journal article·2015-03

Structural features, properties, and relaxations of PMMA-ZnO nanocomposite

Marta Dai Prè, Alessandro Martucci, Darren J. Martin, Sandra Lavina, Vito Di Noto

Journal of Materials Science· Volume 50· Issue 5
Publisher page

Abstract

ZnO nanoparticles are recently attracting a lot of interest due to their novel optical, electrical, mechanical, and chemical properties, due to surface and quantum confinement effects. A stable dispersion of ZnO nanoparticles with a uniform particle diameter of 5 nm has been synthesized via chemical precipitation. The surface of the particles has been functionalized with dodecanethiol for enhanced compatibility and dispersion in polymethylmethacrylate (PMMA). Transparent luminescent nanocomposite powders were obtained using solution mixing and solvent casting of ZnO nanoparticles in PMMA. This powder was used to produce injection-molded luminescent nanocomposites plaques. The effect of the ZnO nanoparticles on the polymer structure has been investigated by employing thermomechanical and dielectric spectroscopy analyses.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Polymer Nanocomposite Synthesis and Irradiation · ZnO doping and properties · Silicone and Siloxane Chemistry

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (21)

Show source-provided references
1. Sun D, Miyatake N, Sue HJ (2007) Transparent PMMA/ZnO nanocomposite films based on colloidal ZnO quantum dots. Nanotechnology 18:15606
2. Zeng H, Duan G, Li Y, Yang S, Xu X, Cai W (2010) Blue luminescence of ZnO nanoparticles based on non-equilibrium processes: defect origins and emission controls. Adv Funct Mater 20:561–57210.1002/adfm.200901884 ↗
3. Wang ZL (2004) Zinc oxide nanostructures: growth, properties and applications. J Phys 16:R829–R858
4. Djurisic AB, Leung YH (2006) Optical properties of ZnO nanostructures. Small 2:944–96110.1002/smll.200600134 ↗
5. Law M, Greene LE, Johnson JC, Saykally R, Yang P (2005) Nanowire dye-sensitized solar cells. Nat Mater 4:455–45910.1038/nmat1387 ↗
6. Suh DI, Lee SY, Hyung JH, Kim TH, Lee SK (2008) Multiple ZnO nanowires field- effect transistors. J Phys Chem C 112:12761281
7. Wang XD, Song JH, Liu J, Wang ZL (2007) Direct-current nanogenerator driven by ultrasonic waves. Science 316:102–10510.1126/science.1139366 ↗
8. Barreca D, Ferrucci AP, Gasparotto A, Maccato C, Maragno C, Tondello E (2007) Temperature-controlled synthesis and photocatalytic performance of ZnO nanoplatelets. Chem Vap Depos 13:618–62510.1002/cvde.200706594 ↗
9. Demir MM, Memesa M, Castignolles P, Wegner G (2006) PMMA/Zinc oxide nanocomposites prepared by in situ bulk polymerization. Macromol Rapid Commun 27:763–77010.1002/marc.200500870 ↗
10. Thakur VK, Thunga M, Madbouly SA, Kessler MK (2014) PMMA-g-SOY as a sustainable novel dielectric material. RSC Adv 4:6677–668410.1039/c3ra46592f ↗
11. Guglieri C, Chaboy J (2010) Characterization of the ZnO–ZnS interface in THIOL-capped ZnO nanoparticles exhibiting anomalous magnetic properties. J Phys Chem C 114:19629–1963410.1021/jp1074303 ↗
12. Li S, Toprak MS, Jo YS, Dobson J, Kim DK, Muhammed M (2007) Bulk synthesis of transparent and homogeneous polymeric hybrid materials with ZnO quantum dots and PMMA. Adv Mater 19:4347–435210.1002/adma.200700736 ↗
13. Brandrup J, Immergut EH, Grulke EA, Abe A, Bloch DR (1999) Polymer handbook, 4th edn. Wiley, New York
14. Ngai KL, Gopalakrishnan TR, Beiner M (2006) Relaxation in poly(alkyl methacrylate)s: change of intermolecular coupling with molecular structure, tacticity, molecular weight, copolymerization, crosslinking, and nanoconfinement. Polymer 47:7222–723010.1016/j.polymer.2006.06.072 ↗
15. Di Noto V, Giffin GA, Vezzù K, Piga M, Lavina S (2012) Broadband dielectric spectroscopy: a powerful tool for the determination of charge transfer mechanisms in ion conductors. In: Knauth P, Di Vona ML (Eds) Solid state proton conductors: properties and applications in fuel cells. Wiley, Weinheim, pp. 107–18010.1002/9781119962502.ch5 ↗
16. Gross S, Camozzo D, Di Noto V, Armelao L, Tondello E (2007) PMMA: a key macromolecular component for dielectric low-κ hybrid inorganic–organic polymer films. Eur Polym J 43:673–69610.1016/j.eurpolymj.2006.12.012 ↗
17. Schmidt-Rohr K, Kulik AS, Beckham HW, Ohlemacher A, Pawelzik U, Boeffel C, Spiess HW (1994) Molecular nature of the beta relaxation in poly(methyl methacrylate) investigated by multidimensional NMR. Macromolecules 27:4733–474510.1021/ma00095a014 ↗
18. Wind M, Graf R, Renker S, Spiess HW (2005) Structural reasons for restricted backbone motion in poly(n-alkyl methacrylates): degree of polymerization, tacticity and side-chain length. Macromol Chem Phys 206:142–15610.1002/macp.200400219 ↗
19. Barsoukov E, Macdonald JR (2005) impedance spectroscopy theory, experiment, and applications, 2nd edn. Wiley, New York10.1002/0471716243 ↗
20. Di Noto V, Barreca D, Furlan C, Armelao L (2000) Zeolitic inorganic-organic polymer electrolytes: a material based on poly(ethylene glycol) 600, SnCl4 and K4Fe(CN)6. Polym Adv Technol 11:108–12110.1002/1099-1581(200003)11:3<108::AID-PAT952>3.0.CO;2-A ↗
21. Fuchs K, Friedrich Chr, Weese J (1996) Viscoelastic properties of narrow-distribution poly(methyl methacrylates). Macromolecules 29:5893–590110.1021/ma951385m ↗