Conjugated microporous polymer-based carbazole derivatives as fluorescence chemosensors for picronitric acid
Source abstract
Abstract
The fluorescent-conjugated microporous polymer-based carbazole derivatives (DCZP and DCZN) have been successfully synthesized by palladium-catalyzed Sonogashira–Hagihara cross-coupling of 1,3,6,8-tetrabromo-9H-carbazole and 1,4-diethynylbenzene monomers using both solution polymerization and miniemulsion polymerization. The resultant DCZP and DCZN are provided with a large BET surface area of over 688 and 97 m2 g−1 with a pore volume of 0.43 and 0.15 cm3 g−1, and the pore distributions are concentrated at around 1.65, 3.82 and 1.99, 2.33 nm. The polymers, especially DCZN, display strong fluorescent emission by excitation at 365 nm in THF suspension and exhibit a high sensitive to picronitric acid, indicating that the three-dimensional π-conjugated polymer frameworks combined with permanent microporous and fluorescent properties make these polymers utilized as sensors for nitroaromatics detection.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Covalent Organic Framework Applications · Metal-Organic Frameworks: Synthesis and Applications · Luminescence and Fluorescent Materials
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (76)
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