Discussion on the influence of DES content in CA-based polymer electrolytes
Source abstract
Abstract
The degree of crystallinity in the matrix formed by cellulose acetate (CA) and lithium bis(trifluoromethanesulfonyl)imide (LiTFSI) were reduced by embedding with deep eutectic solvent (DES) which is a type of ionic mixture synthesized from choline chloride and urea in a specific ratio. The fabrications of thin films were done by solution casting technique. The sample with composition of CA:LiTFSI:DES (28 wt%:12 wt%:60 wt%) appears as the highest conducting sample with the calculated value of 2.61 × 10−3 S cm−1 at ambient temperature. This high conducting sample possesses low relative viscosity so as to have high ion fluidity of 0.19. SEM micrographs were used to study the structural alternation that took place in the presence of DES at different ratio in the polymer electrolytes matrix. The dielectric loss tangent plot reveals the low relaxation time for high conducting sample which has immense movements of lithium conducting ion (Li+). The enhancement in the ionic conductivity of the DES plasticized samples with temperature obeys Arrhenius rule.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Advanced Battery Materials and Technologies · Ionic liquids properties and applications · Conducting polymers and applications
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References (33)
Show source-provided references
1. Rajendran S, Sivakumar M, Subadevi R (2004) Mater Lett 58:641. doi: 10.1016/S0167-577X(03)00585-810.1016/S0167-577X(03)00585-8 ↗
2. Siva Kumar J, Subrahmanyam AR, Jaipal Reddy M, Subba Rao UV (2006) Mater Lett 60:3346. doi: 10.1016/j.matlet.2006.03.01510.1016/j.matlet.2006.03.015 ↗
3. Shriver DF, Papke BL, Ratner MA, Dupon R, Wong T, Brodwin M (1981) Solid State Ion 5:83. doi: 10.1016/0167-2738(81)90199-510.1016/0167-2738(81)90199-5 ↗
4. Armand MB (1986) Annu Rev Mater Sci 16:245. doi: 10.1146/annurev.ms.16.080186.00133310.1146/annurev.ms.16.080186.001333 ↗
5. Ratner MA, Shriver DF (1988) Chem Rev 88:109. doi: 10.1021/cr00083a00610.1021/cr00083a006 ↗
6. Ramesh S, Winie T, Arof AK (2010) J Mater Sci 45:1283. doi: 10.1007/s10853-009-4079-210.1007/s10853-009-4079-2 ↗
7. Reddy MJ, Sreekanth T, Chandrashekar M, Subba Rao UV (2000) J Mater Sci 35:2841. doi: 10.1023/A:100470752125010.1023/A:1004707521250 ↗
8. Vieira DF, Avellaneda CO, Pawlicka A (2007) Electrochim Acta 53:1404. doi: 10.1016/j.electacta.2007.04.03410.1016/j.electacta.2007.04.034 ↗
9. Xu YX, Miladinov V, Hanna MA (2004) Cereal Chem 81:73510.1094/CCHEM.2004.81.6.735 ↗
10. Ning W, Xingxiang Z, Haihui L, Benqiao H (2009) Carbohyd Polym 76:482. doi: 10.1016/j.carbpol.2008.11.00510.1016/j.carbpol.2008.11.005 ↗
11. Selvakumar M, Krishna Bhat D (2008) J Appl Polym Sci 110:594. doi: 10.1002/app.2867110.1002/app.28671 ↗
12. Subramaniam CK, Ramya CS, Ramya K (2008) J Appl Electrochem 41:197. doi: 10.1007/s10800-010-0224-510.1007/s10800-010-0224-5 ↗
13. Ramesh S, Lu S-C (2008) J Power Sources 185:1439. doi: 10.1016/j.jpowsour.2008.07.05510.1016/j.jpowsour.2008.07.055 ↗
14. Webber AJ (1991) J Electrochem Soc 138:2586. doi: 10.1149/1.208728710.1149/1.2087287 ↗
15. Abbott AP, Capper G, Davies DL, Rasheed RK, Tambyrajah V (2003) Chem Commun 39:70. doi: 10.1039/B210714G10.1039/b210714g ↗
16. Jhong H-R, Wong DS-H, Wan C-C, Wang Y-Y, Wei T-C (2009) Electrochem Commun 11:209. doi: 10.1016/j.elecom.2008.11.00110.1016/j.elecom.2008.11.001 ↗
17. Zhang J, Wu T, Chen S, Feng P, Bu X (2009) Angew Chem Int Ed Engl 48:3486. doi: 10.1002/anie.20090013410.1002/anie.200900134 ↗
18. Uma T, Mahalingam T, Stimming U (2003) Mater Chem Phys 82:478. doi: 10.1016/S0254-0584(03)00277-310.1016/S0254-0584(03)00277-3 ↗
19. Jana S, Zhong W-H (2008) J Mater Sci 43:4607. doi: 10.1007/s10853-008-2677-z10.1007/s10853-008-2677-z ↗
20. Ahmad A, Rahman MYA, Low SP, Hamzah H (2011) ISRN Mater Sci 2011:1. doi: 10.5402/2011/40128010.5402/2011/401280 ↗
21. Wu C, Wu F, Bai Y, Feng T, Pan C, Ye L, Feng Z (2009) J Chil Chem Soc 54:299. doi: 10.4067/S0717-97072009000300020
22. Yahya MZA, Ali AMM, Mohammat MF, Hanafiah MAKM, Mustaffa M, Ibrahim SC, Darus ZM, Harun MK (2006) J Appl Sci 6:1287. doi: 10.3923/jas.2006.1287.129110.3923/jas.2006.1287.1291 ↗
23. Winie T, Ramesh S, Arof AK (2009) Phys B 404:4308. doi: 10.1016/j.physb.2009.08.00410.1016/j.physb.2009.08.004 ↗
24. Anantha PS, Hariharan K (2005) Solid State Ion 176:155. doi: 10.1016/j.ssi.2004.07.00610.1016/j.ssi.2004.07.006 ↗
25. Sharma JP, Sekhon SS (2007) Solid State Ion 178:439. doi: 10.1016/j.ssi.2007.01.01710.1016/j.ssi.2007.01.017 ↗
26. Paradhan DK, Choundhary RNP, Samantaray BK (2008) Int J Electrochem Sci 3:59710.1016/S1452-3981(23)15547-7 ↗
27. Singh PK, Kim K-W, Rhee H-W (2008) Electrochem Commun 10:1769. doi: 10.1016/j.elecom.2008.09.01610.1016/j.elecom.2008.09.016 ↗
28. Muralidharan P, Venkateswarlu M, Satyanarayana N (2004) Solid State Ion 166:27. doi: 10.1016/j.ssi.2003.10.01110.1016/j.ssi.2003.10.011 ↗
29. Azizi Samir MAS, Alloin F, Sanchez J-Y, Gorecki W, Dufresne A (2004) J Phys Chem B 108:10845. doi: 10.1021/jp049448310.1021/jp0494483 ↗
30. Ramesh S, Yahaya AH, Arof AK (2002) Solid State Ion 152–153:291. doi: 10.1016/S0167-2738(02)00311-910.1016/S0167-2738(02)00311-9 ↗
31. Yahya MZA, Arof AK (2003) Euro Polym J 39:897. doi: 10.1016/S0014-3057(02)00355-510.1016/S0014-3057(02)00355-5 ↗
32. Ramesh S, Liew C–W, Ezra M, Durairaj R (2010) Thermochim Acta 511:140. doi: 10.1016/j.tca.2010.08.00510.1016/j.tca.2010.08.005 ↗
33. Kumar GG, Kim P, Kim AR, Nahm KS, Elizabeth RN (2009) Mater Chem Phys 115:40. doi: 10.1016/j.matchemphys.2008.11.02310.1016/j.matchemphys.2008.11.023 ↗