl Phys Lett 91(2):02311910.1063/1.2755875 ↗
35. Shi X-L, Cao M-S, Yuan J, Fang X-Y (2009) Dual nonlinear dielectric resonance and nesting microwave absorption peaks of hollow cobalt nanochains composites with negative permeability. Appl Phys Lett 95(16):16310810.1063/1.3250170 ↗
36. Shi L, Zhao Y, Li Y, Han X, Zhang T (2017) Octahedron Fe3O4 particles supported on 3D MWCNT/graphene foam: in-situ method and application as a comprehensive microwave absorption material. Appl Surf Sci 416:329–33710.1016/j.apsusc.2017.04.115 ↗
37. Tong G, Liu Y, Cui T, Li Y, Zhao Y, Guan J (2016) Tunable dielectric properties and excellent microwave absorbing properties of elliptical Fe3O4 nanorings. Appl Surf Lett 108(7):07290510.1063/1.4942095 ↗
38. Shu R, Wu Y, Li W, Zhang J, Liu Y, Shi J, Zheng M (2020) Fabrication of ferroferric oxide–carbon/reduced graphene oxide nanocomposites derived from Fe-based metal–organic frameworks for microwave absorption. Compos Sci Technol 196:10824010.1016/j.compscitech.2020.108240 ↗
39. Shu R, Wan Z, Zhang J, Wu Y, Liu Y, Shi J, Zheng M (2020) Facile Design of three-dimensional nitrogen-doped reduced graphene oxide/multi-walled carbon nanotube composite foams as lightweight and highly efficient microwave absorbers. ACS Appl Mater Interfaces 12(4):4689–469810.1021/acsami.9b16134 ↗
40. Shu R, Li W, Wu Y, Zhang J, Zhang G (2019) Nitrogen-doped Co-C/MWCNTs nanocomposites derived from bimetallic metal–organic frameworks for electromagnetic wave absorption in the X-band. Chem Eng J 362:513–52410.1016/j.cej.2019.01.090 ↗
41. Li X, Yin X, Song C, Han M, Xu H, Duan W, Cheng L, Zhang L (2018) Self-assembly core-shell graphene-bridged hollow MXenes spheres 3D foam with ultrahigh specific EM absorption performance. Adv Funct Mater 28(41):180393810.1002/adfm.201803938 ↗
42. Deng LJ, Zhou PH, Xie JL, Zhang L (2007) Characterization and microwave resonance in nanocrystalline FeCoNi flake composite. J Appl Phys 101(10):10391610.1063/1.2733610 ↗
43. Liao Q, He M, Zhou Y, Nie S, Wang Y, Hu S, Yang H, Li H, Tong Y (2018) Highly cuboid-shaped heterobimetallic metal–organic frameworks derived from porous Co/ZnO/C microrods with improved electromagnetic wave absorption capabilities. ACS Appl Mater Interfaces 10(34):29136–2914410.1021/acsami.8b09093 ↗
44. Hou Y, Cheng L, Zhang Y, Yang Y, Deng C, Yang Z, Chen Q, Du X, Zhao C, Zheng L (2018) Enhanced flexibility and microwave absorption properties of HfC/SiC nanofiber mats. ACS Appl Mater Interfaces 10(35):29876–2988310.1021/acsami.8b07980 ↗
45. Lu Y, Wang Y, Li H, Lin Y, Jiang Z, Xie Z, Kuang Q, Zheng L (2015) MOF-derived porous Co/C nanocomposites with excellent electromagnetic wave absorption properties. ACS Appl Mater Interfaces 7(24):13604–1361110.1021/acsami.5b03177 ↗
46. Fu M, Jiao Q, Zhao Y, Li H (2014) Vapor diffusion synthesis of CoFe2O4 hollow sphere/graphene composites as absorbing materials. J Mater Chem A 2(3):735–74410.1039/C3TA14050D ↗
47. Li X, Qu X, Xu Z, Dong W, Wang F, Guo W, Wang H, Du Y (2019) Fabrication of three-dimensional flower-like heterogeneous Fe3O4/Fe particles with tunable chemical composition and microwave absorption performance. ACS Appl Mater Interfaces 11(21):19267–1927610.1021/acsami.9b01783 ↗
48. Lv J, Cheng Y, Liu W, Quan B, Liang X, Ji G, Du Y (2018) Achieving better impedance matching by a sulfurization method through converting Ni into NiS/Ni3S4 composites. J Mater Chem C 6(7):1822–182810.1039/C7TC05503J ↗
49. Qu B, Zhu C, Li C, Zhang X, Chen Y (2016) Coupling hollow Fe3O4–Fe nanoparticles with graphene sheets for high-performance electromagnetic wave absorbing material. ACS Appl Mater Interfaces 8(6):3730–373510.1021/acsami.5b12789 ↗
50. Song Z, Liu X, Sun X, Li Y, Nie X, Tang W, Yu R, Shui J (2019) Alginate-templated synthesis of CoFe/carbon fiber composite and the effect of hierarchically porous structure on electromagnetic wave absorption performance. Carbon 151:36–4510.1016/j.carbon.2019.05.025 ↗
51. Wang Y, Gao X, Wu X, Zhang W, Luo C, Liu P (2019) Facile design of 3D hierarchical NiFe2O4/N-GN/ZnO composite as a high performance electromagnetic wave absorber. Chem Eng J 375:12194210.1016/j.cej.2019.121942 ↗
52. Wang Y, Di X, Gao X, Wu X, Wang P (2020) Rational construction of Co@C polyhedrons covalently-grafted on magnetic graphene as a superior microwave absorber. J Alloys Compd 843:15603110.1016/j.jallcom.2020.156031 ↗
53. Wang Y, Gao X, Lin C, Shi L, Li X, Wu G (2019) Metal organic frameworks-derived Fe–Co nanoporous carbon/graphene composite as a high-performance electromagnetic wave absorber. J Alloys Compd 785:765–77310.1016/j.jallcom.2019.01.271 ↗
54. Shahzad F, Alhabeb M, Hatter CB, Anasori B, Hong SM, Koo CM, Gogotsi Y (2016) Electromagnetic interference shielding with 2D transition metal carbides (MXenes). Science 353(6304):113710.1126/science.aag2421 ↗
55. Zhang T, Zhang J, Wen G, Zhong B, Xia L, Huang X, Zhao H, Wang H, Qin L (2018) Ultra-light h-BCN architectures derived from new organic monomers with tunable electromagnetic wave absorption. Carbon 136:345–35810.1016/j.carbon.2018.05.001 ↗