Enhanced removal capability of kaolin toward methylene blue by mussel-inspired functionalization
Source abstract
Abstract
Adsorption is an effective and commonly adopted method for removal of organic pollutants from environment. In this work, we described the synthesis and the adsorption behavior of poly(sodium p-styrenesulfonate hydrate) (PSPSH)-modified kaolin, which was obtained by combination of mussel-inspired chemistry and Michael addition reaction. The amino-terminated PSPSH was synthesized by free radical polymerization using cysteamine hydrochloride as the chain transfer agent and sodium p-styrenesulfonate hydrate as the monomer. Raw kaolin and PSPSH-modified kaolin were characterized using several techniques including transmission electron microscopy, Fourier transform infrared spectroscopy, thermal gravimetric analysis, and X-ray photoelectron spectroscopy in detail. The adsorption of methylene blue onto modified kaolin from aqueous solution was investigated, in which the effects of contact time, temperature, solution pH, and initial methylene blue concentration were studied. The experiment data were analyzed using two common adsorption models: Langmuir and Freundlich isotherm models. The kinetic adsorption data were analyzed using pseudo-first-order, pseudo-second-order, and intraparticle diffusion model. The values of thermodynamics constants such as entropy change (ΔS 0), enthalpy change (ΔH 0) and Gibbs free energy (ΔG 0) were also determined. The modified kaolin showed favorable dispersibility and convenient separation, high efficiency, and good regeneration capability in the removal of methylene blue from solution.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Adsorption and biosorption for pollutant removal · Analytical chemistry methods development · Carbon and Quantum Dots Applications
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (59)
Show source-provided references
1. Crini G (2006) Non-conventional low-cost adsorbents for dye removal: a review. Bioresour Technol 97:106110.1016/j.biortech.2005.05.001 ↗
2. Yu B, Zhang X, Xie J, Wu R, Liu X, Li H, Chen F, Yang H, Ming Z, Yang S-T (2015) Magnetic graphene sponge for the removal of methylene blue. Appl Surf Sci 351:76510.1016/j.apsusc.2015.05.185 ↗
3. Cheung W, Szeto Y, McKay G (2009) Enhancing the adsorption capacities of acid dyes by chitosan nano particles. Bioresour Technol 100:114310.1016/j.biortech.2008.07.071 ↗
4. Huang J-H, Zhou C-F, Zeng G-M, Li X, Niu J, Huang H-J, Shi L-J, He S-B (2010) Micellar-enhanced ultrafiltration of methylene blue from dye wastewater via a polysulfone hollow fiber membrane. J Membr Sci 365:13810.1016/j.memsci.2010.08.052 ↗
5. Liu X, Zhou Y, Nie W, Song L, Chen P (2015) Fabrication of hydrogel of hydroxypropyl cellulose (HPC) composited with graphene oxide and its application for methylene blue removal. J Mater Sci 50:6113. doi: 10.1007/s10853-015-9166-y10.1007/s10853-015-9166-y ↗
6. Singaravel GP, Hashaikeh R (2016) Fabrication of electrospun LTL zeolite fibers and their application for dye removal. J Mater Sci 51:1133. doi: 10.1007/s10853-015-9444-810.1007/s10853-015-9444-8 ↗
7. Li Y, Xiao H, Chen M, Song Z, Zhao Y (2014) Absorbents based on maleic anhydride-modified cellulose fibers/diatomite for dye removal. J Mater Sci 49:6696. doi: 10.1007/s10853-014-8270-810.1007/s10853-014-8270-8 ↗
8. Parmar KR, Patel I, Basha S, Murthy Z (2014) Synthesis of acetone reduced graphene oxide/Fe3O4 composite through simple and efficient chemical reduction of exfoliated graphene oxide for removal of dye from aqueous solution. J Mater Sci 49:6772. doi: 10.1007/s10853-014-8378-x10.1007/s10853-014-8378-x ↗
9. Kołodyńska D, Kowalczyk M, Hubicki Z (2014) Evaluation of iron-based hybrid materials for heavy metal ions removal. J Mater Sci 49:2483. doi: 10.1007/s10853-013-7944-y10.1007/s10853-013-7944-y ↗
10. Lei Y, Chen F, Luo Y, Zhang L (2014) Three-dimensional magnetic graphene oxide foam/Fe3O4 nanocomposite as an efficient absorbent for Cr(VI) removal. J Mater Sci 49:4236. doi: 10.1007/s10853-014-8118-210.1007/s10853-014-8118-2 ↗
11. Ai L, Jiang J (2012) Removal of methylene blue from aqueous solution with self-assembled cylindrical graphene–carbon nanotube hybrid. Chem Eng J 192:15610.1016/j.cej.2012.03.056 ↗
12. Han R, Ding D, Xu Y, Zou W, Wang Y, Li Y, Zou L (2008) Use of rice husk for the adsorption of congo red from aqueous solution in column mode. Bioresour Technol 99:293810.1016/j.biortech.2007.06.027 ↗
13. Gupta VK, Mittal A, Jain R, Mathur M, Sikarwar S (2006) Adsorption of Safranin-T from wastewater using waste materials—activated carbon and activated rice husks. J Colloid Interf Sci 303:8010.1016/j.jcis.2006.07.036 ↗
14. Wu Y, Zhang L, Gao C, Ma J, Ma X, Han R (2009) Adsorption of copper ions and methylene blue in a single and binary system on wheat straw. J Chem Eng Data 54:322910.1021/je900220q ↗
15. Suteu D, Bilba D (2005) Equilibrium and kinetic study of reactive dye Brilliant Red HE-3B adsorption by activated charcoal. Acta Chim Slov 52:73
16. Iqbal MJ, Ashiq MN (2007) Adsorption of dyes from aqueous solutions on activated charcoal. J Hazard Mater 139:5710.1016/j.jhazmat.2006.06.007 ↗
17. Suteu D, Nacu A, Cristian G (2001) Removal of methyl violet triphenyl methanic dye using ion exchange celluloses. Cell Chem Technol 35:451
18. Abdullah AL, Salleh MM, Mazlina MS, Noor MMM, Osman M, Wagiran R, Sobri S (2005) Azo dye removal by adsorption using waste biomass: sugarcane bagasse. Int J Eng Technol 2:8
19. Filipkowska U, Klimiuk E, Grabowski S, Siedlecka E (2002) Adsorption of reactive dyes by modified chitin from aqueous solutions. Pol J Environ Stud 11:315
20. Nandi B, Goswami A, Purkait M (2009) Adsorption characteristics of brilliant green dye on kaolin. J Hazard Mater 161:38710.1016/j.jhazmat.2008.03.110 ↗
21. Ghosh D, Bhattacharyya KG (2002) Adsorption of methylene blue on kaolinite. Appl Clay Sci 20:29510.1016/S0169-1317(01)00081-3 ↗
22. Vágvölgyi V, Kovács J, Horváth E, Kristóf J, Makó É (2008) Investigation of mechanochemically modified kaolinite surfaces by thermoanalytical and spectroscopic methods. J Colloid Interf Sci 317:52310.1016/j.jcis.2007.09.085 ↗
23. Waite JH, Housley TJ, Tanzer ML (1985) Peptide repeats in a mussel glue protein: theme and variations. Biochemistry 24:501010.1021/bi00340a008 ↗
24. Lee H, Dellatore SM, Miller WM, Messersmith PB (2007) Mussel-inspired surface chemistry for multifunctional coatings. Science 318:42610.1126/science.1147241 ↗
25. Fei B, Qian B, Yang Z, Wang R, Liu W, Mak C, Xin JH (2008) Coating carbon nanotubes by spontaneous oxidative polymerization of dopamine. Carbon 46:179510.1016/j.carbon.2008.06.049 ↗
26. Zhao Z, Li J, Wen T, Shen C, Wang X, Xu A (2015) Surface functionalization graphene oxide by polydopamine for high affinity of radionuclides. Colloid Surface A 482:258–26610.1016/j.colsurfa.2015.05.020 ↗
27. Han L, Wang Z-M, Lu X, Dong L, Xie C-M, Wang K-F, Chen X-L, Ding Y-H, Weng L-T (2015) Mussel-inspired adhesive and transferable free-standing films by self-assembling dexamethasone encapsulated BSA nanoparticles and vancomycin immobilized oxidized alginate. Colloid Surface B 126:45210.1016/j.colsurfb.2014.12.050 ↗
28. Zhang X, Huang Q, Liu M, Tian J, Zeng G, Li Z, Wang K, Zhang Q, Wan Q, Deng F (2015) Preparation of amine functionalized carbon nanotubes via a bioinspired strategy and their application in Cu 2+removal. Appl Surf Sci 343:1910.1016/j.apsusc.2015.03.081 ↗
29. Zhang X, Fu C, Feng L, Ji Y, Tao L, Huang Q, Li S, Wei Y (2012) PEGylation and polyPEGylation of nanodiamond. Polymer 53:317810.1016/j.polymer.2012.05.029 ↗
30. Zhang X, Ji J, Zhang X, Yang B, Liu M, Liu W, Tao L, Chen Y, Wei Y (2013) Mussel inspired modification of carbon nanotubes using RAFT derived stimuli-responsive polymers. RSC Adv 3:2181710.1039/c3ra44277b ↗
31. Zhang X, Liu M, Zhang X, Deng F, Zhou C, Hui J, Liu W, Wei Y (2015) Interaction of tannic acid with carbon nanotubes: enhancement of dispersibility and biocompatibility. Toxicol Res 4:16010.1039/C4TX00066H ↗
32. Zhang X, Liu M, Zhang Y, Yang B, Ji Y, Feng L, Tao L, Li S, Wei Y (2012) Combining mussel-inspired chemistry and the michael addition reaction to disperse carbon nanotubes. RSC Adv 2:1215310.1039/c2ra22011c ↗
33. Zhang X, Wang K, Liu M, Zhang X, Tao L, Chen Y, Wei Y (2015) Polymeric AIE-based nanoprobes for biomedical applications: recent advances and perspectives. Nanoscale 7(27):11486–1150810.1039/C5NR01444A ↗
34. Wan Q, Liu M, Tian J, Deng F, Zeng G, Li Z, Wang K, Zhang Q, Zhang X, Wei Y (2015) Surface modification of carbon nanotubes by combination of mussel inspired chemistry and SET-LRP. Polym Chem 6:178610.1039/C4PY01565G ↗
35. Wan Q, Mao L, Liu M, Wang K, Zeng G, Xu D, Huang H, Zhang X, Wei Y (2015) Towards development of a versatile and efficient strategy for fabrication of GO based polymer nanocomposites. Polym Chem 6:721110.1039/C5PY01238D ↗
36. Shi Y, Liu M, Wang K, Deng F, Wan Q, Huang Q, Fu L, Zhang X, Wei Y (2015) Bioinspired preparation of thermo-responsive graphene oxide nanocomposites in an aqueous solution. Polym Chem 6:587610.1039/C5PY00844A ↗
37. Tian J, Zhang H, Liu M, Deng F, Huang H, Wan Q, Li Z, Wang K, He X, Zhang X (2015) A bioinspired strategy for surface modification of silica nanoparticles. Appl Surf Sci 357:199610.1016/j.apsusc.2015.09.171 ↗
38. Wan Q, Tian J, Liu M, Zeng G, Huang Q, Wang K, Zhang Q, Deng F, Zhang X, Wei Y (2015) Surface modification of carbon nanotubes via combination of mussel inspired chemistry and chain transfer free radical polymerization. Appl Surf Sci 346:33510.1016/j.apsusc.2015.04.012 ↗
39. Zhang X, Zeng G, Tian J, Wan Q, Huang Q, Wang K, Zhang Q, Liu M, Deng F, Wei Y (2015) PEGylation of carbon nanotubes via mussel inspired chemistry: preparation, characterization and biocompatibility evaluation. Appl Surf Sci 351:42510.1016/j.apsusc.2015.05.160 ↗
40. Tian J, Xu D, Liu M, Deng F, Wan Q, Li Z, Wang K, He X, Zhang X, Wei Y (2015) Marrying mussel inspired chemistry with SET-LRP: a novel strategy for surface functionalization of carbon nanotubes. J Polym Sci A Polym Chem 53:187210.1002/pola.27638 ↗
41. Zhang X, Wang S, Xu L, Ji Y, Feng L, Tao L, Li S, Wei Y (2012) Biocompatible polydopamine fluorescent organic nanoparticles: facile preparation and cell imaging. Nanoscale 4:558110.1039/c2nr31281f ↗
42. Cao Y, Zhang X, Tao L, Li K, Xue Z, Feng L, Wei Y (2013) Mussel-inspired chemistry and michael addition reaction for efficient oil/water separation. ACS Appl Mater Interf 5:443810.1021/am4008598 ↗
43. Xu L, Liu N, Cao Y, Lu F, Chen Y, Zhang X, Feng L, Wei Y (2014) Mercury ion responsive wettability and oil water separation. ACS Appl Mater Interf 6:1332410.1021/am5038214 ↗
44. Wan Q, Liu M, Tian J, Deng F, Dai Y, Wang K, Li Z, Zhang Q, Zhang X, Wei Y (2015) Toward the development of versatile functionalized carbon nanotubes. RSC Adv 5:3831610.1039/C4RA17292B ↗
45. Wan Q, Tian J, Liu M, Zeng G, Li Z, Wang K, Zhang Q, Deng F, Zhang X, Wei Y (2015) Mussel inspired preparation of highly dispersible and biocompatible carbon nanotubes. RSC Adv 5:2532910.1039/C4RA13408G ↗
46. Xie Y, He C, Liu L, Mao L, Wang K, Huang Q, Liu M, Wan Q, Deng F, Huang H (2015) Carbon nanotube based polymer nanocomposites: biomimic preparation and organic dye adsorption applications. RSC Adv 5:8250310.1039/C5RA15626B ↗
47. Xie Y, Huang Q, Liu M, Wang K, Wan Q, Deng F, Lu L, Zhang X, Wei Y (2015) Mussel inspired functionalization of carbon nanotubes for heavy metal ion removal. RSC Adv 5:6843010.1039/C5RA08908E ↗
48. Liu M, Ji J, Zhang X, Zhang X, Yang B, Deng F, Li Z, Wang K, Yang Y, Wei Y (2015) Self-polymerization of dopamine and polyethyleneimine: novel fluorescent organic nanoprobes for biological imaging applications. J Mater Chem B 3:347610.1039/C4TB02067G ↗
49. Nandi B, Goswami A, Purkait M (2009) Removal of cationic dyes from aqueous solutions by kaolin: kinetic and equilibrium studies. Appl Clay Sci 42:58310.1016/j.clay.2008.03.015 ↗
50. Darwish IA, Blake DA (2002) Development and validation of a one-step immunoassay for determination of cadmium in human serum. Anal Chem 74:5210.1021/ac010510r ↗
51. Vimonses V, Lei S, Jin B, Chow CW, Saint C (2009) Adsorption of congo red by three Australian kaolins. Appl Clay Sci 43:46510.1016/j.clay.2008.11.008 ↗
52. Yao Y, Bing H, Feifei X, Xiaofeng C (2011) Equilibrium and kinetic studies of methyl orange adsorption on multiwalled carbon nanotubes. Chem Eng J 170:8210.1016/j.cej.2011.03.031 ↗
53. Hoda N, Bayram E, Ayranci E (2006) Kinetic and equilibrium studies on the removal of acid dyes from aqueous solutions by adsorption onto activated carbon cloth. J Hazard Mater 137:34410.1016/j.jhazmat.2006.02.009 ↗
54. Tan I, Ahmad AL, Hameed B (2008) Adsorption of basic dye on high-surface-area activated carbon prepared from coconut husk: equilibrium, kinetic and thermodynamic studies. J Hazard Mater 154:33710.1016/j.jhazmat.2007.10.031 ↗
55. Annadurai G, Ling LY, Lee J-F (2008) Adsorption of reactive dye from an aqueous solution by chitosan: isotherm, kinetic and thermodynamic analysis. J Hazard Mater 152:33710.1016/j.jhazmat.2007.07.002 ↗
56. Sun D, Zhang X, Wu Y, Liu X (2010) Adsorption of anionic dyes from aqueous solution on fly ash. J Hazard Mater 181:33510.1016/j.jhazmat.2010.05.015 ↗
57. Rauf M, Bukallah S, Hamour F, Nasir A (2008) Adsorption of dyes from aqueous solutions onto sand and their kinetic behavior. Chem Eng J 137:23810.1016/j.cej.2007.04.025 ↗
58. Gobi K, Mashitah M, Vadivelu V (2011) Adsorptive removal of Methylene Blue using novel adsorbent from palm oil mill effluent waste activated sludge: equilibrium, thermodynamics and kinetic studies. Chem Eng J 171:124610.1016/j.cej.2011.05.036 ↗
59. Wang P, Cao M, Wang C, Ao Y, Hou J, Qian J (2014) Kinetics and thermodynamics of adsorption of methylene blue by a magnetic graphene-carbon nanotube composite. Appl Surf Sci 290:11610.1016/j.apsusc.2013.11.010 ↗