journal article·2017-06

Nitrogen-doped multiwalled carbon nanotubes decorated with copper(I) oxide nanoparticles with enhanced capacitive properties

Muhammad Aniq Shazni Mohammad Haniff, Syed Muhammad Hafiz, Khairul Anuar Wahid, Zulkarnain Endut, Mohd Ismahadi Syono, Nay Ming Huang, Saadah Abd Rahman, Ishak Abd Azid

Journal of Materials Science· Volume 52· Issue 11
Publisher page

Abstract

We report on the enhanced capacitive properties of a copper(I) oxide nanoparticle (Cu2O NP)-decorated multiwalled carbon nanotube (MWCNT) forest with nitrogen (N) doping. A careful in situ solid-state dewetting and plasma doping method was developed that ensured homogeneous decoration and contamination-free Cu2O NPs with N doping on the nanotube sidewalls. The morphology and structure of the hybrid materials were characterised by scanning electron microscopy, transmission electron microscopy, energy-dispersive spectroscopy, Raman spectroscopy and X-ray photoemission spectroscopy. The electrochemical performance of the hybrid materials was investigated by cyclic voltammetry and galvanostatic charge/discharge tests in a 0.1 M Na2SO4 electrolyte. The electrochemical tests demonstrated that the Cu2O NP/N-MWCNT electrode exhibits a specific capacitance up to 132.2 F g−1 at a current density of 2.5 A g−1, which is 30% higher than that of the pure MWCNT electrode. Furthermore, the electrode could retain the specific capacitance at 85% stability over 1000 cycles. These observations along with the simple assembly method for the hybrid materials suggest that the Cu2O NP/N-MWCNT could be a promising electrode for supercapacitor applications.
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Research context

OpenAlex topics: Supercapacitor Materials and Fabrication · Advancements in Battery Materials · Advanced battery technologies research

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (37)

Show source-provided references
1. Zhang LL, Zhao XS (2009) Carbon-based materials as supercapacitor electrodes. Chem Soc Rev 38:2520–253110.1039/b813846j ↗
2. Chen T, Dai L (2013) Carbon materials for high-performance supercapacitors. Mater Today 16(7–8):272–28010.1016/j.mattod.2013.07.002 ↗
3. Futaba DN, Hata K, Yamada T, Hiraoka T, Hiyamizu Y, Kakudate Y, Tanaike O, Hatori H, Yumura M, Iijima S (2006) Shape-engineerable and highly densely packed single-walled carbon nanotubes and their application as super-capacitor electrodes. Nat Mater 5:987–99410.1038/nmat1782 ↗
4. Kim Y-T, Ito Y, Tadai K, Mitani T, Kim U-S, Kim H-Y, Cho B-W (2005) Drastic change of electrical double layer capacitance by surface functionalization of carbon nanotubes. Appl Phys Lett 87:23410610.1063/1.2139839 ↗
5. Hussain S, Amade R, Jover E, Bertran E (2013) Nitrogen plasma functionalization of carbon nanotubes for supercapacitor applications. J Mater Sci 48:7620–7628. doi: 10.1007/s10853-013-7579-z10.1007/s10853-013-7579-z ↗
6. Gueon D, Moon JH (2015) Nitrogen doped carbon nanotube spherical particles for supercapacitor applications: emulsion-assisted compact packing and capacitance enhancement. ACS Appl Mater Interfaces 7(36):20083–2008910.1021/acsami.5b05231 ↗
7. Mashayekhi A, Hosseini SM, Amiri MH, Namdar N, Sanaee Z (2016) Plasma-assisted nitrogen doping of VACNTs for efficiently enhancing the supercapacitor performance. J Nanopart Res 18:15410.1007/s11051-016-3470-6 ↗
8. Bi R-R, Wu X-L, Cao F-F, Jiang L-Y, Guo Y-G, Wan L-J (2010) Highly dispersed RuO2 nanoparticles on carbon nanotubes: facile synthesis and enhanced supercapacitance performance. J Phys Chem 114(6):2448–2451
9. Hu L, Chen W, Xie X, Liu N, Yang Y, Wu H, Yao Y, Pasta M, Alshareef HN, Cui Y (2011) Symmetrical MnO2-carbon nanotube-textile nanostructure for wearable pseudocapacitors with high mass loading. ACS Nano 5(11):8904–891310.1021/nn203085j ↗
10. Wang Q, Wen ZH, Li JH (2006) A hybrid supercapacitor fabricated with a carbon nanotube cathode and a TiO2-B nanowire anode. Adv Funct Mater 16(16):2141–214610.1002/adfm.200500937 ↗
11. Cheng K, Zhao B, Zhang W, Shi F, Zheng G, Zhang D, Yang J (2015) High-performance supercapacitor applications of NiO-nanoparticle-decorated millimeter-long vertical aligned carbon nanotube arrays via an effective supercritical CO2-assisted method. Adv Funct Mater 25(47):7381–739110.1002/adfm.201502711 ↗
12. Zhang X, Shi W, Zhu J, Kharistal DJ, Zhao W, Lalia BS, Hng HH, Yan Q (2011) High-power and high-energy-density flexible pseudocapacitor electrodes made from porous CuO nanobelts and single-walled carbon nanotubes. ACS Nano 5(3):2011–2013
13. Sathiya M, Prakash AS, Ramesha K, Tarascon J-M, Shuklas AK (2011) V2O5-anchored carbon nanotubes for enhanced electrochemical energy storage. J Am Chem Soc 133(40):16291–1629910.1021/ja207285b ↗
14. Zhou Y, Qin Z-Y, Li L, Zhang Y, Wei Y-L, Wang L-Fe, Zhu M-F (2010) Polyaniline/multi-walled carbon nanotube composites with core-shell structures as supercapacitor electrode materials. Electrochim Acta 55(12):3904–390810.1016/j.electacta.2010.02.022 ↗
15. Chen S, Zhitomirsky I (2014) Polypyrrole coated carbon nanotubes for supercapacitors, prepared using indigo carmine as a dispersant and dopant. Mater Lett 135:47–5010.1016/j.matlet.2014.07.113 ↗
16. Béguin F, Szostak K, Lota G, Frackowiak E (2005) A self-supporting electrode for supercapacitors prepared by one-step pyrolysis of carbon nanotube/polyacrylonitrile bends. Adv Mater 17(19):2380–238410.1002/adma.200402103 ↗
17. Xu P, Liu J, Liu T, Ye K, Cheng K, Yin J, Cao D, Wang G, Li Q (2016) Preparation of binder-free of CuO/Cu2O/Cu composites: a novel electrode material for supercapacitor applications. RSC Adv 6:28270–2827810.1039/C6RA00004E ↗
18. Kecsenovity E, Endrődi B, Zs Pápa, Hernádi K, Rajeshwar K, Janáky C (2016) Decoration of ultralong carbon nanotubes with Cu2O nanocrystals: a hybrid platform for enhanced photoelectrochemical CO2 reduction. J Mater Chem A 4:3139–314710.1039/C5TA10457B ↗
19. Chen L, Yu Z, Zhu P, Zhou F, Zeng W, Lu DD, Sun R, Wong C (2015) Copper salts mediated morphological transformation of Cu2O from cubes to hierarchical flower-like or microspheres and their supercapacitors performance. Sci Rep 5:967210.1038/srep09672 ↗
20. Kumar R, Rai P, Sharma A (2016) Facile synthesis of Cu2O microstructures and their morphology dependent electrochemical supercapacitor properties. RSC Adv 6:3815–382210.1039/C5RA20331G ↗
21. Venables JA, Spiller GDT, Hanbucken M (1984) Nucleation and growth of thin films. Rep Prog Phys 47(4):39910.1088/0034-4885/47/4/002 ↗
22. Muratore C, Reed AN, Bultman JE, Ganguli S, Cola BA, Veovodin AA (2013) Nanoparticle decoration of carbon nanotubes by sputtering. Carbon 57:274–28110.1016/j.carbon.2013.01.074 ↗
23. Zhong GF, Iwasaki T, Kawarada H (2006) Semi-quantitative study on the fabrication of densely packed and vertically aligned single-walled carbon nanotubes. Carbon 44:2009–201410.1016/j.carbon.2006.01.027 ↗
24. Dresselhaus MS, Jorio A, Hofmann M, Dresselhaus G, Saito R (2010) Perspective on carbon nanotubes and graphene Raman spectroscopy. Nano Lett 10(3):751–75810.1021/nl904286r ↗
25. Okpalugo TIT, Papakonstantinou P, Murphy H, McLaughlin J, Brown NMD (2005) High resolution XPS characterization of chemical functionalized MWCNTs and SWCNTs. Carbon 43:153–16110.1016/j.carbon.2004.08.033 ↗
26. Li S-S, Cong HP, Wang P, Yu SH (2014) Flexible nitrogen-doped graphene/carbon nanotube/Co3O4 paper and its oxygen reduction activity. Nanoscale 6:7534–754110.1039/C4NR02101K ↗
27. Liu H, Zhang Y, Li R, Sun X, Désilets S, Abou-Rachid H, Jaidann M, Lussier LS (2010) Structural and morphological control of aligned nitrogen doped carbon nanotubes. Carbon 48:1498–150710.1016/j.carbon.2009.12.045 ↗
28. Ionescu MI, Zhang Y, Li R, Abou-Rachid H, Sun X (2012) Nitrogen-doping effects on the growth, structure and electrical performance of carbon nanotubes obtained by spray pyrolysis method. Appl Surf Sci 258(10):4563–456810.1016/j.apsusc.2012.01.028 ↗
29. Biesinger MC, Lau LWM, Gerson AR, Smart RSC (2010) Resolving surface chemical states in XPS analysis of first row transition metals, oxides, and hydroxides: Sc, Ti, V, Cu and Zn. Appl Surf Sci 257(3):887–89810.1016/j.apsusc.2010.07.086 ↗
30. Nwanya AC, Obi D, Ozoemena KI, Osuji RU, Awada C, Ruidiger A, Maaza M, Rosei F, Ezema FI (2016) Facile synthesis of nanosheet-like CuO film and its potential application as a high-performance pseudocapacitor electrode. Electrochim Acta 198:220–23010.1016/j.electacta.2016.03.064 ↗
31. Seredych M, Hulicova-Jurcakova D, Lu GQ, Bandosz TJ (2008) Surface functional groups of carbons and the effects of their chemical character, density and accessibility to ions on electrochemical performance. Carbon 46:1475–148810.1016/j.carbon.2008.06.027 ↗
32. Hulicova-Jurcakova D, Seredych M, Lu GQ, Bandosz TJ (2009) Combined effect of nitrogen-and oxygen-containing functional groups of microporous activated carbon on its electrochemical performance in supercapacitors. Adv Funct Mater 19(3):438–44710.1002/adfm.200801236 ↗
33. Patake VD, Joshi SS, Lokhande CD, Joo O-S (2009) Electrodeposited porous and amorphous copper oxide film for application in supercapacitor. Mater Chem Phys 114:6–910.1016/j.matchemphys.2008.09.031 ↗
34. Dubai DP, Dhawale DS, Salunkhe RR, Jamdade VS, Lokhande CD (2010) Fabrication of copper oxide multilayer nanosheets for supercapacitor application. J Alloy Compd 492:26–3010.1016/j.jallcom.2009.11.149 ↗
35. Zhang YX, Kuang M, Huang M, Wen ZQ (2013) Comparative study of carbon black and multi-walled carbon nanotubes as conductive additives on electrochemical performance of branched CuO nanostructures. Int J Electrochem Sci 8:9723–973310.1016/S1452-3981(23)13006-9 ↗
36. Chen P, Chen H, Qiu J, Zhou C (2010) Inkjet printing of single-walled carbon nanotube/RuO2 nanowire supercapacitors on cloth fabrics and flexible substrates. Nano Res 3(8):594–60310.1007/s12274-010-0020-x ↗
37. Reddy ALM, Ramaprabhu S (2007) Nanocrystalline metal oxides dispersed multiwalled carbon nanotubes as supercapacitor electrodes. J Phys Chem C 111:7727–773410.1021/jp069006m ↗