Highly stretchable CNT/MnO2 nanosheets fiber supercapacitors with high energy density
Source abstract
Abstract
Fiber-shaped supercapacitors (FSSCs) are promising devices in the wearable electronics because of their good flexibility, weavability, tiny volume and lightweight. However, the low stretchability and energy density limit their practical applications on wearable electronics requiring deformation and high energy density. It remains challenging to increase the energy densities of FSSCs without sacrificing their stretchability. Herein, we design and construct a wearable, stretchable and high-energy density CNT/MnO2 nanosheets FSSCs by wrapping the fiber supercapacitors on the spandex yarn. The CNT/MnO2 FSSCs show high stretchability up to 80%, ultrahigh capacitances of 685 mF cm−2 and energy density of 15.2 μWh cm−2. Furthermore, the CNT/MnO2 FSSCs have the good flexibility, stability and ultralong cycle life. In addition, we also develop the in situ characterization strategy to evaluate the structure evolution during the stretching process of the CNT/MnO2 FSSCs for better understanding the structure evolution of stretchable FSSCs. This work paves the way for the high-performance stretchable energy storage devices.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Supercapacitor Materials and Fabrication · Advanced Sensor and Energy Harvesting Materials · Conducting polymers and applications
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (66)
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1. Wang C, Xia K, Wang H, Liang X, Yin Z, Zhang Y (2018) Advanced carbon for flexible and wearable electronics. Adv Mater 31:@@1801072@@10.1002/adma.201801072 ↗
2. Koo JH, Kim DC, Shim HJ, Kim TH, Kim DH (2018) Flexible and stretchable smart display: materials, fabrication, device design, and system integration. Adv Funct Mater 28(35):@@1801834@@10.1002/adfm.201801834 ↗
3. Zeng W, Shu L, Li Q, Chen S, Wang F, Tao X-M (2014) Fiber-based wearable electronics: a review of materials, fabrication, devices, and applications. Adv Mater 26(31):5310–533610.1002/adma.201400633 ↗
4. Sun H, Zhang Y, Zhang J, Sun X, Peng H (2017) Energy harvesting and storage in 1D devices. Nat Rev Mater 2(6):@@17023@@10.1038/natrevmats.2017.23 ↗
5. Noh J, Yoon C-M, Kim YK, Jang J (2017) High performance asymmetric supercapacitor twisted from carbon fiber/MnO2 and carbon fiber/MoO3. Carbon 116:470–47810.1016/j.carbon.2017.02.033 ↗
6. Wu X, Han Z, Zheng X, Yao S, Yang X, Zhai T (2017) Core–shell structured Co3O4@NiCo2O4 electrodes grown on flexible carbon fibers with superior electrochemical properties. Nano Energy 31:410–41710.1016/j.nanoen.2016.11.035 ↗
7. Zheng X, Zhang K, Yao L, Qiu Y, Wang S (2018) Hierarchically porous sheath–core graphene-based fiber-shaped supercapacitors with high energy density. J Mater Chem A 6(3):896–90710.1039/C7TA08362A ↗
8. Zhao X, Zheng B, Huang T, Gao C (2015) Graphene-based single fiber supercapacitor with a coaxial structure. Nanoscale 7(21):9399–940410.1039/C5NR01737H ↗
9. Zhang Q, Wang X, Pan Z, Sun J, Zhao J, Zhang J, Zhang C, Tang L, Luo J, Song B, Zhang Z, Lu W, Li Q, Zhang Y, Yao Y (2017) Wrapping aligned carbon nanotube composite sheets around vanadium nitride nanowire arrays for asymmetric coaxial fiber-shaped supercapacitors with ultrahigh energy density. Nano Lett 17(4):2719–272610.1021/acs.nanolett.7b00854 ↗
10. Sun H, You X, Deng J, Chen X, Yang Z, Ren J, Peng H (2014) Novel graphene/carbon nanotube composite fibers for efficient wire-shaped miniature energy devices. Adv Mater 26(18):2868–287310.1002/adma.201305188 ↗
11. Yu D, Goh K, Wang H, Wei L, Jiang W, Zhang Q, Dai L, Chen Y (2014) Scalable synthesis of hierarchically structured carbon nanotube-graphene fibres for capacitive energy storage. Nat Nanotechnol 9(7):555–56210.1038/nnano.2014.93 ↗
12. De Volder MFL, Tawfick SH, Baughman RH, Hart AJ (2013) Carbon nanotubes: present and future commercial applications. Science 339(6119):535–53910.1126/science.1222453 ↗
13. Wang K, Meng Q, Zhang Y, Wei Z, Miao M (2013) High-performance two-ply yarn supercapacitors based on carbon nanotubes and polyaniline nanowire arrays. Adv Mater 25(10):1494–149810.1002/adma.201204598 ↗
14. Su F, Lv X, Miao M (2015) High-performance two-ply yarn supercapacitors based on carbon nanotube yarns dotted with Co3O4 and NiO nanoparticles. Small 11(7):854–86110.1002/smll.201401862 ↗
15. Khandoker N, Hawkins SC, Ibrahim R, Huynh CP, Deng F (2011) Tensile strength of spinnable multiwall carbon nanotubes. Procedia Eng 10:2572–257810.1016/j.proeng.2011.04.424 ↗
16. Kou L, Huang T, Zheng B, Han Y, Zhao X, Gopalsamy K, Sun H, Gao C (2014) Coaxial wet-spun yarn supercapacitors for high-energy density and safe wearable electronics. Nat Commun 5:@@3754@@10.1038/ncomms4754 ↗
17. Choi C, Lee JA, Choi AY, Kim YT, Lepró X, Lima MD, Baughman RH, Kim SJ (2014) Flexible supercapacitor made of carbon nanotube yarn with internal pores. Adv Mater 26(13):2059–206510.1002/adma.201304736 ↗
18. Ren J, Bai W, Guan G, Zhang Y, Peng H (2013) Flexible and weaveable capacitor wire based on a carbon nanocomposite fiber. Adv Mater 25(41):5965–597010.1002/adma.201302498 ↗
19. Ren J, Li L, Chen C, Chen X, Cai Z, Qiu L, Wang Y, Zhu X, Peng H (2013) Twisting carbon nanotube fibers for both wire-shaped micro-supercapacitor and micro-battery. Adv Mater 25(8):1155–115910.1002/adma.201203445 ↗
20. Cheng G, Yang W, Dong C, Kou T, Bai Q, Wang H, Zhang Z (2015) Ultrathin mesoporous NiO nanosheet-anchored 3D nickel foam as an advanced electrode for supercapacitors. J Mater Chem A 3(33):17469–1747810.1039/C5TA05313G ↗
21. Li S, Qi L, Lu L, Wang H (2012) Facile preparation and performance of mesoporous manganese oxide for supercapacitors utilizing neutral aqueous electrolytes. RSC Adv 2(8):3298–330810.1039/c2ra00991a ↗
22. Naoi K, Simon P (2008) New materials and new configurations for advanced electrochemical capacitors. J Electrochem Soc 17(1):34–37
23. Singu BS, Yoon KR (2017) Synthesis and characterization of MnO2-decorated graphene for supercapacitors. Electrochim Acta 231:749–75810.1016/j.electacta.2017.01.182 ↗
24. Yin X, Tang C, Zhang L, Yu ZG, Gong H (2016) Chemical insights into the roles of nanowire cores on the growth and supercapacitor performances of Ni–Co–O/Ni(OH)2 core/shell electrodes. Sci Rep 6(1):1–1210.1038/s41598-016-0001-8 ↗
25. Lee HY, Goodenough JB (1999) Supercapacitor behavior with KCl electrolyte. J Solid State Chem 144(1):220–22310.1006/jssc.1998.8128 ↗
26. Choi C, Sim HJ, Spinks GM, Lepró X, Baughman RH, Kim SJ (2016) Elastomeric and dynamic MnO2/CNT core–shell structure coiled yarn supercapacitor. Adv Energy Mater 6(5):@@1502119@@10.1002/aenm.201502119 ↗
27. Yang Z, Deng J, Chen X, Ren J, Peng H (2013) A highly stretchable, fiber-shaped supercapacitor. Angew Chem Int Ed 52(50):13453–1345710.1002/anie.201307619 ↗
28. Chen T, Hao R, Peng H, Dai L (2015) High-performance, stretchable, wire-shaped supercapacitors. Angew Chem Int Ed 54(2):618–62210.1002/anie.201409385 ↗
29. Xu J, Ding J, Zhou X, Zhang Y, Zhu W, Liu Z, Ge S, Yuan N, Fang S, Baughman RH (2017) Enhanced rate performance of flexible and stretchable linear supercapacitors based on polyaniline@Au@carbon nanotube with ultrafast axial electron transport. J Power Sources 340:302–30810.1016/j.jpowsour.2016.11.085 ↗
30. Zhang Z, Deng J, Li X, Yang Z, He S, Chen X, Guan G, Ren J, Peng H (2015) Superelastic supercapacitors with high performances during stretching. Adv Mater 27(2):356–36210.1002/adma.201404573 ↗
31. Choi C, Kim JH, Sim HJ, Di J, Baughman RH, Kim SJ (2017) Microscopically buckled and macroscopically coiled fibers for ultra-stretchable supercapacitors. Adv Energy Mater 7(6):@@1602021@@10.1002/aenm.201602021 ↗
32. Shang Y, Wang C, He X, Li J, Peng Q, Shi E, Wang R, Du S, Cao A, Li Y (2015) Self-stretchable, helical carbon nanotube yarn supercapacitors with stable performance under extreme deformation conditions. Nano Energy 12:401–40910.1016/j.nanoen.2014.11.048 ↗
33. Yu J, Lu W, Smith JP, Booksh KS, Meng L, Huang Y, Li Q, Byun J-H, Oh Y, Yan Y, Chou T-W (2017) A high performance stretchable asymmetric fiber-shaped supercapacitor with a core–sheath helical structure. Adv Energy Mater 7(3):@@1600976@@10.1002/aenm.201600976 ↗
34. Xu P, Gu T, Cao Z, Wei B, Yu J, Li F, Byun J-H, Lu W, Li Q, Chou T-W (2014) Carbon nanotube fiber based stretchable wire-shaped supercapacitors. Adv Energy Mater 4(3):@@1300759@@10.1002/aenm.201300759 ↗
35. Liu P, Zhu Y, Gao X, Huang Y, Wang Y, Qin S, Zhang Y (2018) Rational construction of bowl-like MnO2 nanosheets with excellent electrochemical performance for supercapacitor electrodes. Chem Eng J 350:79–8810.1016/j.cej.2018.05.169 ↗
36. Li K, Feng S, Jing C, Chen Y, Liu X, Zhang Y, Zhou L (2019) Assembling a double shell on a diatomite skeleton ternary complex with conductive polypyrrole for the enhancement of supercapacitors. Chem Commun 55(91):13773–1377610.1039/C9CC06791D ↗
37. Li K, Liu X, Zheng T, Jiang D, Zhou Z, Liu C, Zhang X, Zhang Y, Losic D (2019) Tuning MnO2 to FeOOH replicas with bio-template 3D morphology as electrodes for high performance asymmetric supercapacitors. Chem Eng J 370:136–14710.1016/j.cej.2019.03.190 ↗
38. Huang Y, Lu J, Kang S, Weng D, Han L, Wang Y (2019) Synthesis and application of MnO2/PANI/MWCNT ternary nanocomposite as an electrode material for supercapacitors. Int J Electrochem Sci 14:9298–931010.20964/2019.09.86 ↗
39. Zhang M, Atkinson KR, Baughman RH (2004) Multifunctional carbon nanotube yarns by downsizing an ancient technology. Science 306(5700):1358–136110.1126/science.1104276 ↗
40. Zheng X, Yao L, Qiu Y, Wang S, Zhang K (2019) Core–sheath porous polyaniline nanorods/graphene fiber-shaped supercapacitors with high specific capacitance and rate capability. ACS Appl Energy Mater 2(6):4335–434410.1021/acsaem.9b00558 ↗
41. Devaraj S, Munichandraiah N (2008) Effect of crystallographic structure of MnO2 on its electrochemical capacitance properties. J Phys Chem C 112(11):4406–441710.1021/jp7108785 ↗
42. Dravid VP, Liu S, Kappes MM (1991) Transmission electron microscopy of chromatographically purified solid state C60 and C70. Chem Phys Lett 185(1):75–8110.1016/0009-2614(91)80143-L ↗
43. Rossi LM, Silva FP, Vono LL, Kiyohara PK, Duarte EL, Itri R, Landers R, Machado G (2007) Superparamagnetic nanoparticle-supported palladium: a highly stable magnetically recoverable and reusable catalyst for hydrogenation reactions. Green Chem 9(4):379–38510.1039/b612980c ↗
44. Liu Z, Xu K, Sun H, Yin S (2015) One-step synthesis of single-layer MnO2 nanosheets with multi-role sodium dodecyl sulfate for high-performance pseudocapacitors. Small 11(18):2182–219110.1002/smll.201402222 ↗
45. Kim SH, Haines CS, Li N, Kim KJ, Mun TJ, Choi C, Di J, Oh YJ, Oviedo JP, Bykova J (2017) Harvesting electrical energy from carbon nanotube yarn twist. Science 357(6353):773–77810.1126/science.aam8771 ↗
46. Foroughi J, Spinks GM, Antiohos D, Mirabedini A, Gambhir S, Wallace GG, Ghorbani SR, Peleckis G, Kozlov ME, Lima MD (2014) Highly conductive carbon nanotube-graphene hybrid yarn. Adv Funct Mater 24(37):5859–586510.1002/adfm.201401412 ↗
47. Wang Y, Song Y, Xia Y (2016) Electrochemical capacitors: mechanism, materials, systems, characterization and applications. Chem Soc Rev 45(21):5925–595010.1039/C5CS00580A ↗
48. Liu J-h, Xu X-y, Lu W, Xiong X, Ouyang X, Zhao C, Wang F, Qin S-y, Hong J-l, Tang J-n (2018) A high performance all-solid-state flexible supercapacitor based on carbon nanotube fiber/carbon nanotubes/polyaniline with a double core–sheathed structure. Electrochim Acta 283:366–37310.1016/j.electacta.2018.06.158 ↗
49. Choi C, Kim KM, Kim KJ, Lepró X, Spinks GM, Baughman RH, Kim SJ (2016) Improvement of system capacitance via weavable superelastic biscrolled yarn supercapacitors. Nat Commun 7(1):1–8
50. Lee JA, Shin MK, Kim SH, Cho HU, Spinks GM, Wallace GG, Lima MD, Lepró X, Kozlov ME, Baughman RH (2013) Ultrafast charge and discharge biscrolled yarn supercapacitors for textiles and microdevices. Nat Commun 4:@@1970@@10.1038/ncomms2970 ↗
51. Qu G, Cheng J, Li X, Yuan D, Chen P, Chen X, Wang B, Peng H (2016) A fiber supercapacitor with high energy density based on hollow graphene/conducting polymer fiber electrode. Adv Mater 28(19):3646–365210.1002/adma.201600689 ↗
52. Huang M, Wang L, Chen S, Kang L, Lei Z, Shi F, Xu H, Liu Z-H (2017) Highly flexible all-solid-state cable-type supercapacitors based on Cu/reduced graphene oxide/manganese dioxide fibers. RSC Adv 7(17):10092–1009910.1039/C6RA28117F ↗
53. Li H, Liang J, Li H, Zheng X, Tao Y, Huang Z-H, Yang Q-H (2019) Activated carbon fibers with manganese dioxide coating for flexible fiber supercapacitors with high capacitive performance. J Energy Chem 31:95–10010.1016/j.jechem.2018.05.008 ↗
54. Xie S, Liu S, Cheng F, Lu X (2018) Recent advances toward achieving high-performance carbon-fiber materials for supercapacitors. Chemelectrochem 5(4):571–58210.1002/celc.201701020 ↗
55. Meng Y, Zhao Y, Hu C, Cheng H, Hu Y, Zhang Z, Shi G, Qu L (2013) All-graphene core–sheath microfibers for all-solid-state, stretchable fibriform supercapacitors and wearable electronic textiles. Adv Mater 25(16):2326–233110.1002/adma.201300132 ↗
56. Cai W, Lai T, Ye J (2015) A spinneret as the key component for surface-porous graphene fibers in high energy density micro-supercapacitors. J Mater Chem A 3(9):5060–506610.1039/C5TA00365B ↗
57. Xiao X, Li T, Yang P, Gao Y, Jin H, Ni W, Zhan W, Zhang X, Cao Y, Zhong J (2012) Fiber-based all-solid-state flexible supercapacitors for self-powered systems. ACS Nano 6(10):9200–920610.1021/nn303530k ↗
58. El-Kady MF, Strong V, Dubin S, Kaner RB (2012) Laser scribing of high-performance and flexible graphene-based electrochemical capacitors. Science 335(6074):1326–133010.1126/science.1216744 ↗
59. Guo F, Xu R, Cui X, Zhang L, Wang K, Yao Y, Wei J (2016) High performance of stretchable carbon nanotube–polypyrrole fiber supercapacitors under dynamic deformation and temperature variation. J Mater Chem A 4(23):9311–931810.1039/C6TA02437H ↗
60. Li M, Zu M, Yu J, Cheng H, Li Q (2017) Stretchable fiber supercapacitors with high volumetric performance based on buckled MnO2/oxidized carbon nanotube fiber electrodes. Small 13(12):@@1602994@@10.1002/smll.201602994 ↗
61. Choi C, Lee JM, Kim SH, Kim SJ, Di J, Baughman RH (2016) Twistable and stretchable sandwich structured fiber for wearable sensors and supercapacitors. Nano Lett 16(12):7677–768410.1021/acs.nanolett.6b03739 ↗
62. Sun J, Huang Y, Fu C, Wang Z, Huang Y, Zhu M, Zhi C, Hu H (2016) High-performance stretchable yarn supercapacitor based on PPy@ CNTs@ urethane elastic fiber core spun yarn. Nano Energy 27:230–23710.1016/j.nanoen.2016.07.008 ↗
63. Zhang Q, Sun J, Pan Z, Zhang J, Zhao J, Wang X, Zhang C, Yao Y, Lu W, Li Q (2017) Stretchable fiber-shaped asymmetric supercapacitors with ultrahigh energy density. Nano Energy 39:219–22810.1016/j.nanoen.2017.06.052 ↗
64. Xu P, Wei B, Cao Z, Zheng J, Gong K, Li F, Yu J, Li Q, Lu W, Byun J-H (2015) Stretchable wire-shaped asymmetric supercapacitors based on pristine and MnO2 coated carbon nanotube fibers. ACS Nano 9(6):6088–609610.1021/acsnano.5b01244 ↗
65. Chen X, Qiu L, Ren J, Guan G, Lin H, Zhang Z, Chen P, Wang Y, Peng H (2013) Novel electric double-layer capacitor with a coaxial fiber structure. Adv Mater 25(44):6436–644110.1002/adma.201301519 ↗
66. Choi C, Kim SH, Sim HJ, Lee JA, Choi AY, Kim YT, Lepró X, Spinks GM, Baughman RH, Kim SJ (2015) Stretchable, weavable coiled carbon nanotube/MnO2/polymer fiber solid-state supercapacitors. Sci Rep 5:@@9387@@10.1038/srep09387 ↗